Plasmon‐driven catalysis in aqueous solutions probed by SERS spectroscopy

Since 2010, the plasmon‐driven catalysis using surface‐enhanced Raman spectroscopy (SERS) in atmospheric environment has been experimentally reported. Recent experimental results since 2014 revealed that catalysis under aqueous condition is much better than that in atmospheric environment. In this paper, we review plasmon‐driven catalysis using SERS under aqueous condition. First, the experimental apparatus developed by ourselves is introduced in detail. Second, we demonstrate the advantages of plasmon‐driven catalysis using SERS under aqueous condition compared to that in atmospheric environment. Third, we review recent experimental results using this measurement method in different experimental settings under aqueous condition. The manipulation of reaction environment effectively provided the possibility to reveal the mechanism of surface plasmon catalysis for different reactions. This method has great potential to apply on ultrasensitive spectral analysis for SERS, catalysis, sensor and biology system under aqueous condition. Copyright © 2016 John Wiley & Sons, Ltd.     

用表面磁光克尔效应实验系统测量铁磁性薄膜的磁滞回线

用自制的表面磁光克尔效应实验系统开发了研究性近代物理实验,测出铁磁性薄膜的磁滞回线,并求得克尔旋转角和克尔椭偏率.     

Effects of size and surface anisotropy on thermal magnetization and hysteresis in the magnetic clusters

Based on Monte Carlo simulation, the spin configurations, thermal magnetization and hysteresis loops of the clusters coated by the surface shell with radial anisotropy are studied. Interestingly, a new multidomain containing a few of subdomains whose easy directions are along those of the configurational anisotropy, a magnetization curve in steps and a first order phase transition from the single domain to the multidomain in the thermal and field magnetization processes, are found, which is as a result of the interplay of the configurational anisotropy, the size effect, the surface anisotropy, the applied field and the thermal fluctuation. In this first order transition, we find a critical temperature, a critical surface anisotropy and a critical size. The simulated temperature dependence of the coercivity of the cluster with the surface anisotropy can be fitted by H_c (T)=H_c (0)(1-C_αT^α) with low value of α, which explains well the experimental results of the nanoparticles. Moreover, it is found that the hysteresis loops and coercivity are strongly affected by the cluster size and the thickness of the surface layer.     

Investigation of hypersonic flows through a cavity with sweepback angle in near space using the DSMC method

Near space has been paid more and more attentionin recent years due to its military application value.However,flow characteristics of some fundamental configurations(e.g.,the cavity) in near space have rarely been investigated due to rarefied gas effects,which make the numerical simulation methods based on continuous flow hypothesis lose validity.In this work,the direct simulation Monte Carlo(DSMC),one of the most successful particle simulation methods in treating rarefied gas dynamics,is employed to explore flow characteristics of a hypersonic cavity with sweepback angle in near space by considering a variety of cases,such as the cavity at a wide range of altitudes 20-60 km,the cavity at freestream Mach numbers of 6-20,and the cavity with a sweepback angle of 30°-90°.By analyzing the simulation results,flow characteristics are obtained and meanwhile some interesting phenomena are also found.The primary recirculation region,which occupies the most area of the cavity,causes pressure and temperature stratification due to rotational motion of fluid inside it,whereas the pressure and temperature in the secondary recirculation region,which is a small vortex and locates at the lower left corner of the cavity,change slightly due to low-speed movement of fluid inside it.With the increase of altitude,both the primary and secondary recirculation regions contract greatly and it causes them to separate.A notable finding is that rotation direction of the secondary recirculation region would be reversed at a higher altitude.The overall effect of increasing the Mach number is that the velocity,pressure,and temperature within the cavity increase uniformly.The maximum pressure nearby the trailing edge of the cavity decreases rapidly as the sweepback angle increases,whereas the influence of sweepback angle on velocity distribution and maximum temperature within the cavity is slight.     

Analytical close-form solutions to the elastic fields of solids with dislocations and surface stress

The concept of eigenstrain is adopted to derive a general analytical framework to solve the elastic field for 3D anisotropic solids with general defects by considering the surface stress. The formulation shows the elastic constants and geometrical features of the surface play an important role in determining the elastic fields of the solid. As an application, the analytical close-form solutions to the stress fields of an infinite isotropic circular nanowire are obtained. The stress fields are compared with the classical solutions and those of complex variable method. The stress fields from this work demonstrate the impact from the surface stress when the size of the nanowire shrinks but becomes negligible in macroscopic scale. Compared with the power series solutions of complex variable method, the analytical solutions in this work provide a better platform and they are more flexible in various applications. More importantly, the proposed analytical framework profoundly improves the studies of general 3D anisotropic materials with surface effects.     

