共查询到20条相似文献,搜索用时 31 毫秒
1.
Xiaojuan Cui Christophe Lengignon Weixiong Zhao Gerard Wysocki Eric Fertein Cécile Coeur Andy Cassez Laurence Croize Weidong Chen Yingjian Wang Weijun Zhang Xiaoming Gao Wenqing Liu Yujun Zhang Fengzhong Dong 《Journal of Quantitative Spectroscopy & Radiative Transfer》2012,113(11):1300-1316
Chemically reactive atmospheric species play a crucial role in tropospheric processes which affect regional air quality and global climate change. Contrary to long-lived species such as greenhouse gases, interference-free accurate and precise concentration assessments of strongly reactive short-lived species represent a real challenge. In this paper, we report on the recent progress in spectroscopic instrumental developments for monitoring of OH, NO3, HONO and NO2 by using modern photonic sources (Quantum Cascade Laser, distributed feedback diode laser, light emitting diode) in conjunction with high-sensitivity spectroscopic measurement techniques such as multi-pass cell based long optical path length absorption spectroscopy, wavelength-modulation enhanced off-axis integrated cavity output spectroscopy, Faraday rotation spectroscopy, incoherent broadband cavity enhanced absorption spectroscopy. The main techniques available for routine atmospheric measurements of OH, NO3 and HONO are overviewed, in comparison with the emerging modern photonic spectroscopy techniques. 相似文献
2.
介绍了基于紫外发光二极管光源的非相干宽带腔增强吸收光谱技术, 并用于实际大气亚硝酸(HONO)和二氧化氮(NO2)的同时测量. 分析了腔内气体的瑞利散射对测量的影响, 测试了紫外发光二极管光源的稳定性, 使用氦气和氮气的瑞利散射差异性标定了镜片反射率随波长的变化曲线, 在HONO吸收峰(368.2 nm)处镜片反射率约为0.99965. 应用Allan方差统计方法确定出测量光谱最佳采集时间为320 s, 对应的HONO和NO2的探测限(1σ)分别为0.22 ppb 和0.45 ppb. 使用非相干宽带腔增强吸收光谱测量装置对大气HONO和NO2进行了连续三日的实际观测, 将测量得到的HONO浓度变化与差分吸收光谱测量装置的测量结果进行对比, 线性相关系数R2为0.917. 相似文献
3.
J. Cousin W. Chen D. Bigourd M. Fourmentin S. Kassi 《Applied physics. B, Lasers and optics》2009,97(4):919-929
We report on the development of a field deployable compact laser instrument tunable over ∼232 cm−1 from 3.16 to 3.41 μm (2932.5–3164.5 cm−1) for chemical species monitoring at the ppb-level. The laser instrument is based on widely tunable continuous-wave difference-frequency
generation (DFG), pumped by two telecom-grade fiber lasers. DFG power of ∼0.3 mW near 3.3 μm with a spectral purity of ∼3.3
MHz was achieved by using moderate pumping powers: 408 mW at 1062 nm and 636 mW at 1570 nm. Spectroscopic performance of the
developed DFG-based instrument was evaluated with direct absorption spectra of ethylene at 3.23 μm (∼3094.31 cm−1). Absorption spectra of vapor-phase benzene near 3.28 μm (∼3043.82 cm−1) were recorded with Doppler-limited resolution. Line intensities of the most intense absorption lines of the ν
12 band near 3043.8 cm−1 were determined to support development of sensitive mid-infrared trace gas detection of benzene vapor in the atmosphere.
Detection of benzene vapor in air at different concentration levels has been performed for the first time using multi-pass
cell enhanced direct absorption spectroscopy at ∼3.28 μm with a minimum detectable concentration of 50 ppb (1σ). 相似文献
4.
