New laser dyes based on 3-imidazopyridylcoumarin derivatives

A comparative analysis of the spectral-luminescent characteristics and generation parameters of a number of 3-imidazopyridylcoumarin derivatives has been carried out under nano- and microsecond excitation by coherent and incoherent light. New coumarin dyes are offered that feature the ability to lase under different types of pumping in the spectral range 525–580 nm; high lasing efficiency reaching 20% and 1% under laser and lamp pumping, respectively; and high photochemical stability (3–5 times higher than that of rhodamine 6 G) under conditions of powerful nonmonochromatic pumping.     

Photoacoustic studies on excitation transfer in Rh6G and RhB dye mixture

The photoacoustic spectra of Rhodamine 6G (Rh6G), Rhodamine B (RhB) dyes and their mixtures were recorded at different concentrations. It is observed that in the mixture the photoacoustic signal increases due to excitation transfer from Rh6G to RhB in the wavelength region 480–530 nm. The excitation transfer rate estimated from these data show that resonance is dominant rather than the collisional transfer process.     

Photoacoustic spectra of some laser dyes

Photoacoustic spectra of rhodamine 110, rhodamine 6 G, rhodamine B, rhodamine 101 and coumarin 102 laser dyes have been recorded at room temperature of 25°C in the spectral range of 350–750 nm. These samples were taken in powder as well as in solution forms. For this purpose the closed and the open photoacoustic cells have been used. It is hoped the present study would be useful for characterization of these dyes.     

Dual-band lasing of benzopyran dyes in the red region of the spectrum

We have studied the spectral and energy characteristics of lasing for two benzopyran dyes in a dispersive cavity with a diffraction grating when the dyes are excited at several different wavelengths using an additional flashlamp-pumped dye laser. These dyes have high fluorescence quantum yield and lase efficiently in the red region of the spectrum. The tuning range of their lasing spectrum is greater than 100 nm. We discuss the characteristic features of conversion of the selective excitation energy by these dye molecules. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 3, pp. 401–404, May–June, 2006.     

Indirect magnetic interaction in the “net fractal” systems

A localized spin system of fractal symmetry with indirect exchange between them is considered. We define a specific class of fractals as the “net fractals” which display multidimensional logarithmic periodicity. Basing on this property we model the effective indirect exchange interaction by the conventional RKKY exchange with the logarithmic coordinates playing role of the real space ones. Finally, we discuss the case of non-ideal “net fractals” in which fractional dynamics of the electrons is expected. In this case we show that RKKY exchange integrals are given by the formulas derived under assumption that a system has a fractional spectral dimension.     

Calculation of the vibronic transition moment when the geometries of the combining states of the molecules are significantly different

The concept of the adiabatic approximation is introduced from a few new standpoints, and the conditions are refined under which we can assume that the total energy of an electronic-vibrational (vibronic) state is the sum of the energies of the “electronic” and the “nuclear” problems and the wave function is represented as the product of the corresponding functions. An expression exactly corresponding to such an approximation is considered for the optical transition matrix element, and its individual terms are analyzed for any change in the geometric structure of the molecule upon optical excitation. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 3, pp. 290–293, May–June, 2006.     

Bergmann–Thomson Energy-Momentum Complex for Solutions More General than the Kerr–Schild Class

In a very well-known paper, Virbhadra’s research group proved that the Weinberg, Papapetrou, Landau and Lifhsitz, and Einstein energy-momentum complexes “coincide” for all metrics of Kerr–Schild class. A few years later, Virbhadra clarified that this “coincidence” in fact holds for metrics more general than the Kerr–Schild class. In the present paper, this study is extended for the Bergmann–Thomson complex and it is proved that this complex also “coincides” with those complexes for a more general than the Kerr–Schild class metric.     

Energy migration in DNA evaluated by the sensitized fluorescence of an intercalation dye

An equation is obtained to calculated the efficiency of energy migration along a biopolymer with transfer of excitation to a fluorescence dye using excitation and absorption spectra. With the aid of bromoethydium intercalating into DNA-phage it is shown that in a solution at room temperature energy is transferred to it only from one or two neighboring nucleotides. The low efficiency of energy migration in relation to DNA under these conditions is explained by the low probability of each event of “cold” and “hot” migration. Institute of Cell Biophysics of the Russian Academy of Sciences, Pushchino, 142292, Moscow Region, Russia. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 65, No. 5, pp. 794–798, September–October, 1998.     

