Characteristics of heat transfer coefficient during nucleate pool boiling of binary mixtures

Experimental studies were conducted on heat transfer on a horizontal platinum wire during nucleate pool boiling in nonazeotropic binary mixtures of R12+R113, R134a+R113, R22+R113 and R22+R11, at pressures of 0.25 to 0.7 MPa and at heat fluxes up to critical heat flux. The substances employed were chosen such that the components of a given mixture had a large difference in saturation temperatures. The boiling features of the mixtures and the pure substances were observed by photography. The relationship between the boiling features and the reduction in heat transfer coefficient in binary mixtures is discussed in order to propose a correlation useful for predicting the experimental data measured over a wide range of low and high heat fluxes. It is shown that the correlation is applicable also to alcoholic mixtures. The physical role of k, which was introduced to evaluate the effect of heat flux on the reduction in heat transfer coefficient, is clarified based on the measured nucleate pool boiling heat transfer data and the visual observations of the boiling features. Received on 13 May 1997     

Enhancement of nucleate pool boiling heat transfer coefficient by reentrant cavity surfaces

The pool boiling of acetone, isopropanol, ethanol and water at atmospheric pressure has been carried out on a plain tube, and five different reentrant cavity (REC) heating tubes. The heat flux has remained in a range of 11–42 kW/m² for all the heating tubes. The enhancement factor, E, has been found to increase with the rise in heat flux, irrespective of the boiling liquid and the test-section tube combinations. For the pool boiling of acetone and isopropanol, the maximum enhancement factor has been attained for REC-2 tube with mouth size of 0.3 mm and for ethanol and water the mouth size could not be optimized, however, the maximum enhancement factor has been attained for REC-4 tube with mouth size of 0.2 mm. A correlation has also been developed to predict the enhancement factor, E, for the pool boiling of the test-liquids on REC heating tubes. This correlation has predicted the enhancement factor, E, in an error band of +12.5 to –7.5%.     

A new model for nucleate boiling heat transfer

A new model to calculate heat transfer coefficients in nucleate boiling is presented. Heat transfer and fluid flow around a single bubble are investigated taking into account the influence of meniscus curvature, adhesion forces and interfacial thermal resistance on the thermodynamic equilibrium at the gas-liquid interface. The model requires only bubble site densities and departure diameters. Further quantities except the thermophysical properties are not needed. From the results bubble growth rates can be derived. As an example nucleate boiling heat transfer coefficients of R-114 were calculated. They agree with experimental values within the experimental accuracy.     

Review of nucleate pool boiling bubble heat transfer mechanisms

Enhanced convection, transient conduction, microlayer evaporation, and contact line heat transfer have all been proposed as mechanisms by which bubbles transfer energy during boiling. Models based on these mechanisms contain fitting parameters that are used to fit them to the data, resulting a proliferation of “validated” models. A review of the recent experimental, analytical, and numerical work into single bubble heat transfer is presented to determine the contribution of each of the above mechanisms to the overall heat transfer. Transient conduction and microconvection are found to be the dominant heat transfer mechanisms. Heat transfer through the microlayer and at the three-phase contact line do not contribute more than about 25% of the overall heat transfer.     

Forced convective boiling heat transfer in microtubes at low mass and heat fluxes

Convective boiling of HCFC123 and FC72 in 0.19, 0.3 and 0.51 mm ID tubes is investigated. The experimental setup as well as the data reduction procedure has carefully been designed, so that the relative uncertainty interval of the measured heat transfer coefficient in microtubes is kept within ±10%. Up to 70 K liquid superheat over the saturation temperature is observed at low heat and mass fluxes. The onset of the superheat is found to be dependent on the mass flux and the boiling number of the refrigerant examined. In the saturated boiling regime, the heat transfer characteristics are much different from those in conventional-size tubes. The heat transfer coefficient is monotonically decreased with increasing the vapor quality, and becomes independent of the mass flux. Most empirical formulas are not in accordance with the present experimental data. Since the prediction using the nucleate boiling term of Kandlikar’s empirical correlations coincides with the present results, the convection effect should be minor in microtubes. On the other hand, the pressure loss characteristics are qualitatively in accordance with the conventional correlation formula while quantitatively much lower. These phenomena can be explained by the fact that the annular flow prevails in microtubes.     

