Simultaneous treatment of polymer surface by EUV radiation and ionized nitrogen

In this paper chemical modification of a poly(vinylidene fluoride) surface by extreme ultraviolet (EUV) irradiation in a presence of ionized nitrogen was demonstrated for the first time. Nitrogen gas, injected into an interaction region, was ionized and excited by the EUV radiation from a laser-plasma source. The ionization degree and excited states of nitrogen were investigated using EUV spectrometry and the corresponding spectra are presented. Chemical modification of polymer after combined EUV and ionized nitrogen treatment was investigated using X-ray photoelectron spectroscopy. A?significant contribution of nitrogen atoms in near-surface layer of the polymer after the treatment was demonstrated.     

Near-surface modification of optical properties of fused silica by low-temperature hydrogenous atmospheric pressure plasma

In this Letter, we report on the near-surface modification of fused silica by applying a hydrogenous atmospheric pressure plasma jet at ambient temperature. A significant decrease in UV-transmission due to this plasma treatment was observed. By the use of secondary ion mass spectroscopy, the composition of the plasma-modified glass surface was investigated. It was found that the plasma treatment led to a reduction of a 100 nm thick SiO2 layer to SiOx of gradual depth-dependent composition. For this plasma-induced layer, depth-resolved characteristic optical parameters, such as index of refraction and dispersion, were determined. Further, a significant plasma-induced increase of the concentration of hydrogen in the bulk material was measured. The decrease in transmission is explained by the plasma-induced near-surface formation of SiOx on the one hand and the diffusion of hydrogen into the bulk material on the other hand.     

Effect of adsorption on the surface mobility of charge carriers in a semiconductor substrate

The effect of adsorption on the carrier mobility in the near-surface region of a semiconductor substrate has been investigated within the framework of the Schrieffer model. The dependence of the carrier surface mobility on the concentration of adatoms has been determined. The systems chosen for the study are the gases adsorbed on the surface of semiconductor oxides. Empirical estimates of the surface mobility, which are based on modification of conventional volume scattering mechanisms, have been proposed.     

Surface structure of alumina ceramics during irradiation by a pulsed electron beam

The structural transformations that occur in the near-surface layer in alumina ceramics during irradiation by a pulsed electron beam generated by a forevacuum plasma electron source are studied. The modification of the surface properties of the ceramics is shown to be caused by the formation of regions consisting of close-packed and identically oriented crystallites within every grain. The crystallites are elongated: their length and width are 0.5–1.5 μm and the transverse size is 0.1–0.2 μm.     

Evolution of vacancy defects and dislocations in surface layers of iron as a result of pulsed electron beam treatment

Using a micro-beam of ions (PIXE, RBS), a slow positron beam, measurements of positron lifetime, TEM and SEM techniques, formation of vacancy defects and dislocations has been found in a near-surface iron layer as a result of pulsed electron beam treatment. It has been shown that as a result of the HCEB treatment regions of a low local electron density are formed, which seem to be “embryos” for craters. In spite of the crater formation and high dislocation density (exceeding 10¹⁰ cm⁻²) in a near-surface layer, we found a decrease in wear resistance to dry friction and an increase in microhardness.     

Effect of the high-speed impact of a shaped-charge jet on the strength of titanium alloys

The effect of the high-speed impact of a shaped-charge jet on the structure and strength of commercially pure VT1 titanium and VT22, VT3-1, and PT-3V titanium alloys is studied in comparison with AK6 aluminum alloy and Br OTsS bronze. The strength is characterized in terms of the microhardness. The microhardness versus structure is analyzed in the near-surface layer along the channel formed by the shaped-charge jet. The results obtained are used to qualitatively estimate the structural modification, type of fracture, and strength of targets made of the alloys.     

Optimizing the Parameters of Zr Alloy Doping with Al,Fe, and Mo via the Irradiation of Respective Films on Zr Surfaces Using Ar Ions

The effect the sputtering of a film–substrate system has on the modification of near-surface layers of zirconium alloy E110 (Zr–1% Nb) in the ionic mixing regime upon irradiation by a beam of argon ions with a wide energy spectrum is considered. It is shown that to increase the atoms’ efficiency of penetration and achieve the optimum doping conditions via ionic mixing upon irradiation by a beam of ions with a broad energy spectrum, the ion energy in the beam must be increased while simultaneously lowering the reduced atomic beam mass by using a combined ion beam of different masses.     

