Effects of anionic additives on the rheological behavior of aqueous calcium montmorillonite suspensions

Three different experimental measurements, namely, rheology, particle sizing, and x-ray diffraction (XRD), were used to study the effect of anionic additives on the properties of bentonite suspensions. The three additives were sodium carboxymethylcellulose, xanthan gum, and sodium dodecyl sulfate. Flow curves were obtained from shear stress–shear rate measurements, and the viscoelastic properties were determined from oscillatory and transient measurements. Mineralogical data were evaluated by XRD and the particle size analysis performed by light scattering technique. The presence of the surfactant modifies the face-to-face interactions and yields changes of the mixtures rheological behavior at low deformation rates. Polymers act by coating each clay particle and prevent their agglomeration. Therefore, the additives are responsible for the mechanisms of destructuration and structure reorganization as well as the mixtures viscous and viscoelastic behavior.     

不可压饱和多孔弹性梁、杆动力响应的数学模型

基于多孔介质理论,首先建立了饱和多孔弹性杆件弯曲与轴向变形时动力响应的数学模型.其次,基于多孔弹性梁弯曲变形的数学模型,利用Laplace变换,分析了两端可渗透的饱和多孔弹性悬臂梁在自由端受阶梯载荷作用下的动静力响应,给出了梁弯曲时挠度、弯矩以及孔隙流体压力等效力偶等物理量随时间的响应曲线.发现不可压多孔弹性梁的拟静态响应亦存在Mandel-Cryer现象,多孔弹性梁的挠度具有与粘弹性梁挠度类似的蠕变特征,然而,其应力响应不同于粘弹性梁,随着时间的增加,梁拟静态响应的弯矩逐渐增加,并达到一个稳态值.这些结果有助于揭示植物根茎等力学行为的机理.     

高体积含量非线性黏弹复合材料有效性质

提出了一个细观力学模型,可用于预测高体积含量非线性黏弹复合材料有效性质.该模型基于广义割线模量法、双球法以及Laplace-Carson变换技术.所提出的模型对玻璃微珠填充高密度聚乙烯(GB/HDPE)复合材料的应力应变关系进行了预测,结果与文献实验结果吻合;计算结果还表明在高体积百分比下文中所提出的方法比基于MT方法预测的粘性效应明显减弱;最后还将所提方法与线黏弹框架下的均质化模型做了比较,结果表明GB/HDPE表现出明显的非线性,线黏弹本构无法描述应变率对其力学行为的影响.     

Oldroyd-B黏弹性液滴弹跳行为的改进SPH模拟

基于光滑粒子流体动力学SPH(Smoothed Particle Hydrodynamics)方法对Oldroyd-B黏弹性液滴撞击固壁面产生的弹跳行为进行了模拟与分析。首先,为了解决SPH模拟黏弹性自由表面流出现的张力不稳定性问题,联合粒子迁移技术提出了一种改进SPH方法。然后,对Oldroyd-B黏弹性液滴撞击固壁面产生的铺展行为进行了改进SPH模拟,与文献结果的比较验证了方法的有效性。最后,通过降低Reynolds数捕捉到了液滴的弹跳行为;并在此基础上,分析了液滴黏度比、Weissenberg数和Reynolds数对液滴弹跳行为的影响。结果表明,改进SPH方法可有效地模拟黏弹性自由表面流问题;液滴黏度比、Weissenberg数和Reynolds数对液滴最大回弹高度均有显著的影响。     

Étude de l?adhérence des joncs et des plats composite avec le béton par flexion (beam test)

The Near Surface Mounted (NSM) technique has been used in recent years for the strengthening of reinforced concrete beams. It involves the insertion of strips or rods of polymers reinforced with carbon fiber (CFRP) in the groove made previously in the concrete cover of corresponding surfaces, filled with epoxy adhesive for fixation. In order to characterize the bond behavior of the laminate and rods to concrete, an experimental work of pullout-bending tests was carried out. The pullout force at the laminate and the slip at the free and loaded end were measured. The influences of the concrete strength, the strength of the bond, and bond length on the bonding behavior between the three materials concrete, epoxy adhesive and CFRP were analyzed.     