Mechanistic models for pool nucleate boiling heat transfer: input and validation

Correlations for nucleate boiling heat transfer should be improved, or in the long term possibly be replaced, by the development of mechanistic simulations that include the non-uniform spacing and variable characteristics of the nucleation sites and non-linear interactions between the sites. This paper discusses the interactions that should be included in simulations and some lessons from a first attempt to validate a particular simulation against experimental spatio-temporal data for wall temperature. Input data for nucleation site positions and characteristics are a particular problem and the prospects for obtaining this data from measurements that are independent of boiling are discussed.     

The influence of oil on nucleate pool boiling heat transfer

The influence of various oil contents in R134a is investigated for nucleate pool boiling on copper tubes either sandblasted or with enhanced heating surfaces (GEWA-B tube). Polyolester oils (POE) (Reniso Triton) with medium viscosity 55 cSt (SE55) and high viscosity 170 cSt (SE170) were used. Heat transfer coefficients were obtained for boiling temperatures between −28.6 and +20.1°C. The oil content varied from 0 to 5% mass fraction. For the sandblasted tube and the SE55 oil the heat transfer coefficients for the refrigerant/oil-mixture can be higher or lower than those for the pure refrigerant, depending on oil mass fraction, boiling temperature and heat flux. In some cases the highest heat transfer coefficients were obtained at a mass fraction of 3%. For the 170 cSt oil there is a clear decrease in heat transfer for all variations except for a heat flux 4,000 W/m² and −10.1°C at 0.5% oil content. The heat transfer coefficients are compared to those in the literature for a smooth stainless steel tube and a platinum wire. For the enhanced tube and 55 cSt oil the heat transfer coefficients are clearly below those for pure refrigerant in all cases. The experimental results for the sandblasted tube are compared with the correlation by Jensen and Jackman. The calculated values are within +20 and −40% for the medium viscosity oil and between +50% and −40% for the high viscosity oil. A correlation for predicting oil-degradation effects on enhanced surfaces does not exist.     

Mass transfer behavior at bubble surface during nucleate boiling

 Interfacial mass transfer mechanisms played an essential role to the high heat transfer efficiency noted for nucleate boiling. There existed a zone around the bubble surface that exhibited zero net mass flux, termed herein as the “zero-flux zone”. This work investigated analytically the interfacial vaporization and condensation processes around a boiling bubble, based on which the positional dependence of zero-flux zone was derived. For a stationary bubble the zero-flux zone shifted to the upper hemisphere with decreasing wall superheat and/or with increasing contact angle. Moreover, the bubble growth (shrinkage) largely enhanced (retarded) such a trend. At the extreme condition where the bubble grew at a very fast speed the entire bubble surface would be subject to liquid evaporation only. Experiments observed a “thermal jet” emerging from the bubble cap, which was attributed to the interfacial vapor condensation flux at the bubble cap. Received on 11 December 2000 / Published online: 29 November 2001     

Experimental study of nucleate boiling heat transfer under low gravity conditions using TLCs for high resolution temperature measurements

Heat transfer in nucleate boiling is strongly influenced by a very small circular area in the vicinity of the three phase contact line where a thin liquid film approaches the heated wall. This area is characterised by high evaporation rates which trigger a local temperature drop in the wall. The wall temperature drop can be computed using an existing nucleate boiling model. To verify the complex model and the underlying assumptions, an experiment was designed with an artificial nucleation site in a thin electrically heated wall featuring a two-dimensional, high resolution temperature measurement technique using unencapsulated thermochromic liquid crystals and a high speed colour camera. The shape of the bubble is observed simultaneously with a second high speed camera. Experiments were conducted in a low gravity environment of a parabolic flight, causing larger bubble departure diameters than in normal gravity environments. Thus, it was possible to measure the evolution of the predicted temperature drop in a transient boiling process.     