研究激光激发的声表面波与材料近表面缺陷的振荡效应

根据激光激发声表面波的热弹运动方程及热传导方程, 采取有限元技术对方程进行求解, 得到声表面波传播波形图. 当声表面波经过近表面缺陷时, 声表面波与近表面缺陷之间产生一种振荡效应, 通过近表面缺陷的振荡波形幅值存在一个逐渐增加后又逐渐减小的过程. 当声表面波经过不同深度的近表面缺陷时, 振荡信号中心频率存在一定的变化规律. 数值仿真结果表明: 当近表面缺陷深度从0.1 mm到0.5 mm变化时, 振荡效应产生的振荡信号中心频率从0.4 MHz到0.76 MHz变化, 振荡信号中心频率与近表面缺陷深度呈近似线性关系, 这为近表面缺陷的定量检测提供了一种理论基础.     

Measurements of near-surface bubble plumes in the open ocean with implications for high-frequency sonar performance

This study examines near-surface bubble data obtained with a self-contained 200-kHz inverted echo-sounder deployed at Ocean Station Papa (NE Pacific, 1400 km west of Vancouver Is.) over an 81-day period in the spring of 1996. The instrument operated continuously, recording calibrated volume scattering profiles from near-surface bubbles with 3-s and 30-cm resolution. The data show the frequent occurrence of bubbles organized into vertical, plume-like structures, presumably drawn downwards by turbulence and other near-surface circulations. Average bubble plume penetrations of up to 15 m were observed, with maximum penetrations up to 25 m. Within the plumes, the backscatter cross section exhibited an exponential decay with depth, with e-folding scale in the range 0.5 to 3 m, increasing proportionally to the square of average plume depth. Using standard models for bubble scattering, and incorporating recent acoustic resonator measurements of bubble-size distributions along with actual bubble plume data, high-frequency near-surface sonar performance models were developed. These models show that on a ping-to-ping basis the bubble plume structures can induce significant spatial variations in the reverberation level and path-integrated extinction losses to near-surface targets.     

Calculation of energy characteristics of the metal surface taking into account the lattice relaxation effects

Within the framework of the electron-density functional theory method, a self-consistent calculation of the shift of two near-surface ionic planes in different metals has been carried out. The effect of the near-surface lattice relaxation on the surface energy of metals and on the electron work function from these metallic surfaces has been investigated. To describe the arising strong inhomogeneity of the electronic system in the near-surface region, gradient corrections have been taken into account for the kinetic and exchange-correlation energy. To calculate the effect of electron-ion interaction on the energy characteristics of the surface, the Heine-Abarenkov pseudopotential has been used.     

Simulation of composition modification in ZnSe by nanosecond radiation of excimer laser

A numerical simulation of the composition modification induced in ZnSe by nanosecond irradiation of the KrF excimer laser (λ = 248 nm, τ = 20 ns) has been carried out. Intensive evaporation of components has shown to results in the material surface cooling and forming a nonmonotone temperature profile with maximum temperature in semiconductor volume at the distance of ∼6 nm from the surface. As a result of evaporation and diffusion of components formation of the near-surface layer with nonstoichiometric composition takes place and enrichment of selenium reaches maximum value not on the surface, but in the semiconductor volume.     

High-resolution X-ray topography

X-ray double-crystal topography is, together with section topography, the most deformation-sensitive method. Its advantages and problems are discussed especially in view of the widely spread Lang topography. There are advantages regarding sensitivity, exposure time and the simplicity of contrast evaluation. The disadvantage of its sensitivity to sample warping can be overcome to some extent by a special double-crystal technique with an adaptable bending of the collimator crystal compensating for a homogeneous sample curvature. In contrast to other techniques, double-crystal topography preserves its high-deformation sensitivity also in reflection geometry. That is advantageous if near-surface defects and deformations are investigated as shown by several examples.     

金属纳米球-纳米圆盘结构中表面等离激元共振模式的电磁场增强研究

表面等离激元自诞生以来已有一百多年的历史,并逐渐形成了一门新的学科——表面等离激元光子学.位于金属纳米结构中的局域表面等离激元可产生非常显著的近表面电场增强,并成功应用于诸多研究领域当中,而对局域表面等离激元与外界入射光中磁场的相互作用的研究则相对较少.该研究在前期已有的研究基础之上模拟计算了金属纳米球-纳米圆盘结构间...     

