超弹性材料本构关系的最新研究进展

超弹性材料是工程实际中的常用材料, 具有在外力作用下经历非常大变形、在外力撤去后完全恢复至初始状态的特征. 超弹性材料是典型的非线性弹性材料, 其性能可通过材料的应变能函数予以表征. 近几十年来, 围绕应变能函数形式的构造, 已提出许多超弹性材料本构关系研究的数学模型和物理模型, 但适用于多种变形模式和全变形范围的完全本构关系仍是该领域期待解决的重要问题. 本文从3个不同角度, 对超弹性材料本构关系研究的最新进展进行了总结和分析: (1)不同体积变化模式, 包含不可压与可压两种; (2)多变形模式, 包含单轴拉伸、剪切、等双轴以及复合拉剪等多个种类; (3)全范围变形程度, 包含小变形、中等变形到较大变形范围. 超弹性材料本构关系研究的最新进展表明, 为了全面描述具体材料的实验数据并在实际问题中应用超弹性材料, 需要建立适合于多种变形模式和全变形范围的可压超弹性材料的完全本构关系. 对实际超弹性材料完全本构关系的建立及可压超弹性材料应变能函数的构造, 笔者还提出了相应的实施步骤和研究方法.      

一类可压缩超弹性圆柱体轴线上的空穴现象

对于由一类均匀各向同性可压缩的广义Varga材料组成的实心圆柱体,研究其在给定的外表面拉伸和轴向拉伸或压缩共同作用下的轴对称变形问题.利用能量变分原理得到了问题的控制方程和边界条件,并求得了描述柱体径向对称变形的参数型解析解和描述圆柱体轴线上空穴生成和增长的空穴分岔解.给出了与泊松比和轴向伸长相关的径向临界伸长的表达式和空穴生成后的应力表达式;并通过数值算例讨论了这些参数对圆柱体轴线上空穴生成和增长、圆柱体的径向位移以及应力的集中和突变的影响,同时给出了相应的数值模拟.     

Simple shearing and azimuthal shearing of an internally balanced compressible elastic material

The finite deformation response of a compressible internally balanced elastic material is studied for deformations that involve progressive shearing. The internally balanced material theory requires that an equation of internal balance is satisfied at each material point. This arises from the constitutive theory which makes use of a multiplicative decomposition of the deformation gradient. Satisfaction of the internal balance requirement then yields the most energetically favorable decomposition. Here we consider a particular compressible internally balanced material model that is motivated by a Blatz–Ko type energy from the conventional hyperelastic theory. The conventional hyperelastic theory occurs as a special limiting case of the internally balanced constitutive theory. More generally, the internally balanced material exhibits softer mechanical behavior. This gives rise to a stress-plateau in the simple shearing response whereas such plateaus do not occur in the corresponding hyperelastic treatment. The boundary value problem for azimuthal shearing with a possible radial stretching is then studied. The internally balanced material response is again found to be softer than that of the hyperelastic limiting case. This is manifest in terms of an upper bound to the applied twisting moment for the existence of solutions to the boundary value problem. In contrast, the hyperelastic limiting case has solutions for all values of applied moment.     

Constitutive Models for Compressible Nonlinearly Elastic Materials with Limiting Chain Extensibility

Constitutive models are proposed for compressible isotropic hyperelastic materials that reflect limiting chain extensibility. These are generalizations of the model proposed by Gent for incompressible materials. The goal is to understand the effects of limiting chain extensibility when the compressibility of polymeric materials is taken into account. The basic homogeneous deformation of simple tension is considered and simple closed-form relations for the deformation characteristics are obtained for slightly compressible materials. An explicit first-order approximation is obtained for the lateral contraction and for the Poisson function in terms of the axial extension which is shown to be valid for each of two specific compressible versions of the Gent model. One of the main results obtained is that the effect of limiting chain extensibility is to stiffen the material relative to the neo-Hookean compressible case. Mathematics Subject Classifications (2000) 74B20, 74G55.     

Understanding the need of the compression branch to characterize hyperelastic materials

Soft biological tissues are frequently modeled as hyperelastic materials. Hyperelastic behavior is typically ensured by the assumption of a stored energy function with a pre-determined shape. This function depends on some material parameters which are obtained through an optimization algorithm in order to fit experimental data from different tests. For example, when obtaining the material parameters of isotropic, incompressible models, only the extension part of a uniaxial test is frequently taken into consideration. In contrast, spline-based models do not require material parameters to exactly fit the experimental data, but need the compression branch of the curve. This is not a disadvantage because as we explain herein, to properly characterize hyperelastic materials, the compression branch of the uniaxial tests (or valid alternative tests) is also needed, in general. Then, unless we know beforehand the tendency of the compression branch, a material model should not be characterized only with tensile tests. For simplicity, here we address isotropic, incompressible materials which use the Valanis-Landel decomposition. However, the concepts are also applicable to compressible isotropic materials and are specially relevant to compressible and incompressible anisotropic materials, because in biomechanics, materials are frequently characterized only by tensile tests.     