Effect of surfactant additives on nucleate pool boiling heat transfer of refrigerant-based nanofluid

Effect of surfactant additives on nucleate pool boiling heat transfer of refrigerant-based nanofluid was investigated experimentally. Three types of surfactants including Sodium Dodecyl Sulfate (SDS), Cetyltrimethyl Ammonium Bromide (CTAB) and Sorbitan Monooleate (Span-80) were used in the experiments. The refrigerant-based nanofluid was formed from Cu nanoparticles and refrigerant R113. The test surface is horizontal with the average roughness of 1.6 μm. Test conditions include a saturation pressure of 101.3 kPa, heat fluxes from 10 to 80 kW m⁻², surfactant concentrations from 0 to 5000 ppm (parts per million by weight), and nanoparticle concentrations from 0 to 1.0 wt.%. The experimental results indicate that the presence of surfactant enhances the nucleate pool boiling heat transfer of refrigerant-based nanofluid on most conditions, but deteriorates the nucleate pool boiling heat transfer at high surfactant concentrations. The ratio of nucleate pool boiling heat transfer coefficient of refrigerant-based nanofluid with surfactant to that without surfactant (defined as surfactant enhancement ratio, SER) are in the ranges of 1.12-1.67, 0.94-1.39, and 0.85-1.29 for SDS, CTAB and Span-80, respectively, and the values of SER are in the order of SDS > CTAB > Span-80, which is opposite to the order of surfactant density values. The SER increases with the increase of surfactant concentration and then decreases, presenting the maximum values at 2000, 500 and 1000 ppm for SDS, CTAB and Span-80, respectively. At a fixed surfactant concentration, the SER increases with the decrease of nanoparticle concentration. A nucleate pool boiling heat transfer correlation for refrigerant-based nanofluid with surfactant is proposed, and it agrees with 92% of the experimental data within a deviation of ±25%.     

Experimental study on the heat transfer coefficient of water flow boiling in mini/microchannels

The heat transfer coefficients of the evaporative water flow in mini/microchannels are studied experimentally to explore the novel heat dissipation for high power electronics. Two sets of parallel channels which are 61 channels with hydraulic diameter of 0.293 mm and 20 channels with hydraulic diameter of 1.2 mm are investigated respectively. The inlet and outlet temperatures of fluids, and the temperatures beneath the channels are measured to calculate the heat dissipation of the evaporative water in channels. The experiments are carried out with the mass flow rates range from 11.09 kg/(m² s) to 44.36 kg/(m² s) for minichannels and 49.59 kg/(m² s) to 198.37 kg/(m² s) for microchannels. The effective heat flux range from 5 W/cm² to 50 W/cm², and the resulted outlet vapor qualities range from 0 to 0.8. The relations of the heat transfer coefficient with heat flux and vapor quality are analyzed according to the results. The experimental heat transfer coefficients are compared with the prediction of latest developed correlations. A new correlation takes the effect of Bond number is proposed, and be verified that it is effective to predict the heat transfer coefficient of both minichannels and microchannels in a large range of vapor qualities.     

Flow boiling heat transfer of R134a and R404A in a microfin tube at low mass fluxes and low heat fluxes

An experimental investigation of flow boiling heat transfer in a commercially available microfin tube with 9.52 mm outer diameter has been carried out. The microfin tube is made of copper with a total fin number of 55 and a helix angle of 15°. The fin height is 0.24 mm and the inner tube diameter at fin root is 8.95 mm. The test tube is 1 m long and is electrically heated. The experiments have been performed at saturation temperatures between 0 and −20°C. The mass flux was varied between 25 and 150 kg/m²s, the heat flux from 15,000 W/m² down to 1,000 W/m². All measurements have been performed at constant inlet vapour quality ranging from 0.1 to 0.7. The measured heat transfer coefficients range from 1,300 to 15,700 W/m²K for R134a and from 912 to 11,451 W/m²K for R404A. The mean heat transfer coefficient of R134a is in average 1.5 times higher than for R404A. The mean heat transfer coefficient has been compared with the correlations by Koyama et al. and by Kandlikar. The deviations are within ±30% and ±15%, respectively. The influence of the mass flux on the heat transfer is most significant between 25 and 62.5 kg/m²s, where the flow pattern changes from stratified wavy flow to almost annular flow. This flow pattern transition is shifted to lower mass fluxes for the microfin tube compared to the smooth tube.     

A survey of experimental heat transfer data for nucleate pool boiling of liquid metals and a new correlation

The experimental data for heat transfer during nucleate pool boiling of saturated liquid metals on plain surfaces are surveyed and a new correlation is presented. The correlation is h = Cq^0.7p_r^m, where C and m are, respectively, 13.7 and 0.22 p_r < 0.001 and 6.9 and 0.12 for p_r > 0.001 (h is in W/m² K and q in W/m²). This correlation has been verified with data for K, Na, Cs, Li, and Hg from 17 sources over the reduced pressure (p_r) range of 4.3 × 10⁻⁶ to 1.8 × 10⁻². The correlation of Subbotin et al. was found unsatisfactory, but a modified correlation was developed that also gives good agreement with most of the data.     

