一类爆轰合成用乳化炸药的爆轰反应特征

结合热分解特性、爆轰产物状态及数值计算探讨所制备的含Fe、Mn(Zn)元素乳化炸药的爆轰反 应特征。对该系列乳化炸药及其爆轰产物分别进行DSC和DTG实验、XRD检测和TEM 表征,通过比较不 同类型炸药及其爆轰产物的热分解特征、爆轰产物的成分和形貌、晶型畸变度等研究该类炸药爆轰反应特征; 并通过数值计算研究和佐证了不同温度和压强状态下,爆轰固体产物可能存在状态。结果表明:硝酸铵有利 于炸药爆轰时形成相对比较均匀和平稳的爆轰反应结构,而这种结构有利于可重复性合成比较单一和均匀 的爆轰产物。高密度炸药的爆轰产物比低密度炸药的相对纯净。低密度炸药不完全爆轰,导致了爆轰产物杂 质较多;数值计算结果表明,爆轰固体产物分布相图可以辅助分析爆轰固体产物可能存在状态及Mn(Zn)的 爆轰合成机制。     

Magnetoelastic fracture of soft ferromagnetic materials

Effects of magnetic field on fracture toughness of soft ferromagnetic materials were studied using experimental techniques and theoretical models. The manganese–zinc ferrite with a single-edge-notch-beam (SENB) were chosen to be the specimen and the Vickers’ indentation specimen subjected to a magnetic field were chosen to be the specimens. Results indicate that there is no significant variations of the measured fracture toughness of the manganese–zinc ferrite ceramic in the presence of the magnetic field. The theoretical model involves an anti-plane shear crack with finite length in an infinite magnetostrictive body where an in-plane magnetic field prevails at infinity. Magnetoelasticity is used. The crack-tip elastic field is different from that of the classical mode III fracture problem. Furthermore, the magnetoelastic fracture of the soft ferromagnetic material was studied by solving the stress field for a soft ferromagnetic plane with a center-through elliptical crack. The stress field at the tip of a slender elliptical crack is obtained for which only external magnetic field normal to the major axis of the ellipse is applied at infinity. The results indicate that the near field stresses are governed by the magnetostriction and permeability of the soft ferromagnetic material. The induction magnetostrictive modulus is a key parameter for finding whether magnetostriction or magnetic-force-induced deformation is dominant near the front an elliptically-shaped crack. The influence of the magnetic field on the apparent toughness of a soft ferromagnetic material with a crack-like flaw can be regarded approximately in two ways: one possesses a large induction magnetostrictive modulus and the other has a small modulus. Finally, a small-scale magnetic-yielding model was developed on the basis of linear magnetization to interpret the experimental results related to the fracture of the manganese–zinc ferrite ceramics under magnetic field. Studied also is the fracture test of the soft ferromagnetic steel with compact tension specimens published in the existing literature.     

Flow boiling enhancement of FC-72 from microporous surfaces in minichannels

The microporous coatings can remarkably enhance the liquid boiling heat transfer. Therefore, they are promising to be introduced into minichannels in the design of the cooling system of high-power microchips. However, the flow boiling heat transfer characteristics from microporous surfaces in the minichannels have not been extensively studied, and the pertinent knowledge is rather fragmentary. The present research is an experimental investigation on flow boiling of a dielectric fluid FC-72 from microporous coating surfaces in horizontal, rectangular minichannels of 0.49, 0.93 and 1.26 mm hydraulic diameter. Effects of coating structural parameters, such as the particle diameter and coating thickness, were investigated to identify the optimum microporous coating for heat transfer enhancement. All microporous surfaces in this paper were found to significantly enhance FC-72 flow boiling heat transfer in minichannels. With the optimum coating, the heat transfer coefficients could be 7-10 times those of the uncoated surface, and the boiling wall temperature was reduced by about 10 K. The flow boiling phenomena in the present minichannels were distinctly different from those in conventional-sized channels, due to the wall confinement effect on vapor bubbles. The confinement effect was evaluated by taking the contributions of the liquid mass flux and channel size into consideration. It was found that the very strong confinement effect was unfavorable with respect to flow boiling enhancement of the microporous coatings in the minichannels.     

