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三烷基氧膦是用于高放废液处理的萃取剂,本文试验了在辐照剂量为1×10^4Gy-1×10^6Gy时TRPO损失率。结果表明,100%(V/V)TRPO在λ辐照剂量10^4Gy-10^6Gy变化时,辐解损失率为1.2%-1.6%;30%(V/V)TRPO-煤油在辐照剂量10^4Gy-10^5Gy时,辐解损失率基本不变(0.33%-0.34%),而在1×10^6Gy时增加到0.77%。均低于磷酸三丁酯的 相似文献
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本文用荧光光度法对硫酸介质中螺内酯和十二烷基硫酸钠(SDS)形成的胶束配合物的性能进行了系统研究。利用胶束的增敏增稳作用,提出了测定螺内酯的荧光光度新方法,方法线性范围宽,为1.4×10-9-4.3×10-6mol·L-1,灵敏度高,检出限为1.2×10-9mol·L-1。应用本法于片剂中螺内酯的测定,结果满意 相似文献
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本文用荧光光度法对硫酸介质中螺内酯和十二烷基硫酸钠(SDS)形成的胶束配合物的进行了系统研究。利用胶束的增敏增稳作用,提出了测定螺内酯的荧光光度新方法,方法线性范围宽,为1.4×10^-9-4.3×10^-6mol·L^-1,灵敏度高,检出限为1.2×10^-9mol·L^-1,应用本法于片剂中螺内酯的测定,结果满意。 相似文献
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本主要研究了3-溴-N-乙基吩噻嗪(Br-P)在各种酸度、增敏溶剂、感光效应等条件下的荧光变换现象,并确定了最佳的发光体系。方法简单、准确可靠,其线性范围为1×10^-7 ̄1×10^-4mol/L,检出限为1×10^-8mol/L,RSD〈2.8%。 相似文献
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不除氧条件下环糊精诱导室温磷光法测定喹啉 总被引:4,自引:0,他引:4
在不除氧条件下,10mL含喹啉/β-CD溶液中只需加入15μL1,2-二溴丙烷(DBP)作重原子微扰剂,就能产生强而稳定的室温磷光信号。最大λex/λem=273/496nm。喹啉浓度在5.0×10^-7 ̄5.0×10^-5mol/L,5.0×10^-4mol/L,两段三个数量级范围与室温磷光信号有良好的线性关系,最低检测限7.4×10^-8mol/L。本体系的特点是DBP用量少,从而减少了因过量 相似文献
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本文给出了发射探针和电容探针测量等离子体电位的实验和方法。发射探针采用直流功率加热,并在较强电子发射条件下运行(I_(e0)/I_(e0)>1)。电容探针表面二次电子发射系数δ≥1。本文对发射探针的电子发射性能、工作电流、电容探针的输入、输出电压关系进行了标定实验。得到了电容探针的校准系数分别为3×10(-3)、5×10(-4)。实验给出了MM-4会切中心等离子体电位V_(p4)=-82±9-122±12V;MM-4U东、西会切中心等离子体电位分别为V_(P4u1)=-52.9±3.2V,V_(P4u2)=-62±3.2V。 相似文献
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在0.15mol/LHAc-NH4Ac支持电解质中,使用0.1g/L的邻菲罗啉(o-Phen)采用经典极谱仪测定其离子络合物吸附波,分光光度法测定铁离子,检出下限分别达到:铅离子为1.50×10^-10mol/L,铁离子为3.581×10^-7mol/L。该方法在回收率为99.2%-100.4%之间,具有较好的选择性。 相似文献
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高TcBOLOMETER 总被引:7,自引:0,他引:7
章给出了高Tc超导红外探测器的理论分析;器件设计。并报道了用GdBa2Cu3O7-x薄膜制备的红外探测器的实验结果。得到的最好结果是噪声等效功率NEP(500,10,1)=1.4×10^-11WHz^-1/2;探测率D^*(500,10,1)4.2×10^9cmHz^1/2W^-1;响应度Rv=1065V/W。 相似文献
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The mean-square displacement of alkali metals is studied theoretically using our local Heine-Abarenkov-type model potential in the perturbational scheme. The temperature-dependent mean-square displacement of alkali metals decreases as function of the compressed volume. Lindemann's criterion for melting xm, which is defined as the ratio of two times the root-mean-square displacement to the nearest-neighbour distance, is found to be nearly constant for five alkali metals. The volume effect on the melting temperature of alkali metals is studied by keeping xm constant. The obtained melting curve increases as function of the compressed volume and are qualitatively in good agreement with the observed tendency for alkali metals. 相似文献
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Tomoaki Niiyama Shin-ichi Sawada Sawada Kensuke S. Ikeda Yasushi Shimizu 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2014,68(4):1-13
To elucidate the atomistic diffusion mechanism responsible for the rapid diffusion in alkali halide nano particles, called Spontaneous Mixing, we execute molecular dynamics simulations with empirical models for KCl-KBr, NaCl-NaBr, RbCl-RbBr and KBr-KI. We successfully reproduce essential features of the rapid diffusion phenomenon. It is numerically confirmed that the rate of the diffusion clearly depends on the size and temperature of the clusters, which is consistent with experiments. A quite conspicuous feature is that the surface melting and collective motions of ions are inhibited in alkali halide clusters. This result indicates that the Surface Peeling Mechanism, which is responsible for the spontaneous alloying of binary metals, does not play a dominant role for the spontaneous mixing in alkali halide nanoclusters. Detailed analysis of atomic motion inside the clusters reveals that the Vacancy Mechanism is the most important mechanism for the rapid diffusion in alkali halide clusters. This is also confirmed by evaluation of the vacancy formation energy: the formation energy notably decreases with the cluster size, which makes vacancy formation easier and diffusion more rapid in small alkali halide clusters. 相似文献
