Fine structure in the α decay of202Rn

The α decay of mass-separated²⁰²Rn is studied at the ISOLDE separator. Time sequential α-singles spectra together with α-X-t and α-e-t coincidence events are collected. Fine structure in the α decay is observed and feeding of a low-lying 0 ₂ ⁺ state at 816 keV in¹⁹⁸Po is evidenced. This 0⁺ state can be interpreted as the bandhead of an intruder-state based deformed band, coexisting with the spherical groundstate band. Mixing between normal and intruder states is discussed. A preliminary α-decay study of²⁰⁰Rn did not yet reveal any fine structure.     

Experimental and theoretical investigations of the Knight shift of Pd and Ag in the alloy system Ag x Pd1−x

The Knight shift of Pd in Ag _x Pd_1–x has been determined for concentrationsx0.2. In full accordance with the expectations based on the behaviour of the magnetic susceptibility, it was found that the Knight shift of Pd is rapidly reduced in magnitude by adding Ag to Pd. To allow for a detailed interpretation of this finding, we have performed Korringa-Kohn-Rostoker coherent potential approximation (KKR-CPA) band structure calculations for Ag _x Pd_1–x . These calculations clearly demonstrate that the decrease in spin susceptibility with increasingx is accompanied with a decrease in core polarization. In contrast to Pd, the negative Knight shift of Ag on the Pd-rich side of the system is caused by the valence band contribution, as it is demonstrated by our calculations. This is caused by an intersite effect in analogy to the transferred hyperfine field found for non-magnetic elements dissolved in a magnetic host.     

Simple approximation of cross sections for nuclear reactions involving Z = 3–12, 14 nuclei

A compact cross section data base is obtained for almost 5000 nonresonance nuclear reactions involving stable and unstable Be, B, C, N, O, F, Ne, Na, Mg, and Si isotopes. The calculations are performed using the Sãn Paulo potential and the barrier penetration formalism. The calculated cross sections are approximated by simple analytical formulas. The results are necessary for simulating nuclear burning in neutron stars.     

X-Ray spectral and theoretical investigations of the electronic structure of phenylcyclosilanes (SiPh2) n (n = 4–6)

The X-ray emission SiKα_{1, 2} and SiKβ₁ spectra of a series of phenylcyclosilanes (SiPh₂) _n (n = 4–6) have been obtained. Using the results of quantum-chemical calculations in the density functional theory approximation, the fine structure of SiKβ₁ spectra has been interpreted. Distributions of densities of electron states of silicon atoms over the valence band have been constructed and the types of chemical bonds providing the Si-Si and Si-Ph interactions have been established. Based on the theory of natural bond orbitals, the chemical bonding in the studied series of phenylcyclosilanes has been analyzed.     

Development of the device prototype based on the semiconductor–carbon nanotubes structure for optical radiation detection and study of its parameters

A light-receiving device prototype based on the semiconductor–carbon nanotubes (CNTs) structure consisting of 16 cellular structured sensitive elements grown on the same substrate is developed. The topology of sensitive cells represents holes through metallization and insulator layers to the semiconductor from which the CNT array grows to the top metallization layer. The device prototype parameters are determined as follows: the effective wavelength range is within 400–1100 nm, the operational speed is no longer than 30 μs, the coefficients of peak sensitivity reached at wavelengths of 640 and 950 nm are 197 and 193 μA/W, respectively.     

Decay properties of neutron-deficient nuclei in the region Z = 86–92

Neutron deficient isotopes of elements Z = 86-92 have been produced by heavy-ion fusion reactions ¹²C + ²⁰⁸Pb, ²⁰⁹Bi, ²²Ne + ²⁰⁸Pb, ⁵¹V + ¹⁷⁰Er, and ⁵⁰Ti + ¹⁷⁰Er. The evaporation residues were investigated by means of α- and α-γ-spectroscopy after in-flight separation from the projectile beam by the velocity filter SHIP and implantation into a 16-strip position-sensitive Si-detector. New or improved decay data for ^{225, 226}U, ^{216, 217m, 218}Pa, ^{215, 216, 217}Th, ^{214, 215, 216, 216m}Ac, ²¹⁴Ra and ²¹³Rn have been obtained. Received: 5 April 2000 / Accepted: 28 July 2000     

Dispersion and nonlinear frequancy shift of natural waves in the Bose–Einstein condensate

Quantum mechanics equations for a system of the Bose particles are represented in the form of material field equations. A nonlinear equation for the macroscopic one-particle wave function is derived. Using the Krylov–Bogolyubov–Mitropol’skii method for equations in partial derivatives, nonlinear waves in the Bose–Einstein condensate are investigated. In the cubic approximation, dispersion relations for waves are derived and nonlinear frequency shift is calculated in the first- and third-order approximations for the interaction radius.     

