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聚丙烯酸水溶液及α-A12O3悬浮液的流变性研究 总被引:1,自引:0,他引:1
研究了pH、聚丙烯酸(PAA)浓度和分子量对PAA水溶液的粘度的影响,发现溶液的流变行为与溶液中PAA高分子链的离子化程度和构型密切相关,高分子链刚性程度的增加和链的伸展使溶液在pH为7~9时的粘度最大;研究了在PAA溶液中引入陶瓷粉体后悬浮液的粘度变化,发现当陶瓷粉体和PAA的量达到一定比值时悬浮液体系的粘度达到最小值,同时发现陶瓷粉体的粒径大小与这一粘度最小值和悬浮液流变特性也有关. 相似文献
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醇/水介质对PEG大分子单体与BMA分散共聚反应的影响 总被引:1,自引:0,他引:1
通过端基反应法合成了苯乙烯单封端的聚乙二醇(St- PEG)大分子单体,使其与甲基丙烯酸丁酯(BMA)在乙醇 水混合介质中进行分散共聚,得到了聚乙二醇接枝的聚甲基丙烯酸丁酯(PBMA- g -PEG)高分子微球.PBMA- g -PEG共聚物的亲溶剂 疏溶剂平衡将影响微球的形成,反应结束时,体系随BMA浓度和介质中水含量的变化呈现出4种不同的状态,透明清液、乳液、伴有沉淀或凝胶的乳液和凝胶.用透射电子显微镜(TEM)和激光光散射(LLS)对乳液体系的粒径及其形态进行了表征,表明所得接枝高分子微球形态规整具有较好的单分散性.通过控制介质中水的含量和BMA的浓度可得粒径在4 0~5 0 0nm范围的PBMA -g -PEG微球. 相似文献
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聚合物粘弹性的分子理论,主要是以Rou-se的珠簧模型为基础发展起来的。Rouse模型未曾考虑到分子链之间存在着缠结效应,因此只适用于稀溶液,而无法推广到高分子浓溶液和熔体等稠厚体系。即使象零切粘度与分子 相似文献
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《The Journal of chemical thermodynamics》2004,36(8):665-670
Densities, viscosities and water activities of aqueous solutions of polyvinylpyrrolidone have been determined experimentally at T=(298.15, 308.15, 318.15 and 328.15) K. From the density data, the apparent specific volume of polymer and the partial specific volume of polymer and water have been calculated. From the viscosity data, the viscosity and number average molecular weight of polymer have been calculated. From the water activity data, the vapour pressure of solutions has been calculated. Densities, viscosities and water activities have been correlated successfully with an general equation which takes into account the influence of the polymer concentration and the temperature. 相似文献
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Wenchao Jiang Zhaowei Hou Xiaolin Wu Kaoping Song Erlong Yang Bin Huang Chi Dong Shouliang Lu Liyan Sun Jian Gai Shichun Yao Yunchao Wang Chunlin Nie Dengyu Yuan Qinghua Xu 《Molecules (Basel, Switzerland)》2022,27(12)
Relative permeability of polymer flooding plays a very important role in oil field development. This paper aimed to measure and calculate the relative permeability curves of polymer flooding more accurately. First, viscosity variation law of polymer in porous media was studied. Rock particles of different diameters and cementing agent were used to make artificial cores and hydrophobically associating polymer solutions were prepared for experiments. Polymer solutions were injected into the cores filled with crude oil and irreducible water. In the process of polymer flooding, produced fluid was collected at different water saturations and locations of the core. Polymer solutions were separated and their viscosities were measured. With the experimental data, the viscosity variation rule of polymer transporting in porous media was explored. The result indicates that the viscosity retention rate of polymer solutions transporting in porous media has power function relationship with the water saturation and the dimensionless distance from the core inlet. Finally, the relative permeability curves of polymer flooding were measured by unsteady state method and the viscosity variation rule was applied to the calculation of the relative permeability curves. 相似文献
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Sami Hietala Andreas Nystrm Heikki Tenhu Anders Hult 《Journal of polymer science. Part A, Polymer chemistry》2006,44(11):3674-3683
Four generations of dendronized polymers with a methacrylate backbone and hydroxy‐functionalized aliphatic polyester dendrons based on 2,2‐bis(methylol)propionic acid were studied in solutions by rheological measurements, dynamic light scattering, turbidimetry, and 1H NMR self‐diffusion measurements to reveal the effect of increasing hydrophilicity and molecular size on their solution properties. The studied polymers were interesting new amphiphiles with a hydrophobic main chain and a hydrophilic shell. Evidence of aggregation upon the heating of the first‐generation polymer in an aqueous solution was obtained by dynamic light scattering and turbidimetry, reflecting the effect of the hydrophobic polymer backbone, whereas the higher generation polymers did not show aggregation upon heating. Although the dimensions of the polymers were observed to increase with increasing generation, all the polymers exhibited low viscosities and Newtonian flow behavior in both aqueous and dimethyl sulfoxide solutions. The relative viscosities of the polymers in water and dimethyl sulfoxide showed that the conformation of the polymers was somewhat more open in dimethyl sulfoxide, and this led to higher viscosities than those in water, in agreement with the 1H NMR diffusion measurements, by which the dimensions were found to be larger for the polymers dissolved in dimethyl sulfoxide. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3674–3683, 2006 相似文献
