共查询到18条相似文献,搜索用时 93 毫秒
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极性分子型电流变液是一种新型的电流变材料.其介电颗粒上吸附极性分子,极性分子在颗粒间强局域电场作用下发生取向是产生巨电流变效应的关键.通过对Ca—Ti—O(CTO)体系极性分子型电流变液电流密度的测量发现,其导电行为遵从Poole-Frenkel效应的规律,这是极性分子型电流变液的重要特征之一.而500 ℃处理过的CTO粉体不含极性分子,所配制的电流变液无巨电流变效应,其电流密度随外电场强度近似地呈线性关系,显示出传统电流变液特性. 相似文献
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一般液体在温度降低到凝固点时发生液 -固转变 .而电流变液则是在电场作用下可从液体转变成固体的物质 ,其剪切强度随电场的增加而变大 ,这种变化快速、可逆 .它是独一无二的软硬程度可调节的智能材料 ,有重要应用价值 .最近温维佳博士等研究成功具有巨电流变效应的材料 ,是电流变液研究的重大突破 .封面示意此种电流变液在不同电场强度时 ,剪切强度值所相应的物质 ,分别相当于硅油、豆腐、硬泡沫、硬橡胶和塑料 .封面右下角图中为巨电流变流体 .详细报道见本期第 777— 779页 .电流变液研究获重大突破——发现巨电流变效应$中国科学院物理… 相似文献
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极性分子型电流变液 总被引:2,自引:0,他引:2
电流变液在电场作用下软硬连续可调的奇特性质具有广泛和重要的应用价值。传统电流变液是基于颗粒极化产生的相互作用,根据介电理论预测,其剪切屈服强度的上限约为10 kPa。电流变液被发明50年来,阻碍其应用的主要原因是剪切强度低。近年来发明的“极性分子型电流变液”是一类新型电流变液,其屈服强度比传统电流变液大一个数量级以上,且与电场强度呈线性关系,这一点和传统电流变液中的平方关系也明显不同。文章作者提出了极性分子在颗粒间强局域电场中的取向并与极化电荷作用的模型,成功地解释了观察到的实验现象。根据这一原理,有可能制备出屈服强度高达MPa的电流变液。 相似文献
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电流变液的研究进展及应用前景 总被引:3,自引:0,他引:3
电场致流变液体(电流变液)是一些高介电小颗粒和低介电油液的混合体,它在高电场作用下呈现液体与固体间的变换,变换时间为几毫秒,而且变换可逆。阐明了电流变液的原理,综述了电流变液在机制、材料及应用等方面的研究现状,并介绍了电流变液在技术和工业上广泛的应用前景。 相似文献
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根据电流变液中球形颗粒的运动模型,研究了颗粒质量很小时,电流变液中颗粒运动的渐近状态,利用微分不等式理论,给出了相应运动的渐近估计.
关键词:
电流变液
微分不等式理论
渐近估计 相似文献
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电流变阻尼器的抗冲击性能研究 总被引:3,自引:0,他引:3
从理论和试验两个方面研究了所设计的电流变阻尼器在大冲击下的抗冲击性能,分析了电流变液性能与阻尼器结构参数对抗冲击性能的影响。认为采用高性能的电流变液体及改变结构参数,都可以使电流变阻尼器的高速缓冲性能提高。电流变液流速对电流变液的屈服应力影响显著,其值随流速的增加按指数规律减小。从定性、定量两个方面分析了电流变阻尼器作为阻尼器效果不明显的原因为:由电流变效应引起的阻尼力在整个液压阻力所占比例太小,不能通过改变电压来使液压阻力具有很大的调节可控范围。 相似文献
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制备了二氧化钛前驱体粉体, 它具有优良的巨电流变效应, 但不含一水草酸钙的成分. 通过X射线衍射谱、扫描电子显微镜、电感耦合等离子体光谱仪和热失重-质谱联用仪等一系列实验手段, 对二氧化钛前驱体粉体进行了表征, 发现它是非晶形态的纳米粉体, 其主要成分为TiOC2O4·2H2O和TiO(OH)2. 由二氧化钛前驱体配置的电流变液具有与钛酸钙前驱体电流变液类似的温度特征, 即 当处理温度超过160℃后, 电流变液的屈服强度会逐渐降低, 至200℃后, 巨电流变效应完全消失. 通过对比分析发现, 伴随上述巨电流变效应消失过程的化学反应是TiOC2O4·2H2O 在加热过程中失去了结晶水. 这些特征在所有钛酸盐系列的电流变液中均可观察到, 因此我们推断TiOC2O4·2H2O是钛酸盐系列巨电流变液中的关键物质.