Nitrous acid (HONO) is important as a significant source of hydroxyl radical (OH) in the troposphere and as a potent indoor
air pollutant. It is thought to be generated in both environments via heterogeneous reactions involving nitrogen dioxide (NO2). In order to enable fast-response HONO detection suitable for eddy-covariance flux measurements and to provide a direct
method that avoids interferences associated with derivatization, we have developed a 2-channel tunable infrared laser differential
absorption spectrometer (TILDAS) capable of simultaneous high-frequency measurements of HONO and NO2. Beams from two mid-infrared continuous-wave mode quantum cascade lasers (cw-QCLs) traverse separate 210 m paths through
a multi-pass astigmatic sampling cell at reduced pressure for the direct detection of HONO (1660 cm−1) and NO2 (1604 cm−1). The resulting one-second detection limits (S/N=3) are 300 and 30 ppt (pmol/mol) for HONO and NO2, respectively. Our HONO quantification is based on revised line-strengths and peak positions for cis-HONO in the 6-micron spectral region that were derived from laboratory measurements. An essential component of ambient HONO
measurements is the inlet system and we demonstrate that heated surfaces and reduced pressure minimize sampling artifacts. 相似文献
5.
Gain versus tuning issues to Q-switch with Yb<Superscript>3+</Superscript>:LSO and amplify broad-bandwidth pulses 总被引:1,自引:0,他引:1
We report on the development of Incoherent Broadband Cavity Enhanced Absorption Spectroscopy (IBBCEAS) using a blue light
emitting diode (LED) for the detection of NO2 in laboratory ambient air. Absorption of the oxygen collisional pair in the atmosphere was also detected in the same spectral
range. The mirror reflectivity was determined using a standard gas sample mixture of NO2, and calibrated with the help of the absorption spectrum of the oxygen collisional pair in pure oxygen at atmospheric pressure.
Optimization of the experimental parameters was investigated and is discussed in detail. For the first time in IBBCEAS involving
broadband absorption spectra, averaging time for signal-to-noise ratio enhancement has been optimized using Allan variance
plot. 18.1 ppbv NO2 in laboratory ambient air has been retrieved from the absorption spectra using differential fitting method over a 40 nm spectral
region centered at 470 nm. A minimum detection sensitivity of about 2.2 ppbv (1σ) for NO2 at atmospheric pressure has been achieved using the optimal averaging time of 100 s by means of a high finesse optical cavity
formed with two moderate reflectivity (∼99.55%) mirrors. No purging of the cavity mirrors by high purity He or N2 gas streams was necessary to prevent contamination of the mirror faces for the in situ measurements. 相似文献
6.
R. Peeters G. Berden A. Apituley G. Meijer 《Applied physics. B, Lasers and optics》2000,71(2):231-236
A compact open-path optical ammonia detector is developed. A tunable external-cavity diode laser operating at 1.5 μm is used
to probe absorptions of ammonia via the cavity-enhanced absorption (CEA) technique. The detector is tested in a climate chamber.
The sensitivity and linearity of this system are studied for ammonia and water at atmospheric pressure. A cluster of closely
spaced rovibrational overtone and combination band transitions, observed as one broad absorption feature, is used for the
detection of ammonia. On these molecular transitions a detection limit of 100 ppb (1 s) is determined. The ammonia measurements
are calibrated independently with a chemiluminescence monitor. Compared to other optical open-path detection methods in the
1–2 μm region, the present result shows an improved sensitivity for contactless ammonia detection by over one order of magnitude.
Using the same set-up, a detection limit of 100 ppm (1 s) is determined for the detection of water at atmospheric pressure.
Received: 19 January 2000 / Revised version: 6 March 2000 / Published online: 7 June 2000 相似文献
7.