Linear viscoelasticity of styrenic block copolymers–clay nanocomposites

In this work, the rheological behavior of block copolymers with different morphologies (lamellar, cylindrical, spherical, and disordered) and their clay-containing nanocomposites was studied using small amplitude oscillatory shear. The copolymers studied were one asymmetric starblock styrene–butadiene–styrene copolymer and four styrene–ethylene/butylenes–styrene copolymers with different molecular architectures, one of them being modified with maleic anhydride. The nanocomposites of those copolymers were prepared by adding organophilic clay using three different preparation techniques: melt mixing, solution casting, and a hybrid melt mixing–solution technique. The nanocomposites were characterized by X-ray diffraction and transmission electron microscopy, and their viscoelastic properties were evaluated and compared to the ones of the pure copolymers. The influence of copolymer morphology and presence of clay on the storage modulus (G′) curves was studied by the evaluation of the changes in the low frequency slope of log G′× logω (ω: frequency) curves upon variation of temperature and clay addition. This slope may be related to the degree of liquid- or solid-like behavior of a material. It was observed that at temperatures corresponding to the ordered state, the rheological behavior of the nanocomposites depended mainly on the viscoelasticity of each type of ordered phase and the variation of the slope due to the addition of clay was small. For temperatures corresponding to the disordered state, however, the rheological behavior of the copolymer nanocomposites was dictated mostly by the degree of clay dispersion: When the clay was well dispersed, a strong solid-like behavior corresponding to large G′ slope variations was observed.     

Evidence for re-entrant behavior in laponite–PEO systems

We observe evidence of re-entrant behavior in dispersions of a discotic clay, laponite, with added polymer. Under basic conditions, neat laponite forms a disordered colloidal glass. Rheologically, this phase behaves as a viscoelastic solid, and dynamic light scattering shows evidence of non-ergodic behavior. Addition of low molecular weight poly(ethylene oxide) (PEO) melts the glass, resulting in a low-viscosity liquid with fast dynamics. We believe this is due to a depletion force caused by excess PEO chains in solution. A viscoelastic solid is re-formed with the addition of high molecular weight PEO, which we believe to be caused by polymer chains bridging between laponite particles. The physics in our system is quite different from the hard sphere/nonadsorbing polymer systems for which re-entrant glass transitions have been reported in the literature; however, we believe there may be similarities between these phenomena. To our knowledge, this is the first evidence of a type of re-entrant behavior in anisotropic colloids.     

Effective viscoelastic behavior of particulate polymer composites at finite concentration

Polymeric materials usually present some viscoelastic behavior. To improve the mechanical behavior of these materials, ceramics materials are often filled into the polymeric materials in form of fiber or particle. A micromechanical model was proposed to estimate the overall viscoelastic behavior for particulate polymer composites, especially for high volume concentration of filled particles. The method is based on Laplace transform technique and an elastic model including two-particle interaction. The effective creep compliance and the stress and strain relation at a constant loading rate are analyzed. The results show that the proposed method predicts a significant stiffer response than those based on Mori-Tanaka's method at high volume concentration of particles.     

大发小轿车发动机连杆的疲劳性能研究

本文对大发小轿车发动机连杆进行了疲劳性能测试，发现绝大部分连杆都在压痕根部处断裂，为此对压痕所造成的残余应力进行了测试和研究，提出了提高连杆疲劳性能的措施。本文在循环应力比Ｒ从２．５到—３之间进行了广泛的疲劳试验，并找到包括平均压应力范围等寿命曲线规律，对平均压应力在疲劳中的作用有了进一步认识。     

Fully resolved simulations of viscoelastic suspensions by an efficient immersed boundary-lattice Boltzmann method