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Chun Lou Yang Pu Yonggang Zhao Yang Bai Bin Yao Dunxi Yu 《Proceedings of the Combustion Institute》2021,38(3):4199-4206
To mitigate the slagging, fouling and high-temperature corrosion problems caused by alkali metals during coal combustion process, measurement of time-resolved alkali metals release is very important. The paper proposed an in-situ approach for measuring sodium (Na) release in coal combustion by Flame Emission Spectroscopy (FES). Through the analysis of spontaneous emission spectra and a calibration procedure, the concentration of gas phase Na, temperature and thermal radiation can be obtained. Firstly, experimental measurement of Zhundong coal particles burning in a flat flame burner was done. Two kinds of Zhundong coal with similar proximate and ultimate analyses, but different ash composition were used. The Na-release history measured by FES was compared with that by LIBS. Results showed that the Na-release at the devolatilization, char, and ash stages can be distinguished by FES. The higher Si/Al content in ash can suppress the Na-release at the ash stage. Moreover, FES method was extended to the measurement of Na-release in four industrial boiler furnaces of two Zhundong coal-fired power plants. Results showed the Na-release measured by FES can reflect the change of fuel and load, and both temperature and thermal radiation play key roles in Na-release in coal combustion. 相似文献
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The resonance fluorescence spectra of a degenerate three-level atom of the V-type in the field of an intense monochromatic wave with an arbitrary polarization composition are investigated. Analytical expressions are derived for the resonance fluorescence spectra, and the angular distribution of spontaneous fluorescence of atoms is analyzed for the D-line emitted by vapors of alkali atoms. It is shown that the number of lines in the spectrum may decrease in the case of the linear polarization of spontaneous radiation. The radiation relaxation operator is obtained for the D-line of alkali metals in the case when an atom is near the metal surface. Interference effects for such systems are analyzed. 相似文献
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In the present paper, an equation of state has been obtained in case of liquid alkali metals like Na, K, Rb and Cs from sound
velocity measurements. The theory developed gives very good agreement for both the sound velocity and the volume as a function
of pressure at different temperatures in these liquid alkali metals. Further, the variation of non-linear parameter,B / A, as a function of pressure and temperature is also studied. 相似文献
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The electron work function in alloys and compounds containing alkali metals, which are of interest for the designing of new photocathode materials and further development of the theory of electron emission, is studied. It is shown that a number of applied and theoretical issues in this field are poorly understood. These are the temperature and concentration dependences of the electron work function in binary metallic systems, the surface activity of components that are inactive in alloys with alkali metals, and some others. 相似文献
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D. Rayane A. R. Allouche R. Antoine I. Compagnon M. Broyer Ph. Dugourd 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):9-13
The permanent electric dipole moment of metal
atom-C60 compounds is measured. A column
(alkali) and a row (transition metals) of the periodic table are
systematically investigated. Most of the experimental results
are obtained at high temperature when the atom is mobile on the
C60 cage. For a given example
(NaC60), the dipole moment is also
measured by a different method at low temperature and both
results are consistent. For alkali, the results are compared to
ab initio calculations. A
good agreement is obtained, both for absolute values and for the
evolution of the bonding in the alkali column. For transition
metals, the relative values of the dipole moments are in
qualitative agreement with the ionic character of the compounds. 相似文献