外部光注入的光泵浦自旋垂直腔表面发射激光器中的两个混沌偏振分量对两个复杂形状目标中的多区域精确测距

基于外部光注入的光泵浦自旋垂直腔表面发射激光器(vertical cavity surface-emitting laser,VCSEL)的两个混沌偏振分量,提出了对两个复杂形状目标中的多区域精确测距方案.这里,两个混沌偏振探测波具有飞秒量级快速动态并且被双极性sinc波形调制,使它们具有时空不相关特性.利用这些特性,...     

Granular flows in a rotating drum: the scaling law between velocity and thickness of the flow

The flow of dry granular material in a half-filled rotating drum is studied. The thickness of the flowing zone is measured for several rotation speeds, drum sizes and beads sizes (size ratio between drum and beads ranging from 47 to 7400). Varying the rotation speed, a scaling law linking mean velocity vs. thickness of the flow, v∼h^m, is deduced for each couple (beads, drum). The obtained exponent m is not always equal to 1, the value previously reported for a drum in litterature, but varies with the geometry of the system. For small size ratios, exponents higher than 1 are obtained due to a saturation of the flowing zone thickness. The exponent of the power law decreases with the size ratio, leading to exponents lower than 1 for high size ratios. These exponents imply that the velocity gradient of a dry granular flow in a rotating drum is not constant. More fundamentally, these results show that the flow of a granular material in a rotating drum is very sensible to the geometry, and that the deduction of the “rheology” of a granular medium flowing in such a geometry is not obvious.     

Grain boundary grooving in bi-crystal thin films induced by surface drift-diffusion driven by capillary forces and applied uniaxial tensile stresses

Grain boundary (GB) grooving, induced by surface drift-diffusion and driven by the combined actions of capillary forces and applied uniaxial tensile stresses, is investigated in bi-crystal thin films using self-consistent dynamical computer simulations. A physico-mathematical model, based on the irreversible thermodynamics treatment of surfaces and interfaces with singularities allowed auto-control of the otherwise free-motion of the triple junction at the intersection of the grooving surface and the GB, without having any a priori assumption on the equilibrium dihedral angles. In the present theory, the generalised driving forces for stress-induced surface drift-diffusion arise not only from the usual elastic strain energy density (ESED), but also much stronger elastic dipole tensor interactions (EDTI) between the applied stress field and the mobile atomic species situated at the surface layer and in the GB regions. Accelerated groove-deepening kinetics shows that the surface drift-diffusion enhanced by the applied uniaxial tensile stresses through EDTI is dominant over the GB flux leakage at the triple junction. At high uniaxial stress levels (≥500?MPa for a 100-nm thick copper film), a sequential time-frame for micro-crack nucleation and growth is recorded just before specimen failure took place. These non-equilibrium thermokinetics discoveries (kinetics and energetics) contradict or at least do not support the hypothesis of the steady-state diffusive GB micro-crack formation and propagation due to ‘constant’ flux drainage through GB enhanced by tensile stresses acting normal to it.     

Exact solutions for the flow of Casson fluid over a stretching surface with transpiration and heat transfer effects

The effects of transpiration on forced convection boundary layer non-Newtonian fluid flow and heat transfer toward a linearly stretching surface are reported.The flow is caused solely by the stretching of the sheet in its own plane with a velocity varying linearly with the distance from a fixed point.The constitutive relationship for the Casson fluid is used.The governing partial differential equations corresponding to the momentum and energy equations are converted into non-linear ordinary differential equations by using similarity transformations.Exact solutions of the resulting ordinary differential equations are obtained.The effect of increasing Casson parameter,i.e.,with decreasing yield stress(the fluid behaves as a Newtonian fluid as the Casson parameter becomes large),is to suppress the velocity field.However,the temperature is enhanced as the Casson parameter increases.It is observed that the effect of transpiration is to decrease the fluid velocity as well as the temperature.The skin-friction coefficient is found to increase as the transpiration parameter increases.     

Charge order driven by Fermi-arc instability and its connection with pseudogap in cuprate superconductors

The recently discovered charge order is a generic feature of cuprate superconductors, however, its microscopic origin remains debated. Within the framework of the fermion-spin theory, the nature of charge order in the pseudogap phase and its evolution with doping are studied by taking into account the electron self-energy (then the pseudogap) effect. It is shown that the antinodal region of the electron Fermi surface is suppressed by the electron self-energy, and then the low-energy electron excitations occupy the disconnected Fermi arcs located around the nodal region. In particular, the charge order state is driven by the Fermi-arc instability, with a characteristic wave vector corresponding to the hot spots of the Fermi arcs rather than the antinodal nesting vector. Moreover, although the Fermi arc increases its length as a function of doping, the charge order wave vector reduces almost linearity with the increase of doping. The theory also indicates that the Fermi arc, charge order and pseudogap in cuprate superconductors are intimately related to each other, and all of them emanates from the electron self-energy due to the interaction between electrons by the exchange of spin excitations.     

