一维金属光栅嵌入磁性介质纳米结构下的横向磁光克尔效应的增强

本文在一维金属光栅嵌入磁性介质的体系中实现了横向磁光克尔效应的增强.通过最优化金属光栅的嵌入深度来有效激发磁性介质中的波导模式与金属条带上的局域等离激元模式,从而使横向磁光克尔效应的响应得到巨大增强.本文提出了一种用于增强横向磁光克尔效应的新型等离激元微纳结构,这种结构可以应用于高性能磁光器件的设计.     

壳层纳米颗粒的光散射行为研究

本文主要研究了Au-Si球型壳层纳米颗粒在电磁波作用下的散射行为,并将其与实心Au球、空心Au球、实心Si球和空心Si球的光散射行为进行了对比。利用Mie散射理论计算得出Au-Si球型壳层纳米颗粒在外加电磁波作用下的各阶电响应和磁响应,观察壳层结构的几何参数对电偶和磁偶共振峰位置的影响,并进一步研究Au材料中的电偶响应与Si材料中的电偶(磁偶)响应之间的耦合关系,找到其中的耦合规律。通过对单个球型壳层纳米颗粒散射行为的研究,为利用该颗粒周期性排列制备具有特殊电磁性质的人工特异材料提供理论指导。     

直流电对金属液电磁净化的影响

推导了矩形管通电金属液的感应磁场,基于磁流体力学方程组,数值计算了二维金属液诱生流场,并追踪了夹杂物颗粒在流场中的运动轨迹.结果表明,金属液的感应磁场不可忽视,其诱生流场干扰了外加磁场下夹杂物的正常迁移,电磁净化宜采用扁管和圆管;同时,利用感应磁场的自约束性,单电流可实现金属液的电磁净化.     

第五讲 自旋极化输运及隧道巨磁电阻效应

简要回顾了利用量子隧道效应测定铁磁金属传导电子自旋极化率的研究历史，综述了自旋极化电子隧穿产应导致的“铁磁金属／非磁绝缘体／铁磁金属”三层平面型隧道结中的巨磁电阻效应以及“铁磁金属／非磁绝缘体”颗粒膜系统中的隧穿类型巨磁电阻效应的研究进展。     

磁性金属颗粒膜磁光-Kerr效应增强现象研究

基于磁性金属颗粒膜Kerr磁光效应的关系,结合电子跃迁和自由电子共振模型及实验数据,分析了金属颗粒膜的磁光Kerr旋转和Kerr椭偏现象,由分析研究表明：在磁性金属颗粒材料中Kerr旋转和Kerr椭偏率光谱(Kerr效应)中的共振峰不是由单一电子的跃迁引起,其中由于等离子体激化元的存在,而引起的等离子体共振行为在此产生了相当的影响. 亦即对磁光Kerr旋转和Kerr椭偏率起作用的是电子跃迁与自由电荷载流子的等离子共振相互作用共同引起的. 这一结论与对较大Kerr效应的4f 化合物的相关实验强烈的Kerr效应和明显的共振结构相一致,这在铥原子化合物（TmS,TmSe）和铈化合物（CeSb,CeSb0.75Te0.25,CeTe.）及L10FePt膜中都已观察到这一现象.     

垂直入射条件下金属环的谐振特性

本文研究垂直入射条件下水平极化和垂直极化时金属开口谐振环(split ring resonator, SRR)的电磁响应行为. 通过分析这两种情况下的透射系数、介电常数和磁导率, 发现垂直极化时, SRR可以产生电谐振实现负介电常数, 其频段远高于磁谐振频段; 水平极化时, SRR只能产生磁谐振实现负磁导率, 其频段与水平入射时的SRR的磁谐振频段相对应. 通过仿真对此进行了证明, 并对产生电谐振和磁谐振的原因进行了分析.     

磁性金属颗粒膜磁光-Kerr效应增强现象研究

基于磁性金属颗粒膜Kerr磁光效应的关系,结合电子跃迁和自由电子共振模型及实验数据,分析了金属颗粒膜的磁光Kerr旋转和Kerr椭偏现象,由分析研究表明:在磁性金属颗粒材料中Kerr旋转和Kerr椭偏率光谱(Kerr效应)中的共振峰不是由单一电子的跃迁引起,其中由于等离子体激化元的存在,而引起的等离子体共振行为在此产生了相当的影响.亦即对磁光Kerr旋转和Kerr椭偏率起作用的是电子跃迁与自由电荷载流子的等离子共振相互作用共同引起的.这一结论与对较大Kerr效应的4f化合物的相关实验强烈的Kerr效应和明显的共振结构相一致,这在铥原子化合物(Tm S,Tm Se)和铈化合物(Ce Sb,Ce Sb0.75Te0.25,Ce Te.)及L10Fe Pt膜中都已观察到这一现象.     

