Mechanism of the formation of an uncompensated magnetic moment in bacterial ferrihydrite nanoparticles

The magnetic properties of antiferromagnetic nanoparticles of FeOOH · nH₂O with sizes of 3–7 nm, which are products of vital functions of Klebsiella oxytoca bacteria, have been studied. Particles exhibit a superparamagnetic behavior. The characteristic blocking temperature is 23 K. Analysis of the magnetization curves shows that the mechanism of the formation of the uncompensated magnetic moment of particles is the random decompensation of magnetic moments of Fe³⁺ ions both on the surface and in the bulk of the antiferromagnetic particle. In this mechanism, the exchange coupling between the uncompensated magnetic moment of the particle and its antiferromagnetic “core” is implemented. It has been found that the temperature dependence of the uncompensated magnetic moment has the form 1 — constT ².     

The (p, 2p) reaction for slightly deformed nuclei

A perturbation approach for the calculation of (p, 2p) angular correlations for slightly deformed nuclei is developed using the formalism of the distorted wave t-matrix approximation (DWTA) in the static limit where approximations that incorporate absorption and focussing effects are used for the spin-orbit independent optical-model waves. Using a finite-range off-shell t-matrix that fits p-p scattering at 90° to approximate the p-p interaction inside the nucleus, a zero-order calculation is performed and normalized to ¹⁹F(p, 2p)¹⁸O angular correlation data at 42.7 MeV. A rms study is undertaken in order to parametrize the bound-state and the sensitivity of the shape of the angular correlation to the rms value is observed. The deformation of the bound-state is introduced using normalized perturbation theory and calculations with various values of the deformation parameter β for prolate and oblate deformations are performed and the results are compared. The shape of the (p, 2p) angular correlation is shown to be highly sensitive to the degree of deformation and is consistent with the shape dependence of the correlation to the rms value of the bound-state wave function.     

Effect of anomalously slow motions of particles with spins of 1/2 on the shape of the magnetic resonance line of pairs of particles

A non-Markovian version of the Liouville stochastic equation was used to analyze spin relaxation in a pair of particles with spins 1/2 and the dipole-dipole interaction between the spins. The particles were involved in anomalously slow stochastic relative rotation described by the angular correlation function K(t) ～ 1/t ^α with α < 1. The Liouville stochastic equation could be used to describe memory effects in the kinetic dependence of rotational relaxation resulting in a very slow descent of K(t). Our analysis showed that the anomalous relative motion of radicals manifested itself in special features of the shape of the magnetic resonance line of the particle pair.     

Frequency (field) dependent NMR relaxation rate in the interrupted metallic strand model

We calculate the nuclear magnetic resonance rate T^?1₁ arising from the electron-nuclear hyperfine contact interaction, within the interrupted metallic strand model. The electron levels are assumed to have an energy half width Γ and a mean spacing Δ₀ and it is assumed that all segments have the same nuclear spin temperature. In the limit Γ ? Δ₀, T^?1₁ has nearly the same behaviour for kT ? Δ₀ and kT?Δ₀. It is proportional to temperature but has a Lorentzian magnetic field dependence with halfwidth H= Γ/μ_B. At low fields it is enhanced over the value for a normal metal by the factor Δ₀/Γ.This anomalous behaviour arises from the suppression of electron spin flip processes by a magnetic field and should always occur when electronic states are localised, that is when there is a locally discrete electron energy spectrum. Therefore it may be relevant not only to certain linear chain conductors but to other cases of electron localisation.The present model provides an additional possible source of frequency dependence of T₁ in linear chain materials. In certain materials especially those containing defects, it may be more appropriate than the currently accepted mechanism which involves electron spin diffusion in one dimension.     

