Ti5O5 superstructures of cubic titanium monoxide

A cubic model is proposed for the Ti₅O₅ (Ti₅?O₅□ ≡ Ti₉₀?₁₈O₉₀□₁₈) superstructure of nonstoichiometric titanium monoxide Ti _x O _z with double imperfection. The unit cell of the cubic Ti₅O₅ superstructure has the threefold lattice parameter of the unit cell of the basis disordered B1 structure of Ti _x O _z monoxide and belongs to space group $Pm\bar 3m$ . The channel of the disorder-order transition, i.e., Ti _x O _z (space group $Fm\bar 3m$ )-Ti₅O₅ (space group $Pm\bar 3m$ ), includes 75 superstructure vectors of seven stars {k ₁₀}, {k ₇}, {k ₆₍₁₎}, {k ₆₍₂₎}, {k ₄₍₁₎}, {k ₄₍₂₎}, and {k ₁}. The distribution functions of Ti and O atoms over the sites of the cubic Ti₅O₅ superstructure are calculated. A comparison of the X-ray and electron diffraction data obtained for ordered TiO_1.087 monoxide with the theoretical simulation results supports the existence of the cubic Ti₅O₅ superstructure. The cubic (space group $Pm\bar 3m$ ) Ti₅O₅ superstructure is shown to be a high-temperature structure relative to the well-known monoclinic (space group C2/m) superstructure of the same type.     

Quinazoline-2,4(1H,3H)-diones inhibit the growth of multiple human tumor cell lines

Quinazoline-2,4( $1H,3H$ )-diones exhibit a wealth of biological activities including antitumor proliferation. We established an improved method for the synthesis of quinazoline-2,4( $1H,3H$ )-dione derivatives with three points of molecular diversity. Data indicate that compounds 60 (average $\text{ logGI}_{50} \!=\! -6.1$ ), 65 (average $\text{ logGI}_{50} \!=\! -6.13$ ), 69 (average $\text{ logGI}_{50} \!=\! -6.44$ ), 72 (average $\text{ logGI}_{50} \!=\! -6.39$ ), and 86 (average $\text{ logGI}_{50} = -6.45$ ) significantly inhibited the in vitro growth of 60 human tumor cell lines tested. Structure–activity relationship analyses indicate that chlorophenethylureido is the necessary substituent at the $\text{ D}_{3}$ diversity point (7-position of quinazoline-2,4( $1H,3H$ )-dione), in particular, $o$ -chlorophenethylurea (69) achieved optimal activity. $o$ - or $m$ -Chlorophenethyl substitutions (69 and 72) at the $\text{ D}_{2}$ diversity point (3-position of quinazo line-2,4( $1H,3H$ )-dione) gave the most potent compounds. Methoxyl and 4-methylpiperazin-1-yl substitution at the $\text{ D}_{1}$ diversity point (6-position of quinazoline-2,4( $1H,3H$ )-dione skeleton) may yield better activity than other groups. The quinazoline-2,4( $1H,3H$ )-dione scaffold can be effectively replaced by 2 $H$ -benzo[b][1,4]thiazin-3(4 $H$ )-one.     

Influence of assortativity and degree-preserving rewiring on the spectra of networks

Newman’s measure for (dis)assortativity, the linear degree correlation coefficient $\rho _{D}$ , is reformulated in terms of the total number N _k of walks in the graph with k hops. This reformulation allows us to derive a new formula from which a degree-preserving rewiring algorithm is deduced, that, in each rewiring step, either increases or decreases $\rho _{D}$ conform our desired objective. Spectral metrics (eigenvalues of graph-related matrices), especially, the largest eigenvalue $\lambda _{1}$ of the adjacency matrix and the algebraic connectivity $\mu _{N-1}$ (second-smallest eigenvalue of the Laplacian) are powerful characterizers of dynamic processes on networks such as virus spreading and synchronization processes. We present various lower bounds for the largest eigenvalue $\lambda _{1}$ of the adjacency matrix and we show, apart from some classes of graphs such as regular graphs or bipartite graphs, that the lower bounds for $\lambda _{1}$ increase with $\rho _{D}$ . A new upper bound for the algebraic connectivity $\mu _{N-1}$ decreases with $\rho _{D}$ . Applying the degree-preserving rewiring algorithm to various real-world networks illustrates that (a) assortative degree-preserving rewiring increases $\lambda _{1}$ , but decreases $\mu _{N-1}$ , even leading to disconnectivity of the networks in many disjoint clusters and that (b) disassortative degree-preserving rewiring decreases $\lambda _{1}$ , but increases the algebraic connectivity, at least in the initial rewirings.     