关键词:
电流变液
钛酸盐
极性分子 相似文献
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The yield stress of our newly developed electrorheological (ER)
fluids consisting of dielectric nano-particles suspended in silicone oil
reaches hundreds of kPa, which is orders of magnitude higher than that of
conventional ones. We found that the polar molecules adsorbed on the
particles play a decisive role in such new ER fluids. To explain this polar
molecule dominated ER (PM-ER) effect a model is proposed based on the
interaction of polar molecule-charge between the particles, where the local
electric field is significantly enhanced and results in the polar molecules
aligning in the direction of the electric field. The model can well explain
the giant ER effect and a near-linear dependence of the yield stress on the
electric field. The main effective factors for achieving high-performance
PM-ER fluids are discussed. The PM-ER fluids with the yield stress higher
than one MPa can be expected. 相似文献
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Cheng Hai Hong 《Journal of Macromolecular Science: Physics》2013,52(4):683-692
We synthesized phosphoric acid (PA) doped polyaniline (PANI) particles (PANI‐PA) and investigated their electrorheological (ER) and dielectric characteristics when they were dispersed in silicone oil. Flow curves of the PANI‐PA based ER fluid under several applied electric field strengths were analyzed using a shear stress model. We also examined ER characteristics based on the relaxation time obtained from the dielectric spectrum. 相似文献
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Theoretical investigations on electrorheological (ER) fluids usually rely on computer simulations. An initial approach for these studies would be the point-dipole (PD) approximation, which is known to err considerably when the particles approach and finally touch each other due to many-body and multipolar interactions. Thus various works have attempted to go beyond the PD model. Being beyond the PD model, previous attempts have been restricted to either local-field effects only or multipolar effects only, but not both. For instance, we recently proposed a dipole-induced-dipole (DID) model which is shown to be both more accurate than the PD model and easy to use. This work is necessary because the many-body (local-field) effect is included to put forth the many-body DID model. The results show that the multipolar interactions can indeed be dominant over the dipole interaction, while the local-field effect may yield a correction. 相似文献
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Based on conduction model and cubic particle model, the relationship between current density and shear yield stress of electrorheological (ER) fluids was calculated and compared with some reported experimental results. The conductivity of the insulating oils is found to have been changed by the mixed particles. Several ways to decrease insulating liquid conductivity and increase the conductivity ratio of ER fluids have been proposed to prepare ER fluids with high shear yield stresses but low current densities. 相似文献
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Based on conduction model and cubic particle model, the relationship between current density and shear yield stress of electrorheological (ER) fluids was calculated and compared with some reported experimental results. The conductivity of the insulating oils is found to have been changed by the mixed particles. Several ways to decrease insulating liquid conductivity and increase the conductivity ratio of ER fluids have been proposed to prepare ER fluids with high shear yield stresses but low current densities. 相似文献
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研究了纳米二氧化钛包覆高岭土和钇掺杂钛酸钡两种电流变液的微波反射行为.实验发现,在垂直于微波传播方向电场作用下,两种电流变液微波反射系数均随电场强度的增大而增大;钇掺杂钛酸钡电流变液微波反射系数变化幅度比二氧化钛包覆高岭土电流变液宽,并且电场调节的能力随浓度的增加有减弱的趋势.对钇掺杂钛酸钡电流变液存在一个临界浓度,低于这个浓度,电场的调控能力随电场强度的增加而增大,高于这个浓度,电场的调控能力随电场的增加先增大后减小.另外,二氧化钛包覆高岭土电流变液反射回波相位随电场强度的增大出现最大值后逐渐减小趋于平
关键词:
电流变液
微波反射
相位 相似文献
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物理化学性能稳定的二甲基硅油常作为电流变液分散相, 当与纳米量级的介电颗粒混合组成电流变悬浮液时, 在非密闭环境下极易挥发, 时间足够长时, 可完全挥发. 本文通过实验研究了纳米二氧化钛颗粒对二氧化钛和硅油组成的悬浮液中硅油挥发增强现象, 分析表明, 纳米颗粒在电流变悬浮液的硅油气-液界面上形成纳米尺度的凸型曲面, 使液面上蒸气压大大提高, 导致挥发增强. 本文还对颗粒浓度, 环境温度和硅油黏度等对硅油挥发增强效应的影响进行了系统的研究和分析. 相似文献