The p-40Ca and n-40Ca mean fields from the iterative moment approach

The real part V(r; E) of the p-⁴⁰Ca and n-⁴⁰Ca mean fields is extrapolated from positive towards negative energies by means of the iterative moment approach, which incorporates the dispersion relation between the real and imaginary parts of the mean field. The potential V(r; E) is the sum of a Hartree-Fock type component V^HF, (r; E) and a dispersive correction δV(r; E); the latter is due to the coupling of the nucleon to excitations of the ⁴⁰Ca core. The potentials V(r; E) and V_HF(r; E) are assumed to have Woods-Saxon shapes. The calculations are first carried out in the framework of the original version of the iterative moment approach, in which both the depth and the radius of the Hartree-Fock type contribution depend upon energy, while its diffuseness is constant and equal to that of V(r; E). The corresponding extrapolation towards negative energies is somewhat sensitive to the detailed parametrization of the energy dependence of the imaginary part of the mean field, which is the main input of the calculation. Moreover, the radius of the calculated Hartree-Fock type potential then increases with energy, in contrast to previous findings in ²⁰⁸Pb and ⁸⁹Y. A new version of the iterative moment approach is thus developed in which the radial shape of the Hartree-Fock type potential is independent of energy; the justification of this constraint is discussed. The diffuseness of the potential V(r; E) is assumed to be constant and equal to that of V_HF(r; E). The potential calculated from this new version is in good agreement with the real part of phenomenological optical-model potentials and also yields good agreement with the single-particle energies in the two valence shells. Two types of energy dependence are considered for the depth U_HF(E) of the Hartree-Fock type component, namely a linear and an exponential form. The linear approximation is more satisfactory for large negative energies (E < −30 MeV) while the exponential form is better for large positive energies (E > 50 MeV). This is explained by relating the energy dependence of U_HF(E) to the nonlocality of the microscopic Hartree-Fock type component. Near the Fermi energy the effective mass presents a pronounced peak at the potential surface. This is due to the coupling to surface excitations of the core and reflects the energy dependence of the potential radius. The absolute spectroscopic factors of low-lying single-particle excitations in ³⁹Ca, ⁴¹Ca, ³⁹K and ⁴¹Sc are found to be close to 0.8. The calculated p-⁴⁰Ca and n-⁴⁰Ca potentials are strikingly similar, although the two calculations have been performed entirely independently. The two potentials can be related to one another by introducing a Coulomb energy shift. Attention is drawn to the fact that the extrapolated energy dependence of the real part of the mean field at large positive energy sensitively depends upon the assumed behaviour of the imaginary part at large negative energy. Yet another version of the iterative moment approach is introduced, in which the radial shape of the HF-type component is independent of energy while both the radius and the diffuseness of the full potential V(r; E) depend upon E. This model indicates that the accuracy of the available empirical data is probably not sufficient to draw reliable conclusions on the energy dependence of the diffuseness of V(r; E).     

Enhancement of low-field magnetoresistance in Fe3O4 particles induced by ball milling

A series of Fe₃O₄ particles with different size have been obtained by mechanical ball milling from t=0-450 h. Crystal structure and microstructure of the samples are analyzed by XRD and SEM. An emphasis has been placed on magnetic and transport properties. The experimental results indicate that the sample t=350 exhibits an enhancement of magnetoresistance (MR) comparing with initial powder compress sample (t=0). The low-field magnetoresistance reaches MR=−6.04% at Verwey temperature 120 K and MR=−2.54% at 290 K. Thermal behavior TGA analysis and investigation of magnetic properties have revealed that there is an oxide layer on surface of Fe₃O₄ particles. It is considered that the enhanced magnetoresistance can be taken into account in terms of spin-dependent tunneling effect between Fe₃O₄ particles.Temperature dependence of magnetization and resistivity are measured in order to study electrical and magnetic behavior near Verwey transition. In addition, we also discuss ball milling time dependence of coercivity H_c and specific magnetization M_s of these samples.     

Peculiarities of deformation of compliant coatings with increased strength

Influence of elasticity module of coating material on the parameters of hard compliant coatings deformation has been analysed. Calculation using two-dimensional model has shown that maximum coating deformation is achieved at the ratio of flow rate U to the parameter C _t ⁰ = (E/3ρ)^0.5 approximately equal to 2.5, however, velocity of wall surface motion has first local maximum at U/C _t ⁰≈1. The range of coating parameters’ values at which compromise between its hardness and intensity of interaction with turbulent flow is provided has been determined. For rubbery materials with Poisson coefficient of about 0.5, correlations of the flow velocity and parameter C _t ⁰ shall be in the range 1÷1.5. It is shown that at such parameters, the mean square value of the coating surface deflection/inflection is less than the viscous sublayer thickness, its correlation with the wavelength is very small and equals (1÷5)·10⁻⁴. Such form of deformed surface fundamentally differs from the parameters of the wave wall in Kendall’s experiments which results are used for calculation of inverse influence of wall deformation on the flow. It was assumed that solid compliant coatings do not cause instability of interaction with the ambient flow.     