Micromechanics of cleavage fracture initiation in ferritic steels by carbide cracking

Cleavage fracture in ferritic steels is often initiated in brittle carbides randomly distributed in the material. The carbides break as a result of a fibre loading mechanism in which the stress levels in the carbides are raised, as the surrounding ferrite undergoes plastic deformation. The conditions in the vicinity of the nucleated micro-crack will then determine whether the crack will penetrate or be arrested by the ferrite. The ferrite is able to arrest nucleated cracks through the presence of mobile dislocations, which blunt and shield the microcrack and thus lowers the stresses at the crack tip. Hence, the macroscopic toughness of the material directly depends on the ability of the ferrite to arrest nucleated micro-cracks and in turn on the plastic rate sensitivity of the ferrite. The initiation of cleavage fracture is here modelled explicitly in the form of a micro-crack, which nucleates in a brittle carbide and propagates into the surrounding ferrite. The carbide is modelled as an elastic cylinder or in a few cases an elastic sphere and the ferrite as an elastic viscoplastic material. The crack growth is modelled using a cohesive surface, where the tractions are governed by a modified exponential cohesive law. It is shown that the critical stress, required to propagate a microcrack from a broken carbide, increases with decreasing plastic rate sensitivity of the ferrite. The results also show that a low stress triaxiality and a high aspect ratio of the carbide promote the initiation of cleavage fracture from a broken carbide.     

微孔膜对锌空气电池失水的影响

将不同规格的微孔膜覆盖于锌空气电池气体扩散电极表面,探究微孔膜对锌空气电池失水和性能的影响。实验结果表明:在微孔间距小于临界间距时,覆盖微孔膜可使锌空气电池的失水量减少40%~80%,而不会阻碍氧气的传输。微孔数目越少,电池失水量越少,放电性能也越好。当微孔间距达到临界值时,电池失水量达到最小值。氧气在微孔膜上的通量远高于水蒸汽在微孔膜上的通量。     

A NOVEL HYDROTHERMAL SYNTHESIS METHOD FOR BARIUM FERRITE

In the present work, fine barium ferrite powder has been synthesized through a one-step hydrothermal process in an autoclave at [OH^-]/[Cl^-] ratio of 2:1 in the temperature range from 180 to 260℃ using barium chloride(BaCl2), ferrous chloride (FeCl2) and potassium nitrate (KNO3) as the starting materials. Both particle size and saturation magnetization (Ms) increase with increasing hydrothermal reaction temperature, while the intrinsic coercivity (iHc) peaks at 685 Oe at 230℃. Morphology progress from the barium ferrite precursor particles to the barium hexaferrite particles has been monitored with increasing hydrothermal reaction time at 230℃ in the autoclave.     

Optically sliced measurement of velocity and pH distribution in microchannel

A simultaneous measurement technique for the velocity and pH distribution was developed by using a confocal microscope and a 3CCD color camera for investigations of a chemical reacting flow field in a microchannel. Micron-resolution particle image velocimetry and laser induced fluorescence were utilized for the velocity and pH measurement, respectively. The present study employed fluorescent particles with 1 μm diameter and Fluorescein sodium salt whose fluorescent intensity increases with an increase in pH value over the range of pH 5.0–9.0. The advantages of the present system are to separate the fluorescence of particles from that of dye by using the 3CCD color camera and to provide the depth resolution of 5.0 μm by the confocal microscope. The measurement uncertainties of the velocity and pH measurements were estimated to be 5.5 μm/s and pH 0.23, respectively. Two aqueous solutions at different pH values were introduced into a T-shaped microchannel. The mixing process in the junction area was investigated by the present technique, and the effect of the chemical reaction on the pH gradient was discussed by a comparison between the proton concentration profiles obtained from the experimental pH distribution and those calculated from the measured velocity data. For the chemical reacting flow with the buffering action, the profiles from the numerical simulation showed smaller gradients compared with those from the experiments, because the production or extinction of protons was yielded by the chemical reaction. Furthermore, the convection of protons was evaluated from the velocity and pH distribution and compared with the diffusion. It is found that the ratio between the diffusion and convection is an important factor to investigate the mixing process in the microfluidic device with chemical reactions.     

Synthesis and stability evaluation of hierarchical silicoaluminophosphates with different structural frameworks in the methanol to olefins process

Silicoaluminophosphates (SAPOs) with different pore structures were synthesized through the implementation of polyethylene glycol (PEG) as a mesopores impregnation agent. Using PEGs with different molecular weights (MWs) and concentrations in the synthesis precursor, several samples were synthesized and characterized. Applying a PEG capping agent to the precursors led to the formation of tuned mesopores within the microporous matrix of the SAPO. The effects of the PEG molecular weight and PEG/Al molar ratio were investigated to maximize the efficiency of the catalyst in the methanol-to-olefin (MTO) process. Using PEG with a MW of 6000 resulted in the formation of both Zeolite Rho and chabazite structural frameworks (i.e., DNL-6 and SAPO-34). Pure SAPO-34 samples were successfully prepared using PEG with a MW of 4000. Our results showed that the PEG concentrations affect the porosity and acidity of the synthesized materials. Furthermore, the SAPO-34 sample synthesized with PEG (MW of 4000) and a PEG/Al molar ratio of 0.0125 showed a superior catalytic stability in the MTO reaction owing to the tuned bi-modal porosity and tailored acidity pattern. Finally, through reactivation experiments, it was found that the catalyst is stable even after several regeneration cycles.     

