Tunable UV radiation at short wavelengths (188–240 nm) generated by sum-frequency mixing in lithium borate

Sum-frequency mixing (₃=₁+₂) of UV laser radiation (₁=266 nm and 213 nm) and tunable coherent infrared light (₂=1.2–2.6 m) in lithium borate (LBO) generates radiation at short wavelengths (₃=188–242 nm). The UV radiation at ₁ is produced by the fourth and fifth harmonic of a pulsed Nd-YAG laser. The infrared light is generated with an optical parametric oscillator of beta barium borate. The phase-matching angle is measured as function of ₃ and compared with calculated values. For UV laser radiation at shorter wavelengths (173 nm₁213 nm) the calculations predict an extension of the tuning range of the sum-frequency generated at ₃ to wavelengths as short as the LBO transmission cutoff at 160 nm.     

Realization of holonomic constraints and freezing of high frequency degrees of freedom in the light of classical perturbation theory. Part II

As in Part I of this paper, we consider the problem of the energy exchanges between two subsystems, of which one is a system of harmonic oscillators, while the other one is any dynamical system ofn degrees of freedom. Such a problem is of interest both for the realization of holonomic constraints of classical mechanics, and for the freezing of the internal degrees of freedom in molecular collisions. The results of Part I, which referred to the particular case =1, are here extended to the more difficult case >1. For the rate of energy transfer we find exponential estimates of Nekhoroshev's type, namely of the form exp (_*/)^1/a , where is a positive real number giving the size of the involved frequencies, and _* anda are constants. For the particularly relevant constanta we find in generala=1/ however, in the particular case when the frequencies are equal (collision of identical molecules), we finda=1 independently of , as conjectured by Jeans in the year 1903.     

Schrödinger Operators with Empty Singularly Continuous Spectra

Let H be a semibounded perturbation of the Laplacian H ₀ in L ²( ^d ). For an admissible function sufficient conditions are given for the completeness of the scattering system (H), (H ₀). If is the exponential function and if e^{– H} is an integral operator we denote the kernel of the difference D = e^{– H} – e^{– H} ₀ by D (x, y), > 0. The singularly continuous spectrum of H is empty if^d dx ^d dy |D(x,y)| (1 + |y|²)< for some > 1. This result is applied to potential perturbations and to perturbations by imposing Dirichlet boundary conditions.     

Mean-Field Critical Behavior for the Contact Process

The contact process is a model of spread of an infectious disease. Combining with the result of ref. 1, we prove that the critical exponents take on the mean-field values for sufficiently high dimensional nearest-neighbor models and for sufficiently spread-out models with d>4:()– _c as _c and ()( _c–)^–1 as _c, where () and () are the spread probability and the susceptibility of the infection respectively, and _c is the critical infection rate. Our results imply that the upper critical dimension for the contact process is at most 4.     

Analysis of the order parameter for uniform nearest particle system

The uniform nearest particle system (UNPS) is studied, which is a continuoustime Markov process with state space . The rigorous upper bound ^(mf) = ( – 1)/ for the order parameter ₂, is given by the correlation identity and the FKG inequality. Then an improvement of this bound ^(mf) is shown in a similar fashion; C( – 1)/|log( – 1) for >1. Recently, Mountford proved that the critical value _c=1. Combining his result and our improved bound implies that if the critical exponent exists, it is strictly greater than the mean-field value 1 in the weak sense.     

Positron annihilation in synthetic zeolites (II) magnetic quenching effect

Positron lifetime spectra were re-measured for a series of synthetic zeolites using a large time window of observation. Magnetic quenching experiments were also performed for the zeolites, and it has been confirmed that both the ₄ and the ₃ components are due to o-Ps. The annihilation rate of the third component, ₃, showed a good correlation with the size of the largest voids, which is similar to the correlation reported for other compounds. However the annihilation rate of the longest-lived component, ₄, showed a poor correlation with the void size. The ₃ component has thus been assigned to o-Ps in the regular voids of the zeolites, and the ₄ component to that escaped to inter-particle open spaces.     

