近场拉曼光谱在纳米结构表征中的应用

近场拉曼光谱是近场光学领域中的新型技术,因其可对纳米结构进行光谱表征而备受科学研究者的关注。 文章从光学的角度简述了将近场光学与拉曼光谱相结合成为近场拉曼光谱的原理,介绍了近场拉曼光谱技术的优势,详细阐述了近场拉曼光谱在单壁碳纳米管、生物样品、热电晶体、染料分子等纳米结构表征中的应用,展现了近场拉曼光谱技术广阔的应用前景。     

光存储技术中超分辨近场结构研究进展

超分辨近场结构(Super-RENS)是近场光学存储中最具有潜力和应用前景的方案之一。介绍了Super-RENS从基本类型到第三代Super-RENS的发展历程,简述了掩膜材料的研究进展以及Super-RENS在不同记录系统中的应用。展望了它的发展前景。     

纳变尺度的光学成像与纳米光谱：近场光学与近场光学显微镜的进展

近场光学是指当光探测器及探测器一样品间距均小于辐射波长条件下的光学现象，利用近场光学扫描显微镜和近场光谱仪，不但能够以突破衍射极限的超高分辨率在纳米尺度实现光学成像，而且还可获得纳米微区的光谱信息，文章介绍近场光学的原理及其在凝聚态物理领域中的应用与进展，并给出了我们的初步结果。     

半导体四探针技术中二维电流场电势分布有限元分析

对四探针测试半导体薄层电阻中二维电流场的电势分布采用有限元法(FEM)数值计算,并提出了计算模型。对几种常用的测试结构进行计算其电势分布证明了有限元方法的正确性。与以前所采用的镜像源法和图形变换法相比,该方法具有对任意形状的样品和任意放置探针具有同样简单和计算通用的特点。     

近场光学显微镜观察到纳米尺度的折射率变化

日本京都大学研究人员用近场光学显微镜(ＮＳＯＭ)在透明的聚合物膜上制作了纳米尺度的折射率图样 ,而薄膜的透明度及表面形态均未受到严重影响 .实验中用的是 3μｍ厚的聚合物薄膜 ,它是用自转镀层法在甲苯溶液中把在聚合物 (异丁烯酸甲脂ｍｅｔｈｙｌｍｅｔｈａｃｒｙｌａｔｅ)中掺杂的 3 苯基 2 ,5 诺卜拿丁 2羧酸 (3 ｐｈｅｎｙｌ 2 ,5 ｎｏｒｂｏｒｎａｄｉｅｎｅ 2 ｃａｒｂｏｘｙｌｉｃａｃｉｄ)镀到盖板玻璃片上而成的 .折射率图样是用照明模式ＮＳＯＭ设备制作的 ,该设备具有一个剪切力尖端取样距离调节功能 ,以及一个锥形探…     

超分辨近场结构的研究进展及其应用

超分辨近场结构由于突破了传统远场光学衍射极限的限制,在纳米光储存、微纳米加工、基于局域表面等离子体增强的生物传感器方面展现出良好的应用前景,因此吸引了众多研究者的目光.文章简要介绍了超分辨近场结构的发展历程、相应的工作机理、最新研究动态及其在超高密度光存储、近场光刻中的应用状况,并对未来的工作重点做出展望.     

柱形分布的电荷产生的电势

将无限长线电荷看成二维平面上的一个“源”,利用电势叠加原理计算了无限长柱形均匀分布的电荷产生的电势.这些柱体的截面电荷分布包括可解析表示和不可求解表示两种,后者可以通过数值计算给出结果.因此这种方法实际上可以计算任意截面柱形电荷分布的电势.通过计算,展示了各种电荷分布所产生电场的特性和共同特征.     

静电场中零电势点的确定和电势的计算

在静电场中,零电势点位置的确定,对电势计算的方便与否起着致关重要的作用.下面就4种情况,简述零电势点位置的确定及相应电势的计算公式.1 点电荷电场中各点电势的计算 例1 设一带电量为Q的点电荷,放在相对电容率为εT的无限大均匀电介质中,求空间各点的电势.     

基于纳米孔径激光器的近场光存储的最新发展

近几年发展起来的近场光学原理和方法为实现超高密度光学数据存储开辟了新的技术途径。基于近扬光学方法的最小信息记录单元尺寸突破了经典光学分辨率的衍射极限 ,理论存储密度高达 1 0 0 0Gb/平方英寸 ,受到了研究人员和工业界的广泛关注。着重介绍了用于近场光学存储的纳米孔径激光器的原理、结构、优点 ,对它的实现方法和发展状况作了详细的阐述 ,并对其在近场光存储领域未来的发展趋势进行了展望     

纳米尺度的光学成像与纳米光谱———近场光学与近场光学显微镜的进展

近场光学是指当光探测器及探测器－样品间距均小于辐射波长条件下的光学现象．利用近场光学扫描显微镜和近场光谱仪，不但能够以突破衍射极限的超高分辨率在纳米尺度实现光学成像，而且还可获得纳米微区的光谱信息．文章介绍近场光学的原理及其在凝聚态物理领域中的应用与进展，并给出了我们的初步结果     

Electric potential distribution near nanocone arrays on metal substrates

Based on the nanostructured surface model,where conical nanoparticle arrays grow out symmetrically from a plane metal substrate,a theoretical model of the local electric potential near nanocones is built when a uniform external electric field is applied.In terms of this model,the electric potential distribution near the nanocone arrays is obtained and given by a curved surface using a numerical computation method.The computational results show that the electric potential distribution near the nanocone arrays exhibit an obvious geometrical symmetry.These results could serve as a basis for explaining many abnormal phenomena,such as the abnormal infrared effects(AIREs) which are found on nanostructured metal surfaces,as well as a reference for investigating the applications of nanomaterials,such as nanoelectrodes and nanosensors.     