Kasyutich V.L. Bale C.S.E. Canosa-Mas C.E. Pfrang C. Vaughan S. Wayne R.P. 《Applied physics. B, Lasers and optics》2003,76(6):691-697
We present an application of cavity-enhanced absorption spectroscopy with an off-axis alignment of the cavity formed by two
spherical mirrors and with time integration of the cavity-output intensity for detection of nitrogen dioxide (NO2) and iodine monoxide (IO) radicals using a violet laser diode at λ=404.278 nm. A noise-equivalent (1σ≡ root-mean-square variation
of the signal) fractional absorption for one optical pass of 4.5×10-8 was demonstrated with a mirror reflectivity of ∼0.99925, a cavity length of 0.22 m and a lock-in-amplifier time constant
of 3 s. Noise-equivalent detection sensitivities towards nitrogen dioxide of 1.8×1010 molecule cm-3 and towards the IO radical of 3.3×109 molecule cm-3 were achieved in flow tubes with an inner diameter of 4 cm for a lock-in-amplifier time constant of 3 s. Alkyl peroxy radicals
were detected using chemical titration with excess nitric oxide (RO2+NO→RO+NO2). Measurement of oxygen-atom concentrations was accomplished by determining the depletion of NO2 in the reaction NO2+O→NO+O2. Noise-equivalent concentrations of alkyl peroxy radicals and oxygen atoms were 3×1010 molecule cm-3 in the discharge-flow-tube experiments.
Received: 4 February 2003 / Revised version: 10 March 2003 / Published online: 12 May 2003
RID="*"
ID="*"Corresponding author. Fax: +44-1865/275-410, E-mail: vlk@physchem.ox.ac.uk 相似文献
8.
I. Ventrillard-Courtillot E. Sciamma O’Brien S. Kassi G. Méjean D. Romanini 《Applied physics. B, Lasers and optics》2010,101(3):661-669
In the past decade, due to a growing awareness of the importance of air quality and air pollution control, many diagnostic
tools and techniques have been developed to detect and quantify the concentration of pollutants such as NO
x
, SO
x
, CO, and CO2. We present here an Incoherent Broad-Band Cavity-Enhanced Spectroscopy (IBB-CEAS) set-up which uses a LED emitting around
625 nm for the simultaneous detection of NO2 and NO3. The LED light transmitted through a high-finesse optical cavity filled with a gas sample is detected by a low resolution
spectrometer. After calibration of the spectrometer with a NO2 reference sample, a linear multicomponent fit analysis of the absorption spectra allows for simultaneous measurements of
NO2 and NO3 concentrations in a flow of ambient air. The optimal averaging time is found to be on the order of 400 s and appears to be
limited by the drift of the spectrometer. At this averaging time the smallest detectable absorption is 2×10−10 cm−1, which corresponds to detection limits of 600 pptv for NO2 and 2 pptv for NO3. This compact and low cost instrument is a promising diagnostic tool for air quality control in urban environments. 相似文献
9.
10.
Multipass optical cell based upon two cylindrical mirrors for tunable diode laser absorption spectroscopy 总被引:1,自引:0,他引:1
A compact multipass optical cell based upon a front cylindrical mirror with a central input/output hole and a rear cylindrical
mirror is described for application to tunable diode laser absorption spectroscopy. Rotation of the rear cylindrical mirror
and small variations of the cell base length (∼110 mm) have been used to achieve different spot patterns and path lengths.
CO2 and CH4 direct absorption measurements using the developed cell with a fibre-coupled distributed-feedback laser at 1605.5 nm have
been performed. A noise-equivalent absorption sensitivity of 2.5×10-8 cm-1 Hz-1/2 has been determined for 138 passes in the cell and averaging of 2000 consecutive scans within 1.93 s.
PACS 42.55.Px; 39.30.+w; 42.62.Fi; 42.60.-v 相似文献
11.
