Phonons,Diffusons, and the Boson Peak in Two-Dimensional Lattices with Random Bonds

Within the model of stable random matrices possessing translational invariance, a two-dimensional (on a square lattice) disordered oscillatory system with random strongly fluctuating bonds is considered. By a numerical analysis of the dynamic structure factor S(q, ω), it is shown that vibrations with frequencies below the Ioffe-Regel frequency ω_IR are ordinary phonons with a linear dispersion law ω(q) ∝ q and a reciprocal lifetime б ~ q³. Vibrations with frequencies above ω_IR, although being delocalized, cannot be described by plane waves with a definite dispersion law ω(q). They are characterized by a diffusion structure factor with a reciprocal lifetime б ~ q², which is typical of a diffusion process. In the literature, they are often referred to as diffusons. It is shown that, as in the three-dimensional model, the boson peak at the frequency ωb in the reduced density of vibrational states g(ω)/ω is on the order of the frequency ω_IR. It is located in the transition region between phonons and diffusons and is proportional to the Young’s modulus of the lattice, ω _b ≃E.

     

Theory of sparse random matrices and vibrational spectra of amorphous solids

The random matrix theory has been used for analyzing vibrational spectra of amorphous solids. The random dynamical matrix M = AA ^T with nonnegative eigenvalues ɛ = ω² has been investigated. The matrix A is an arbitrary square (N-by-N) real sparse random matrix with n nonzero elements in each row, mean values 〈A _ij 〉 = 0, and finite variance 〈A _ij ²〉 = V ². It has been demonstrated that the density of vibrational states g(ω) of this matrix at N, n ≫ 1 is described by the Wigner quarter-circle law with the radius independent of N. For n ≪ N, this representation of the dynamical matrix M = AA ^T makes it possible in a number of cases to adequately describe the interaction of atoms in amorphous solids. The statistics of levels (eigenfrequencies) of the matrix M is adequately described by the Wigner surmise formula and indicates the repulsion of vibrational terms. The participation ratio of the vibrational modes is approximately equal to 0.2–0.3 almost over the entire range of frequencies. The conclusions are in qualitative and, frequently, quantitative agreement with the results of numerical calculations performed by molecular dynamics methods for real amorphous systems.     

On the effective Debye temperatures of the C60 fullerite

The effective Debye temperatures Θ_eff determined for solids by different physical methods have been analyzed and compared. Attention has been focused on the original parameter of the Debye theory of heat capacity, i.e., the translational calorimetric Debye temperature Θ _c ^t (0), and the X-ray Debye temperature Θ _x in the framework of the Debye-Waller theory for the C₆₀ fullerite. It has been established that the true Debye law T ³ is satisfied for the C₆₀ fullerite over a very narrow range of temperatures: 0.4 K ≤ T ≤ 1.8 K. For this reason, the experimental Debye temperatures Θ _c ^t (0) obtained for the C₆₀ fullerite by different authors in the range T > 4.2 K are characterized by a large scatter (by a factor of ∼5). It has been revealed that the value Θ _c ^t (0) = 77.12 K calculated in this paper with the use of the six-term Betts formula from the harmonic elastic constants $ \tilde C_{ijkl} $ \tilde C_{ijkl} of the C₆₀ single crystal in the limit T = 0 K is closest to the true Debye temperature. It has been demonstrated using the method of equivalent moments that the real spectral frequency distribution of translational lattice vibrations g(ω) for the C₆₀ fullerite deviates from a parabolic distribution. The effective Debye temperatures Θ_eff involved in applied problems of thermodynamics of crystals and elastic scattering of different radiations from lattice vibrations have been determined. The quantitative measure of anharmonicity of translational and librational lattice vibrations of the C₆₀ fullerite has been determined. This has made it possible to empirically evaluate the lattice thermal conductivity κ of the C₆₀ fullerite at T ≈ 300 K: κ(300) = 0.80 W (m/K), which is in good agreement with the experimental thermal conductivity κ_exp = 0.78 W (m/K) at T ≈ 250 K.     