Distortion of Anisotropic Hyperelastic Solids Under Pure Pressure Loading: Compressibility, Incompressibility and Near-Incompressibility

The purpose of this note is to examine distortion during pure pressure loading for anisotropic hyperelastic solids. We contrast the corresponding issues in compressible and incompressible hyperelasticity, and then use these results to examine nearly incompressible materials. An anisotropic compressible hyperelastic solid will generally exhibit both volume change and distortion under hydrostatic pressure loading. In contrast, an incompressible hyperelastic solid—both isotropic and anisotropic—exhibits no change to its current state of deformation as the hydrostatic pressure is varied. Nearly incompressible hyperelastic materials are compressible, but approach an incompressible response in an appropriate limit. We examine this limiting process in the context of transverse isotropy. The issue arises as to how to implement a nearly incompressible version of a given truly incompressible material model. Here we examine how certain implementations eliminate distortion under pure pressure loading and why alternative implementations do not eliminate the distortion.     

Finite strain––isotropic hyperelasticity

This paper presents a strain energy density for isotropic hyperelastic materials. The strain energy density is decomposed into a compressible and incompressible component. The incompressible component is the same as the generalized Mooney expression while the compressible component is shown to be a function of the volume invariant J only. The strain energy density proposed is used to investigate problems involving incompressible isotropic materials such as rubber under homogeneous strain, compressible isotropic materials under high hydrostatic pressure and volume change under uniaxial tension. Comparison with experimental data is good. The formulation is also used to derive a strain energy density expression for compressible isotropic neo-Hookean materials. The constitutive relationship for the second Piola–Kirchhoff stress tensor and its physical counterpart, involves the contravariant Almansi strain tensor. The stress stretch relationship comprises of a component associated with volume constrained distortion and a hydrostatic pressure which results in volumetric dilation. An important property of this constitutive relationship is that the hydrostatic pressure component of the stress vector which is associated with volumetric dilation will have no shear component on any surface in any configuration. This same property is not true for a neo-Hookean Green’s strain–second Piola–Kirchhoff stress tensor formulation.     

聚硅氧烷硅胶的黏超弹性力学行为研究

聚硅氧烷硅胶是一类以Si——O键为主链、硅原子上直接连接有机基团的无色透明高分子聚合物, 因其具有优异的超弹性性能而广泛应用于精密减震结构、柔性电子器件等领域. 在聚硅氧烷硅胶减震结构和柔性电子器件的设计中, 材料在大变形和动态加载下的黏超弹性力学行为的精确描述至关重要. 本文针对该问题进行了系统的研究:首先, 将该硅胶的超弹性和黏弹性行为进行解耦, 确定其黏超弹性本构方程的基本框架;其次, 基于单轴拉压、平面拉伸试验确定其准静态超弹性模型的各项参数;再次, 利用霍普金森压杆冲击试验确定其黏弹性模型的各项参数;在此基础上, 将超弹性和黏弹性模型合并为适用于大应变和大应变率的黏超弹性动态本构模型;最后, 利用落锤冲击试验对该硅胶薄片的冲击变形行为进行了研究, 并利用上述建立的动态本构模型对落锤冲击过程进行了有限元模拟. 结果表明:本文建立的黏超弹性本构模型可有效预测该硅胶在冲击载荷下的力学行为, 从而为聚硅氧烷硅胶减震结构和柔性电子器件的优化设计提供了理论和应用基础.      

Thermovisco-hyperelastic behavior of elastomeric materials modified by filler nanoparticles

We present the results of experimental studies of hyperelastic and relaxation properties of polymer composites with elastomeric matrix made of hydrogenated nitrile butadiene rubber filled with nanoparticles of technical carbon in the temperature range 19–150° C. We present typical experimental diagrams of deformation of the material with constant strain rate and the stress relaxation curves at different strain levels under tension and compression conditions. We consider a possible version of constitutive relations for describing some singularities of the behavior of the material under study. We developed a method for determining all the parameters of the accepted relations on the basis of the results of uniaxial tests. We found a nonmonotone dependence of the relaxation modulus on the temperature and proposed a formula for describing this dependence in the temperature range under study. To justify the possible use of the considered constitutive relations to perform calculations under conditions of arbitrary compound stress state, we performed numerical modeling of the compression experiment for cylindrical samples. A rather satisfactory agreement between the computational results and experimental data was obtained.     

