力学系统的扩散运动及量子化

研究位形由扩散过程定义的力学系统．利用变分的路径计算给出系统广义坐标表示的动力学方程，该方程连同连续方程描述系统量子波动随时间演化的概率进程．文末的表示定理指出，在满足适当正规条件的扩散过程和Ｓｃｈｒｄｉｎｇｅｒ方程的解（波函数）之间存在一一对应关系     

A hybrid phenomenological model for ferroelectroelastic ceramics. Part I: Single phased materials

In this part I of a two part series, a rate-independent hybrid phenomenological constitutive model applicable for single phased polycrystalline ferroelectroelastic ceramics is presented. The term “hybrid” refers to the fact that features from macroscopic phenomenological models and micro-electromechanical phenomenological models are combined. In particular, functional forms for a switching function and the Helmholtz free energy are assumed as in many macroscopic phenomenological models; and the volume fractions of domain variants are used to describe the internal material state, which is a key feature of micro-electromechanical phenomenological models. The approach described in this paper is an attempt to combine the advantages of macroscopic and micro-electromechanical material models. Its potential is demonstrated by comparison with experimental data for barium titanate. Finally, it is shown that the model for single phased materials cannot reproduce the material behavior of morphotropic PZT ceramics based on a realistic choice for the material parameters. This serves as a motivation for part II of the series, which deals with the modeling of morphotropic PZT ceramics taking into account the micro-structural specifics of these materials.     

Systematization of relaxation gas dynamics equations. A review

The phenomenological theory of relaxation gas dynamics equations is outlined for laminar flows of multicomponent reacting gases in an approximation analogous to the Navier-Stokes approximation. A system of general equations of relaxation gas dynamics including the level kinetics equations for all excited internal degrees of freedom is formulated on the basis of notions of continuum mechanics. A procedure of going over to particular cases characterized by certain relations between the relaxation times is described and examples of the corresponding closed systems of gas dynamics equations including systems containing the balance equations of the level or mode approximations for the vibrational energy levels of molecules of a gas mixture are given. A method of constructing a database of the models of the rate constants of physicochemical processes as coefficients in the source terms of the balance equations is considered.     

Fractional relaxation and the time-temperature superposition principle

Relaxation processes in complex systems like polymers or other viscoelastic materials can be described by equations containing fractional differential or integral operators. In order to give a physical motivation for fractional order equations, the fractional relaxation is discussed in the framework of statistical mechanics. We show that fractional relaxation represents a special type of a non-Markovian process. Assuming a separation condition and the validity of the thermo-rheological principle, stating that a change of the temperature only influences the time scale but not the rheological functional form, it is shown that a fractional operator equation for the underlying relaxation process results.     

Driving Potentials of Heat and Mass Transport in Porous Building Materials: A Comparison Between General Linear,Thermodynamic and Micromechanical Derivation Schemes

In systems of coupled transport processes the question of the appropriate driving potentials is a point of discussion. In this article, three different approaches to derive models for transport currents are systematically compared. According to a general linear approach, an arbitrary full set of independent state variables and material properties is sufficient to describe any transport current. This approach is derived here from a symmetry principle. Thermodynamic and micromechanical approaches are more complex and even less general, but they allow additional statements about the transport coefficients and they reduce the number of transport processes. In the thermodynamic approach the additional information stems from the calculation of the entropy production rate; the micromechanical approach involves a microphysical model of the considered porous system. As a practical example, the three derivation schemes are applied to the often-encountered case of non-hysteretic heat and moisture transport in homogeneous building materials. It is shown, how the general state variables of a porous system are reduced to only two. Then from the general linear approach it can be seen, that all equations for the moisture transport current using a main driving potential (e.g. moisture content, vapour pressure, chemical potential) and an independent secondary driving potential (e.g. temperature, liquid pressure) are equivalent, without recurrence to the thermodynamic or micromechanical approach. However, the transport coefficients are arbitrary phenomenological functions depending on the two state variables. Based on a literature survey it is shown, which additional statements can be made in the thermodynamic and in the micromechanical approach. The latter yields the pressure-driven model (vapour and liquid pressure as the two driving potentials). Finally it is shown, what is to be expected, if in more complex systems the number of state variables increases.     

Erosion and deposition of solid particles in porous media: Homogenization analysis of a formation damage

The aim of the paper is to model at a large scale, the formation damage in porous media by erosion and deposition of solid particles. We start from the equations governing the pore-scale processes of erosion, deposition, convection and diffusion. The macroscopic equivalent behaviour is investigated by using a homogenization method. Four characteristic models with different dominating phenomena at the pore scale are determined. The main results are twofold: first dispersion-deposition and dispersion-erosion phenomena are shown at the macroscopic scale for peculiar values of the dimensionless numbers; furthermore, and contrarily to phenomenological models, erosion and deposition generally occur in regions of intense and slow flow, respectively.     