小孔流速实验中的排水时间和流量系数的研究

本文以水作为理想流体,考虑到水头损失和孔口缩流效应,对小孔流速实验涉及的容器排水问题进行了系统的理论和实验研究.从理论上推导得出了圆柱形容器排水时间的解析解,分析了排水时间和自由液面速度、流量系数之间的规律,提出了排水时间的等效性.实验上,加工了底部开有不同小孔的大型圆柱形容器,测量了容器排水时间随液面高度的变化关系,借助实验结果计算了流量系数值,验证了容器排水时间的等效性关系,实验结果与理论计算符合较好.     

周期地嵌入电介质球壳的金属表层的表面等离子激元及其与电介质腔体模式的耦合

通过观察金属底板中周期地嵌入电介质球壳的体系的光学吸收性质，研究了表面等离子激元 以及与其他电磁模式的耦合特性.在这种周期结构的金属表面，发现存在两种响应频率，分 别对应于表面等离子激元模式和金属中的电介质腔体模式.在这些响应频率上，可观察到与 它们相对应的吸收峰.由于金属的表面模式不能与平面入射光直接耦合，而腔体模式与平面 入射光和表面等离子激元模式的耦合一般较弱，因而通常情况下这些吸收峰的峰值有限.然 而，通过调整体系中的某些参数，可以使腔体模式和表面模式的频率非常接近，这时二者之 间的耦合强度将大大提高.此时，在相应的频率附近可观察到极强的吸收峰.详细地研究了介 质球壳的物理和几何参数对此共振吸收的影响. 关键词： 腔体模式 表面等离子体模式 共振吸收     

Consensus,Polarization and Hysteresis in the Three-State Noisy q-Voter Model with Bounded Confidence

In this work, we address the question of the role of the influence of group size on the emergence of various collective social phenomena, such as consensus, polarization and social hysteresis. To answer this question, we study the three-state noisy q-voter model with bounded confidence, in which agents can be in one of three states: two extremes (leftist and rightist) and centrist. We study the model on a complete graph within the mean-field approach and show that, depending on the size q of the influence group, saddle-node bifurcation cascades of different length appear and different collective phenomena are possible. In particular, for all values of q>1, social hysteresis is observed. Furthermore, for small values of q∈(1,4), disagreement, polarization and domination of centrists (a consensus understood as the general agreement, not unanimity) can be achieved but not the domination of extremists. The latter is possible only for larger groups of influence. Finally, by comparing our model to others, we discuss how a small change in the rules at the microscopic level can dramatically change the macroscopic behavior of the model.     

一类具时滞的厄尔尼诺-南方涛动充电-放电振子模型的Hopf分岔与周期解问题

研究了一类具时滞的厄尔尼诺-南方涛动充电-放电振子模型. 给出了产生Hopf分岔的临界时滞条件, 利用Mawhin重合度理论,探讨了该模型的周期解问题. 关键词： 时滞 厄尔尼诺-南方涛动模型 Hopf分岔 周期解     

Propagation of travelling waves in sub-excitable systems driven by noise and periodic forcing

It has been reported that traveling waves propagate periodically and stably in sub-excitable systems driven by noise [Phys. Rev. Lett. 88, 138301 (2002)]. As a further investigation, here we observe different types of traveling waves under different noises and periodic forces, using a simplified Oregonator model. Depending on different noises and periodic forces, we have observed different types of wave propagation (or their disappearance). Moreover, reversal phenomena are observed in this system based on the numerical experiments in the one-dimensional space. We explain this as an effect of periodic forces. Thus, we give qualitative explanations for how stable reversal phenomena appear, which seem to arise from the mixing function of the periodic force and the noise. The output period and three velocities (normal, positive and negative) of the travelling waves are defined and their relationship with the periodic forces, along with the types of waves, are also studied in sub-excitable system under a fixed noise intensity. Electronic supplementary material Supplementary Online Material     

Lamellar orientation on the surface of a polymer determined by ToF-SIMS and AFM

The fold and lateral surfaces of chain-folded lamellae of poly(bisphenol-A-co-etheroctane), containing both aliphatic CH₂ and aromatic segments, were investigated by time-of-flight secondary ion mass spectrometry (ToF-SIMS). At low and high crystallization temperatures, the surfaces of the polymer films were shown to consist mainly of edge-on and flat-on lamellae, respectively. Surfaces with a mixture of edge-on and flat-on lamellae were produced at intermediate temperatures. The edge-on and flat-on lamellae were identified by using ions that recognize the flexible and rigid segments of the polymer. Ion images produced using selected ions that are related to the edge-on or flat-on orientation can be used to identify the location of these lamellae on the polymer surface. Our results indicate that ToF-SIMS can be used to detect different lamellar orientations at the surfaces of semi-crystalline polymers.     