Truncated Connectivities in a Highly Supercritical Anisotropic Percolation Model

We consider an anisotropic bond percolation model on $\mathbb{Z}^{2}$ , with p=(p _h ,p _v )∈[0,1]², p _v >p _h , and declare each horizontal (respectively vertical) edge of $\mathbb{Z}^{2}$ to be open with probability p _h (respectively p _v ), and otherwise closed, independently of all other edges. Let $x=(x_{1},x_{2}) \in\mathbb{Z}^{2}$ with 0<x ₁<x ₂, and $x'=(x_{2},x_{1})\in\mathbb{Z}^{2}$ . It is natural to ask how the two point connectivity function $\mathbb{P}_{\mathbf{p}}(\{0\leftrightarrow x\})$ behaves, and whether anisotropy in percolation probabilities implies the strict inequality $\mathbb{P}_{\mathbf{p}}(\{0\leftrightarrow x\})>\mathbb{P}_{\mathbf {p}}(\{0\leftrightarrow x'\})$ . In this note we give an affirmative answer in the highly supercritical regime.     

Energy dependence of {\bar{K}N} interaction in nuclear medium

When the $\bar{K}N$ system is submerged in nuclear medium the $\bar{K}N$ scattering amplitude and the final state branching ratios exhibit a strong energy dependence when going to energies below the $\bar{K}N$ threshold. A sharp increase of $\bar{K}N$ attraction below the $\bar{K}N$ threshold provides a link between shallow $\bar{K}$ -nuclear potentials based on the chiral $\bar{K}N$ amplitude evaluated at threshold and the deep phenomenological optical potentials obtained in fits to kaonic atoms data. We show the energy dependence of the in-medium K ^??? p amplitude and demonstrate the impact of energy dependent branching ratios on the Λ-hypernuclear production rates.     

On Representations of Quantum Conjugacy Classes of GL(n)

Let O be a closed Poisson conjugacy class of the complex algebraic Poisson group GL(n) relative to the Drinfeld-Jimbo factorizable classical r-matrix. Denote by T the maximal torus of diagonal matrices in GL(n). With every ${a \in O \cap T}$ we associate a highest weight module M _a over the quantum group ${U_q \bigl(\mathfrak{g} \mathfrak{l}(n)\bigr)}$ and an equivariant quantization ${\mathbb{C}_{\hbar,a}[O]}$ of the polynomial ring ${\mathbb{C}[O]}$ realized by operators on M _a . All quantizations ${\mathbb{C}_{\hbar,a}[O]}$ are isomorphic and can be regarded as different exact representations of the same algebra, ${\mathbb{C}_{\hbar}[O]}$ . Similar results are obtained for semisimple adjoint orbits in ${\mathfrak{g} \mathfrak{l}(n)}$ equipped with the canonical GL(n)-invariant Poisson structure.     

Structure and optical property changes of Nb_{2}O_{5} particles by Q-switched laser pulses in water

Monoclinic H-type Nb $_{2}$ O $_{5}$ powders subjected to Q-switched laser pulses in water were characterized by X-ray/electron diffraction and optical spectroscopy to have a significant optical property change with accompanied transformation into orthorhombic T-, pseudohexagonal TT-type and an amorphous phase. The T-Nb $_{2}$ O $_{5}$ nanoparticles were (100), (010), (001) and ( $\overline{2} $ 01) faceted and commonly in oriented intergrowth with TT-type or amorphized domains retaining the polymerized block units of the relic H-type. Such multiple-phase nanoparticles were hydrogenated and densified to modify Raman and FTIR bands and to show visible absorptions corresponding to a broad minimum band gap of 2.3–2.8 eV for potential opto-catalytic and electrochromic applications.     

