共查询到20条相似文献，搜索用时 15 毫秒
1.
lINTRODUCTIONThefirstheteronucleartransitionmetalclusterHFeCo,(Co),,wassynthesizedbyChinit13in196Obyusingthepyrolysisofmeta1carbonyldimers.Analysisofcar-bonylIRspectraandX-raypowderpatternsindicatedthatthiscompoundisisostruc-tural.withCo'(CO),,andthushasC,.symmetry(".MaysE'-'ihascarriedoutIRspectraandmassspectraonthiscompoundandkineticisotopestudiesontheprotona-tionoftheanion[FeCo,(CO),,j-,andproposedonthebasisofthisevidencethatthehydrogenatommightbelocatedinthecenterofthecluster.… 相似文献
2.
LU Xiao Ming 《结构化学》2000,(3)
1 ＩＮＴＲＯＤＵＣＴＩＯＮＰｏｌｙｍｏｌｙｂｄａｔｅａｎｉｏｎｓｈａｖｅｂｅｅｎｓｔｕｄｉｅｄｆｏｒｍａｎｙｙｅａｒｓｂｅｃａｕｓｅｏｆｔｈｅｉｒａｐｐｌｉｃａ ｔｉｏｎｉｎｃａｔａｌｙｓｉｓｃｈｅｍｉｓｔｒｙ〔1〕.Ｉｎｔｈｅｓｙｎｔｈｅｓｉｓｏｆｏｒｇａｎｉｃｐｏｌｙｍｏｌｙｂｄａｔｅｄｅｒｉｖａｔｉｖｅｓｕｓｉｎｇａｃｅｔｏｎｅａｓｓｏｌｖｅｎｔ,ｗｅｆｏｕｎｄｔｈａｔｔｈｅｃｏｎｄｅｎｓａｔｉｏｎｒｅａｃｔｉｏｎｏｆａｃｅｔｏｎｅｏｃｃｕｒｒｅｄａｎｄｔｈｅｃｏｎｄｅｎｓａｔｉｏｎｐｒｏｄ… 相似文献
3.
SUN Shu Qing WU Pei Ji ZHU Dao Ben 《结构化学》1999,18(2)
１ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅＮｉ（ｄｍｉｔ）２ｍｏｌｅｃｕｌｅｓｇｉｖｅｒｉｓｅｔｏａｎｕｍｂｅｒｏｆｍｏｌｅｃｕｌａｒｃｏｎｄｕｃｔｏｒｓ〔１，２〕ｉｎａｄｄｉｔｉｏｎｔｏｓｕｐｅｒｃｏｎｄｕｃｔｏｒｓ〔３，４〕．Ｔｈｅｍｕｌｔｙｓｕｌｆｕｒｆ... 相似文献
4.
1INTRODUCTIONBytreatingFeCo2(CO),(p,-S)withgroupVligands[L=PPh,,AsPh,,PBus",p(OEt),j,monosubstitutedderivativesFeCo2(CO),(p,-S)(L)havebeenobtained{1'2i.13C-NMRshowedthatthereplacementofCObyagroupVligandinFeCo,(CO),(p,-S)isatonecobaltatominthemonosubstitutedderivativet2).How-ever,thesubstitutedderivativeofFeCo,(CO),(p,-S)withP(OCH,Ph),hasnotbeenreportedanditscrystalstructurehasnotbeendetermined.WehavesynthesizedthetitlecompoundFeCo,(CO),(p,-S)[P(OCH,Ph),jandtestifiedth… 相似文献
5.