Vibrational spectrum of perfluoroethane

We have obtained IR absorption spectra of a C₂F₆ gas and a C₂F₆ cryosolution in Xe (T = 163 K) in the fundamental and overtone ranges. We have interpreted 28 bands of ¹²C¹²CF₆ and three bands of ¹³C¹²CF₆. In the spectral ranges that correspond to vibrations that are combinations with ν₁, ν₇, and ν₅, we observe multiplets, which we attribute to interactions of the type of Fermi resonances between the states ν₁(A _1g ) ∼ ν₆(A _1g ), ν₇(E _g ) ∼ ν₆ + ν₁₁(E _g ) ∼ 2ν₈(E _g ), ν₅(A _2u ) ∼ ν₈ + ν ₁₁(A _2u ). We reveal an anomalous intensity distribution in the spectrum of an asymmetric isotopologue. For the basic and isotopic configurations of perfluoroethane, we calculate the coefficients of shapes of vibrations and the intensities of absorption bands. We reveal that the behavior of the groups ¹²CF₃ and ¹³CF₃ is indifferent to the excitation of doubly degenerate stretching vibrations ν₇(E _g ) and ν₁₀(Eu).     

Spectral behaviour of the two-photon absorption coefficient in ZnO,CuCl and Bi4Ge3O12

Summary The spectral behaviour of the direct interband two-photon absorption coefficient α⁽²⁾ in ZnO, CuCl and Bi₄Ge₃O₁₂ has been investigated in a large excitation energy range. The experimental results have shown that the α⁽²⁾ spectral behaviour is well described by a parametric formula containing terms with different energy dependence. In particular, for 2ħω-E _g>≈400 meV, the first experimental evidence of 2ħω-E _g)^5/2 dependence has been obtained. As a consequence, each of the various models proposed to predict the α⁽²⁾ dispersion curve gives the correct energy dependence in a limited energy range, due to the poor approximation made in the evaluation of dipole matrix elements. To explain the spectral dependence of the two-photon absorption coefficient, consideration of all the intermediate states is required, with the energy dependence of the dipole matrix elements properly considered. It is shown that the greatest contributions to the oscillator strength come from transitions totally allowed at the critical points. Work partially supported by M.P.I.     

Inelastic scattering of phonons by quadrupole defects with internal degrees of freedom

We solve the quantum mechanical problem of the inelastic scattering of phonons by a quadrupole defect in a crystal lattice for the case of solid parahydrogen whose matrix contains pair complexes of H₂ orthomolecules. By employing the pseudospin approximation for the operator of the energy of quadrupole-quadrupole interaction of the molecules in an orthopair we derive an effective Hamiltonian that describes the interaction of phonons with a pair quadrupole orthodefect in the lattice. We set up the scattering matrix and calculate the effective phonon relaxation time τ(ω, T) as a function of the frequency ω and the crystal temperature T. We also find that a pair quadrupole defect, which has a complicated system of levels, can be replaced by an effective two-level system with temperature-dependent parameters. The fact that a pair quadrupole orthocluster has internal degrees of freedom results in a resonant scattering peak near a certain critical temperature T ₀. Our estimates for H₂ yield T ₀≃ 6–7 K. Finally, we discuss the contribution of this mechanism to the low-temperature thermal conductivity of solid hydrogen. Zh. éksp. Teor. Fiz. 114, 555–569 (August 1998)     

Method of Quantum Characters in Equivariant Quantization

 Let G be a reductive Lie group, g its Lie algebra, and M a G-manifold. Suppose 𝔸 _h (M) is a 𝕌 _h (g)-equivariant quantization of the function algebra 𝔸(M) on M. We develop a method of building 𝕌 _h (g)-equivariant quantization on G-orbits in M as quotients of 𝔸 _h (M). We are concerned with those quantizations that may be simultaneously represented as subalgebras in 𝕌^* _h (g) and quotients of 𝔸 _h (M). It turns out that they are in one-to-one correspondence with characters of the algebra 𝔸 _h (M). We specialize our approach to the situation g=gl(n,ℂ), M=End(ℂ ⁿ ), and 𝔸 _h (M) the so-called reflection equation algebra associated with the representation of 𝕌 _h (g) on ℂ ⁿ . For this particular case, we present in an explicit form all possible quantizations of this type; they cover symmetric and bisymmetric orbits. We build a two-parameter deformation family and obtain, as a limit case, the 𝕌(g)-equivariant quantization of the Kirillov-Kostant-Souriau bracket on symmetric orbits. Received: 28 April 2002 / Accepted: 3 October 2002 Published online: 24 January 2003 RID="*" ID="*" This research is partially supported by the Israel Academy of Sciences grant no. 8007/99-01. Communicated by L. Takhtajan     