Jack Superpolynomials with Negative Fractional Parameter: Clustering Properties and Super-Virasoro Ideals

The Jack polynomials ${P_\lambda^{(\alpha)}}$ at ???= ?(k?+?1)/(r ? 1) indexed by certain (k, r, N)-admissible partitions are known to span an ideal ${I_{N}^{(k,r)}}$ of the space of symmetric functions in N variables. The ideal ${I_{N}^{(k,r)}}$ is invariant under the action of certain differential operators which include half the Virasoro algebra. Moreover, the Jack polynomials in ${I_{N}^{(k,r)}}$ admit clusters of size at most k: they vanish when k?+?1 of their variables are identified, and they do not vanish when only k of them are identified. We generalize most of these properties to superspace using orthogonal eigenfunctions of the supersymmetric extension of the trigonometric Calogero-Moser-Sutherland model known as Jack superpolynomials. In particular, we show that the Jack superpolynomials ${P_\lambda^{(\alpha)}}$ at ???= ?(k?+?1)/(r ? 1) indexed by certain (k, r, N)-admissible superpartitions span an ideal ${\mathcal{I}_{N}^{(k,r)}}$ of the space of symmetric polynomials in N commuting variables and N anticommuting variables. We prove that the ideal ${\mathcal{I}_{N}^{(k,r)}}$ is stable with respect to the action of the negative-half of the super-Virasoro algebra. In addition, we show that the Jack superpolynomials in ${\mathcal {I}_{N}^{(k,r)}}$ vanish when k?+?1 of their commuting variables are equal, and conjecture that they do not vanish when only k of them are identified. This allows us to conclude that the standard Jack polynomials with prescribed symmetry should satisfy similar clustering properties. Finally, we conjecture that the elements of ${\mathcal{I}_{N}^{(k,2)}}$ provide a basis for the subspace of symmetric superpolynomials in N variables that vanish when k?+?1 commuting variables are set equal to each other.     

Spin Effects in the Interaction of Antiprotons with the Deuteron at Low and Intermediate Energies

Antiproton-deuteron scattering is analyzed within the Glauber theory, accounting for the full spin dependence of the underlying \({\bar{N}N}\) amplitudes. The latter are taken from the Jülich \({\bar{N}N}\) models and from a recently published new partial-wave analysis of \({\bar{p}p}\) scattering data. Predictions for differential cross sections and the spin observables \({A_y^d}\) , \({A_y^{\bar{p}}}\) , A _xx , A _yy are presented for antiproton beam energies up to about 300 MeV. The efficiency of the polarization buildup for antiprotons in a storage ring is investigated.     

Influence of temperature on the electric,dielectric and AC conductivity properties of nano-crystalline zinc substituted cobalt ferrite synthesized by solution combustion technique

Cobalt–zinc nanoferrites with formulae Co $_{1-x}$ Zn $_{x}$ Fe $_{2}$ O $_{4}$ , where x = 0.0, 0.1, 0.2 and 0.3, have been synthesized by solution combustion technique. The variation of DC resistivity with temperature shows the semiconducting behavior of all nanoferrites. The dielectric properties such as dielectric constant ( $\varepsilon $ ’) and dielectric loss tangent (tan $\delta )$ are investigated as a function of temperature and frequency. Dielectric constant and loss tangent are found to be increasing with an increase in temperature while with an increase in frequency both, $\varepsilon $ ’ and tan $\delta $ , are found to be decreasing. The dielectric properties have been explained on the basis of space charge polarization according to Maxwell–Wagner’s two-layer model and the hopping of charge between Fe $^{2+}$ and Fe $^{3+}$ . Further, a very high value of dielectric constant and a low value of tan $\delta $ are the prime achievements of the present work. The AC electrical conductivity ( $\sigma _\mathrm{AC})$ is studied as a function of temperature as well as frequency and $\sigma _\mathrm{AC}$ is observed to be increasing with the increase in temperature and frequency.     