An efficient immersed boundary-lattice Boltzmann method (IB-LBM) is proposed for fully resolved simulations of suspended solid particles in viscoelastic flows. Stress LBM based on Giesekus and Oldroyd-B constitutive equation are used to model the viscoelastic stress tensor. A boundary thickening-based direct forcing IB method is adopted to solve the particle–fluid interactions with high accuracy for non-slip boundary conditions. A universal law is proposed to determine the diffusivity constant in a viscoelastic LBM model to balance the numerical accuracy and stability over a wide range of computational parameters. An asynchronous calculation strategy is adopted to further improve the computing efficiency. The method was firstly applicated to the simulation of sedimentation of a single particle and a pair of particles after good validations in cases of the flow past a fixed cylinder and particle migration in a Couette flow against FEM and FVM methods. The determination of the asynchronous calculation strategy and the effect of viscoelastic stress distribution on the settling behaviors of one and two particles are revealed. Subsequently, 504 particles settling in a closed cavity was simulated and the phenomenon that the viscoelastic stress stabilizing the Rayleigh–Taylor instabilities was observed. At last, simulations of a dense flow involving 11001 particles, the largest number of particles to date, were performed to investigate the instability behavior induced by elastic effect under hydrodynamic interactions in a viscoelastic fluid. The elasticity-induced ordering of the particle structures and fluid bubble structures in this dense flow is revealed for the first time. These simulations demonstrate the capability and prospects of the present method for aid in understanding the complex behaviors of viscoelastic particle suspensions.     

Rotational and translational diffusivities of germanium nanowires

Understanding the rheological behavior of dilute dispersions of cylindrical nanomaterials in fluids is the first step towards the development of rheological models for these materials. Individual particle tracking was used to quantify the rotational and translational diffusivities of high-aspect-ratio germanium nanowires in alcohol solvents at room temperature. In spite of their long lengths and high aspect ratios, the rods were found to undergo Brownian motion. This work represents the first time that the effects of solvent viscosity and confinement have been directly measured and the results compared to proposed theoretical models. Using viscosity as a single adjustable parameter in the Kirkwood model for Brownian rods was found to be a facile and versatile way of predicting the diffusivities of nanowires across a broad range of length scales.     

Dynamic rheological properties of a fumed silica grease

The thermo-rheological characteristics of a fumed silica lubricating grease in linear and nonlinear oscillatory experiments have been investigated. The material rheological behavior represents a soft solid being thermo-rheologically complex. There is an abnormal temperature dependency in the range of ??10 to 10 °C which is related to the phase transition of the base oil. The dynamic moduli data in linear viscoelastic envelop (LVE) have been modeled using mode-coupling theory (MCT) in the whole temperature range. Two main relaxation mechanisms can be identified through linear and nonlinear viscoelastic properties related to interaction of the primary particle and its neighbor particles as well as a slow relaxation process which represents the escape of this particle from its “cage”. Finally, it is demonstrated that the dominant yielding process in large amplitude oscillatory experiments can be explained based on either particle cage rupture (consistent with MCT framework) or particle “hopping” out of its cage proposed in soft glassy rheology (SGR) model. It will be discussed that the governing mechanism depends on the applied frequency.     

Non-linear viscoelastic behavior of fumed silica suspensions

Suspensions of fumed silica exhibit a wide range of rheological properties depending on the nature and magnitude of the interparticle forces. In a non-polar fluid, the particles interact through hydrogen bonding and can form a three-dimensional network. The microstructure formation is responsible for the non-linear viscoelastic behavior of fumed silica suspensions, even at very small strain. These non-linear rheological properties have been studied in small amplitude oscillatory experiments as a function of particle size, surface treatment of particles, suspending medium polarity and solids concentration. The non-linear viscoelastic behavior is characterized by a non-sinusoidal waveform of the signal response. For suspensions in a non-polar fluid, both the elastic and the loss moduli are shown to be sensitive to the strain amplitude: the elastic modulus is decreasing with increasing strain whereas the loss moduli is initially increasing with strain. We have chosen to examine the dissipated energy which is clearly related to the breakup of the suspension structure. A comparison of model predictions and the experimental data shows the limitations of these models, recently proposed in the literature to describe the behavior of colloidal suspensions. Received: 9 March 1998 Accepted: 17 November 1998     

Creeping flow through a model fibrous porous medium

Pressure losses and velocity distributions were measured for creeping flow through three model fibrous porous media. The three models consisted of square arrays of circular rods with solid volume fractions of 2.5, 5 and 10%. Measurements of flow resistances are in good agreement with theoretical predictions after wall effects are accounted for using Brinkman’s equation. Two-dimensional velocity vector maps were obtained in each array using particle image velocimetry. The velocity distributions are necessary for identifying non-Newtonian effects in flows with viscoelastic fluids.     