W. Zhao X. Gao W. Chen W. Zhang T. Huang T. Wu H. Cha 《Applied physics. B, Lasers and optics》2007,86(2):353-359
A novel instrument based on an improved off-axis alignment of integrated cavity output spectroscopy (OA-ICOS) in conjunction
with a wavelength modulation (WM) technique, was developed using a DFB diode laser operating in the near infrared at 1.573 μm
(6357.3 cm-1). The laser-based sensor employed a 44 cm optical cavity that provided an effective absorption path length of ∼68 m. A minimum
detectable absorption of approximately 3.6 ppmv Hz-1/2 or 2.3×10-7 Hz-1/2 per optical pass was obtained using second harmonic detection. We demonstrated that by implementation of the WM technique
to OA-ICOS in the near infrared, the detection sensitivity was improved by a factor of 14 compared to that obtained with OA-ICOS.
Measurements of CO2 mixing ratios in ambient air have been performed by using both OA-ICOS and WM-OA-ICOS techniques for performance comparison.
PACS 42.62.Fi; 07.07.Df; 33.20.Ea 相似文献
12.
Spectroscopic sensing of gases can be performed with high sensitivity and photometric precision by cavity ringdown (CRD) absorption
spectroscopy. Our cavity ringdown spectrometer incorporates continuous-wave (cw) tunable diode lasers, fibre-optic coupling
and standard photonics and optical telecommunications components. It comprises a rapidly swept optical cavity in a single-ended
optical heterodyne transmitter–receiver configuration, enabling optical absorption of gases to be recorded either as single-frequency
scanned spectra or as simultaneous, multi-wavelength tailored spectra. By measuring weak near-infrared rovibrational spectra
of carbon dioxide gas (CO2), with high resolution in the vicinity of 1.53 μm, we have realised a noise-limited absorption sensitivity of 2.5×10-9 cm-1 Hz-1/2. Analytical sensitivity limits (both actual and projected) and prospective gas-diagnostic applications are discussed. Our
approach to cw-CRD spectroscopy offers high performance in a relatively simple, low-cost, compact instrument that is amenable
to chemical analysis of trace gases in medical, agricultural, industrial and environmental situations.
Received: 16 May 2002 / Revised version: 3 June 2002 / Published online: 21 August 2002
RID="*"
ID="*"Corresponding author. Fax: +61-2/9850-8313, E-mail: brian.orr@mq.edu.au 相似文献
13.
多轴差分吸收光谱技术(MAX-DOAS)通过测量不同角度的太阳散射光, 获取痕量气体的柱浓度信息, 广泛应用于整层NO2柱浓度的监测. 由于缺少有效观测距离的信息, MAX-DOAS无法获取近地面NO2的体积混合比浓度. 本文分析了消光系数和有效观测距离的关系, 提出了利用能见度信息获取有效观测距离, 进而将MAX-DOAS测量的水平方向NO2斜柱浓度转换为体积混合比浓度的方法. 并在合肥开展了相应的观测实验, 成功实现了基于MAX-DOAS的NO2体积混合比浓度测量. 通过与主动式长程差分吸收光谱仪测量的NO2浓度进行对比, 结果呈现出较好的一致性, 说明了方法的可行性.研究为MAX-DOAS监测近地面NO2体积混合比浓度提供了一种简单有效的方法, 拓展了MAX-DOAS的应用领域.
关键词:
多轴差分吸收光谱技术
大气消光系数
能见度
2体积混合比浓度')" href="#">NO2体积混合比浓度 相似文献
14.
Presented is a compact instrument developed for in situ high-stable and sensitive continuous measurement of trace gases in air, with results shown for ambient methane (CH4) concentration. This instrument takes advantage of recent technology in thermoelectrically cooled pulsed Fabry–Perot (FP) quantum cascaded (QC) laser driving in a pulse mode operating at 7.5 μm to monitor a well-isolated spectral line near the ν4 fundamental band of CH4. A high-quality liquid nitrogen cooled mercury cadmium telluride mid-infrared detector with time discriminating electronics is used along with a total reflection coated gold ellipsoid mirror offering 20 cm single pass optical absorption in an open-path cell to achieve stability of 5.2 × 10?3 under experimental condition of 200 ppm measured ambient CH4. The instrument operates continuously, and integrated software for laser control using direct absorption provides quantitative trace gas measurements without calibration. One may substitute a QC laser operating at a different wavelength to measure other gases. The instrument can be applied to field measurements of gases of environmental concern. 相似文献
15.