Projected Hartree-Fock calculation in intermediate coupling for11B

An intermediate coupling calculation has been carried out for¹¹B using the deformed functions obtained from a Projected Hartree-Fock calculation as a basis. The resulting wave functions give an important improvement for the energy spectrum of the low-lying nonnormal parity levels. TheE2 matrix elements are enhanced with respect to the conventional shell model. Nuclear structure¹¹B; calculated levelsJ, π, B(M1),B(E2). Projected Hartree-Fock method, intermediate coupling.     

Low-lying states of trinuclear mixed-valence cluster: [Fe3S4]0

Low-lying energy states of the [Fe₃S₄]⁰ cluster have been calculated by taking into account the double exchange, superexchange and vibronic interaction. It was found that the adiabatic potential of the excited state withS=0 corresponds to the full delocalization of the “excess” charge. From the analysis of experimental data of Mössbauer spectroscopy and the temperature dependence of the magnetic susceptibility the double exchange parametert≥4000 cm^?1 and the vibronic interaction parameter λ₂/2k cm^?1 have been estimated.     

Resonant paramagnetic enhancement of the thermal and zero-point Nyquist noise

The interaction between a very thin macroscopic solenoid, and a single magnetic particle precessing in a external magnetic field B₀, is described by taking into account the thermal and the zero-point fluctuations of stochastic electrodynamics. The inductor belongs to a RLC circuit without batteries and the random motion of the magnetic dipole generates in the solenoid a fluctuating current I_dip(t), and a fluctuating voltage ε_dip(t), with spectral distribution quite different from the Nyquist noise. We show that the mean square value 〈I_dip²〉 presents an enormous variation when the frequency of precession approaches the frequency of the circuit, but it is still much smaller than the Nyquist current in the circuit. However, we also show that 〈I_dip²〉 can reach measurable values if the inductor is interacting with a macroscopic sample of magnetic particles (atoms or nuclei) which are close enough to its coils.     

Aeolian transport of sand

The airborne transport of particles on a granular surface by the saltation mechanism is studied through numerical simulation of particles dragged by turbulent air flow. We calculate the saturated flux q_s and show that its dependence on the wind strength u_* is consistent with several empirical relations obtained from experimental measurements. We propose and explain a new relation for fluxes close to the threshold velocity u_t, namely, q_s=a(u_*-u_t)^α with α≈2. We also obtain the distortion of the velocity profile of the wind due to the drag of the particles and find a novel dynamical scaling relation. We also obtain a new expression for the dependence of the height of the saltation layer as function of the strength of the wind.     

Exchange of transverse plasmons and electrical conductivity of neutron star cores

We study the electrical conductivity in magnetized neutron star cores produced by collisions between charged particles. We take into account the ordinary exchange of longitudinal plasmons and the exchange of transverse plasmons in collisions between particles. The exchange of transverse plasmons is important for collisions between relativistic particles, but it has been disregarded previously when calculating the electrical conductivity. We show that taking this exchange into account changes the electrical conductivity, including its temperature dependence (thus, for example, the temperature dependence of the electrical resistivity along the magnetic field in the low-temperature limit takes the form ?_‖ ∝ T ^5/3 instead of the standard dependence ?_‖ ∝ T ² for degenerate Fermi systems). We briefly describe the effect of possible neutron and proton superfluidity in neutron star cores on the electrical conductivity and discuss various scenarios for the evolution of neutron star magnetic fields.     

The resonance decay function method in the determination of the pre-factor of the Néel relaxation time of single-domain nanoparticles

In its simple form, the relaxation time of the Néel relaxation process of the magnetic moment of single-domain particles is given by τ_N=τ_0Nexp(σ), σ being the ratio of anisotropy energy to thermal energy. The pre-factor, τ_0N, is normally given a value of 10⁻⁹ s, but values ranging from 10⁻⁸ to 10⁻¹² s have been reported in literature. Here, by means of the field and frequency dependence of the complex magnetic susceptibility, χ(ω,H)=χ′(ω,H)−iχ″(ω,H), of a magnetic fluid sample, in the MHz-GHz range, in conjunction with the determination of the sample decay function, b(t), the pre-factor τ_0N is determined. b(t) is readily obtained through the inverse Fourier transformation relationship, which exists between b(t) and χ″(ω).     