A relation between a.c. spectrum of ergodic Jacobi matrices and the spectra of periodic approximants

We study ergodic Jacobi matrices onl ²(Z), and prove a general theorem relating their a.c. spectrum to the spectra of periodic Jacobi matrices, that are obtained by cutting finite pieces from the ergodic potential and then repeating them. We apply this theorem to the almost Mathieu operator: (H _{, ,} u)(n)=u(n+1)+u(n–1)+ cos(2n+)u(n), and prove the existence of a.c. spectrum for sufficiently small , all irrational 's, and a.e. . Moreover, for 0<2 and (Lebesgue) a.e. pair , , we prove the explicit equality of measures: |_ac|=||=4 –2.Work partially supported by the US-Israel BSF     

Trapping and cascading of eigenvalues in the large coupling limit

We consider eigenvaluesE of the HamiltonianH =–+V+W,W compactly supported, in the limit. ForW0 we find monotonic convergence ofE to the eigenvalues of a limiting operatorH (associated with an exterior Dirichlet problem), and we estimate the rate of convergence for 1-dimensional systems. In 1-dimensional systems withW0, or withW changing sign, we do not find convergence. Instead, we find a cascade phenomenon, in which, as , each eigenvalueE stays near a Dirichlet eigenvalue for a long interval (of lengthO( )) of the scaling range, quickly drops to the next lower Dirichlet eigenvalue, stays there for a long interval, drops again, and so on. As a result, for most large values of the discrete spectrum ofH is close to that ofE , but when reaches a transition region, the entire spectrum quickly shifts down by one. We also explore the behavior of several explicit models, as .Max Kade Foundation FellowPartially supported by USNSF under Grant DMS-8416049On leave of absence from Department of Mathematics and Statistics, Case Western Reserve University, Cleveland, OH 44106, USA. Partially supported by USNSF under Grant DMS-8620231 and the Case Institute of Technology, RIG     

A solvable model exhibiting a glass-like transition

A nonlinear equation of motion of an overdamped oscillator exhibiting a glass-like transition at a critical coupling constant _c is presented and solved exactly. Below _c , in the fluid phase, the oscillator coordinatex(t) decays to zero, while above _c , in the amorphous phase, it decays to a nonzero infinite time limit. Near _c the motion is slowed down by a nonlinear feedback mechanism andx(t) decays exponentially to its long time limit with a relaxation time diverging as (1 – / _c )^–3/2 and (/ _c –1)^–1 for < _c and > _c respectively. At _c x(t) exhibits a power law decay proportional tot ^– with exponent -1/2.     

The Two Dimensional Hubbard Model at Half-Filling. I. Convergent Contributions

We prove analyticity theorems in the coupling constant for the Hubbard model at half-filling. The model in a single renormalization group slice of index i is proved to be analytic in for ||c/i for some constant c, and the skeleton part of the model at temperature T (the sum of all graphs without two point insertions) is proved to be analytic in for ||c/|log T|². These theorems are necessary steps towards proving that the Hubbard model at half-filling is not a Fermi liquid (in the mathematically precise sense of Salmhofer).     

The S-matrix for abstract scattering systems

Let S() be the S-matrix at energy for an abstract scattering system. We derive a bound, in terms of the interaction, on integrals of the form h () S()- _HS ² d, where denotes the Hilbert-Schmidt norm.Supported by the Swiss National Science Foundation.     

On the maximization of the central gravitational red-shift of a schwarzschild sphere with a given surface gravitational red-shift

Following Bondi static, spherically symmetric equilibrium configurations with a core and an envelope have been considered. It has been shown that for any configurations with nonnegative pressure and density and with a surface red-shiftz _s 4.77 arbitrarily large central red-shiftsz _c are possible in the limiting case of arbitrarily large radius. The effects of imposition of further constraints in the form of a real speed of sound not exceeding the speed of light are also examined. It is seen that for a given limiting sound-to-light-speed ratio . (i) There exists a limiting surface red-shiftz _s() 1.71. (ii) A configuration withz _s >z _s() is not possible, (iii) A configuration withz _s=z _s() has a unique and finitez _c=z _c(). (iv) Forz _s<z _s() arbitrarily large central red-shifts can be obtained for configurations with arbitrarily large radii.     

Kac-Moody symmetry of generalized non-linear Schrödinger equations

The classical non-linear Schrödinger equation associated with a symmetric Lie algebra =km is known to possess a class of conserved quantities which from a realization of the algebrak []. The construction is now extended to provide a realization of the Kac-Moody algebrak[, ^–1] (with central extension). One can then define auxiliary quantities to obtain the full algebra [, ^–1]. This leads to the formal linearization of the system.     