Cavity ringdown (CRD) spectroscopy, with its high sensitivity, provides a novel way to perform continuous-wave (cw) stimulated
Raman gain (SRG) spectroscopy, rather than by conventional optically detected coherent Raman techniques. Tunable cw laser
light at ∼1544 nm is used to probe ringdown decay from a rapidly-swept, high-finesse optical cavity containing a gas-phase
sample of interest and itself located inside the cavity of a cw single-longitudinal-mode Nd:YAG ring laser operating at ∼1064.4
nm. This approach is used to measure cw SRG spectra of the ν
1 fundamental rovibrational Raman band of methane gas at ∼2916.5 cm−1. The resulting SRG-CRD resonances have ringdown times longer than in the off-resonance case, in contrast to the usual shorter
ringdown times arising from absorption and other loss processes. Previously reported noise-equivalent sensitivities have been
substantially improved, by using a second ringdown cavity to facilitate subtraction of infrared-absorption background signals.
Moreover, by employing a ringdown cavity in the form of a ring, the SRG-pump and CRD-detected Stokes beams can co-propagate
uni-directionally, which significantly reduces Doppler broadening. 相似文献
16.
Development of a tunable mid-IR difference frequency laser source for highly sensitive airborne trace gas detection 总被引:4,自引:0,他引:4
Richter D Fried A Wert BP Walega JG Tittel FK 《Applied physics. B, Lasers and optics》2002,75(2-3):281-288
The development of a compact tunable mid-IR laser system at 3.5 μm for quantitative airborne spectroscopic trace gas absorption
measurements is reported. The mid-IR laser system is based on difference frequency generation (DFG) in periodically poled
LiNbO3 and utilizes optical fiber amplified near-IR diode and fiber lasers as pump sources operating at 1083 nm and 1562 nm, respectively.
This paper describes the optical sensor architecture, performance characteristics of individual pump lasers and DFG, as well
as its application to wavelength modulation spectroscopy employing an astigmatic Herriott multi-pass gas absorption cell.
This compact system permits detection of formaldehyde with a minimal detectable concentration (1σ replicate precision) of
74 parts-per-trillion by volume (pptv) for 1 min of averaging time and was achieved using calibrated gas standards, zero air
background and rapid dual-beam subtraction. This corresponds to a pathlength-normalized replicate fractional absorption sensitivity
of 2.5×10-10 cm-1.
Received: 29 April 2002 / Published online: 21 August 2002
RID="*"
ID="*"Corresponding author. Fax: +1-303/497-1492, E-mail: dr@ucar.edu 相似文献
17.
Cavity ringdown (CRD) absorption spectroscopy enables spectroscopic sensing of gases with a high sensitivity and accuracy. Instrumental improvements result in a new high-performance continuous-wave (cw) CRD spectrometer using a rapidly-swept cavity of simple design. It employs efficient data-acquisition procedures, high-reflectivity mirrors, a low-adsorption flow cell, and various compact fibre-optical components in a single-ended transmitter-receiver configuration suitable for remote sensing. Baseline noise levels in our latest cw-CRD experiments yield a competitive noise-equivalent absorption limit of ∼5×10-10 cm-1Hz-1/2, independent of whatever molecules are to be detected. Measurements in the near-infrared wavelength range of 1.51–1.56 μm yield sub-ppmv (i.e., ppbv or better) sensitivity in the gas phase for several representative molecules (notably CO2, CO, H2O, NH3, C2H2, and other hydrocarbons). By measuring spectroscopic features in the 1.525 μm band of C2H2 gas, we realise detection limits of 19 nTorr (2.5×10-11 atm) of neat C2H2 (Doppler-limited at low pressure) and 0.37 ppbv of C2H2 in air (pressure-broadened at 1 atm). Our cw-CRD spectrometer is a high-performance sensor in a relatively simple, low-cost, compact instrument that is amenable to chemical analysis of trace gases in medicine, agriculture, industry, and the environment. PACS 07.07.Df; 07.57.Ty; 42.62.Fi 相似文献
18.