Coset Constructions of Logarithmic (1, p) Models

One of the best understood families of logarithmic onformal field theories consists of the (1, p) models (p =  2, 3, . . .) of central charge c _{1, p} =1 ? 6(p ? 1)²/p. This family includes the theories corresponding to the singlet algebras ${\mathcal{M}(p)}$ and the triplet algebras ${\mathcal{W}(p)}$ , as well as the ubiquitous symplectic fermions theory. In this work, these algebras are realised through a coset construction. The ${W^{(2)}_n}$ algebra of level k was introduced by Feigin and Semikhatov as a (conjectured) quantum hamiltonian reduction of ${\widehat{\mathfrak{sl}}(n)_k}$ , generalising the Bershadsky–Polyakov algebra ${W^{(2)}_3}$ . Inspired by work of Adamovi? for p = 3, vertex algebras ${\mathcal{B}_p}$ are constructed as subalgebras of the kernel of certain screening charges acting on a rank 2 lattice vertex algebra of indefinite signature. It is shown that for p≤5, the algebra ${\mathcal{B}_p}$ is a quotient of ${W^{(2)}_{p-1}}$ at level ?(p ? 1)²/p and that the known part of the operator product algebra of the latter algebra is consistent with this holding for p> 5 as well. The triplet algebra ${\mathcal{W}(p)}$ is then realised as a coset inside the full kernel of the screening operator, while the singlet algebra ${\mathcal{M}(p)}$ is similarly realised inside ${\mathcal{B}_p}$ . As an application, and to illustrate these results, the coset character decompositions are explicitly worked out for p =  2 and 3.     

Finite W-Superalgebras and Truncated Super Yangians

Let ${Y_{m|n}^{\ell}}$ be the super Yangian of general linear Lie superalgebra for ${\mathfrak{gl}_{m|n}}$ . Let ${e \in \mathfrak{gl}_{m\ell|n\ell}}$ be a “rectangular” nilpotent element and ${\mathcal{W}_e}$ be the finite W-superalgebra associated to e. We show that ${Y_{m|n}^{\ell}}$ is isomorphic to ${\mathcal{W}_e}$ .     

Self-Avoiding Walk is Sub-Ballistic

We prove that self-avoiding walk on ${\mathbb{Z}^d}$ is sub-ballistic in any dimension d ≥ 2. That is, writing ${\| u \|}$ for the Euclidean norm of ${u \in \mathbb{Z}^d}$ , and ${\mathsf{P_{SAW}}_n}$ for the uniform measure on self-avoiding walks ${\gamma : \{0, \ldots, n\} \to \mathbb{Z}^d}$ for which γ ₀ = 0, we show that, for each v > 0, there exists ${\varepsilon > 0}$ such that, for each ${n \in \mathbb{N}, \mathsf{P_{SAW}}_n \big( {\rm max}\big\{\| \gamma_k \| : 0 \leq k \leq n\big\} \geq vn \big) \leq e^{-\varepsilon n}}$ .     

K S 0 , Λ and ≡ production at intermediate to high pT from Au+Au collisions at \sqrt {s_{NN} } = 39, 11.5 and 7.7 GeV

We report on the p _T dependence of nuclear modification factors (R _CP) for K _S ⁰ , ??, ?? and the $\bar NK_S^0 $ ratios at mid-rapidity from Au+Au collisions at $\sqrt {s_{NN} } $ = 39, 11.5 and 7.7 GeV. At $\sqrt {s_{NN} } $ = 39 GeV, the R _CP data show a baryon/meson separation at intermediate p _T and a suppression for K _S ⁰ for p _T up to 4.5 GeV/c; the $\bar \Lambda K_S^0 $ shows baryon enhancement in the most central collisions. However, at $\sqrt {s_{NN} } $ = 11.5 and 7.7 GeV, R _CP shows less baryon/meson separation and $\bar NK_S^0 $ shows almost no baryon enhancement. These observations indicate that the matter created in Au+Au collisions at $\sqrt {s_{NN} } $ = 11.5 or 7.7 GeV might be distinct from that created at $\sqrt {s_{NN} } $ = 39 GeV.     