Einstein’s “Zur Elektrodynamik...” (1905) Revisited, With Some Consequences

Einstein, in his “Zur Elektrodynamik bewegter K?rper”, gave a physical (operational) meaning to “time” of a remote event in describing “motion” by introducing the concept of “synchronous stationary clocks located at different places”. But with regard to “place” in describing motion, he assumed without analysis the concept of a system of co-ordinates.In the present paper, we propose a way of giving physical (operational) meaning to the concepts of “place” and “co-ordinate system”, and show how the observer can define both the place and time of a remote event. Following Einstein, we consider another system “in uniform motion of translation relatively to the former”. Without assuming “the properties of homogeneity which we attribute to space and time”, we show that the definitions of space and time in the two systems are linearly related. We deduce some novel consequences of our approach regarding faster-than-light observers and particles, “one-way” and “two-way” velocities of light, symmetry, the “group property” of inertial reference frames, length contraction and time dilatation, and the “twin paradox”. Finally, we point out a flaw in Einstein’s argument in the “Electrodynamical Part” of his paper and show that the Lorentz force formula and Einstein’s formula for transformation of field quantities are mutually consistent. We show that for faster-than-light bodies, a simple modification of Planck’s formula for mass suffices. (Except for the reference to Planck’s formula, we restrict ourselves to Physics of 1905.)     

Anti-stokes fluorescence of polymethine dyes excited by a titanium-sapphire laser

Fluorescence of symmetric polymethine dye solutions (λ _abs ^max ≈ 700 nm) upon anti-Stokes excitation by cw radiation of a titanium-sapphire laser (781 nm) is first investigated. A series of six compounds with analogous composition and spectral and luminescent properties is investigated. It is demonstrated that in addition to the anti-Stokes component, the Stokes component with a maximum at 820 nm (referred to the H-aggregates of initial dyes) is observed in the fluorescence spectra of solutions of the examined molecules when dye concentration increases to 10⁻³ M. Dependences of the anti-Stokes and Stokes component intensities on the exciting radiation power are obtained that confirm a linear excitation character. On examples of xanthene and polymethine dyes, the use of organic fluorophors for anti-Stokes laser cooling and some other possible applications of the anti-Stokes fluorescence are discussed. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 63–70, March, 2007.     

Composite boson many-body theory for Frenkel excitons

We present a many-body theory for Frenkel excitons which takes into account their composite nature exactly. Our approach is based on four commutators similar to the ones we previously proposed for Wannier excitons. They allow us to calculate any physical quantity dealing with N excitons in terms of “Pauli scatterings” for carrier exchange in the absence of carrier interaction and “interaction scatterings” for carrier interactions in the absence of carrier exchange. We show that Frenkel excitons have a novel “transfer assisted exchange scattering”, specific to these excitons. It comes from indirect Coulomb processes between localized atomic states. These indirect processes, commonly called “electron-hole exchange” in the case of Wannier excitons and most often neglected, are crucial for Frenkel excitons, as they are the only ones responsible for the excitation transfer. We also show that in spite of the fact that Frenkel excitons are made of electrons and holes on the same atomic site, so that we could naively see them as elementary particles, they definitely are composite objects, their composite nature appearing through various properties, not always easy to guess. The present many-body theory for Frenkel excitons is thus going to appear as highly valuable to securely tackle their many-body physics, as in the case of nonlinear optical effects in organic semiconductors.     

“Non-Gibbsian” States and their Gibbs Description

The driving principle behind this paper is the following thesis: “Every physically reasonable random field has to be a Gibbs random field”. In this paper the so-called “non-Gibbsian” random fields are considered. The usual definition of the Gibbs field is generalized in such a way so as to include some of the discovered “non-Gibbsian” fields. The new definition is then used to show that the projection of the two-dimensional Ising model onto the one-dimensional sublattice ℤ¹ falls into the class of the generalized Gibbs fields. Received: 13 March 1998 / Accepted: 19 June 1998     

Collective excitations in small carbon cluster

We apply the time-dependent local density approximation to the small carbon clusters. The carbon clusters of chain and ring shapes are found to show strong π-electron transitions. An interpretation is given for them as the one-dimensional plasmon excitation. Presented by K. Yabana at the International Conference on “Atomic Nuclei and Metallic Clusters”, Prague, September 1–5, 1997.     

Generation of singlet oxygen by indotricarbocyanine dyes in low-polarity media

We present the results of a study of the spectral luminescence properties of three groups of indotricarbocyanine dyes, each of which is formed from compounds with the same cation and different anions. In high-polarity solvents, in the absorption and emission spectra of the dyes we see one type of center; in low-polarity solvents, due to the presence of different ionic forms of the dyes (free ions, contact ion pairs), we observe either one type or two types of centers. By analysis of the luminescence of molecular oxygen in the 1.27 μm spectral region, we determined the efficiency of photosensitization of ¹O₂ formation by dyes in deuterated solvents. We have shown that in low-polarity solvents, the yield for singlet oxygen generation is higher for indotricarbocyanine dyes which are found in the contact ion pair state and which also contain a heavy atom (I) in the anion. We have observed that an increase in the fraction of contact ion pairs in solution as the dye concentration increases or when an additional salt is introduced leads to an increase in the quantum yield for generation of singlet oxygen. In polar deuterated acetonitrile, the counterion has no effect on the efficiency of photosensitization of oxygen by the dyes. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 5, pp. 684–693, September–October, 2008.     