１ ＩＮＴＲＯＤＵＣＴＩＯＮＩｎｒｅｃｅｎｔｙｅａｒｓ,ｔｈｅｚｉｎｉｃｃｏｍｐｏｕｎｄｓｃｏｎｔａｉｎｉｎｇｓｕｌｆｕｒａｎｄｎｉｔｒｏｇｅｎａｔｔｒａｃｔｍｏｒｅａｎｄｍｏｒｅａｔｔｅｎｔｉｏｎｂｅｃａｕｓｅｏｆｔｈｅｉｒｄｅｅｐｒｅｌａｔｉｏｎｓｈｉｐｗｉｔｈｂｉｏ－ｉｎｏｒｇａｎｉｃｃｈｅｍｉｓｔｒｙ〔１〕．Ｚｉｎｉｃｓｕｌｆｉｄｅｐｌａｙｓａｎｉｍｐｏｒｔａｎｔｒｏｌｅｄｕｅｔｏｉｔｓｓｉｇｎｉｆｉｃａｎｔｉｎｖｏｌｖｅｍｅｎｔｉｎｔｈｅｓｔｕｄｙｏｆｔｈｅｐｈｏｓｐｈｏｒｓ,ｓｅｍｉ… 相似文献
6.
ＳｙｎｔｈｅｓｉｓａｎｄＣｈａｒａｃｔｅｒｉｚａｔｉｏｎｏｆＳｎ┐ＷＣｏｍｐｌｅｘｅｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＰｈ３ＳｎＷ（ＣＯ）３Ｃ５Ｈ４ＣＨ３＊ＷＡＮＧＪｉ－Ｔａｏ＊＊，ＨＥＨａｉ－Ｙａｎｇ，ＸＵＹｕ－Ｍｉｎｇ，ＺＨＡＮＧＹｕｎ... 相似文献
7.
1mTRODUCTION.Theimportantprogressinmagnetostructuralchemistryinthepastfewyearsisthesystematicdevel0pmentofstructurallyorderedbimetalliccompound"'.Thefami-liesofcrystallineandam0rphouscomplexes[MM'(cdta)j.xH,O(M,M'maybethefirsttransitionmetalorthesecondmaingroupelements)haveprovidedniceex-amplesofstructuralversatilityinmagneticstudiest2-6i,wherequiteafewstructuresmentionedabove,includingbimetallicandhomometalliccompoundscomprisingcop-per0rothermetalatoms,havebeeninvestigated"-".Ontheother… 相似文献
8.
INTRODUCTIONPalladiumcomplexesplayanimportantroleinmanycatalyticreactions,especial-lyincarbonylationofolefins.InordertostudytherelationshipbetweenthestructureandproPertyofpalladiumcomplexcatalyst,thetitlecomplexwassynthesizedanditsstructurewascharacterizedbyX-raydiffractionmethod.2EXPERmENT2.1SynthesisAmixtureofmorpholine(o-lmol)andCuCl(O.2mol)inmethanol(8OmL)wasrefluxedfor6h.AftercoolingthesolutionwasfilteredrePeat-edlyunti1theclearfiltratewasobtained.BrownCuCl.C'H,NOcrystalswer… 相似文献
9.