Decay rate ratios of \varUpsilon (5S)\to B{\bar{B}} reactions

We calculate the decay rate ratios for OZI allowed decays of ?(5S) to two B mesons by using the decay amplitudes which incorporate the wave function of the ?(5S) state. We obtain the result that the branching ratio of the ?(5S) decay to $B_{s}^{*}{\bar{B}}_{s}^{*}$ is much larger than the branching ratio to $B_{s}{\bar{B}}_{s}^{*}$ or ${\bar{B}}_{s}B_{s}^{*}$ , in good agreement with the recent experimental results of CLEO and BELLE. This agreement with the experimental results is made possible since the nodes of the ?(5S) radial wave function induce the nodes of the decay amplitude. We find that the results for the ?(5S) decays to $B_{u}^{(*)}{\bar{B}}_{u}^{(*)}$ or $B_{d}^{(*)}{\bar{B}}_{d}^{(*)}$ pairs are sensitive to the parameter values used for the potential between heavy quarks.     

Charmonium rescattering effects in \psi(2S) \rightarrow \gamma \eta_{c}^{} decay

Charmonium rescattering effects in the M1 transition of $ \psi$ (2S) $ \rightarrow$ $ \gamma$ $ \eta_{c}^{}$ are investigated by modeling a $ \chi_{{cJ}}^{}$ or J/ $ \psi$ rescattering into a $ \eta_{c}^{}$ final state. The absorptive and dispersive part of the transition amplitudes for the rescattering loops of $ \eta$ $ \psi$ ( $ \gamma^{{\ast}}_{}$ ) and $ \gamma$ $ \chi$ ( $ \psi$ ) are separately evaluated. The numerical results show that the contribution from the $ \gamma$ $ \chi$ ( $ \psi$ ) rescattering process is negligible. Compared with the virtual D $ \bar{{D}}$ (D ^*) rescattering processes, the $ \eta$ $ \psi$ ( $ \gamma^{{\ast}}_{}$ ) process may be regarded as the next-leading order of the hadronic loop mechanism, which only offers the partial decay width of ～ 0.045 keV to the $ \psi$ (2S) $ \rightarrow$ $ \gamma$ $ \eta_{c}^{}$ .     

Antineutrino science in KamLAND

The primary goal of KamLAND is a search for the oscillation of \({\bar{\nu }}_\mathrm{e}\) ’s emitted from distant power reactors. The long baseline, typically 180 km, enables KamLAND to address the oscillation solution of the “solar neutrino problem” with \({\bar{\nu }}_{e} \) ’s under laboratory conditions. KamLAND found fewer reactor \({\bar{\nu }}_{e} \) events than expected from standard assumptions about \(\overline{\nu }_e\) propagation at more than 9 \(\sigma \) confidence level (C.L.). The observed energy spectrum disagrees with the expected spectral shape at more than 5 \(\sigma \) C.L., and prefers the distortion from neutrino oscillation effects. A three-flavor oscillation analysis of the data from KamLAND and KamLAND + solar neutrino experiments with CPT invariance, yields \(\Delta m_{21}^2 \) = [ \(7.54_{-0.18}^{+0.19} \times \) 10 \(^{-5}\) eV \(^{2}\) , \(7.53_{-0.18}^{+0.19} \times \) 10 \(^{-5}\) eV \(^{2}\) ], tan \(^{2}\theta _{12}\) = [ \(0.481_{-0.080}^{+0.092} \) , \(0.437_{-0.026}^{+0.029} \) ], and sin \(^{2}\theta _{13}\) = [ \(0.010_{-0.034}^{+0.033} \) , \(0.023_{-0.015}^{+0.015} \) ]. All solutions to the solar neutrino problem except for the large mixing angle region are excluded. KamLAND also demonstrated almost two cycles of the periodic feature expected from neutrino oscillation effects. KamLAND performed the first experimental study of antineutrinos from the Earth’s interior so-called geoneutrinos (geo \({\bar{\nu }}_{e} \) ’s), and succeeded in detecting geo \({\bar{\nu }}_{e} \) ’s produced by the decays of \(^{238}\) U and \(^{232}\) Th within the Earth. Assuming a chondritic Th/U mass ratio, we obtain \(116_{-27}^{+28} {\bar{\nu }}_{e}\) events from \(^{238}\) U and \(^{232}\) Th, corresponding a geo \({\bar{\nu }}_{e}\) flux of \(3.4_{-0.8}^{+0.8}\times \) 10 \(^{6}\) cm \(^{-2}\)  s \(^{-1}\) at the KamLAND location. We evaluate various bulk silicate Earth composition models using the observed geo \({\bar{\nu }}_{e} \) rate.     