Effective stimulated emission and excited-state absorption cross-section spectra of para-phenylene-ethynylene polymers

The effective stimulated emission cross-section spectra, em,eff(), the stimulated emission cross-section spectra, em(), and the excited-state absorption cross-section spectra, ex()=em()–em,eff(), of the conjugated polymers poly(2,5-dioctadecyloxy-paraphenylene-ethynylene-co-2,5-thienyl) (OPT) and poly(2,5-dioctadecyloxy-paraphenylene-ethynylene-co-2,5-pyridinyl) (OPP) in tetrahydrofuran are determined in the fluorescence region. em,eff() determined by a fluorescence amplification technique is found to be small compared to em() indicating that ex() is nearly as large as em(). The laser excitation to the wide inhomogeneously broadened S1-absorption band leads to the formation of spectrally structured inhomogeneously broadened lattice relaxed exciton conformations extending on average over two monomer units which are thought to be responsible for upper-to-lower-state stimulated emission and lower-to-upper-state (excited-state) absorption.     

The lateral photovoltaic effect in CdS-Cu2S heterojunction solar cell

The lateral photovoltaic effect has been observed in CdS-Cu₂S thin-film solar cells. The effect is more pronounced on the CdS side than on the Cu₂S side of the cells. On the CdS side, where the contacts were formed by soldering Cu wire by indium and then applying Ag paint, the photovoltage developed were found to increase as the point of illumination was moved towards the contact. The spectral response of photovoltage for coevaporated cells shows a peak at=0.5m (2.45 eV). But for topotaxial cells two peaks, one at=0.5m and the other at=0.65m (1.89eV) were observed. A band model has been proposed for the heat-treated optimized cells.     

Theory of fluctuations in limit-cycles of second-order bifurcation type

The fluctuations in limit cycles of second-order bifurcation (transition from a stable to an unstable focus) are investigated near the bifurcation point _c, being an external control parameter. Two different methods are applied: a time- and space-dependent Fokker-Planck equation obtained from an ^1/2-expansion of the master equation ( being the volume) and a time- and space-dependent Langevin equation. Both methods give the same results. It is shown that the dependence of the radial correlation on ² = | – _c| and the time-behaviour of the phase correlation (ensemble dephasing) are determined by the dimensionality of space.     

Determination of the Coefficient of Laser Radiation Reflection from Dielectric Targets in Vacuum

We present the results of experimental determination of the coefficients of laser radiation reflection (₁ 10.6 m and ₂ 1.06 m) from dielectric targets of complex chemical composition in vacuum with allowance for a regime of developed plasma formation.     

The asymmetric contact process on a finite set

The contact process onZ has one phase transition; let _c be the critical value at which the transition occurs. Let _N be the extinction time of the contact process on {0,...,N}. Durrett and Liu (1988), Durrett and Schonmann (1988), and Durrett, Schonmann, and Tanaka (1989) have respectively proved that the subcritical, supercritical, and critical phases can be characterized using a large finite system (instead ofZ) in the following way. There are constants ₁() and ₂() such that if < _c , lim _{N N} /logN = 1/₁(); if > _c , lim _N log _N /N = ₂(); if = _c , lim _{N N} /N= and lim _{N N} /N ⁴=0 in probability. In this paper we consider the asymmetric contact process onZ when it has two distinct critical values _c1< _c2. The arguments of Durrett and Liu and of Durrett and Schonmann hold for < _c1 and > _c2. We show that for [ _c1< _c2), lim _{N N} /N=-1/, (where _i is an edge speed) and for = _c2, lim _N log _N /logN=2 in probability.     

Superradiating 4P-4S-3P cascade of sodium vapour arising on the leading edge of the exciting laser pulse

Investigations of the superradiating cascade of sodium vapour 4P-4S-3P ₁ = 2.21 µm and ₂=1.14 µm) arising on the leading edge of the exciting laser pulse were carried out. The dependences of the actual delay time _D of the ₁ pulse on the population rise time of the laser-excited 4P state were measured and compared with those calculated following the existing theoretical model. The dependence of the actual delay time _D on the inverse density of excited atoms 1/N* is also presented. Analysis of this dependence revealed the influence of the Doppler dephasing and of the second, ₂, transition on the formation of the ₁ superradiance.     

The asymmetric contact process at its second critical value

The asymmetric contact process onZ has two distinct critical values ₁ > ₂ (at least with sufficient asymmetry). One can consider the process on {0,...,N} and analyze the time (which we call _N ) till complete vacany starting from complete occupation. Its behavior has already been resolved for all regions of except for =₂. For this value, Schinazi proved that lim _N log _N /logN=2 in probability and conjectured that _N /N ² converges in distribution. It is that result that we prove in this paper. We rely heavily on the Brownian motion behavior of the edge particle, which comes from Galves and Presutti and Kuczek.