LI Xue a YAO Hai Jun b HU Chun Hua a DOU Jian Min a c Sun Jie d JIN Ruo Shui b ZHENG Pei Ju a ② a 《结构化学》1999,(5)
１ ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｆｉｒｓｔｐｏｌｙｈｅｄｒａｌｒｕｔｈｅｎａｂｏｒａｎｅｉｓｓｔｒｕｃｔｕｒａｌｌｙｔｙｐｉｆｉｅｄｂｙｔｈｅｃｏｍｐｏｕｎｄ〔（ＰＰｈ３）２ＲｕＢ１０Ｈ８（ＯＥｔ）２〕ｉｎ１９８４〔１〕,ｗｈｉｃｈｉｓｏｂｔａｉｎｅｄｉｎ４０％ｙｉｅｌｄｂｙｔｈｅｒｅａｃｔｉｏｎｏｆｔｈｅｃｌｏｓｏｄｅｃａｂｏｒａｎｅａｎｉｏｎＢ１０Ｈ１０２－ｗｉｔｈ〔ＲｕＣｌ２（ＰＰｈ３）３〕ｉｎｅｔｈａｎｏｌ／ｃｈｌｏｒｏｆｏｒｍｓｏｌｕｔｉｏｎ．Ｒｅｓｅａｒｃｈｅｒｓｈａｖｅｓｙ… 相似文献
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１ ＩＮＴＲＯＤＵＣＴＩＯＮＷｅｈａｖｅｓｈｏｗｎａｎｉｎｔｅｒｅｓｔｉｎｅｘｏｐｏｌｙｈｅｄｒａｌｃｙｃｌｉｚａｔｉｏｎｏｆｍｅｔａｌｌｉｇａｎｄｓｔｏｃｌｕｓｔｅｒ．ＡｓｅｒｉｅｓｏｆｍｅｔａｌｌａｂｏｒａｎｅｃｏｍｐｏｕｎｄｓｃｏｎｔａｉｎｉｎｇｆｉｖｅｍｅｍｂｅｒｅｄｒｉｎｇｓｓｕｃｈａｓＭ－Ｏ－Ｃ－Ｏ－ＢａｎｄＭ－Ｓ－Ｃ－Ｏ－Ｂａｒｅｓｙｎｔｈｅｓｉｚｅｄａｎｄｃｈａｒａｃｔｅｒｉｚｅｄ．Ｔｈｅｇｒｏｕｐｓｏｆｃｙｃｌｉｚａｔｉｏｎｉｎｃｌｕｄｅａｃｅｔａｔｅ〔１〕,ｂｅｎｚｏａｔ… 相似文献
11.
１ＩＮＴＲＯＤＵＣＴＩＯＮＯｃｔａｃａｒｂｏｎｙｌｄｉｃｏｂａｌｔｉｓａｖｅｒｙｃｏｎｖｅｎｉｅｎｔｓｔａｒｔｉｎｇｍａｔｅｒｉａｌｆｏｒｔｈｅｐｒｅｐａｒａｔｉｏｎｏｆａｌｍｏｓｔａｎｙｃｏｂａｌｔｃｏｍｐｏｕｎｄ〔１〕．Ｔｈｅｒｅａｃｔｉｏｎｓｏ... 相似文献
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1mTRODUCT1ONBinuclearcoppercomplexesareimportantnotonlyincoordinationchemistryandmagnetostructuralstudiesbutalsoinpracticalapplication.tliInanattempttoseekthedisPersionandemulationreagentsofCWM(themixtureofcoalandwater),thetitlecomP0undwassynthesizedbyanoxidativepreparationmethodt2i,whosesynthesisandstructurearedifferentfromthosedescribedbyWangetoft3i.Here,0nlythesynthesisandstructureofthetitlecomP0undarereportedandthestudiesofitsappli-cationareinprogress.2EXPERIMENTAL2.1Preparati0n… 相似文献
13.
1 INTRODUCTION Halide fluxes are excellent media for growing single crystals of chalcogenides[1~5]. On our research in the Ln-Cu-Zn-Se system to find new phases and to search for potential infrared ceramic materials, two new compounds, KHo2CuSe4 and KEr2CuSe4, were synthesized from the reaction of the precursor with KCl flux[6]. In an attempt to synthesize the homologous sulfide by the same method using KBr as flux in a sealed evacuated quartz tube, single crystals of Ho4S3Si2O7 w… 相似文献
14.
WANG Ying ② YAN Lian-He 《结构化学》2006,(10)
1 INTRODUCTION The ability of dialkyldithiocarbamate anion, -S2- CNR2 (dtc) ligand, to bind metal has been known for many years[1, 2]. It forms a chelate with virtually all transition elements and is proven to be a versatile chelating agent for the separation and extract of metals in analytical chemistry and mineral floa- ting[3～5]. Water soluble dialkyldithiocarbamate com- plexes have been tested in various medical appli- cations[6]. Some of substituted dithiocarbamate salts also show … 相似文献
15.