Transient analysis of viscoelastic helical rods subject to time-dependent loads

The transient analysis of viscoelastic helical rods subject to time-dependent loads are examined in the Laplace domain. The governing equations for naturally twisted and curved spatial rods obtained using the Timoshenko beam theory are rewritten for cylindrical helical rods. The curvature of the rod axis, effect of rotary inertia and, shear and axial deformations are considered in the formulation. The material of the rod is assumed to be homogeneous, isotropic and linear viscoelastic. The viscoelastic constitutive equations are written in the Boltzmann–Volterra form. Ordinary differential equations in canonical form obtained in the Laplace domain are solved numerically using the complementary functions method to calculate the dynamic stiffness matrix of the problem. The solutions obtained are transformed to the real space using an appropriate numerical inverse Laplace transform method. Numerical results for quasi-static and dynamic response of viscoelastic models are presented in the form of graphics.     

Nonlinearly Viscoelastic Nanoindentation of PMMA Under a Spherical Tip

The Oliver-Pharr method has been well established to measure Young’s modulus and hardness of materials without time-dependent behavior in nanoindentation. The method, however, is not appropriate for measuring the viscoelastic properties of materials with pronounced viscoelastic effects. One well-known phenomenon is the formation of unloading “nose” or negative stiffness during unloading that often occurs during slow loading-unloading in nanoindentation on a viscoelastic material. Most methods in literature have only considered the loading curve for analysis of viscoelastic nanoindentation data while the unloading portion is not analyzed adequately to determine the nonlinearly viscoelastic properties. In this paper, nonlinearly viscoelastic effects are considered and modeled using the nonlinear Burgers model. Nanoindentation was conducted on poly-methylmethacrylate (PMMA) using a spherical indenter tip. An inverse problem solving approach is used to allow the finite element simulation results to agree with the nanoindentation load–displacement curve during the entire loading and unloading stage. This approach has allowed the determination of the nonlinearly viscoelastic behavior of PMMA at submicron scale. In addition, the nanoindentation unloading “nose” has been captured by simulation, indicating that the negative stiffness in the viscoelastic material is the result of memory effect in time-dependent materials.     

Shock pulse attenuation in a nonlinear viscoelastic solid

Thin, one-dimensional shock pulses were generated in a nonlinear viscoelastic material (polymethyl methacrylate) by a new experimental technique. The observed pulse attenuation was compared with an approximate theory based on the viscoelastic shock amplitude equation. The central assumption of this approximate theory is that the unloading wave propagates as a simple wave. Given an initial pulse shape it is shown that the attenuation and the pulse shape at any later time are accurately approximated. The calculated attenuation in polymethyl methacrylate agreed well with the experimental results.     

Inverse problem for the viscoelastic medium with discontinuous wave impedance

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Rheology of cocoa-pod husk aqueous system. Part-I: steady state flow behavior

A fundamental rheological data describing the flow behavior of an aqueous system prepared from an agricultural harvest residue, cocoa-pod husk in fixed chemical environment, has been presented. Shear stress and viscosity data were obtained and analyzed at different solid concentrations in order to investigate basic particle interactions and how far the aqueous system conforms to relevant standard rheological models. The resulting suspension is a complex non-Newtonian thixotropic viscoelastic system, highly flocculating, weakly gel-like and conforming reasonably with the Power-Law, Herschel-Bulkley, Cross, and Carreau models. The result is consistent with that of a flocculated system indicating that this agricultural waste could serve as a filler material in conventional organic-based matrix materials for affordable composite fabrication for panels.     

线黏弹性球面发散应力波的频率响应特性

基于线黏弹性球面波Laplace域的理论解, 得到了不同传播距离处粒子速度、粒子位移、应力、应变等力学量的传递函数。以标准线性固体模型为例, 重点讨论了粒子速度频率响应函数的传播特征, 指出随着传播距离的增加, 粒子速度幅频响应函数的高频响应会低于低频响应, 而在理想弹性条件下, 粒子速度幅频响应函数的高频响应一直高于低频响应。以弹性半径为0.025 m的空腔爆炸为例, 采用Laplace数值逆变换方法对粒子速度波形的演化进行了分析, 给出了粒子速度强间断幅值及粒子速度峰值随传播距离变化的衰减规律曲线, 指出黏弹性介质中粒子速度幅值的衰减曲线介于理想弹性介质中粒子速度幅值衰减曲线和黏弹性介质中粒子速度强间断幅值衰减曲线之间。