A Statistical Mechanics Approach for a Rigidity Problem

We focus the problem of establishing when a statistical mechanics system is determined by its free energy. A lattice system, modelled by a directed and weighted graph (whose vertices are the spins and its adjacency matrix M will be given by the system transition rules), is considered. For a matrix A(q), depending on the system interactions, with entries which are in the ring Z[a ^q :a∈R ⁺] and such that A(0) equals the integral matrix M, the system free energy β _A (q) will be defined as the spectral radius of A(q). This kind of free energy will be related with that normally introduced in Statistical Mechanics as proportional to the logarithm of the partition function. Then we analyze under what conditions the following statement could be valid: if two systems have respectively matrices A,B and β _A = β _B then the matrices are equivalent in some sense. Issues of this nature receive the name of rigidity problems. Our scheme, for finite interactions, closely follows that developed, within a dynamical context, by Pollicott and Weiss but now emphasizing their statistical mechanics aspects and including a classification for Gibbs states associated to matrices A(q). Since this procedure is not applicable for infinite range interactions, we discuss a way to obtain also some rigidity results for long range potentials.     

Corrections to scaling in the q-state Potts model within Gaussian closure approximation

Corrections to scaling in the q-state Potts model due to departures of the initial condition from scaling morphology are studied at zero temperature in phase-ordering kinetics within Gaussian closure approximation. When the corrections to scaling are included, the equal time correlation function has the form G(r,t) = g₀(r/L)+L^-ωg₁(r/L) + ..., where L is the coarsening length scale. Both the correction-to-scaling exponent ω and the correction-to-scaling function g₁(x) are calculated for different values of q. The correction-to-scaling exponent ω is found to be nontrivial and depends on q. The corrections to scaling are found to be large (relative to scaling function g₀(x) itself) at large scaling variable x.     

Effect of plasmon-phonon excitations on the coefficient of reflection from the surface of hexagonal silicon carbide

The coefficient R(ν) of reflection from the surface of 6H-SiC single crystals is studied in the case in which the long-wavelength optical vibrations of the lattice are coupled with the electron plasma. It is shown for the first time that the anisotropy of the properties of electrons and phonons in 6H-SiC gives rise to special features in the spectrum of the coupled vibrations and the transparency regions. It is found, in particular, that if the axis of the crystal lies in the polarization plane of the incident radiation (0<θ<90°), for 30 cm⁻¹⩽ν _p⊥<320 cm⁻¹ the spectrum of R(ν) acquires three regions of transparency and opacity, and for ν _p⊥⩾320 cm⁻¹ four such regions, which are absent in an isotropic medium. The width of these regions is found to depend on the electron concentration in the conduction band and on the angle θ. Zh. éksp. Teor. Fiz. 116, 646–654 (August 1999)     

Remarks on positive semigroups

Let ℳ be a von Neumann algebra with a cyclic and separating vector Ω and let ω(·) denote the corresponding vector state, i.e., ω(A)=(Ω, AΩ) A ∈ ℳ. We have proved that a positive semigroup τ on ℳ can induce the dynamical semigroup in the GNS representation associated with ω if the state ω is a τ-invariant one. Some applications are given.     

