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Ga2O3 and GaN semiconductor hollow spheres 总被引:6,自引:0,他引:6
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The Crystal Structure of Cu2M(BO3)O2 (M = Fe3+, Ga3+) Single Crystals of the compounds Cu2M(BO3)O2 (M = Fe3+ (I), Ga3+ (II)) were obtained by a B2O3 flux-technique. They crystallize in a monoclinic distorted variant of a Ludwigite structure with a partly ordered metal distribution. X-ray investigations on single crystals led to the space group C–P21/c (No. 14); I: a = 3.108(1); b = 12.003(1); c = 9.459(3) Å; b? = 96.66(3)°; Z = 4 and II: a = 3.1146(2); b = 11.921(3); c = 9.477(2) Å; b? = 97.91(2)°; Z = 4. All metal-sites are distorted octahedraly coordinated by oxygen-ions. The structure contains isolated planar BO3-units and oxygen which is not coordinated to boron. 相似文献
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Petre A. L. Auroux A. Gervasini A. Caldararu M. Ionescu N. I. 《Journal of Thermal Analysis and Calorimetry》2001,64(1):253-260
The surface properties of supported gallium oxide catalysts prepared by impregnation of various supports (γ-Al2O3, SiO2, TiO2, ZrO2) were investigated by adsorption microcalorimetry, using ammonia and water as probe molecules. In the case of acidic supports
(γ-Al2O3, ZrO2, TiO2), the acidic character of supported gallium catalysts always decreased in comparison with gallium-free supports; on very
weakly acidic SiO2, new acidic centers were created when depositing Ga2O3. The addition of gallium oxide decreased the hydrophilic properties of alumina, titania and zirconia, but increased the amount
of water adsorbed on silica. The catalytic performances in the selective catalytic reduction of NO by C2H4 in excess oxygenwere in the order Ga/Al2O3>Ga/TiO2>Ga/ZrO2>>Ga/SiO2. This order is more related to the quality of the dispersion of Ga2O3 on the support than to the global acidity of the solids.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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Platinum‐Promoted Ga/Al2O3 as Highly Active,Selective, and Stable Catalyst for the Dehydrogenation of Propane 下载免费PDF全文
Jesper J. H. B. Sattler Dr. Ines D. Gonzalez‐Jimenez Dr. Lin Luo Brien A. Stears Dr. Andrzej Malek Dr. David G. Barton Dr. Beata A. Kilos Dr. Mark P. Kaminsky Tiny W. G. M. Verhoeven Eline J. Koers Prof. Dr. Marc Baldus Prof. Dr. Bert M. Weckhuysen 《Angewandte Chemie (International ed. in English)》2014,53(35):9251-9256
A novel catalyst material for the selective dehydrogenation of propane is presented. The catalyst consists of 1000 ppm Pt, 3 wt % Ga, and 0.25 wt % K supported on alumina. We observed a synergy between Ga and Pt, resulting in a highly active and stable catalyst. Additionally, we propose a bifunctional active phase, in which coordinately unsaturated Ga3+ species are the active species and where Pt functions as a promoter. 相似文献
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Several Ti-incorporated Ga-oxide (Ga2O3) thin films with different amounts of Ti contents have been prepared by vacuum evaporation method on glass and silicon substrates. The Ti incorporation level was measured with energy dispersion X-ray spectroscopy (EDX) method. The crystalline structure of the prepared films was determined with X-ray diffraction method. Experimental data indicate that Ti4+ ions doped in host Ga2O3 form solid solutions (SS) even with so large Ti% content ∼10.4% wt. All the prepared solid solutions have the known orthorhombic (ɛ-phase) phase of Ga2O3. The doping controls the optical and electrical properties of the host Ga2O3. It was found that the bandgap of the prepared undoped Ga oxide is 5.23 eV, which was decreased monotonically with increasing of Ti doping level so that it is possible to engineer the bandgap. Furthermore, the electrical measurements show that with Ti doping, it is possible to turn the high-k Ga oxide into low-k dielectric material. The optical sensitivity of the capacitance, dissipation factor, and ac-conductance of the Ga2O3:Ti films grown on Si was studied as a function of Ti-doping level. It was observed that the prepared Ga2O3:Ti film with 6–10% doping level has the highest photosensitivity among the other samples. 相似文献
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Dr. Xin Zhou Prof. Dr. Emiel J. M. Hensen Prof. Dr. Rutger A. van Santen Prof. Dr. Can Li 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(23):6915-6926
Density functional theory (DFT) calculations are used to explore water adsorption and activation on different α‐Ga2O3 surfaces, namely (001), (100), (110), and (012). The geometries and binding energies of molecular and dissociative adsorption are studied as a function of coverage. The simulations reveal that dissociative water adsorption on all the studied low‐index surfaces are thermodynamically favorable. Analysis of surface energies suggests that the most preferentially exposed surface is (012). The contribution of surface relaxation to the respective surface energies is significant. Calculations of electron local density of states indicate that the electron‐energy band gaps for the four investigated surfaces appears to be less related to the difference in coordinative unsaturation of the surface atoms, but rather to changes in the ionicity of the surface chemical bonds. The electrochemical computation is used to investigate the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) on α‐Ga2O3 surfaces. Our results indicate that the (100) and (110) surfaces, which have low stability, are the most favorable ones for HER and OER, respectively. 相似文献
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Yueming Zhai Junfeng Zhai Dan Wen Ming Zhou Lihua Zhang Shaojun Dong 《Electrochemistry communications》2008,10(8):1172-1175
A facile magnetic control system was designed in bioelectrocatalytic process based on functionalized iron oxide particles. The iron oxide particles were modified with glucose oxidase, and ferrocene dicarboxylic acid was used as electron transfer mediator. Functionalized iron oxide particles can assemble along the direction of applied magnetic field, and the directional dependence of the assembled iron oxide particles can be utilized for device purposes. We report here how such functionalized magnetic particles are used to modulate the bioelectrocatalytic signal by changing the orientation of the applied magnetic field. 相似文献
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《Mendeleev Communications》2021,31(5):718-720
This communication describes a new method for immobilizing indium oxide nanoparticles (∼20 nm) on the surface of reduced graphene oxide. Dispersion of graphene oxide with added In2O3 nanoparticles was treated in supercritical isopropanol, both a reducing agent of graphene oxide and a reaction medium. The resulting nanocomposite was characterized by different methods of physical and chemical analysis. 相似文献
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晶体结构;水热合成;一种新颖层状磷酸镓化合物[Ga3(PO4)4](H3NCH2CH2)2NH2的合成与结构表征 相似文献
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Ksenia Shablinskaya Elena Murashova Zhanafiya Kurenbaeva Alexander Yaroslavtsev Yurii Seropegin Dariusz Kaczorowski 《ChemInform》2013,44(41):no-no
Ce4Ru3Ga3 (I) and La3Ru2Ga2 (II) are synthesized by arc melting of the elements under Ar followed by annealing (873 K, 30 d). 相似文献
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