A sensor based on quartz-enhanced photoacoustic spectroscopy (QEPAS) was evaluated for the detection of trace levels of ethylene
at atmospheric pressure using a fiber coupled DFB diode laser emitting in the 1.62 μm spectral range. A noise-equivalent QEPAS signal of ∼4 ppm C2H4 was achieved for a 0.7 s data acquisition time using wavelength-modulation with a second-harmonic detection scheme on the
strongest C2H4 absorption peak at 6177.14 cm−1 with an average optical power of ∼15 mW. Improved detection sensitivity of 0.5 and 0.3 ppm C2H4 (1σ) was demonstrated using longer averaging time of 70 and 700 s, respectively. Important characteristics for the QEPAS based
sensor operation in real-world conditions are presented, particularly the influence of external temperature variations. Furthermore,
the response time of the ethylene sensor was measured in different configurations and it is shown that the QEPAS technique
can provide a response time in a few seconds range even without active gas flow. 相似文献
19.
E.C. Richard K.K. Kelly R.H. Winkler R. Wilson T.L. Thompson R.J. McLaughlin A.L. Schmeltekopf A.F. Tuck 《Applied physics. B, Lasers and optics》2002,75(2-3):183-194
We describe a near-infrared in situ tunable diode laser spectrometer developed for atmospheric measurements of CH4 in the upper troposphere and lower stratosphere (UT/LS). The instrument is designed to provide fast-response (0.5–1 Hz) measurements
and operate autonomously on the NASA WB-57F high-altitude aircraft. A single-mode InGaAsP distributed feedback laser diode
operating at 1.6537 μm scans continuously over the R(3) rotation–vibration transition in the 2ν3 band. We use a direct absorption technique incorporating a custom-designed long path length (252 m) low-volume (3.6 L) astigmatic
Herriott cell. The present detection sensitivity is 5×1010 molecules cm-3, corresponding to ∼20 ppbv in the UT/LS, with the main limit to instrument precision being background optical interference
fringes. In-flight performance is demonstrated by presentation of recent data.
Received: 25 January 2002 / Revised version: 5 April 2002 / Published online: 21 August 2002
RID="*"
ID="*"Corresponding author. Fax: +1-303/497-5373, E-mail: richard@al.noaa.gov 相似文献
20.
The paper presents a signal processing system used for nitrogen dioxide detection employing cavity enhanced absorption spectroscopy.
In this system, the absorbing gas concentration is determined by the measurement of a decay time of a light pulse trapped
in a cavity.
The setup includes a resonance optical cavity, which was equipped with spherical and high reflectance mirrors, the pulsed
diode laser (414 nm) and electronic signal processing system. In order to ensure registration of low-level signals and accurate
decay time measurements, special preamplifier and digital signal processing circuit were developed.
Theoretical analyses of main parameters of optical cavity and signal processing system were presented and especially signal-to-noise
ratio was taken into consideration. Furthermore, investigation of S/N signal processing system and influence of preamplifier
feedback resistance on the useful signal distortion were described.
The aim of the experiment was to study potential application of cavity enhanced absorption spectroscopy for construction of
fully optoelectronic NO2 sensor which could replace, e.g., commonly used chemical detectors. Thanks to the developed signal processing system, detection
limit of NO2 sensor reaches the value of 0.2 ppb (absorption coefficient equivalent = 2.8 × 10−9 cm−1). 相似文献