Simultaneous measurement of bubble size,velocity and void fraction in two‐phase bubbly flows with time‐resolved X‐ray imaging

Key parameters of two‐phase flows, such as void fraction and microscale bubble size, shape and velocity, were simultaneously measured using time‐resolved X‐ray imaging. X‐ray phase‐contrast imaging was employed to obtain those parameters on microbubbles. The void fraction was estimated from X‐ray absorption. The radii of the measured microbubbles were mostly smaller than 20 µm, and the maximum velocity was 39.442 mm s^?1, much higher than that in previous studies. The spatial variations of the void fraction were consecutively obtained with a small time interval. This technique would be useful in the experimental analysis of bubbly flows in which microbubbles move at high speed.     

超导线的表面区域处理提高其磁场下的输运能力

对超导体在外磁场中的特性进行了归纳,外磁场在超导体中有磁场穿透深度限制,超导体表面有超导壁垒效应和表面钉扎作用,造成了外磁场在超导线表层密度最大而芯部没有磁通穿过.表面钉扎和壁垒效应存在的竞争主要集中在表面刺入超导体的柱形空穴.为了提高超导线在外电场中的输运能力,在制备上常用提高钉扎性能,而这也有阻碍电流的作用,对超导线芯部区域没有提高钉扎作用的必要,反而因为它有害于电流传输.根据这些理论尝试设计出多层结构的超导线,内芯是致密的净超导体晶体结构,外面是与磁场穿透深度厚度相同的一层掺杂、取代等作用提高钉扎性能的外场渗透层,在超导材料表面与包套材料之间是纳米修饰或者其他手段提高表面钉扎能力的连接层,减少连接层的垂直超导线的柱形纳米空穴可提高壁垒效应.这种结构因为减少了常规制备中不考虑内部没有磁通而仍然有钉扎处理材料对载流子的散射作用,这种结构使超导线的输运能力得到了一定提高.     

Seasonal variation of oxygen-18 in precipitation and surface water of the Poyang Lake Basin,China

Based on the monthly δ¹⁸O value measured over a hydrology period in precipitation, runoff of five tributaries and the main lake of the Poyang Lake Basin, combined with hydrological and meteorological data, the characteristics of δ¹⁸O in precipitation (δ¹⁸O_PPT) and runoff (δ¹⁸O_SUR) are discussed. The δ¹⁸O_PPT and δ¹⁸O_SUR values range from?2.75 to?14.12 ‰ (annual mean value=?7.13 ‰ ) and from?2.30 to?8.56 ‰, respectively. The seasonal variation of δ¹⁸O_PPT is controlled by the air mass circulation in this region, which is dominated by the Asian summer monsoon and the Siberian High during winter. The correlation between the wet seasonal averages of δ¹⁸O_SUR in runoff of the rivers and δ¹⁸O_PPT of precipitation at the corresponding stations shows that in the Poyang Lake catchment area the river water consists of 23% direct runoff (precipitation) and 77% base flow (shallow groundwater). This high proportion of groundwater in the river runoff points to the prevalence of wetland conditions in the Poyang Lake catchment during rainy season. Considering the oxygen isotopic composition of the main body of Poyang Lake, no isotopic enrichment relative to river inflow was found during the rainy season with maximum expansion of the lake. Thus, evaporation causing isotopic enrichment is a minor component of the lake water balance in the rainy period. During dry season, a slight isotopic enrichment has been observed, which suggests a certain evaporative loss of lake water in that period.     

强激光与固体靶作用产生的表面电子加速和辐射研究

利用单电子在固体靶表面准静态电磁场中运动的模型和非线性汤姆孙散射理论,研究了以大角度斜入射的强激光照射在固体靶表面产生的沿靶面方向发射的高能超热电子的运动及其产生的电磁辐射脉冲. 数值模拟表明,靶表面的电子在靶面附近的准静态电磁场和反射的激光场中作振荡. 当电子振荡频率接近激光频率时,电子被有效加速,被加速的电子主要沿靶面方向运动并产生向前的阿秒脉冲辐射. 讨论了电子在加速前的不同初始速度分布对辐射脉冲的时间和空间特性的影响,模拟了不同初始状态的多电子相干辐射脉冲的频谱特性. 关键词： 表面准静态电磁场 超热电子 阿秒脉冲 相干辐射