无额外自由度广义有限元非线性分析

将无额外自由度的广义有限元法由线弹性分析扩展到弹塑性大变形分析.局部强化函数的构建依赖于已有节点,不引入额外自由度,避免了线性相关性问题.在更新拉格朗日框架下,通过控制方程弱形式的线性化推导得到了节点内力的率形式,并分为材料和几何两部分.考虑超弹性和亚弹-塑性两种材料模型,采用Newton-Raphson迭代求解,给出...     

On constitutive modelling of porous neo-Hookean composites

In this paper a hyperelastic constitutive model is developed for neo-Hookean composites with aligned continuous cylindrical pores in the finite elasticity regime. Although the matrix is incompressible, the composite itself is compressible because of the existence of voids. For this compressible transversely isotropic material, the deformation gradient can be decomposed multiplicatively into three parts: an isochoric uniaxial deformation along the preferred direction of the material (which is identical to the direction of the cylindrical pores here); an equi-biaxial deformation on the transverse plane (the plane perpendicular to the preferred direction); and subsequent shear deformation (which includes “along-fibre” shear and transverse shear). Compared to the multiplicative decomposition used in our previous model for incompressible fibre reinforced composites [Guo, Z., Peng, X.Q., Moran, B., 2006, A composites-based hyperelastic constitutive model for soft tissue with application to the human annulus fibrosus. J. Mech. Phys. Solids 54(9), 1952–1971], the equi-biaxial deformation is introduced to achieve the desired volume change. To estimate the strain energy function for this composite, a cylindrical composite element model is developed. Analytically exact strain distributions in the composite element model are derived for the isochoric uniaxial deformation along the preferred direction, the equi-biaxial deformation on the transverse plane, as well as the “along-fibre” shear deformation. The effective shear modulus from conventional composites theory based on the infinitesimal strain linear elasticity is extended to the present finite deformation regime to estimate the strain energy related to the transverse shear deformation, which leads to an explicit formula for the strain energy function of the composite under a general finite deformation state.     

Effects of large deformation and material nonlinearity on spherical indentation of hyperelastic soft materials

Up to now, the indentation of hyperelastic soft materials has not been completely understood. In this paper, the spherical indentation on hyperelastic soft solids was systematically investigated through theoretical analysis and finite element method (FEM). The validation and application of the Hertzian load-displacement relation for indentation of hyperelastic soft materials were clarified, the effects of large deformation and material nonlinearity on spherical indentation of hyperelastic soft materials were analyzed and discussed. It was found that the complicated indentation behaviors of hyperelastic soft solids mainly depended on the coupling interactions of large deformation and material nonlinearity. Besides, we proposed two new nonlinear elastic contact models to separate the effects of large deformation and material nonlinearity on spherical indentation responses of hyperelastic soft solids. Our efforts might help to enhance the understanding of hyperelastic indentation problems and provided necessary instructions for the mechanical characterization of hyperelastic soft materials.     

多孔硅橡胶有限变形的粘弹性行为

针对孔隙度较大（孔隙度大于50％）的硅橡胶材料在有限变形时的粘弹性行为，从建立描述材料粘弹性特征的松驰函数和变形特征的应变能函数出发，提出了适合多孔隙、可压硅橡胶材料的非线性粘弹性力学行为的本构关系，松驰函数和应变能函数可解耦为等容和体积变形两部分，并引入了拟时间的概念来反映变形对材料特征时间的影响，利用硅橡胶材料的单轴压缩松驰实验与材料模型进行了对比，讨论了多孔硅橡胶的等容变形和体积变形对应力松驰的影响。     

Separation phenomena at the interface of a finitely deformed composite sphere

The problem of the finite deformation of a composite sphere subjected to a spherically symmetric dead load traction is revisited focusing on the formation of a cavity at the interface between a hyperelastic, incompressible matrix shell and a rigid inhomogeneity. Separation phenomena are assumed to be governed by a vanishingly thin interfacial cohesive zone characterized by uniform normal and tangential interface force–separation constitutive relations. Spherically symmetric cavity shapes (spheres) are shown to be solutions of an interfacial integral equation depending on the strain energy density of the matrix, the interface force constitutive relation, the dead loading and the volume concentration of inhomogeneity. Spherically symmetric and non-symmetric bifurcations initiating from spherically symmetric equilibrium states are analyzed within the framework of infinitesimal strain superimposed on a given finite deformation. A simple formula for the dead load required to initiate the non-symmetrical rigid body mode is obtained and a detailed examination of a few special cases is provided. Explicit results are presented for the Mooney–Rivlin strain energy density and for an interface force–separation relation which allows for complete decohesion in normal separation.     