CO2 pressure broadening and shift coefficients for the 1–0 band of HCl and DCl

CO₂ broadened spectra of the 1–0 band of H³⁵Cl and H³⁷Cl, observed near 2886 cm^?1, and the 1–0 band of D³⁵Cl and D³⁷Cl, located near 2089 cm^?1, have been recorded at room temperature and five total pressures between 150 and 700 Torr, using a Bruker IFS125HR Fourier transform spectrometer. Spectra of pure HCl were also recorded. CO₂ broadening and shift coefficients of HCl and DCl have been measured using multi-spectrum non-linear least squares fitting of Voigt profiles. The analysis of the 1–0 band of DCl was complicated by the presence of overlapping CO₂ bands, which were included in the treatment as absorption coefficients calculated taking line-mixing effects into account.     

Effect of water–methanol content on the structure of Nafion in the sandwich model and solvent dynamics in nano-channels; a molecular dynamics study

Continuing an ongoing study, molecular dynamics (MD) simulations were performed to investigate the effects of methanol concentration on Nafion morphology, such as the size of solvent cluster, solvent location, and polymer structure via the sandwich model. Our survey shows that high methanol concentrations resulted in increment of solvent cluster size in Nafion membrane. The sulfonic acid clusters also befall much in order as subsequent layers of such ionic clusters are formed. The number of neighbouring hydronium ions around a sulfur atom is independent of methanol concentration, but the first shell of hydronium and water around sulfonic acid clusters is broader. Although methanol would prefer to interact with water molecules rather than sulfonic acid groups, gathering of methanol molecules via hydrophobic self-aggregation is preferred. Methanol is located closer to the hydrophobic part of the polymer than water, while water is located closer to the hydrophilic part of the polymer. It was found that methanol distributes specifically more than water in nano-channels. Investigation of solvent dynamics in nano-channels shows that diffusion coefficients (D) of water, methanol, and hydronium decrease with increasing methanol concentration and they may be ordered as follows: D _Water?>?D _Methanol?>?D _Hydronium (D _Water?≈?1.6–2.0D _Methanol and D _Methanol?≈?2.1–3.0D _Hydronium).     

First-principles study of the local structure and crystal field of Yb2＋ in sodium and potassium halides

The local coordination structures around the doping Yb 2+ ions in sodium and potassium halides were calculated by using the first-principles supercell model.Both the cases with and without the charge compensation vacancy in the local environment of the doping Yb 2+ were calculated to study the effect of the doping on the local coordination structures of Yb 2+.Using the calculated local structures,we obtained the crystal-field parameters for the Yb 2+ ions doped in sodium and potassium halides by a method based on the combination of the quantum-chemical calculations and the effective Hamiltonian method.The calculated crystal-field parameters were analyzed and compared with the fitted results.     

Geometry and material optimization of the extraordinary magnetoresistance in the semiconductor–metal hybrid structure

The effects of geometry and material parameters on the extraordinary magnetoresistance (EMR) of the rectangular semiconductor–metal hybrid structure have been studied systematically using the finite-element method (FEM). We find that the EMR depends sensitively on the placement of the voltage probes and explain the origin of the EMR enhancement in the asymmetric voltage probe configuration. The width of the metal is important for the EMR effect as well as the width of the semiconductor. The low-field EMR shows an approximate quadratic with the mobility of semiconductor, while the high-field EMR gradually saturates with the increase of mobility due to the little change of hall angle. To obtain significant EMR effect, the ration of conductivity of metal and semiconductor should be larger than 10⁴${10}^4$.     

Entanglement for two-atom Tavis–Cummings model with degenerate two-photon transitions in the presence of the Stark shift

The dynamics of atom–field entanglement for two two-level atoms with degenerate two-photon transitions interacting with one-mode radiation field with taking into account the Stark shift is investigated. Asymptotic solutions for system state vectors are obtained in the approximation of large initial coherent fields. The atom–field entanglement is investigated also on the basis of the linear atomic entropy dynamics. The possibility of the system being initially in a pure disentangled state to revive into this state during the evolution process is shown. Conditions and times of disentanglement are derived.     

