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有机锡试剂在有机合成中的某些新应用 总被引:1,自引:0,他引:1
本文阐述有机锡试剂在有机台成巾的一些新应用。在钯催化下,有机锡试剂与亲电试剂进行偶联,条件温和,收率高。有机锡试剂促进醇醛缩合,可用于不对称合成中。 相似文献
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本文根据化学工业在 2 1世纪面临的要求———开发创新环境友好工艺 ,介绍了几种新的负载型试剂 ,如固体酸、固体碱等 ,以及它们在某些有机合成反应 ,如Friedel Crafts反应、硝化反应、卤代反应、Michael反应及一系列氧化反应中的应用。 相似文献
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本文综述了合成含N-烷基氨基酸或α,α-二取代氨基酸位阻肽的偶合试剂研究新进展,并对这些新的偶合试剂及偶合方法的优点和不足予以评述。 相似文献
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本文综述了合成含N-烷基氨基酸或α,α-二取代氨基酸位阻肽的偶合试剂研究新进展,并对这些新的偶合试剂及偶合方法的优点和不足予以评述。 相似文献
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Results are summarized on the synthesis of reagents for the determination of noble and heavy metals (sulfonitrophenol M, sulfochlorophenolazorhodanine (Rhodazol KhS), chlorophenolazorhodanine (Rhodazol Kh), sulfobenzeneazorhodanines, p-phenolazo-3-aminorhodanine, benzeneazobenzeneazorhodanine, sulfochlorophenolazothiopropiorhodanine (tyrodine), and hexaoxacycloazochrom), methods for their purification and identification, the determination of the concentration of the active compound in reagents, and techniques for the storage of reagents and the preparation of working solutions. 相似文献
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Polymeric reagents offer a range of unique advantages. Intramolecular reactions, such as the cyclization of peptides or Dieckmann cyclizations, can be brought about by attaching the reactive molecules at remote points along a polymer chain. In contrast, if the reactive molecules are anchored in close proximity on a polymeric support then intermolecular reactions occur, as demonstrated for a ketone synthesis. Apart from such proximity effects, cooperative effects can also be exploited, e.g. in the formation of a 2:1 complex of a crown ether and an alkali metal ion. The hydrolysis of an ester with polyvinylimidazole provides a detailed illustration of hydrophobic interactions. The simple separation of polymer-bound and low-molecular compounds by filtration is another significant advantage. 相似文献
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Hamid Salimi Azam Rahimi Ali Pourjavadi 《Monatshefte für Chemie / Chemical Monthly》2007,138(4):363-379
Summary. Polymer supported reagents have found many applications in recent years. Scientists in research laboratories of agrochemical
and pharmaceutical industries now routinely utilize these compounds to prepare ensembles of small organic molecules for screening.
This review is aimed to highlight some of the most important applications of these promising materials in organic synthesis.
Furthermore, an extensive listing of polymeric reagents that were recently used in organic synthesis is included. 相似文献
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Hamid Salimi Azam Rahimi Ali Pourjavadi 《Monatshefte für Chemie / Chemical Monthly》2007,14(1):363-379
Polymer supported reagents have found many applications in recent years. Scientists in research laboratories of agrochemical
and pharmaceutical industries now routinely utilize these compounds to prepare ensembles of small organic molecules for screening.
This review is aimed to highlight some of the most important applications of these promising materials in organic synthesis.
Furthermore, an extensive listing of polymeric reagents that were recently used in organic synthesis is included. 相似文献
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Dr. Thomas Q. Davies Prof. Michael C. Willis 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(35):8918-8927
Sulfinylamines (R−N=S=O), monoaza analogues of sulfur dioxide, have been known for well over a century, and their reactivity as sulfur electrophiles and in Diels-Alder reactions is well-established. However, they have only rarely been used in organic synthesis in recent decades despite the increasing prominence of compounds containing N=S=O functionality, such as sulfoximines and sulfonimidamides. This Minireview aims to bring wider visibility to the unique chemistry enabled by this class of compounds. We focus on advances from the last 10 years, including the first examples of their use in the one-pot syntheses of sulfoximines and sulfonimidamides. Also covered are the reactions of sulfinylamines with carbon-centred radicals, their use for formation of heterocycles through cycloadditions, and catalytic enantioselective allylic oxidation of alkenes via a hetero-ene reaction. These examples highlight the different reactivity modes of sulfinylamines and their underappreciated potential for forming molecules which contain high- or low-valent sulfur, or even no sulfur at all. 相似文献
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Samata E. Shetgaonkar Ritu Mamgain Kotaro Kikushima Toshifumi Dohi Fateh V. Singh 《Molecules (Basel, Switzerland)》2022,27(12)
The chemistry of polyvalent iodine compounds has piqued the interest of researchers due to their role as important and flexible reagents in synthetic organic chemistry, resulting in a broad variety of useful organic molecules. These chemicals have potential uses in various functionalization procedures due to their non-toxic and environmentally friendly properties. As they are also strong electrophiles and potent oxidizing agents, the use of hypervalent iodine reagents in palladium-catalyzed transformations has received a lot of attention in recent years. Extensive research has been conducted on the subject of C—H bond functionalization by Pd catalysis with hypervalent iodine reagents as oxidants. Furthermore, the iodine(III) reagent is now often used as an arylating agent in Pd-catalyzed C—H arylation or Heck-type cross-coupling processes. In this article, the recent advances in palladium-catalyzed oxidative cross-coupling reactions employing hypervalent iodine reagents are reviewed in detail. 相似文献
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It was shown that the sensitivity of analytical procedures using organic reagents can be significantly increased if a poorly soluble complex of an element with an analytical reagent is oxidized to the products of complete oxidation of organic compounds (CO2, H2O, and NH3or N2for nitrogen-containing reagents). Knowing the amount of the consumed oxidant, one can easily determine the amount of the organic constituent of the complex and, hence, the amount of the complex-forming element. Vanadium salts were proposed as oxidants. The effects of medium acidity, oxidant concentration, time of heating, and temperature on the completeness of oxidation were studied. Based on the results obtained, it was demonstrated for a number of organic compounds that liquid-phase oxidation is highly promising and that trace amounts of elements can be determined by conventional titrimetric methods. The determination of phosphorous with diantipyrylmethane is illustrated by an example (1 mL of a 0.1 M vanadate solution corresponds to 10 g phosphorous). 相似文献
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