Asymptotic pseudotrajectories and chain recurrent flows,with applications

We present a general framework to study compact limit sets of trajectories for a class of nonautonomous systems, including asymptotically autonomous differential equations, certain stochastic differential equations, stochastic approximation processes with decreasing gain, and fictitious plays in game theory. Such limit sets are shown to be internally chain recurrent, and conversely.     

New nonlinear multi-scale models for wrinkled membranes

A new macroscopic approach to the modelling of membrane wrinkling is presented. Most of the studies of the literature about membrane behaviour are macroscopic and phenomenological, the influence of wrinkles being accounted for by nonlinear constitutive laws without compressive stiffness. The present method is multi-scale and it permits to predict the wavelength and the spatial distribution of wrinkling amplitude. It belongs to the family of Landau–Ginzburg bifurcation equations and especially relies on the technique of Fourier series with slowly varying coefficients. The result is a new family of macroscopic membrane models that are deduced from Föppl–von Kármán plate equations. Numerical solutions are presented, giving the size of the wrinkles as a function of the applied compressive and tensile stresses.     

On the direct interactions between heat transfer,mass transport and chemical processes within gradient elasticity

The behaviour of complex material systems often results from the combined effects of several multi-scale mechanisms and simultaneously occurring coupled physical processes. In this paper, we focus on such complex response of a class of geomaterials in which heat conduction, mass diffusion, chemical reactions and gradient-type elastic strain mechanisms interact. Our purpose is to develop within a formal thermodynamic framework a complete set of constitutive equations which account for most of the possible aforementioned direct couplings and the associated relevant size effects in a unified phenomenological way. For the sake of simplicity, the volume element is described at the macroscopic scale as a classical homogeneous continuous mixture of chemically active species. Based on theories of second-gradient elasticity endowed with the concepts of both nonlocality residual and constitutive insulation condition, a thermo-diffuso-chemo-elastic formulation is proposed in the restricted case of small perturbations. Coupling terms entering the relevant constitutive relations are discussed throughout the paper. Then, the model is applied to a simple one-dimensional situation, in which only the mechanical response is reported. The implementation of such modelling in a finite element code should enable us to address more specific problems, such as the stress solution phenomenon in hollow cylinders subjected to external loading.     

Application of group analysis to stochastic equations of fluid dynamics

Group analysis is used to study stochastic equations of fluid dynamics. Determining equations for admitted Lie groups of transformation involving independent and dependent variables and Wiener processes are obtained. It is shown that, as in the case of deterministic differential equations, admitted groups make it possible to reduce invariant solutions of stochastic differential equations to solutions with a smaller number of independent variables.     

Nonequilibrium vibration-dissociation phenomena behind a propagating shock wave: Vibrational population calculation

An analysis of nonequilibrium phenomena behind a plane shock is presented concerning the vibrational relaxation and the dissociation of a pure diatomic gas. In the first part, the temperature range is 600 K–2500 K and the dissociation processes are neglected. The population of each vibrational level is computed by solving relaxation and conservation equations. The relaxation process is described by the master equations of each vibrational level. The vibrational transition probabilities appearing in the relaxation equations are calculated analytically and take into account the anharmonicity of molecular vibration and the potential angular dependence. The populations obtained are compared to those calculated using a Treanor model and to those calculated with a nonequilibrium Boltzmann distribution. For moderately high levels significant differences may be observed. The importance of the V-V process is found to be weak for the transitions involving the lowest levels. In the second part, the temperature range is 2500 K–5500K and the dissociation process is taken into account as well as the gas dynamic behavior which did not appear in several recent works. The kinetic equations are transformed to obtain a first order differential system and the resolution of such a system coupled with the conservation equations leads to the population of each vibrational level. The vibrational transition probabilities associated with the atom-molecule interaction are deduced from the cross section calculation used in the first part. The bound-free transition probabilities are obtained, following Marrone and Treanor, assuming that dissociation must occur preferentially from the higher vibrational states: the Marrone and Treanor probability model is extended and employed with an anharmonic oscillator. In the present investigation, behind the shock wave, the evolution of the population distribution expressed as a function of the distance is not monotonous: a lag time appears as shown experimentally in previous works for the macroscopic parameters. For moderately high levels the influence of the anharmonicity and those of the V-V processes appear significant and strongly related. In a general way, in both temperature ranges investigated, the V-V processes reduce the effects of the T-V transfer. Finally the influence of thecharacteristic probability temperature U of Marrone and Treanor is analyzed and a method of determination of local varying U is proposed.     