Effects of oxygen concentration and irradiation defects on the oxidation corrosion of body-centered-cubic iron surfaces: A first-principles study

Oxidation corrosion of steels usually occurs in contact with the oxygen-contained environment, which is accelerated by high oxygen concentration and irradiation. The oxidation mechanism of steels is investigated by the adsorption/solution of oxygen atoms on/under body-centered-cubic (bcc) iron surfaces, and diffusion of oxygen atoms on the surface and in the near-surface region. Energetic results indicate that oxygen atoms prefer to adsorb at hollow and long-bridge positions on the Fe(100) and (110) surfaces, respectively. As the coverage of oxygen atoms increases, oxygen atoms would repel each other and gradually dissolve in the near-surface and bulk region. As vacancies exist, oxygen atoms are attracted by vacancies, especially in the near-surface and bulk region. Dynamic results indicate that the diffusion of O atoms on surfaces is easier than that into near-surface, which is affected by oxygen coverage and vacancies. Moreover, the effects of oxygen concentration and irradiation on oxygen density in the near-surface and bulk region are estimated by the McLean's model with a simple hypothesis.     

Surface magnetism of real iron borate monocrystals

A theory of the surface magnetism of iron borate, FeBO₃, allowing for the non-ideality of the crystal structure of the near-surface layer is constructed. Since the magnetizing field of a near-surface layer appears to be inversely proportional to the tenth power of the crystal lattice parameter, the influence of the non-ideality on the surface magnetism should be substantial. The suggested models of reconstruction make it possible to describe experiments if the magnitude of the deformations is in agreement with literature data. The theoretical dependence of the value of the surface anisotropy on the concentration of point defects in a near-surface layer of the crystal is also established.     

扩散场扇扫重建格林函数实现近表盲区缺陷检测

针对结构近表盲区缺陷检测难题,发展了一种扩散声场扇扫重建格林函数的超声检测方法.在对扩散场扇扫重建格林函数理论分析的基础上,通过5 MHz超声相控阵探头对铝块近表盲区缺陷进行了检测实验并对影响成像结果的延时时间、时间窗宽和扫查方式进行了分析.结果显示,该方法可以有效检测铝块近表1.5?3 mm的盲区缺陷;扇形扫查方式的...     

Threshold Conditions for Bulk Second-Order Nonlinearity and Near-Surf ace Second-Order Nonlinearity in Thermally Poled Infrasil Silica

Generation of bulk second-order nonlinearity in silica glass requires higher poling temperature or longer poling time than that of near-surface second-order nonlinearity. The threshold conditions for initiating the bulk second-order nonlinearity are studied on Infrasil fused silica glass. The threshold poling time is strongly dependent on the poling temperature. The near-surface second-order nonlinearity is also studied, especially the dependence of thickness of the nonlinear layer on the poling temperature, poling voltage and poling time. Secondary-ion mass-spectroscopy measurement showed depletion of Na⁺ ions at the anodic surface. We assume there is an ionic wave during poling traveling from the anodic surface to generate the dipolar electric field that induces the near-surface second-order nonlinearity.     

激光在近表面弹性性质梯度变化的材料中激发超声波的数值分析

激光激发超声波为评价材料近表面弹性性质提供了有效的手段. 考虑到由于冲击硬化、表面热处理、表面氧化等引起的金属材料近表面层弹性性质的变化，建立了一种激光在基底上的梯度材料中激发超声波的理论模型. 用有限元方法模拟了热弹条件下脉冲激光作用于材料上表面激发出的超声波及其传播过程，研究了近表面层离散的层数对超声波的产生和传播的影响，并分别讨论了表面层“变硬”和“变软”两种情况下声表面波的模式变化及用二维傅里叶变换得到各模式的色散曲线. 为进一步研究近表面层的弹性性质建立合理的计算模型及材料性质的反演提供了理论依 关键词： 超声波 有限元法 近表面弹性性质 色散     

Ambipolar tunneling in near-surface quantum wells

We study the photoluminescence from a near-surface quantum well in the regime of ambipolar tunneling to the surface states. Under steady-state excitation an electric field develops self-consistently due to the condition of equal tunneling currents for electrons and holes. The field induces a Stark shift of the photoluminescence signal which compares well with experimental data from near-surface GaAs/AlGaAs single quantum wells.     

利用水平阵模态域波束形成判别声源深度*

针对近水面声源和水下声源的深度判别问题,根据近水面声源难以激发低阶模态的物理现象,研究利用声源波数谱结构和波数位置的不同来分辨近水面声源和水下声源。通过采用MVDR的谱估计方法进行模态域波束形成,补偿水平阵各阵元之间各号简正波的相位差,获得主瓣窄、旁瓣低的声源信号波数谱。波数谱的波数位置与频率呈近似线性关系,水中声速剖面、海底参数、海深都会影响波数谱的具体结构和位置。此外,声源信号的到达角估计误差同样也会影响波数谱主瓣的位置估计。数值仿真结果表明,在浅海负跃层声速剖面条件下,可利用水平阵模态域波束形成判别声源深度,区分近水面声源和水下声源。