Transport phenomena in a partially lonized Lorentzian magnetoplasma

Some transport coefficients are evaluated for a homogeneous, partially ionized Lorentzian plasma in the presence of a uniform external magnetic field. The electronion collisions are taken into account by means of the modified Fokker-Planck equation and the electron-neutral collision frequency, ν_en is taken as velocity (ω) dependent or velocity independent, depending on the energy range under consideration. The variation of the transport coefficients with magnetic field is determined for ν_en ∝ ω^s (s being a positive or negative integer) and one finds that qualitatively this behavior does not change by changing either the collision frequency or the velocity dependence of the collision frequency; however for weak magnetic fields the magnitudes of these transport coefficients increase with the decrease in ν_en or s, whereas for strong magnetic fields the transverse components of the transport coefficients decrease and the Hall components tend to saturate with the decrease of either the collision frequency or s.     

A precursor superconductivity approach to magnetic field effects in the pseudogap phase

We demonstrate that the observed dependences of T_c and T^∗ on small magnetic fields can be readily understood in a precursor superconductivity approach to the pseudogap phase. In this approach, the presence of a pseudogap at T_c (but not at T^∗) and the associated suppression of the density of states lead to very different sensitivities to pair-breaking perturbations for the two temperatures. Our semi-quantitative results address the puzzling experimental observation that the coherence length ξ is weakly dependent on hole concentration x throughout most of the phase diagram. We present our results in a form which can be compared with the recent experiments of Shibauchi et al. and argue that orbital effects contribute in an important way to the H dependence of T^∗.     

The ratio of the quadrupole moments of the isotopes95Mo and97Mo

The spin-lattice relaxation timesT ₁ of the NMR signals of⁹⁵Mo and⁹⁷Mo in aqueous K₂MoO₄ solutions were determined by the inversion recovery technique. To separate the relaxation rates due to electric quadrupole interaction and due to magnetic dipole interaction, pure H₂O and mixtures of H₂O and D₂O were used as solvent. No dependence of the ratio of the relaxation ratesT ₁(⁹⁵Mo)/T ₁(⁹⁷Mo) on the composition of the solvent was to be detected, i.e. the relaxation due to magnetic dipole interaction may be neglected. From the ratio of the relaxation rates the absolute value of the ratio of the quadrupole moments of the molybdenum isotopes was evaluated: ¦Q(⁹⁷Mo)/Q(⁹⁵Mo)¦ = 11.4 ±0.3.     

Two-nucleon transfer reactions between heavy ions

DWBA formulation of the two-nucleon transfer reactions between heavy ions is presented, neglecting the recoil effect. The perturbation is assumed to act between the core and each of the transferred pair. When we approximate the interaction so as to act between the core and the c. m. of the pair, we can extend the method commonly used in analysing (t, p) and (p, t) reactions. Integrals appearing in the DWBA form factor are evaluated exactly. Calculations are compared with the experimental data in the case of the²⁶Mg(¹⁸O,¹⁶O)²⁸Mg reaction.     

A buoyant flow structure in a magnetic field: Quasi-steady states and linear-nonlinear transitions

The confined evolution of a buoyant blob of fluid subject to a vertical magnetic field is investigated in the limit of low magnetic Reynolds number. When the applied magnetic field is strong, the rise velocity of the blob is small. As the vorticity diffuses along the magnetic field lines, a quasi-steady state characterised by a balance between the work done by buoyancy and Ohmic dissipation is eventually reached at time tqs∼(L²/δ²)τ, where L is the axial dimension of the fluid domain, δ is the radius of the buoyant blob and τ is the magnetic damping time. However, when the applied magnetic field is weak or the axial length is sufficiently large compared to the blob size, the growth of axial velocity eventually makes the advection of vorticity significant. The typical time for the attainment of this nonlinear phase is , where N₀ is the magnetic interaction parameter at time t=τ. The order-of-magnitude estimates for the timescales tqs and tnl are verified by computational experiments that capture both the linear and nonlinear phases.     

The role of iterative isobar processes in nuclear matter and the effective nucleon-nucleon interaction

A calculation is performed using lowest order Brueckner theory in momentum space, with explicit isobar configurations included through the coupled channel mathod. The effective interaction for the¹ S ₀-⁵ D ₀ channel is extracted from this calculation. Two different transition potentials are used — one due to Green and Niskanen (1976), the other, due to Green and co-workers (1978). The nucleon-nucleon (NN) interaction used is the Reid soft core potential, compensated for the inclusion of the explicit isobar channel. The effective interaction shows marked momentum dependence in the intermediate range. The loss of attraction depends on the transition potential one chooses. The correlation function involving the nucleon-isobar intermediate state is anti-correlated to the NN part.