Nonresonance spin-lattice absorption of ultrasound in Ising magnets

A theory of nonresonant acoustic absorption in Ising magnets is constructed by the nonequilibrium statistical operator method. It is assumed that the spins are coupled with the sound via modulation of the Ising exchange integral, and the nonresonant absorption is due to the interaction of the spin system with the thermal vibrations of the lattice. The frequency dependence of the absorption χ″(ω), which has an analytical form different from that of the well-known Debye function, is determined. The temperature dependence of χ″(ω), which is made up of 1) the averages of the vibrational variables and 2) the temperature dependence of the spin correlation functions of the linear Ising model, is analyzed. It is shown that the cross-coupling of the two subsystems (Ising and Zeeman) produces a second absorption peak at low frequencies together with the peak characteristic of the Debye curve. Fiz. Tverd. Tela (St. Petersburg) 39, 516–521 (March 1997)     

Transport theory of multiterminal hybrid structures

We derive a microscopic transport theory of multiterminal hybrid structures in which a superconductor is connected to several spin-polarized electrodes. We discuss the non-perturbative physics of extended contacts, and show that such contacts can be well represented by averaging out the phase of the electronic wave function. The intercontact Andreev reflection and elastic cotunneling conductances are identical if the phase can be averaged out, namely in the presence of at least one extended contact. The maximal conductance of a two-channel contact is proportional to (e ²/h)(a ₀/D)²exp[-D/ξ(ω^*)], where D is the distance between the contacts, a₀ the lattice spacing, ξ(ω) is the superconducting coherence length, and ω^* is the cross-over frequency between a perturbative regime ( ω < ω^*) and a non perturbative regime ( ω^* < ω < Δ). Received 18 June 2001 and Received in final form 17 January 2002     

Phonon scattering by paraelastic defects

The relaxation timeτ(ω) for the scattering of the lattice waves of frequencyω by the paraelastic defects has been calculated by using the Feynman graph method, applied to a previous theoretical model [8]. A simple expression for the resonance component ofτ(ω)⁻¹ has been derived.

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Zusammenfassung Die Relaxationszeitτ(ω) für die Streuung der Gitterwellen der Frequenzω an den paraelastischen Defekten wurde nach der Methode der Feynmanschen Graphen berechnet, wobei ein früheres theoretisches Modell [8] angewendet wurde. Ein einfacher Ausdruck für den Resonanzteil vonτ(ω)⁻¹ wurde hergeleitet.

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Résumé Nous avons calculé le temps de relaxationτ(ω) des ondes du réseau de fréquenceω, qui sont diffusées par des défauts para-élastiques, en appliquant la méthode des graphes de Feynman à un modèle théorique antérieur [8]. Une simple expression pour la partie résonante deτ(ω)⁻¹ a été dérivée.

     

Construction of Fredholm representations and a modification of the Higson-Roe corona

The Fredholm representation theory is well adapted to the construction of homotopy invariants of non-simply-connected manifolds by means of the generalized Hirzebruch formula [σ(M)] = 〈L(M)ch _A f*ξ, [M]〉 ∈ K _A ⁰(pt) ⊗ Q, where A = C*[π] is the C*-algebra of the group π, π = π ₁(M). The bundle ξ ∈ K _A ⁰(Bπ) is the canonical A-bundle generated by the natural representation π → A. Recently, the first author constructed a natural family of Fredholm representations that lead to a symmetric vector bundle on the completion of the fundamental group with a modification of the Higson-Roe corona, provided that the completion is a closed manifold.     

New method for detection of exciton Bose condensation using stimulated two-photon emission