Molecular dynamic simulation of core–shell structure: study of the interaction between modified surface of nano-SiO2 and PAMAA in vacuum and aqueous solution

The interaction between acrylamide acrylicacid copolymer (PAMAA) and the modified surface of nano-SiO₂ is investigated using the molecular dynamic (MD) simulation. The binding energies (E_binding) of interface, the concentration profiles of PAMAA and functional groups (carboxyl and acylamino) of corresponding model, the mean square displacements (MSD) and diffusion coefficients (D) of PAMAA in four systems with different modifiers are all calculated at 325 K in vacuum. Vinyl trimethoxy silane (VTEOS) shows best modification effect in the systems mentioned above. Furthermore, the effects of temperature on the interaction between VTEOS modified surface of nano-SiO₂ and PAMAA are studied at 300, 325, 350, 375 and 400 K in aqueous solution. Interesting results show that, water molecular layer reduces with the increase of temperature, and then improves the interaction between PAMAA and VTEOS modified surface of nano-SiO₂. The corresponding E_binding of interface, the radial distribution functions (RDF) of carbon atoms on the surface and oxygen atoms of water molecules, the concentration profiles of PAMAA on the surface of nano-SiO₂, the MSD and D of PAMAA are all studied seriously to find the reason of this counterintuitive phenomenon.     

Stability study of a model for the Klein–Gordon equation in Kerr space-time

The current early stage in the investigation of the stability of the Kerr metric is characterized by the study of appropriate model problems. Particularly interesting is the problem of the stability of the solutions of the Klein–Gordon equation, describing the propagation of a scalar field of mass $\mu $ in the background of a rotating black hole. Rigorous results prove the stability of the reduced, by separation in the azimuth angle in Boyer–Lindquist coordinates, field for sufficiently large masses. Some, but not all, numerical investigations find instability of the reduced field for rotational parameters $a$ extremely close to $1$ . Among others, the paper derives a model problem for the equation which supports the instability of the field down to $a/M \approx 0.97$ .     

A Simple Systematical Law of E2＋ Values for Heavy Nuclei in the NpNn Scheme and the Evolution of the Z=64 Shell Gap

A systematics of excitation energy of the first 2^＋ state E2＋ in even-even heavy nuclei （A ≥ 120） is studied in the NpNn scheme. It is found that a simple exponential function describes the dependence of E2＋ values on NpNn values very well. In addition, the Z = 64 shell gap is reexamined by investigating the systematics of the 52 ≤ Z ≤66 region. It is found that the Z = 64 shell gap is largest at N = 82 and becomes smMler with either increasing or decreasing of neutron numbers. The effects of this shell gap become negligible for counting the valence proton numbers when N ≥ 92 or N ≤ 72.     

Evolution of magnetic domain structure of martensite in Ni–Mn–Ga films under the interplay of the temperature and magnetic field

Ferromagnetic shape memory Ni-Mn-Ga films with 7M modulated structure were prepared on MgO （001） substrates by magnetron sputtering. Magnetization process with a typical two-hysteresis loop indicates the occurrence of the reversible magnetic field-induced reorientation. Magnetic domain structure and twin structure of the film were controlled by the in- terplay of the magnetic and temperature field. With cooling under an out-of-plane magnetic field, the evolution of magnetic domain structure reveals that martensitic transformation could be divided into two periods： nucleation and growth. With an in-plane magnetic field applied to a thermomagnetic-treated film, the evolution of magnetic domain structure gives evidence of a reorientation of twin variants of martensite. A microstructural model is described to define the twin structure and to produce the magnetic domain structure at the beginning of martensitic transformation; based on this model, the relationship between the twin structure and the magnetic domain structure for the treated film under an in-plane field is also described.     

Precision measurement of L X-ray wavelenghts and line widths for 74 ≦ Z ≦ 95 and their interpretation in terms of nuclear perturbations

Techniques for the precision measurement of x-ray lines using the two-crystal spectrometer are discussed, and then applied to measurement of the L x-ray spectra of the transuranic elements uranium, neptunium plutonium, and americium. In all, 52 emission lines and 4 L_III absorption edges were measured, all of them with higher precision than has heretofore been obtained and many of them for the first time. Using these data, the binding energies of the electrons for these atoms were computed. The L_II-L-_III level splitting was computed and compared with theory and it was found that current theory is not sufficient to account quantitatively for the observed data. Certain features of the emission line widths are discussed and given qualitative explanations in terms of the Coster-Kronig transition L_III-L_IIIM_V and hyperfine structure. The observed hyperfine structure is due to the large magnetic moment of Np²³⁷ which leads to increased widths of certain of the Np lines. It is believed that this is the first experimental observation of hyperfine structure in x-ray spectra.