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Intrinsic viscosities for a given polyelectrolyte in salt free and low-salt solvents reported in literatures are normally not comparable, because of inadequate valuation procedures. This article describes a theoretically justified reliable method, which is free of any model assumptions: The so called Wolf plot (logarithm of the relative viscosity as a function of polymer concentration) enables the unequivocal determination of intrinsic viscosities for all kinds of macromolecules, irrespective of whether they are chain molecules of different architecture or globular polymers, whether they are charged or uncharged. The validation of the method was examined by evaluation of the viscosities of a polyelectrolyte, some uncharged polymers of different architectures, uncharged polymer blends, and some literature data. 相似文献
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D. J. Worsfold 《Journal of Polymer Science.Polymer Physics》1982,20(1):99-106
Reasons have been advanced why in some cases concentrated-polymer-solution viscosity measurements are not a suitable method for determining the degree of association of groups attached to polymer chains. These are based on the finite lifetimes of associates compared with the finite lifetimes of the entanglements, which are the major contributors to concentrated-polymer-solution viscosities. The validity of these reasons has been checked in a system where the degree of association of polymer chains can be measured spectroscopically. It was found that the viscosity of these solutions was considerably less than that calculated by the concentrated-solution viscosity equation for solutions of polymers of the average molecular weight expected from the spectroscopically found degree of association. 相似文献
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Careful measurements of the dilute solution viscosities of polyethylene glycol and polyvinylalcohol in water were carried out. The reduced viscosities of both polymer solutions plot upward curves atextremely dilute concentration levels similar to the phenomena observed for many polymer solutions in theearly 1950's. Upon observation of the changes of the flow times of pure water in and the wall surfacewettability of the viscometer after measuring solution viscosity, a view was formed that the observed viscosityabnormality at extremely dilute concentration regions is solely due to the effect of adsorption of polymerchains onto the wall surface of viscometer. A theory of adsorption effect based on the Langmuir isothermswas proposed and a mathematical analysis for data treatment was performed. The theory could adequatelydescribe the existing viscosity data. It seems necessary to correct the viscosity result of dilute polymersolutions measured by glass capillary viscometer by taking into account the effect of adsorption in all cases. 相似文献
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《液相色谱法及相关技术杂志》2012,35(10):1911-1934
Abstract An on-line viscometer which measures the eluent pressure drop across a long capillary was developed for use in aqueous size exclusion chromatography (SEC). Intrinsic viscosities of several polymer standards were calculated from data collected by the viscometer. These viscosities agree well with the measurements made with a Ubbelohde four-bulb shear dilution viscometer. The on-line viscometer becomes more sensitive as polymer hydro-dynamic volume increases. Therefore, it can be more effective than a refractive index detector for SEC analysis of high molecular weight, water soluble polymers. 相似文献
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M. R. Ambler 《Journal of polymer science. Part A, Polymer chemistry》1973,11(1):191-201
A method has been developed for determining simultaneously the molecular weight of a broad-distribution polymer and the Mark-Houwink coefficients for that polymer type by using only GPC and intrinsic viscosity data. Standardized samples of poly(vinyl chloride), polystyrene, polybutadiene, and an experimental cycloolefin polymer were analyzed by this method. Shear-corrected intrinsic viscosities were used in all cases because of the high molecular weights involved. Molecular weight data for all samples were found to be in good agreement with molecular weight data obtained by membrane osmometry and from other GPC techniques. The proposed technique provides a means for calculating the molecular weight of a single polymer sample through universal calibration of GPC without knowledge of the Mark-Houwink coefficients for that polymer type. 相似文献
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Two-phase mixtures of diesel fuel and aqueous ethanol were microemulsified and data were collected on rheological properties, densities, water tolerance and critical solution temperatures. For the detergentless system of diesel fuel, aqueous ethanol and butanol it was found that the relative viscosity varied directly with the volume percent of the dispersed water phase and approximates Einstein's formula. With ionic systems it was found that relative viscosities varied with increasing volume percent of dispersed water by values greater than those predicted by Brinkman and Roscoe for suspensions of diverse particle size. Water tolerances for ionic systems were greater than those observed with 1-butanol. The nature of the surfactant and its concentration determine to a large degree the microemulsion's physical properties. 相似文献