An investigation is reported of stimulated two-photon emission by Bose-condensed excitons accompanied by a coherent two-exciton recombination, i.e., by simultaneous recombination of two excitons with opposite momenta leaving unchanged the occupation numbers of exciton states with momenta p≠0. Raman light scattering (RLS) accompanied by a similar two-exciton recombination (or production of two excitons) is also analyzed. The processes under consideration can occur only if a system contains Bose condensate, so their detection can be used as a new method to reveal Bose condensation of excitons. The recoil momentum, which corresponds to a change in the momentum of the electromagnetic field in the processes, is transferred to phonons or impurities. If the recoil momentum is transmitted to optical phonons with frequency ω ₀ ^s , whose occupation numbers are negligible, and the incident light frequency satisfies ω<2Ω, where Ω_=Ω−ω ₀ ^s is the difference frequency and Ω is the light frequency corresponding to the recombination of an exciton with zero momentum, stimulated two-photon emission and RLS with coherent two-exciton recombination give rise to a line at 2Ω_ −ω and an anti-Stokes component at ω+2Ω_, respectively. For ω2Ω_ the RLS spectrum contains Stokes and anti-Stokes components at frequencies ω±2Ω_, whereas stimulated two-photon emission is impossible. Formulas for the cross sections at finite temperatures are obtained for the processes under consideration. Our estimates indicate that a spectral line at 2Ω_−ω, corresponding to the stimulated two-photon emission accompanied by coherent optical phonon-assisted two-exciton recombination can be experimentally detected in Cu₂O. Zh. éksp. Teor. Fiz. 115, 1353–1376 (April 1999)     

Studies of interface phonons

The vibrational modes localized at the interface between two distinct crystals have been studied for a simple crystal model obeying all of the invariance conditions required for models used in studies of dynamical properties of crystal surfaces, and giving rise to Rayleigh surface waves. The two crystals are assumed to be semi-infinite simple cubic and to have the same lattice parameter a. They differ by their mass (M and M_A) and the central force interactions between first (K and K_a) and second nearest neighbors $\text{1}\text{2}\text{K}$ and $\text{1}\text{2}\text{K}{}_{\mathrm{A}}$. The interface is obtained by coupling the (001) free surfaces of these distinct crystals by central force intractions (K^'). We find that the variation of the interaction conditions (K^') at the interface and of the $\text{(}\text{K}\text{M}\text{)}\text{(}\text{K}{}_{\mathrm{A}}\text{M}{}_{\mathrm{A}}\text{)}$ parameter has the following qualitative effects on the properties of surface and bulk phonons. When (K^') increases from zero to a finite value, the frequencies of the surface phonons increase and are splitted in the case of two identical crystals. One can say that the surface phonons are transformed into interface modes. For some values of $\text{K}{}^{\mathrm{\text{'}}}\text{K}$ and $\text{(}\text{K}\text{M}\text{)}\text{(}\text{K}{}_{\mathrm{<mtext>A</mtext>}}\text{M}{}_{\mathrm{<mtext>A</mtext>}}\text{)}$ parameters these interface phonons may be admixed with bulk phonons and thus become virtual interface states.     

The Characteristic Classes of Morita Equivalent Star Products on Symplectic Manifolds

In this paper we give a complete characterization of Morita equivalent star products on symplectic manifolds in terms of their characteristic classes: two star products ⋆ and ⋆' on (M,ω) are Morita equivalent if and only if there exists a symplectomorphism ψ\colon M M such that the relative class t(⋆, ψ^⋆(⋆')) is 2 π i-integral. For star products on cotangent bundles, we show that this integrality condition is related to Dirac's quantization condition for magnetic charges. Received: 19 July 2001 / Accepted: 23 January 2002     

A Derivative Formula for the Free Energy Function

We consider bond percolation on the Z ^d lattice. Let M _n be the number of open clusters in B(n)=[−n,n] ^d . It is well known that E _p M _n /(2n+1) ^d converges to the free energy function κ(p) at the zero field. In this paper, we show that s²_p(M_n)/(2n+1)^d\sigma^{2}_{p}(M_{n})/(2n+1)^{d} converges to −p(1−p)κ′(p).     

Kinematic mechanism of the modulation of the spectral intensity in the spatially uniform system of Hubbard fermions

Using the exact representation of the Green’s function constructed in terms of the Hubbard operators, it has been shown that the kinematic interaction that induces the spin-fluctuation processes in the spatially uniform system of Hubbard fermions leads to significant variations in the spectral intensity A(k, ω) in the Brillouin zone. As a result, the modulation of A(k, ω) appears in the Fermi contour. The sign of the hopping integral within the first coordination sphere is determined by the contour section, where A(k, ω) decreases according to the angle-resolved photoemission spectroscopy data.