Nickel doped zinc oxide nanoparticles produced by hydrothermal decomposition of nickel-doped zinc hydroxide nitrate

Zinc hydroxide nitrate, an anionic exchanger layered material, undoped as well as doped with 2–10% nickel, was synthesized by using a pH-controlled precipitation method. The layered materials were then used to produce the undoped and nickel-doped zinc oxides by hydrothermal-treatment. X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy confirmed the formation of pure phase undoped and nickel-doped layered materials, as well as the products of the hydrothermal-treated materials, nanostructured zinc oxides. Optical studies of the nanostructured zinc oxides showed a decrease in band gap with increasing content of the doping agent, nickel.     

Jump Condition for Diffusive and Convective Mass Transfer Between a Porous Medium and a Fluid Involving Adsorption and Chemical Reaction

In this paper, mass transfer at the fluid–porous medium boundaries is studied. The problem considers both diffusive and convective transport, along with adsorption and reaction effects in the porous medium. The result is a mass flux jump condition that is expressed in terms of effective transport coefficients. Such coefficients (a total dispersion tensor and effective reaction and adsorption coefficients) may be computed from the solution of the corresponding closure problem here stated and solved as a function of the Péclet number (Pe), the porosity and a local Thiele modulus. For the case of negligible convective transport (i.e., ), the closure problem reduces to the one recently solved by the authors for diffusion and reaction between a fluid and a microporous medium.     

含纳微米硼酸盐和二烷基二硫代磷酸锌液体石蜡润滑下钢—钢体系的摩擦磨损性能研究

在四球试验机上考察了含纳微米硼酸盐及二烷基二硫代磷酸锌（ZDDP）复配添加剂的液体石蜡润滑下钢－钢摩擦副的摩擦学性能。采用X射线光电子能谱仪和扫描电子显微镜分析了复配体系的作用机理。结果表明：纳微米硼酸盐／ZDDP复配添加剂对钢－钢摩擦副的抗磨作用产生对抗效应，在摩擦过程中的某一阶段摩擦系数突然升高，磨损加剧；在试验初期，磨斑表面较为光滑，相应的边界润滑膜为物理和化学吸附膜；随着试验时间的延长，钢球磨斑表面吸附膜表面破裂，磨斑表面变得粗糙并形成微小磨屑碎片，相应的摩擦系数突然升高；随着试验时间的进一步延长，添加剂同钢球磨损表面发生摩擦化学反应，并生成含B、N、S和P等元素的摩擦化学反应膜，从而使摩擦系数波动减小。     

应力和组分占比对马氏体-铁素体双相钢中磁巴克豪森噪声的影响

磁巴克豪森噪声(MBN)技术在马氏体-铁素体双相钢的微观结构及应力无损评价与表征中具有巨大潜力.为探究拉应力和铁素体占比对磁巴克豪森噪声的影响规律及权重,在0?200MPa范围内实验测得了具有不同铁素体占比的双相钢MBN信号.重点分析了MBN蝶形曲线双峰峰值(分别代表马氏体和铁素体)在应力和铁素体占比两因素耦合条件下的...     

基于均匀化理论的页岩微观多孔黏土强度特性

页岩强度是页岩油气开发所必需的基础技术参数之一,对页岩强度的研究贯穿于钻完井、压裂工艺施工的全过程.常规宏观室内实验存在试样获取困难、耗时较长,受井下工矿制约,地球物理方法获取资料品质欠佳且增加了井下设备卡、埋风险.因此,提出基于均匀化理论评价页岩微观多孔黏土强度的方法,进行多孔黏土组成与力学分析.基于耗散能原理和Drucker-Prager准则,开展了微观多孔黏土的强度与$\pi$函数的应变求解分析;讨论黏土颗粒与粒间孔隙的力学特性,建立多孔黏土的均匀化应变能;采用强度均匀化理论构建微观非线性函数模型,建立与多孔黏土组成、摩擦系数、内聚系数等参数相关的均匀化函数模型;基于纳米力学实验、量纲分析和有限元模拟,分析多孔黏土硬度、强度与组成的内在关系.研究结果表明,页岩微观多孔黏土的弹性模量和硬度与黏土堆积密度正相关,当黏土堆积密度一定时,硬度与内聚系数的比值受摩擦系数影响较大,为非线性递增;通过量纲分析和有限元模拟,求解页岩微观多孔黏土关于硬度--强度--堆积密度的$\pi$函数,揭示页岩微观黏土矿物的组成与力学性质的关系,为进一步深入研究页岩细观强度参数和宏观强度预测奠定基础.      