基于横观各向同性超弹性理论的短纤维增强橡胶本构模型的建立与应用Establishment and application of short fiber reinforced rubber constitutive model based on transversely isotropic hyperelastic theory

提出了一种能够表征短纤维增强橡胶的横观各向同性超弹性本构模型,并结合试验体系,对其在数值分析中的应用方法和效果进行了研究。基于连续介质力学理论,建立了横观各向同性材料的应变能函数,推导得到不同变形形式下的应力应变关系,给出材料参数辨识试验方法,并成功应用于某短纤维增强橡胶测试中,得到表征其超弹性特性的相关材料参数。利用有限元软件ANSYS对不同纤维排布方向的单轴拉伸和平行纤维方向的平面拉伸进行仿真计算,并对比相应试验数据,以验证材料参数的可靠性。最后基于已验证的本构模型,建立了某铣槽装备减振环仿真模型,并对其进行了校核计算。研究结果表明,本文提出的本构模型能够有效表征短纤维增强橡胶的静态力学特性并且方便嵌入现有的有限元软件中,具有材料参数少、测试简便和结果准确等特点,工程实用性强。     

Equivalent and separable strain-energy functions in compressible,finite elasticity

A material non-uniqueness is identified for isotropic, homogeneous, hyperelastic, compressible materials. This non-uniqueness is a special case of the hyperelastic null Lagrangian. Equivalence classes of strain-energy functions (SEFs) are then obtained. This equivalence can be used to extend in a natural way some of the common SEF used in incompressible elasticity to compressible elasticity. The familiar Valanis–Landel separable form of the SEF for incompressible materials is extended in this way. Some necessary restrictions are imposed on this new form and its behaviour in uniaxial tension is discussed. Previous problems in using the Valanis–Landel form of the SEF in compressible elasticity have been overcome.     

基于能量密度等效的超弹性压入模型与双压试验方法

针对超弹性材料压入问题, 本文基于能量密度中值等效原理, 提出了描述球、平面、锥3类压头独立压入下载荷、深度、压头几何尺寸和Mooney-Rivlin本构关系参数之间关系的半解析超弹性压入模型(semi-theoretical hyperelastic-material indentation model, SHIM), 进而提出了球、平面、锥压入组合的双压试验方法(indentation method due to dual indenters, IMDI). 正向验证表明, 基于系列超弹性材料的本构关系参数, 由SHIM分别预测的球、平面、锥3类压入下的载荷-位移曲线与有限元分析(finite element analysis, FEA)结果之间密切吻合; 反向验证表明, 基于系列超弹性材料的FEA条件本构关系下3类压入的载荷-位移曲线, 由双压试验方法预测的Mooney-Rivlin本构关系与FEA条件本构关系密切吻合. 针对3种超弹性橡胶, 完成了球、平面、锥压入试验, 应用双压试验方法获得的3组Mooney-Rivlin本构关系均与单轴拉伸试验结果吻合良好.      

The Effects of Compressibility on Inhomogeneous Deformations for a Class of Almost Incompressible Isotropic Nonlinearly Elastic Materials

Experimental data for simple tension suggest that there is a power–law kinematic relationship between the stretches for large classes of slightly compressible (or almost incompressible) non-linearly elastic materials that are homogeneous and isotropic. Here we confine attention to a particular constitutive model for such materials that is of generalized Varga type. The corresponding incompressible model has been shown to be particularly tractable analytically. We examine the response of the slightly compressible material to some nonhomogeneous deformations and compare the results with those for the corresponding incompressible model. Thus the effects of slight compressibility for some basic nonhomogeneous deformations are explicitly assessed. The results are fundamental to the analytical modeling of almost incompressible hyperelastic materials and are of importance in the context of finite element methods where slight compressibility is usually introduced to avoid element locking due to the incompressibility constraint. It is also shown that even for slightly compressible materials, the volume change can be significant in certain situations.      

用于超弹性分析的高效杂交应变--EAS固体壳单元的研究

提出了一个用于橡胶材料分析的弱变分方程，基于一个可压缩Neo—Hookean模型，将EAS模式和杂交元法有机地结合起来，推导了一个高效、稳定的杂交应变——EAS固体壳单元，通过巧妙地选择应交插值函数和本文中提出的一个精化措施，克服了橡胶材料所表现出的大应变超弹性本构为杂交元正交化法的实施所带来的困难，保证了整个单元列式都仅采用低阶高斯积分，显著提高了计算效率，确保橡胶材料不可压缩性计算的顺利进行，并克服了固体壳元的厚度自锁问题。