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From experimental data of the magnetic susceptibilityχ for various B-elements (Tab. 2 and 3) the contributionχ e from electrons of the outer shell has been derived. Theχ e-values of theliquid B-elements are found to be distributed systematically in the periodic table (Tab. 4). Most of these values can readily be interpreted by simplified theories (Larmor-Langevin-term for non-metallic, Pauli-Landau-term offree electrons for metallic melts). Some complicated cases (e.g. liquid Te) can be explained by considering the chemical bond. Besidesχ e, the temperature dependency of the susceptibility and its change by melting are discussed in detail (Tab. 6 and 7). 相似文献
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Heinz Bässler 《Zeitschrift für Physik B Condensed Matter》1964,2(3):187-203
The steady-state current-voltage characteristic of the d.c. conductivity was measured for several liquid hydrocarbons, as well as its dependence on electrode spacing and — material. A hopping model is proposed in order to interpret the results. The temperature dependence of the conductivity of every hydrocarbon obeys the law
$$\sigma = \sigma _1 + \sigma _2 = \sigma _{01} \exp ( - E_1 /kT) + \sigma _{02} \exp ( - E_2 /kT)$$ 相似文献
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