D2车轮钢原始组织对滑动磨损性能的影响

采用MRH-5A型环块磨损试验机对D2车轮钢及U71Mn钢轨钢采取对摩方式进行滑动磨损试验,研究原始组织对D2车轮钢滑动磨损性能的影响. 结果表明:以回火索氏体(TS)为原始组织的D2车轮钢比片状珠光体组织(P)+先共析铁素体(F)的D2车轮钢具有更好的耐磨性能. P+F和TS表面磨损机制均以磨粒磨损和黏着磨损为主,而P+F表面磨损更严重且伴随大块白层剥落现象. TS塑性变形层更薄,其内的铁素体细化成纳米晶,粒状渗碳体不发生剪切变形,主要以溶解为主,不易形成较厚的白层,不发生大块剥落现象,提高耐磨性能.      

Micromechanics of plastic deformation and phase transformation in a three-phase TRIP-assisted advanced high strength steel: Experiments and modeling

The micromechanics of plastic deformation and phase transformation in a three-phase advanced high strength steel are analyzed both experimentally and by microstructure-based simulations. The steel examined is a three-phase (ferrite, martensite and retained austenite) quenched and partitioned sheet steel with a tensile strength of ~980 MPa. The macroscopic flow behavior and the volume fraction of martensite resulting from the austenite–martensite transformation during deformation were measured. In addition, micropillar compression specimens were extracted from the individual ferrite grains and the martensite particles, and using a flat-punch nanoindenter, stress–strain curves were obtained. Finite element simulations idealize the microstructure as a composite that contains ferrite, martensite and retained austenite. All three phases are discretely modeled using appropriate crystal plasticity based constitutive relations. Material parameters for ferrite and martensite are determined by fitting numerical predictions to the micropillar data. The constitutive relation for retained austenite takes into account contributions to the strain rate from the austenite–martensite transformation, as well as slip in both the untransformed austenite and product martensite. Parameters for the retained austenite are then determined by fitting the predicted flow stress and transformed austenite volume fraction in a 3D microstructure to experimental measurements. Simulations are used to probe the role of the retained austenite in controlling the strain hardening behavior as well as internal stress and strain distributions in the microstructure.     

等离子喷涂铁基涂层的疲劳磨损裂纹行为

采用等离子喷涂制备了铁基涂层,使用球盘式疲劳磨损试验机进行涂层的疲劳磨损试验,利用声发射技术在线判断涂层开裂,并通用透射电子显微镜（TEM）分析了试验前后涂层内部微观结构,研究了喷涂层疲劳磨损裂纹的扩展行为。结果表明：制备的涂层致密,结合状态良好,主要相为铁素体,同时存在大量的非晶-纳米晶相,利用声发射技术能够表征涂层的临界失效状态,其内部疲劳磨损裂纹主要以韧性穿晶断裂的形式扩展。     

Rate effects on toughness in elastic nonlinear viscous solids

A micromechanics-based constitutive relation for void growth in a nonlinear viscous solid is proposed to study rate effects on fracture toughness. This relation is incorporated into a microporous strip of cell elements embedded in a computational model for crack growth. The microporous strip is surrounded by an elastic nonlinear viscous solid referred to as the background material. Under steady-state crack growth, two dissipative processes contribute to the macroscopic fracture toughness—the work of separation in the strip of cell elements and energy dissipation by inelastic deformation in the background material. As the crack velocity increases, voids grow in the strain-rate strengthened microporous strip, thereby elevating the work of separation. In contrast, the energy dissipation in the background material decreases as the crack velocity increases. In the regime where the work of separation dominates energy dissipation, toughness increases with crack velocity. In the regime where energy dissipation is dominant, toughness decreases with crack velocity. Computational simulations show that the two regimes can exist in certain range of crack velocities for a given material. The existence of these regimes is greatly influenced by the rate dependence of the void growth mechanism (and the initial void size) as well as that of the bulk material. This competition between the two dissipative processes produces a U-shaped toughness-crack velocity curve. Our computational simulations predict trends that agree with fracture toughness vs. crack velocity data reported in several experimental studies for glassy polymers and rubber-modified epoxies.     

