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1.
A barometric calorimeter technique has been developed to characterize the temporal evolution of combustion in confined explosions. By comparing pressure measurements for explosions in air versus nitrogen, one can make visible the gasdynamic (pressure) consequences of the exothermic energy release. The late-time chamber pressure measurement is used to evaluate the final mass-fraction of products produced by combustion. Combustion completeness varied from 50–89% over a wide range of stoichiometrics. A thermodynamic model of combustion in a calorimeter is proposed. The model was applied to the TNT-air system; chamber pressures varied between 1 bar and 1 kbar for fuel mass-fractions between 1 and 99%. Chamber temperature reached a maximum of 2.099 K at a fuel mass loading of 36%. We will show that combustion is a more-effective energy release mechanism for creating high temperatures and pressures in a confined explosion than the detonation mechanism.  相似文献   

2.
Understanding the causes and mechanisms of large explosions, especially dust explosions, is essential for minimising devastating hazards in many industrial processes. It is known that unconfined dust explosions begin as primary (turbulent) deflagrations followed by a devastating secondary explosion. The secondary explosion may propagate with a speed of up to 1000 m/s producing overpressures of over 8–10 atm, which is comparable with overpressures produced in detonation. Since detonation is the only established theory that allows rapid burning producing a high pressure that can be sustained in open areas, the generally accepted view was that the mechanism explaining the high rate of combustion in dust explosions is deflagration-to-detonation transition. In the present work we propose a theoretical substantiation of an alternative mechanism explaining the origin of the secondary explosion producing high speeds of combustion and high overpressures in unconfined dust explosions. We show that the clustering of dust particles in a turbulent flow ahead of the advancing flame front gives rise to a significant increase of the thermal radiation absorption length. This effect ensures that clusters of dust particles are exposed to and heated by radiation from hot combustion products of dust explosions for a sufficiently long time to become multi-point ignition kernels in a large volume ahead of the advancing flame. The ignition times of a fuel–air mixture caused by radiatively heated clusters of particles is considerably reduced compared with the ignition time caused by an isolated particle. Radiation-induced multipoint ignitions of a large volume of fuel–air ahead of the primary flame efficiently increase the total flame area, giving rise to the secondary explosion, which results in the high rates of combustion and overpressures required to account for the observed level of overpressures and damage in unconfined dust explosions, such as for example the 2005 Buncefield explosion and several vapour cloud explosions of severity similar to that of the Buncefield incident.  相似文献   

3.
In this paper, laser-induced ignition was investigated for compressed natural gas–air mixtures. Experiments were performed in a constant volume combustion chamber, which simulate end of the compression stroke conditions of a SI engine. This chamber simulates the engine combustion chamber conditions except turbulence of air–fuel mixture. It has four optical windows at diametrically opposite locations, which are used for laser ignition and optical diagnostics simultaneously. All experiments were conducted at 10 bar chamber pressure and 373 K chamber temperature. Initial stage of combustion phenomena was visualized by employing Shadowgraphy technique using a high speed CMOS camera. Flame kernel development of the combustible fuel–air mixture was investigated under different relative air–fuel ratios (λ=1.2?1.7) and the images were interrogated for temporal propagation of flame front. Pressure-time history inside the combustion chamber was recorded and analyzed. This data is useful in characterizing the laser ignition of natural gas–air mixture and can be used in developing an appropriate laser ignition system for commercial use in SI engines.  相似文献   

4.
陈福振  强洪夫  苗刚  高巍然 《物理学报》2015,64(11):110202-110202
燃料在炸药爆炸驱动下形成燃料空气爆炸云团, 进而引燃爆炸, 对目标造成毁伤. 本文在前期提出的光滑离散颗粒流体动力学方法(SDPH)的基础上, 引入描述炸药由爆轰到膨胀整个过程的Jones-Wilkins-Lee状态方程及描述气体快速燃烧过程的EBU-Arrhenius燃烧模型, 建立了求解战斗部起爆、燃料抛撒和燃料二次引燃爆炸问题的新型SDPH方法. 设计了圆环形燃料颗粒在炸药爆炸驱动下运动抛撒的算例进行数值验证, 结果与理论相符; 对燃料空气炸药(FAE)云雾的形成和发展过程进行了数值模拟, 分析了云雾的形态, 并与实验结果进行对比, 符合较好, 同时分析了不同起爆方式对云雾团成型的影响; 最后, 在云雾团成型的基础上, 引入蒸发燃烧模型对FAE的燃烧爆炸过程进行了模拟研究. 结果表明, 本文建立的数学模型和计算方法可以较好的模拟燃料空气炸药抛撒成雾及云雾燃烧爆炸过程, 为该类武器装备的设计研究提供了较好的数值方法.  相似文献   