Resonant dislocation motion in NaCl crystals in the EPR scheme in the Earth’s magnetic field with pulsed pumping

Resonant dislocation motions in NaCl(Ca) crystals under the simultaneous action of the Earth’s magnetic field B _Earth (～66 μT) and a pulsed pump field $\tilde B$ of sufficient amplitude $\tilde B_m $ and certain duration τ have been detected and studied. The measured dislocation path peaks l(τ) have a maximum at τ = τ _r ≈ 0.53 μs. The resonance criterion has been found to be the ordinary EPR condition in which the g-factor is close to 2 and the optimum inverse pulse duration τ _r ^?1 is used instead of the harmonic pump field frequency ν _r . The largest peak l(τ) height is reached at mutually orthogonal dislocation (L) and magnetic field (B _Earth and $\tilde B$ ) orientations. Pulsed field rotation to the position $\tilde B$ ‖ B _Earth significantly decreases but does not “kill” the effect. For dislocations parallel to the Earth’s field (L ‖ B _Earth), the resonance almost disappears even at $\tilde B$ ⊥ B _Earth. In the optimum geometry of experiments, as the pump field amplitude $\tilde B_m $ decreases from 17.6 to 10 μT, the path peak height l _r = l(τ _r ) decreases only by 7.5%, remaining at the level of l _r ～ 10² μm, and at a $\tilde B_m $ further fall-off to 4 μT, it rapidly decreases to background values. In this case, the relative density of mobile dislocations similarly decreases from ～90 to 40%. Possible physical mechanisms of the observed effect have been discussed.     

Radiative open charm decay of the Y(3940) , Z(3930) , X(4160) resonances

We determine the radiative decay amplitudes for the decay into D^* and $ \bar{{D}}$ $ \gamma$ , or D ^* _s and $ \bar{{D}}_{s}^{}$ $ \gamma$ of some of the charmonium-like states classified as X , Y , Z resonances, plus some other hidden charm states which are dynamically generated from the interaction of vector mesons with charm. The mass distributions as a function of the $ \bar{{D}}$ $ \gamma$ or $ \bar{{D}}_{s}^{}$ $ \gamma$ invariant mass show a peculiar behavior as a consequence of the D ^* $ \bar{{D}}^{*}_{}$ nature of these states. The experimental search of these magnitudes can shed light on the nature of these states.     

Preliminary studies of the Raman spectra of \hbox {Ag}_{2}\hbox {Te}\hbox { and }\hbox {Ag}_{5}\hbox {Te}_{3}

The theoretical calculations indicated that the monoclinic low-temperature phase of silver telluride $(\upbeta \hbox {-Ag}_{2}\hbox {Te})$ is a new binary topological insulator with highly anisotropic single Dirac cone surface. We obtained $\upbeta \hbox {-Ag}_{2}\hbox {Te}$ crystal ingots containing few grains by the Bridgman method. We also deposited thin films of tellurium, $\hbox {Ag}_{5}\hbox {Te}_{3}\hbox { and }(\hbox {Te+Ag}_{5}\hbox {Te}_{3})$ by thermal evaporation method. The Raman spectra of $\upbeta \hbox {-Ag}_{2}\hbox {Te}$ , tellurium and $\hbox {Ag}_{5}\hbox {Te}_{3}$ were measured at three excitation wave lengths: 633, 515 and 488 nm. The Raman active modes of $\upbeta \hbox {-Ag}_{2}\hbox {Te}$ , tellurium and $\hbox {Ag}_{5}\hbox {Te}_{3}$ are situated at frequencies below 300  $\hbox {cm}^{-1}$ while vibrations of other phases appear at higher frequencies.