磁电子学讲座 第五讲 自旋极化输运及隧道巨磁电阻效应

简要回顾了利用量子隧道效应测定铁磁金属传导电子自旋极化率的研究历史．综述了自旋极化电子隧穿效应导致的“铁磁金属／非磁绝缘体／铁磁金属”三层平面型隧道结（简称ＦＭ／Ｉ／ＦＭ隧道结）中的巨磁电阻效应以及“铁磁金属／非磁绝缘体”颗粒膜系统中的隧穿类型巨磁电阻效应的研究进展．     

过渡金属掺杂的扶手椅型氮化硼纳米带的磁电子学特性及力-磁耦合效应

基于密度泛函理论的第一性原理计算方法,研究了多种过渡金属(TM)掺杂扶手椅型氮化硼纳米带(ABNNR-TM)的结构特点、磁电子特性及力-磁耦合效应.计算的结合能及分子动力学模拟表明ABNNRTM的几何结构是较稳定的,同时发现对于不同的TM掺杂,ABNNRs能表现出丰富的磁电子学特性,可以是双极化磁性半导体、一般磁性半导体、无磁半导体或无磁金属.双极化磁性半导体是一种重要的稀磁半导体材料,它在巨磁阻器件和自旋整流器件上有重要的应用.此外,力-磁偶合效应研究表明:ABNNR-TM的磁电子学特性对应力作用十分敏感,能实现无磁金属、无磁半导体、磁金属、磁半导体、双极化磁性半导体、半金属等之间的相变.特别是呈现的宽带隙半金属对于发展自旋电子器件有重要意义.这些结果表明:可以通过力学方法来调控ABNNR-TM的磁电子学特性.     

FexSn100-x合金颗粒薄膜的反常霍耳效应

采用离子束溅射的方法制备了一系列不同原子比的FexSn100-x合金颗粒膜,系统地研究了该体系的反常霍耳效应.在该薄膜中发现了铁磁金属/非磁金属体系中最大的霍耳电阻率,讨论了不同原子配比、薄膜厚度对霍耳效应的影响.通过研究饱和霍耳电阻率ρxys同电阻率ρxx的关系,讨论了反常霍耳效应的机理.     

Mössbauer study of new functional metal/polymer nanocomposites with spatially oriented FeGa particles

Mössbauer spectroscopy has been applied to study the structure and magnetostriction interdependence of metall/polymer composites with spatially oriented FeGa particles in a polymer matrix. Composites were synthesized combining modified polyurethane with nanocrystalline mechanosynthesized particles of magnetostrictive FeGa composition through polymerization to achieve a considerable magnetostrictive response. To increase magnetoelastic effects a spatial particle arrangement in the polymer matrix was generated. The magnetostrictive composition of the mechanosynthesized particles has been determined by Mössbauer spectroscopy, X-ray diffraction and TEM at different stages of ball milling. The microstructure of the composites via the particle orientation in the polymer has been researched by SEM and Conversion Mössbauer spectroscopy with the registration of resonant X-rays. The spatial particle inhomogeneity and magnetic anisotropy have been analyzed in order to reveal the factors determining the functional properties of the manufactured composites. Three-fold enhancement of the magnetostrictive response for FeGa/polyurethane composites with non-standard magnetic anisotropy has been demonstrated.     

Polymer-inorganic composite with ultradisperse gadolinium particles

The objects of investigation are polystyrene-based composites with ultradisperse particles (including nanoparticles) of metallic Gd and SiO₂. The composites prepared by milling starting materials in a barrel mill at room temperature are studied by the ferromagnetic resonance method, transmission electron microscopy (TEM), and reflection X-ray diffraction (RXD). It is found that the magnetic subsystem of the composites is formed by magnetic nanoclusters, Gd crystallites 30 ± 10 nm across, which possess volume and surface magnetic anisotropy and pass into the superparamagnetic state at 210 ± 10 K. It is also found that the Landau-Lifshitz equation with the damping term in the Landau-Lifshitz form provides the best quantitative fit to experimental data for the ferromagnetic resonance of superparamagnetic metal nanoparticles.     

Magnetic behavior of iron and iron-oxide nanoparticle/polymer composites

An inert gas condensation technique was used to prepare nanometer-sized particles of metallic iron and iron oxide. The particles were passivated by the controlled oxidation of the particle surface leading to an Fe-oxide shell-Fe core structure. Nanoparticle–polymer composites were obtained by spin casting mixtures of nanoparticles and polymethylmethacrylate films. The magnetic properties of the nanoparticles compressed into pellets and dispersed in the composites were both studied. The particles were observed to exhibit increased coercivity and exchange bias. The exchange bias was observed to increase with oxide shell thickness. The magnetism in the nanoparticle composites was studied as a function of nanoparticle loading. It was observed that when the particles were dispersed into the nanocomposite the coercivity was increased, suggesting a heightened anisotropy barrier. Similarly, the magnetic relaxation results indicate that the composites exhibit significantly reduced relaxations through the entire temperature range, as compared to the compressed pellet. This observation supports the possibility of heightened anisotropy barriers due to reduced dipolar interactions.     

