仿生辐射制冷的研究进展

辐射制冷是一种通过光谱调控来实现降温的新型制冷技术,相比于传统的主动制冷技术,如吸收式制冷、压缩制冷等,具有独特的优势,在环境保护和能源利用方面具有重要意义.本文首先从辐射制冷的基本原理出发,介绍了自然界中生物所具有的辐射降温特性.不同生物通过其材料、微观结构、行为等实现辐射制冷调控,为人类探究新型辐射制冷材料和器件带来了启发.本文也归纳了生物的辐射制冷机制,总结了生物结构的优化方法,并介绍了当前仿生辐射制冷的研究进展,对仿生辐射制冷的研究方向、应用前景和材料制备方法进行了展望.高功率、智能化的辐射制冷材料和器件是未来仿生辐射制冷的重要发展方向,先进微纳加工技术的融入将使仿生辐射制冷在未来具有更广阔的市场和应用.     

Effect of radiative cooling on collapsing charged grains

The effect of the radiative cooling of electrons on the gravitational collapse of cold dust grains with fluctuating electric charge is investigated. We find that the radiative cooling as well as the charge fluctuations, both, enhance the growth rate of the Jeans instability. However, the Jeans length, which is zero for cold grains and nonradiative plasma, becomes finite in the presence of radiative cooling of electrons and is further enhanced due to charge fluctuations of grains resulting in an increased threshold of the spatial scale for the Jeans instability.     

亚微米局域空心光束的产生及其在单原子囚禁与冷却中的应用理论研究

提出了一种采用单模光纤、环形二元相位板和微透镜组成的光束整形系统产生亚微米局域空心光束的方案. 根据瑞利-索莫菲衍射积分公式, 数值计算了微透镜焦平面附近的场分布, 详细研究了空心光束的暗斑尺寸与单模光纤模场半径和微透镜焦距的关系. 数值计算结果表明: 在微透镜焦平面附近光场分布近似对称, 在焦点处场强近似为零, 周围场强逐渐增大, 形成半径约为0.4 μm的三维封闭的球形空心光场区域, 即亚微米局域空心光束. 当局域空心光束为蓝失谐时, 光场中的原子将被囚禁在光场最弱处. 若加上抽运光, 原子将受到蓝失谐局域空心光束与抽运光共同激发的强度梯度Sisyphus冷却. 本文利用该方案产生的亚微米局域空心光束构建单原子的囚禁与冷却器件, 并以单个⁸⁷Rb原子为例, 利用Mont-Carlo方法研究亚微米局域空心光束中单原子囚禁与强度梯度冷却的动力学过程, 结果表明利用该器件可以获得温度在5.8 μK量级的超冷单原子.     

Properties of plasma radiation during discharges with improved confinement on HL-2A Tokamak

In the recent experiment on the HL-2A tokamak,two types of improved confinement regimes have been achieved in different configurations.One is the improved confinement regime in limiter configuration during electron cyclotron resonant heating (ECRH),characterized by a sharp decrease in H α emission accompanied by an increase in the total radiation of plasma,the line averaged electron density and the stored energy of plasma.The other is high confinement regime (H-mode) in divertor configuration during a combination of ECRH and Neutral beam injection (NBI) heating,characterized with edge localized modes (ELMs) besides the features mentioned above.The ELMs are found to be localized on the plasma edge (r/a ≥ 0.8),causing average losses of particles and stored energy in the ranges of about 1-3% and 3-5% respectively during a single ELM event.So far,the ELMs observed in the HL-2A are type III ELMs with low amplitude and high repetition frequency in a range from 200 Hz to 350 Hz.An investigation of the radiated power density profiles shows that radiative cooling effect plays a significant role in the transition back to the L-mode and the triggering of ELM events.     

Efficient one-pot synthesis of Ag nanoparticles loaded on N-doped multiphase TiO2 hollow nanorod arrays with enhanced photocatalytic activity

The simultaneous Ag loaded and N-doped TiO₂ hollow nanorod arrays with various contents of silver (Ag/N-THNAs) were successfully synthesized on glass substrates by one-pot liquid phase deposition (LPD) method using ZnO nanorod arrays as template. The catalysts were characterized by Raman spectrum, field-emission scanning electron microscopy (FESEM), high-resolution transmission electron microscope (HRTEM), ultraviolet-vis (UV-vis) absorption spectrum and X-ray photoelectron spectroscopy (XPS). The results suggest that AgNO₃ additive in the precursor solutions not only can promote the anatase-to-rutile phase transition, but also influence the amount of N doping in the samples. The photocatalytic activity of all the samples was evaluated by photodegradation of methylene blue (MB) in aqueous solution. The sample exhibited the highest photocatalytic activity under UV light illumination when the AgNO₃ concentration in the precursor solution was 0.03 M, due to Ag nanoparticles acting as electron sinks; When the AgNO₃ concentration was 0.07 M, the sample performed best under visible light illumination, attributed to the synergetic effects of Ag loading, N doping, and the multiphase structure (anatase/rutile).     