耦合近场仿真及初步验模测试实验研究

针对电磁耦合仿真结果的校验需求,建立了基于光纤电场传感器的验模测试实验系统,对某模型的仿真结果进行了近场耦合验模测试。初步实验结果表明,在一定区域内,测试结果与仿真结果呈现趋势性一致,并对部分区域与仿真结果不符合的原因进行了分析,为下一步仿真模型优化和测试方法手段改进奠定了基础。     

外电场下BH分子势能函数

运用密度泛函B3P86方法和cc-PV5Z基组,获得了BH分子基态在不同外电场下的键长、偶极矩和振动频率等物理性质参数.通过分析物理性质参数,判断离解电场所处的范围,设置合适的参数扫描该范围的单点能获得势能曲线.结果表明物理性质参数和势能值随外电场的变化而变化,特别是在反向电场中.利用Morse势模型拟合无外场下势能函数,得到的拟合参数与实验值吻合较好,采用偶极近似构建外电场下的势能函数模型,编制程序拟合对应的势能函数,得出拟合参数,再计算临界离解电场参量,结果与数值计算值较为一致,说明构建的模型是可靠和准确的.为分析外场下分子光谱、动力学特性和分子Stark效应冷却囚禁提供理论参考.     

Electric Microfield Distributions in Dense One‐ and Two‐Component Plasmas

The electric microfield distributions have been calculated using an integral‐equation method for one‐component plasmas proposed by Iglesias [1] and the coupling‐parameter integration technique for two‐component plasmas proposed by Ortner et al. [2]. Electric microfield distributions are studied in the frame of the Kelbg pseudopotential model, taking into account quantum‐mechanical effects (diffraction, quantum symmetry effects) and screening effects. The screened pseudopotential is represented in a numerically approximated form. The results are compared with simulation results obtained by other authors. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

全内反射式衍射光栅近场光学特性

利用傅里叶模式理论分析了具有高衍射效率的全内反射式衍射光栅在TE 和TM偏振态下的近场光分布特点,讨论了光栅结构参数以及入射角度对光栅内电场增强的影响。结果表明：全内反射光栅内部电场分布对偏振态较敏感,光栅槽深和占宽比对电场增强影响较小,光栅内的峰值电场随光栅周期增大而增大,并且峰值电场随着入射角度的增大而减小。在应用于高功率激光时,降低光栅内部的电场增强可以有效降低损伤风险。     

Partial electrical potential distribution around nanospheres in metallic nanostructured films

In light of the nanostructured surface model, where half-spherical nanoparticles grow out symmetrically from a plane metallic film, the mathematical model for the partial electrical potential around nanospheres is developed when a uniform external electric field is applied. On the basis of these models, the three-dimensional spatial distribution of the partial electrical potential is obtained and given in the form of a curved surface using a numerical computation method. Our results show that the electrical potential distribution around the nanospheres exhibits an obvious geometrical symmetry. These results could serve as a reference for investigating many abnormal phenomena such as abnormal infrared effects, which are found when CO molecules are adsorbed on the surface of nanostructured transition metals.     

Electric Field Gradients of Fluorides Calculated by the Full Potential KKR Green's Function Method

We report on the calculation of electric field gradients (EFGs) of MgF₂, MnF₂, CoF₂, NiF₂ and ZnF₂. EFGs were calculated by the full potential Korringa–Kohn–Rostoker (KKR) Green's function method in the framework of the density functional theory. While EFG calculation of these fluorides are rather difficult in the muffin-tin-potential model, due to its sensitivity to the muffin-tin radius, no difficulties arise in the present full potential treatments. EFGs calculated by this method well reproduce experimental data.     

均匀带电细圆环的电场

限据点电荷电势和场的叠加原理，导出了均匀带电细圆环电势和电场的级数表达式．     

Piano-Convex Solid Immersion Mirror with a Small Aperture for Near-field Optical Data Storage

We proposed and developed a new solid immersion mirror (SIM) for near-field optical data storage. The SIM has some advantages, especially in manufacturing, because its shape is similar to a general plano-convex lens. Making an aperture of about 130 nm in diameter just on the focus area of the SIM, a bit-data recording onto a photochromic thin film was carried out. Minimum diameter of the written marks was estimated to be 180nm. We also demonstrated readout experiments where a recorded medium was rotating and a gap between the SIM and the disk was controlled with capacitance sensing. This is the first result of reading with a rotating disk using an SIM containing a small aperture.This paper was originally presented at the 10th Optical Near Field Workshop, which was held on June 27-28, 2001 at Osaka University, organized by the Optical Near Field Group, the Optical Society of Japan, an affiliate of the Japan Society of Applied Physics.