Magneto-transport and magnetic properties of (1-x)La0.7Ca0.3MnO3+xAl2O3 composites

We report magneto-transport and magnetic properties of (1-x)La_0.7Ca_0.3MnO₃+xAl₂O₃ composites synthesized through a solid-state reaction method combined with a high energy milling method. Most interestingly, the effective magnetic anisotropy is found to decrease with increase in the non-magnetic insulating Al₂O₃ phase fraction in the composites. In addition, we observed that the magnitude of low-field magnetoresistance arising from spin-polarized tunneling of conduction electrons, as well as that of high-field magnetoresistance, displays a Curie-Weiss law-like behavior. Finally, we found that the temperature dependence of low and high-field magnetoresistance is controlled predominantly by the nature of temperature response of surface magnetization of the particles.     

铁电/铁磁三相颗粒复合材料的磁电性能计算

采用格林函数方法给出了三相复合材料的磁电系数的解析式，对稀土-铁合金/压电陶瓷/高分子（Terfenol-D/PZT/PVDF）三相颗粒复合材料的磁电系数进行了计算.计算结果给出了复合材料的磁电性能与材料显微结构的关系，包括三相颗粒复合材料的磁电性能随组分、颗粒的长径比、PZT颗粒的电极化方向以及外磁场的变化趋势，可为实验设计提供参考和指导.通过合理设计，三相磁电复合材料的性能可以达到数百mV/A.作为一种新的磁电复合材料，三相颗粒复合材料有望成为一种新型高性能易制备的磁电材料. 关键词： 磁电效应 复合材料 格林函数     

Magnetoelastic modelling of composites containing randomly dispersed ferromagnetic particles

Coupled magnetoelastic behaviour is investigated for two-phase composites containing randomly dispersed ferromagnetic particles under both magnetic and mechanical loading. The pair-wise particle interactions for magnetic field and elastic field are first defined by the solution for two particles embedded in the infinite domain, which is explicitly solved by the Green's function technique. By integrating the interactions from all other particles in the representative volume element, the homogenized magnetic and elastic fields are then obtained. Effective magnetostriction due to the magnetic interaction force is further derived. Without consideration of magnetic loading, this micromechanical model provides an effective elasticity with the pair-wise particle interactions. By dropping the interaction term, this model is reduced into Mori–Tanaka's model. Finally, magnetoelasticity is numerically solved by considering the magnetomechanical coupling effect. It is predicted that the effective Young's modulus and shear modulus decrease along with the increase of magnetic loading for random composites.     

Effect of composition and thermal treatment on the properties and microstructure of Co–SiO<Subscript>2</Subscript> films

The effect of various physical factors (chemical composition, temperature, and thermal treatment) on the macroscopic properties of Co–SiO₂ film composites produced by ion-plasma sputtering of mosaic targets has been investigated. The microstructure parameters have been estimated indirectly by analyzing the magnetization curves and the temperature dependence of magnetization. It has been concluded that the model of homogeneous noninteracting superparamagnetic particles of hexagonal Co is applicable for describing the magnetic properties of the film composites under study over a rather wide range of compositions.     

Magnetic properties of 3<Emphasis Type="Italic">d</Emphasis>-metal nanocrystalline films

The problem of designing high-resistivity soft magnetic materials based on 3d-metal nanocrystal-line films is discussed. To increase the electrical resistivity, nanogranular composites are proposed; they consist of superparamagnetic particles embedded into a dielectric matrix. To obtain the required soft magnetic properties in such composites, it is necessary to realize magnetic ordering due to the effects of magnetic interaction between nanoparticles. As an example, magnetic films that exhibit good high-frequency properties in a range up to several hundreds of megahertz are presented.     

Preparation of Fe3O4/poly(styrene-butyl acrylate-[2-(methacryloxy)ethyl]trimethylammonium chloride) by emulsifier-free emulsion polymerization and its interaction with DNA

Cationic magnetic polymer particles Fe₃O₄/poly(styrene-butyl acrylate-[2-(methacryloxy)ethyl]trimethylammonium chloride), a type of potential gene carrier, were prepared by emulsifier-free emulsion polymerization with oleic acid modified magnetite Fe₃O₄, styrene, butyl acrylate and [2-(methacryloxy)ethyl]trimethylammonium chloride) (METAC). The morphology of the particles was characterized by transmission electron microscopy and the composites of particles were characterized by FT-IR spectroscopy, X-ray diffraction. These results showed that magnetic particles were well dispersed in polymers with the content of about 15%(wt/wt). The composites exhibited superparamagnetism and possessed a certain level of magnetic response. The interactions between the particles with calf-thymus DNA (ct DNA) were confirmed by zeta potential measurement, UV-vis spectroscopy and fluorescence spectroscopy. The DNA-binding capacity determined by the agarose gel electrophoresis showed good binding capacity of the emulsion to DNA. These results suggested the potential of the cationic magnetic polymer emulsion as gene target delivery carrier.