Efficient radiative transfer simulations for a broadband infrared radiometer—Combining a weighted mean of representative frequencies approach with frequency selection by simulated annealing

We present a method to efficiently simulate the measurements of a broadband infrared instrument. The High Resolution Infrared Radiation Sounder (HIRS) instrument is used as example to illustrate the method. The method uses two basic ideas. Firstly, the channel radiance can be approximated by a weighted mean of the radiance at some representative frequencies, where the weights can be determined by linear regression. Secondly, a near-optimal set of representative frequencies can be found by simulated annealing.The paper does not only describe and analyze the method, it also describes how the method was used to derive optimized frequency grids for the HIRS instruments on the satellites TIROS N, NOAA 6-19, and Metop A. The grids and weights as well as the optimization algorithm itself are openly available under a GNU public license.     

Mechanism of the excitation of single pure mode L（0, 2） and its interaction with the defect in a hollow cylinder

Guided elastic waves have a great potential in pipe inspection as an efficient and low-cost nondestructive evaluation （NDE） technique, among which the wave of mode L（0, 2） receives a lot of attention because this mode is the fastest mode in a weakly dispersive region of frequency to minimize dispersion effects over a long distance and sensitive to the defects distributed circumferentially. Though many experimental and numerical researches have already been carried out about the excitation of L（0, 2） and its interaction with the defect in a hollow cylinder, its excitation mechanism has not been clarified yet. In this paper based on the transient response solution of the hollow cylinder, derived by the method of eigenfunction expansion, the theory about the exciting mechanism of mode L（0, 2） is advanced and the effects of the spatial distribution, vibration frequency and direction of the external force on the excitation are discussed. And the pure mode L（0, 2） is excited successfully under the parameters obtained through theoretical analysis. Furthermore, its interactions with some kinds of defects in hollow cylinders are simulated with the method of finite element analysis （FEA） and the results agree well with those obtained by other researchers.     

Preparation and characterization of novel Pd/SiO2 and Ca-Pd/SiO2 egg-shell catalysts with porous hollow silica

Novel egg-shell structured monometallic Pd/SiO₂ and bimetallic Ca-Pd/SiO₂ catalysts were prepared by an impregnation method using porous hollow silica (PHS) as the support and PdCl₂ and Ca(NO₃)₂·4H₂O as the precursors. It was found from transmission electron microscope (TEM), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD) that Pd was loaded on PHS with a particle size of 5-12 nm in Pd/SiO₂ samples and the Pd particle size in Ca-Pd/SiO₂ was smaller than that in Pd/SiO₂ since Ca could prevent Pd particles from aggregating. X-ray photoelectron spectroscopy (XPS) analyses exhibited that Pd 3d_5/2 binding energies of Pd/SiO₂ and Ca-Pd/SiO₂ were 0.2 and 0.9 eV lower than that of bulk Pd, respectively, as a result of the shift of the electron cloud from Pd to oxygen in Pd/SiO₂ and to both oxygen and Ca in Ca-Pd/SiO₂. The activity of Ca-Pd/SiO₂ egg-shell catalyst for CO hydrogenation and the selectivity to methanol, with a value of 36.50 mmol_CO mol⁻¹_Pd s⁻¹ and 100%, respectively, were much higher than those of the catalysts prepared with traditional silica gel as the support, owing to the porous core-shell structure of the PHS support.     

Experimental quantification of natural convective heat transfer within annulus space filled with a H2O-Cu nanofluid saturated porous medium. Application to electronics cooling

This experimental study deals with cooling electronics contained in a hemispherical cavity whose cupola is maintained isothermal, being its base inclined at an angle varying from 0° (horizontal disc with the cupola oriented upwards) to 135°. The active component is a dome centered on this base. The space between the differentially heated elements of the assembly is filled with a porous medium of high porosity saturated by a water–copper nanofluid whose volume fraction varies between 0% (pure water) and 7%. The Rayleigh number based on the radius of the cupola reaches high values up to 7.29 × 10¹⁰ given the important surface heat flux generated by the device during operation. The ratio between the thermal conductivity of the solid matrix and that of the base fluid ranges between 0 (interstitial volume without porous medium) and 41.4 corresponding to the intended applications. This experimental study done with an industrial prototype at scale 1 quantifies the natural convective heat transfer via the Nusselt number determined for many configurations obtained by varying the solid-fluid thermal conductivity ratio, the inclination angle, the Rayleigh number, and the volume fraction. The study clearly shows that the cooling performance of the Cu-H₂O nanofluid degrades with its age and the number of times it has been used. Analysis of the results reproducibility also proves the irreversibility of the performance. The measured values were compared with those obtained in a recent numerical study based on the volume control method. The observed deviations taking into account the experimental uncertainty margins validate the mathematical model implemented in the numerical approach.