１ ＩＮＴＲＯＤＵＣＴＩＯＮＩｎｏｕｒｅｆｆｏｒｔｓｔｏｄｅｖｅｌｏｐｔｈｅｌｏｗ－ｖａｌｅｎｃｅＭｏ－ＳＲｃｏｍｐｏｕｎｄｓ,ｗｅｈａｖｅｆｏｕｎｄａｎＭｏ（０）－ｃｏｍｐｏｕｎｄ,〔Ｍｏ２（ＳＲ）２（ＣＯ）８〕２－,ｗｈｉｃｈｉｓｏｂｔａｉｎｅｄｆｒｏｍｔｈｅｒｅａｃｔｉｏｎｏｆＭｏ（ＣＯ）６ｗｉｔｈＲＳ－ｉｎｈｉｇｈｙｉｅｌｄ,ｐｏｓｓｅｓｓｅｓａｎｉｎｔｅｒｅｓｔｉｎｇｔｗｏ－ｅｌｅｃｔｒｏｎｔｒａｎｓｆｅｒｐｒｏｐｅｒｔｙ．Ｎｕｍｅｒｏｕｓｋｉｎｄｓｏｆｄｉｎｕｃｌｅａｒｍｏｌｙｂｄｅ… 相似文献
16.
１ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｃｈｅｍｉｓｔｒｙｏｆｃｏｍｐｏｕｎｄｓｗｉｔｈｄｍｉｔ（ｄｍｉｔ＝１,３ ｄｉｔｈｉｏｌｅ ２ ｔｈｉｏｎｅ ４,５ ｄｉｔｈｉｏｌａｔｅ）ｈａｓａｔｒａｃｔｅｄｃｏｎｓｉｄｅｒａｂｌｅａｔｅｎｔｉｏｎｒｅｃｅｎｔｌ... 相似文献
17.
1INTRoDUCTIONAlotofresultsoncobaltcomplexstructureshavebeenreportedforseveraldecades.Theinterestofresearchinthisfieldhasneverbeenreducedbecausethecobaltcomplexesplayaveryimportantroleinthelifescienceandcatalysis,etc[1-6).WereportherethesynthesisandstructureofcomplexCo(C,NO,H'),.H,O.2EXPERIMENTALAllreagentsandsolventsusedareofARgradefromcommericalsourceswithoutfurtherpurification.ThetitlecompoundCo(C,NO,H,),.H,Owassynthesizedbythefollowingmethod.When2.4g(ca.1mmol)ofCoCl2.6H2Ow… 相似文献
18.
本文报道了标题簇合物的快原子轰击质谱(FAB—MS)研究,提出了标题簇合物质谱的可能断裂途径及其结构相关性。指出标题簇合物的FAB—MS与电子轰击谱(EI—MS)所表现的两种迥然不同的断裂模式。观察到单立方烷缺一个顶点和缺二个顶点的碎片离子如[WFe_2S_3(S_2CNC_4H_8)_2]~+、(MoFe_2S_3(S_2CNC_4H_8)_3]~+和[WFeS_3(S_2CNC_4H_8)_3]~+、[MoFe_3S_3(S_2CNC_4H_8)_2]~+等,而后者的簇芯(MoFe_3S_3)结构具有缺口的立方烷状构型特点,是目前合成工作者期待合成但尚未合成出的一种固氮模型物。 相似文献
19.
ZHANG Min KONG Fan Rong 《结构化学》1999,18(2)
１ＩＮＴＲＯＤＵＣＴＩＯＮＭｅｔａｌｉｃｃｏｍｐｌｅｘｅｓｏｆｓｃｈｉｆｂａｓｅｓｈａｖｅａｔｒａｃｔｅｄｔｈｅａｔｅｎｔｉｏｎｏｆｒｅｓｅａｒｃｈｅｒｓｄｕｅｔｏｔｈｅｉｒａｎｔｉｖｉｒａｌ，ｆｕｎｇｉｓｔａｔｉｃ，ａｎｄｃａｔａｌｙｔｉｃａｃｔｉ... 相似文献
20.