Spectroscopic properties of DNA-acridine orange biopolymer films

Using electronic absorption, luminescence, and vibrational spectroscopy, we study the properties of DNA-acridine orange biopolymer films. The conformational structure of DNA molecules in the film is examined at different levels of the relative humidity, and the state of dye molecules incorporated into the structure of the biopolymer is estimated. These structures were formed according to the “guest-host” principle and the dye molecule acts as the “guest” and the “host” is the intercalative DNA binding sites. In such system dye molecules demonstrate high luminescence capability and are the uniform optical centers and their fluorescence spectrum doesn’t depend on excitation wavelength.     

Simultaneous antigen detection using multiplex dyes

To detect several antigens simultaneously, antibodies directed against different antigens were immobilized on a quartz surface. The antigens were tagged with multiplex, dyes, which show different fluorescence lifetimes but similar excitation and emission spectra. The antigens were detected by recognizing the characteristic fluorescence lifetime. Furthermore, the effect of labeling of the dye on the antigen molecules was examined.     

Some distinctive features in the behavior of small-scale artificial ionospheric irregularities at mid-and high latitudes

We present the results of experimental studies of some features in the behavior of small-scale artificial irregularities (SSAIs) at mid-and high latitudes based on the “Sura” and EISCAT/HEATING HF facilities. Observations were performed by the method of aspect scattering using a network of diagnostic paths having a common reception point located near St. Petersburg. We found that an extremely long duration of the second (slow) stage of SSAI relaxation of up to 5 min occurs in the evening hours when the ionosphere above the “Sura” facility is illuminated by the Sun, but the solar terminator travels through the magnetically conjugated ionosphere. The conjecture is made that the processes initiated by the terminator are mostly responsible for secondary ionospheric turbulence maintaining the irregularities above “Sura.” A drastic increase in the Doppler spectra width of the scattered signals is revealed when the magnetically conjugate point of the ionosphere is located on the shade side of the terminator, but the ionosphere above the “Sura” facility is still lighted. It is assumed that the “ run away” of photoelectrons from the day to the night side could reduce the threshold of excitation of artificial irregularities, leading to an increase in their intensity. The presence of fairly intense scattered signals was detected from the “Sura” and EISCAT/HEATING experimental results both under conditions of pulsed HF heating after continuous heater-on periods and cycled HF heating by short pulses. In the case of pulsed heating by short pulses with duration τ_p < 100 ms and average radiated power P_a below the threshold power P_thr of the SSAI generation cutoff the irregularities can be maintained due only to striction parametric instabilities. The excitation of irregularites under the cycled HF pumping with the pulse duration τ_p = 384 ms for P_a comparable with P_thr was detected. The aspect-angle dependence, or the so-called magnetic zenith effect, was found in the SSAI intensity. The residual turbulence aftereffects played a significant role in the SSAI development. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 50, No. 8, pp. 678–694, August 2007.     

Measurement of the Majorana effect in a molecule using a switched magnetic field and quantum beat detection

By means of quantum beat spectroscopy we investigated the dynamics of magnetic moments associated with hyperfine levels in the molecule under “spin-flip conditions”. Oriented molecules in a cold beam were prepared by excitation with a circularly polarized laser pulse () in a weak magnetic field (). Subsequently, they were exposed to a rapid field inversion which left the magnetic moment in its initial orientation. The initially created coherences among the excited hf levels were conserved after field reversal and thus were explored to characterize the changes in the level structure due to this “Majorana spin-flip” process. Received: 4 February 1999     

Ultrasonic assisted synthesis of styrylpyridinium dyes: Optical properties and DFT calculations

The ultrasonic technique has received considerable attention in several fields; in particular, it gained rapid momentum in organic synthesis due to the larger reaction rates, milder reaction conditions, and better yields. We report herein a facile synthesis of a series of styrylpyridinium based dyes under ultrasonic irradiation. Within short reaction time (15 min) under ultrasonic irradiation, compared to normal laboratory conditions, (4–16 h), we can achieve good to excellent yields. The reaction time is shortened because ultrasound can accelerate the generation of the nucleophile of the pyridinium salt and subsequently a nucleophilic addition of an aldehyde followed by dehydration affords the styrylpyridinium dye, (Knoevenagel condensation). The photophysical properties of all compounds are comprehensively investigated in different solvents. All the compounds exhibit negative solvatochromism both in absorption and fluorescence emission spectra. Such behavior is due to the higher dipole moment of these molecules at the ground state. DFT calculations were performed to understand the electronic structure of the molecules. Our results show the high efficacy of sonochemistry over other methods for preparation of styrylpyridinium dyes.