单轴拉伸过程中双相不锈钢局部微观变形行为的细观力学有限元分析

针对双相不锈钢中奥氏体相和铁素体相分别展开了纳米压痕实验,并通过有限元反演得到两相各自的拉伸应力-应变关系,利用Voronoi Tessellation法生成代表性的微结构体积单元,对双相不锈钢的单轴拉伸行为进行了有限元仿真和模拟,研究了双相不锈钢在拉伸过程中的局部应力、应变分布和演化规律．结果表明,利用Voronoi Tessellation法建立单元模型,结合本文通过纳米压痕实验获取的两相力学性能参数,可以很好地模拟双相不锈钢的整体单拉行为,奥氏体比铁素体软,拉伸载荷下双相不锈钢的应变集中在奥氏体中,应力集中在铁素体中;局部应力应变的分布特征与两相分布特征和晶粒形状有关,最大应变值主要集中在奥氏体晶粒狭长且尖锐的区域,而最大应力则主要发生在铁素体晶粒狭长和尖锐的区域;对于奥氏体和铁素体晶粒占比相当的双相不锈钢,其虽然可以具有较为综合的宏观力学性能,但是其微观应力集中的区域和应力最大值相对较大．研究成果为进一步揭示双相不锈钢局部失效机理奠定了基础．     

Dynamic Thermal Deformation Measurement of Large-Scale, High-Temperature Piping in Thermal Power Plants Utilizing the Sampling Moiré Method and Grating Magnets

Fast and accurate deformation measuring techniques show promising potential for monitoring high-temperature piping and other machinery in the energy sector, such as in thermal, steam, or nuclear power plants. Optics-based, nonintrusive, and real-time monitoring systems are critical for preventing high-temperature steam leaks, unexpected accidents, explosions, and other failures that can have catastrophic consequences for the power supply, the workers, and the public. In this study, a dynamic thermal deformation measurement technique utilizing the sampling Moiré method and grating magnets is developed for large-scale, high-temperature piping in a thermal power plant. Because of the high temperature of the piping of nearly 300 °C several 100 mm by 100 mm ferrite magnets were placed to select locations of the high-temperature piping. In each ferrite magnet, a regular, two-dimensional binary grating pattern with a pitch of 15 mm was painted on the surface, and the grating magnets were used as the reference grating to analyze the small in-plane displacement distribution using the sampling Moiré method. A compensation method of misalignment angle is also proposed to improve the measurement accuracy. The effect on vibration remove, mirage due to conversion in air, wide angle of camera lens, and compensation of misalignment angle, are discussed. The experimental results showed that our measurement technique is suitable for evaluation of high-temperature, large-scale infrastructure.     

Poromechanics of microporous media

Microporous media, i.e., porous media made of pores with a nanometer size, are important for a variety of applications, for instance for sequestration of carbon dioxide in coal, or for storage of hydrogen in metal-organic frameworks. In a pore of nanometer size, fluid molecules are not in their bulk state anymore since they interact with the atoms of the solid: they are said to be in an adsorbed state. For such microporous media, conventional poromechanics breaks down.In this work we derive poroelastic constitutive equations which are valid for a generic porous medium, i.e., even for a porous medium with pores of nanometer size. The complete determination of the poromechanical behavior of a microporous medium requires knowing how the amount of fluid adsorbed depends on both the fluid bulk pressure and the strain of the medium. The derived constitutive equations are validated with the help of molecular simulations on one-dimensional microporous media. Even when a microporous medium behaves linearly in the absence of any fluid (i.e., its bulk modulus does not depend on strain), we show that fluid adsorption can induce non-linear behavior (i.e., its drained bulk modulus can then depend significantly on strain). We also show that adsorption can lead to an apparent Biot coefficient of the microporous medium greater than unity or smaller than zero.The poromechanical response of a microporous medium to adsorption significantly depends on the pore size distribution. Indeed, the commensurability (i.e., the ratio of the size of the pores to that of the fluid molecules) proves to play a major role. For a one-dimensional model of micropores with a variety of pore sizes, molecular simulations show that the amount of adsorbed fluid depends linearly on the strain of the medium. We derive linearized constitutive equations which are valid when such a linear dependence of the adsorbed amount of fluid on the strain is observed.As an application, the case of methane and coal is considered. Molecular simulations of an adsorption of methane on a microporous realistic model for coal are performed with a flexible solid skeleton. The applicability of the set of linearized constitutive equations to this case is discussed and the results are shown to be consistent with swelling data measured during a classical adsorption experiment.