Optimization of heat transfer coefficient correlation at supercritical pressure using genetic algorithms

The paper presents a new heat transfer correlation of water at supercritical pressure after review on existing heat transfer correlations. The new correlation is optimized by genetic algorithms based on existing test data. Based on current results, we conclude that genetic algorithms are effective to search a global optimized correlation but it is important to carefully select representative and authentic test data to reach an optimized solution and special attention needs to be paid on the deteriorated heat transfer region in the design of supercritical water reactor because it can not be predicted well by any correlations reviewed. Supported by the National Basic Research Program of China (973 Program No. 2007CB209800) and Atomic Energy of Canada Limited.     

Nucleate boiling heat transfer in aqueous solutions with carbon nanotubes up to critical heat fluxes

In this study, pool boiling heat transfer coefficients (HTCs) and critical heat fluxes (CHFs) are measured on a smooth square flat copper heater in a pool of pure water with and without carbon nanotubes (CNTs) dispersed at 60 °C. Tested aqueous nanofluids are prepared using multi-walled CNTs whose volume concentrations are 0.0001%, 0.001%, 0.01%, and 0.05%. For the dispersion of CNTs, polyvinyl pyrrolidone polymer is used in distilled water. Pool boiling HTCs are taken from 10 kW/m² to critical heat flux for all tested fluids. Test results show that the pool boiling HTCs of the aqueous solutions with CNTs are lower than those of pure water in the entire nucleate boiling regime. On the other hand, critical heat flux of the aqueous solution is enhanced greatly showing up to 200% increase at the CNT concentration of 0.001% as compared to that of pure water. This is related to the change in surface characteristics by the deposition of CNTs. This deposition makes a thin CNT layer on the surface and the active nucleation sites of the surface are decreased due to this layer. The thin CNT layer acts as the thermal resistance and also decreases the bubble generation rate resulting in a decrease in pool boiling HTCs. The same layer, however, decreases the contact angle on the test surface and extends the nucleate boiling regime to very high heat fluxes and reduces the formation of large vapor canopy at near CHF. Thus, a significant increase in CHF results in.     

Experimental investigation in pool boiling heat transfer of ammonia/water mixture and heat transfer correlations

The nucleate pool boiling heat transfer coefficient of ammonia/water mixture was investigated on a cylindrical heated surface at low pressure of 4-8 bar and at low mass fraction of 0 < x_NH3 < 0.3 and at different heat flux. The effect of mass fraction, heat flux and pressure on boiling heat transfer coefficient was studied. The results indicate that the heat transfer coefficient in the mixture decreases with increase in ammonia mass fraction, increases with increase in heat flux and pressure in the investigated range. The measured heat transfer coefficient was compared with existing correlations. The experimental data were predicted with an accuracy of ±20% by the correlation of Calus&Rice, correlation of Stephan-Koorner and Inoue-Monde correlation for ammonia/water mixture in the investigated range of low ammonia mass fraction. The empirical constant of the first two correlations is modified by fitting the correlation to the present experimental data. The modified Calus&Rice correlation predicts the present experimental data with an accuracy of ±18% and the modified Stephan-Koorner correlation with an accuracy of ±16%.     

A study of nucleate boiling and critical heat flux with EHD enhancement

The paper describes results from an experimental and theoretical study of the effect of an electric field on nucleate boiling and the critical heat flux (CHF) in pool boiling of R123 at atmospheric pressure on a horizontal wall with a smooth surface. Two designs of electrode (parallel rods and wire mesh) were used. The experimental data exhibit some differences from the data obtained by other researchers in similar experiments on a wall with a different surface finish and with a slightly different design of wire mesh electrode. The hydrodynamic model for EHD enhancement of CHF cannot reconcile the differences. A theoretical model has been developed for the growth of a single vapour bubble on a superheated wall in an electric field, leading to a numerical simulation based on the level-set method. The model includes matching of sub-models for the micro- and macro-regions, conduction in the wall, distortion of the electric field by the bubble, the temperature dependence of electrical properties and free-charge generation. In the present form of the model, some of these effects are realised in an approximate form. The capability to investigate dry-spot formation and wall temperature changes that might lead to CHF has been demonstrated.