A phenomenological theory for elastic superconductors

The purpose of the present study is to develop a phenomenological theory for elastic superconductors that is based on a rigorous thermodynamical internal variable theory in which the concept of complex internal variable is introduced to include the phase effect of quantum mechanics. Two phenomena of superconductivity, i.e., perfect conductivity and perfect diamagnetism, can be explained in the formulation. In the equilibrium state, this theory can be reduced to the well-known Ginzburg-Landau (GL) theory. Upon linearizing the field equations, boundary conditions and constitutive equations, the governing equations of the rigid-body state and the perturbed state are obtained. These equations then serve to analyze the effect of the hydrostatic deformation on the penetration depth, the GL coherence length and the critical field.     

随机平均规范形方法

计算随机规范形系数是应用随机规范形方法的关键．提出一种应用随机平均计算随机规范形系数的方法．为了说明方法的有效性,对白噪声激励的Duffing系统,经过变换,对于相应的平均方程,比较了精确解、规范形方法解和能量包络方法解的稳态概率密度,结果表明,当非线性项系数较小时,三者完全一致．当非线性项系数较大时,规范形方法所得解与精确解相差不大．     

Higher-order macroscopic measures

We present generalizations of Hill's classical results concerned with the macroscopic strain and stress measures. Generalizations involve polynomial boundary conditions and polynomial moments of the microscopic fields. It is shown that for higher-order polynomials certain boundary conditions and moments should be excluded from considerations in order to guarantee unique relationships between boundary data and macroscopic measures. Particularly simple relationships are obtained for spherical specimens, for which higher-order macroscopic measures are defined in terms of spherical harmonics. Also it is demonstrated that higher-order macroscopic measures and constitutive equations can be useful in multi-scale analysis of problems formulated in terms of integral equations.     

基于正则结构的各向异性损伤演化律

在Rice的正则结构框架下，推导出基于共轭力的各向异性损伤演化律。其中损伤变量采用二阶裂隙张量，它是固体内微裂纹的一个宏观测度。推导过程不涉及自由能的具体形式，主要结果包括损伤势函数及演化方程的解析表达式。在唯象的损伤力学模型里，损伤演化方程经常以唯象方程的形式出现。研究了唯象方程成立的条件及损伤特征张量的解析表达式。引入了广义裂隙张量及脆性指数的概念，并介绍了它们的作用和意义。     

Kinetic models for dilute solutions of dumbbells in non-homogeneous flows revisited

We propose a two-fluid theory to model a dilute polymer solution assuming that it consists of two phases, polymer and solvent, with two distinct macroscopic velocities. The solvent phase velocity is governed by the macroscopic Navier–Stokes equations with the addition of a force term describing the interaction between the two phases. The polymer phase is described on the mesoscopic level using a dumbbell model and its macroscopic velocity is obtained through averaging. We start by writing down the full phase-space distribution function for the dumbbells and then obtain the inertialess limits for the Fokker–Planck equation and for the averaged friction force acting between the phases from a rigorous asymptotic analysis. The resulting equations are relevant to the modelling of strongly non-homogeneous flows, while the standard kinetic model is recovered in the locally homogeneous case.     

Data assimilation for non-linear tidal models

A data assimilation procedure to incorporate measurements into a non-linear tidal model by using Kalman-filtering techniques is developed. The Kalman filter is based on the two-dimensional shallow water equations. To account for the inaccuracies, these equations are embedded into a stochastic environment by introducing a coloured system noise process into the momentum equations. The continuity equation is assumed to be perfect. The deterministic part of the equations is discretized using an ADI method, the stochastic part using the Euler scheme. Assuming that the system noise is less spatially variable than the underlying water wave process, this stochastic part can be approximated on a coarser grid than the grid used to approximate the deterministic part. A Chandrasekhar-type filter algorithm is employed to obtain the constant-gain extended Kalman filter for weakly non-linear systems. The capabilities of the filter are illustrated by applying it to the assimilation of water level measurements into a tidal model of the North Sea.     

Long Asymptotic Correlation Time for Non-Linear Autonomous Itô's Stochastic Differential Equation

Itô's stochastic differential equations theory is a common approach to analysis of stochastic phenomena in various systems. In many applications, an important feature of the systems is the flicker effect. It is well known that it cannot be described with linear autonomous scalar equations of the above kind. The reason is that the flicker effect is usually associated with a correlation time which is much greater than the correlation time in the linear case. In the present work, we discuss modelling of the long correlation time with the help of non-linear autonomous scalar Itô's stochastic differential equation which includes non-linear drift. The expression for the asymptotic correlation time as time separation tends to zero is derived in terms of the equation. We formulate the condition for this time to be long in the above sense. It is pointed out that this condition can hold if the nonlinear damping is reduced compared to the linear case. These results are illustrated with an example of the equation with non-linear drift of a specific form.