5.
The results of experimental studies of the nonideal detonation of high-density, high-energy aluminum-ammonium perchlorate-organic fuel-HE compositions and of the blast waves it generates in a channel filled with air are presented. Aluminum-enriched compositions have high densities (up to 2 g/cm3) and high heats of explosion, nearly twice that for TNT. The studies were performed to work out scientific fundamentals of controlling nonideal detonation and to explore the possibility of creating new high-energy high-density formulations with an enhanced fugacity effect. The factors that enable controlling the nonideal detonation of such charges were determined. It was demonstrated that, at RDX contents above 15%, the detonation velocity increases linearly with the charge density while the critical detonation diameter decreases. Adjusting the density, HE content, ratio of the components makes it possible to vary the detonation velocity in high-density charges over a wide range, from 4 to 7 km/s. The experimental data were compared to the thermodynamically calculated velocity of ideal detonation. For the compositions under study, the pressure- time histories of the blast wave generated in a cylindrical tube by the expanding detonation products at different distances from the charge were measured. The results were compared to analogous data obtained under the same conditions for the detonation of the same mass of TNT (100 g). The parameters of blast waves generated by the test compositions are markedly superior to those characteristic of TNT: the pressure at the leading front of the wave and pressure impulse at a given distance from the charge were found to be 1.5–2.0 (or even more) times those observed for TNT. The TNT equivalency at pressures 30–60 atm has similar values. The TNT equivalencies in pressure and pressure impulse depend nonmonotonically on the distance from the charge, so far unclear why. It was established that the interaction between excess fuel and air oxygen during the expansion of detonation products contributes little to supporting the blast wave.  相似文献   

6.
Experiments on the detonation of high-density (1.8 g/cm3) aluminum-ammonium perchlorate-paraffin-RDX formulations in an unconfined space demonstrated their high efficiency at pressure amplitudes within 0.3–7.0 atm. The relative pressure amplitude and impulse of the blast waves with respect to the analogous characteristics of TNT charges of the same mass were found to be 1.3–2.4. The TNT equivalents in pressure and impulse vary with the distance nonmonotonically, ranging within 1.4–2.8. The blast wave produced by an infield explosion of a 1.42-kg composite charge demonstrated its high performance characteristics. Measurements at blast wave amplitudes of 1 to 20 atm gave a TNT equivalent in pressure of up to 3 and a TNT equivalent in impulse of 1.3 to 1.8. The high parameters of blast waves in an unconfined space originate from both the high-energy characteristics of the systems themselves and the afterburning of excess metal fuel in air. To estimate the extent of participation of the reaction of excess metal fuel with air in supporting the blast wave, numerical simulations of the generation of blast waves for various rates of mixing of detonation products with air at the contact surface were conducted. The main elements of the mechanisms of the processes that determine the efficiency of explosive systems with a heat release spread in space and time were considered. It was concluded that an optimal regime of blast wave generation, capable of ensuring a prolonged attenuation of the wave with the distance, could be realized for low-velocity detonation.  相似文献   

7.
The combustion of two fuels with disparate reactivity such as natural gas and diesel in internal combustion engines has been demonstrated as a means to increase efficiency, reduce fuel costs and reduce pollutant formation in comparison to traditional diesel or spark-ignited engines. However, dual fuel engines are constrained by the onset of uncontrolled fast combustion (i.e., engine knock) as well as incomplete combustion, which can result in high unburned hydrocarbon emissions. To study the fundamental combustion processes of ignition and flame propagation in dual fuel engines, a new method has been developed to inject single isolated liquid hydrocarbon droplets into premixed methane/air mixtures at elevated temperatures and pressures. An opposed-piston rapid compression machine was used in combination with a newly developed piezoelectric droplet injection system that is capable of injecting single liquid hydrocarbon droplets along the stagnation plane of the combustion chamber. A high-speed Schlieren optical system was used for imaging the combustion process in the chamber. Experiments were conducted by injecting diesel droplet of various diameters (50 µm < do < 400 µm), into methane/air mixtures with varying equivalence ratios (0 < ϕ < 1.2) over a range of compressed temperatures (700 K < Tc < 940 K). Multiple autoignition modes was observed in the vicinity of the liquid droplets, which were followed by transition to propagating premixed flames. A computational model was developed with CONVERGE™, which uses a 141 species dual-fuel chemical kinetic mechanism for the gas phase along with a transient, analytical droplet evaporation model to define the boundary conditions at the droplet surface. The simulations capture each of the different ignition modes in the vicinity of the injected spherical diesel droplet, along with bifurcation of the ignition event into a propagating, premixed methane/air flame and a stationary diesel/air diffusion flame.  相似文献   

8.
A novel stable energetic compound (E)‐1,2‐diamino‐1,2‐dinitrodiboron (DANB) was theoretically designed based on the structure of 1,1‐diamino‐2,2‐dinitroethene (FOX‐7). Atomization method in combination with Hess' law was used to predict the heat of formation. The detonation velocity (D) and detonation pressure (P) of DANB were approximatively estimated by using Kamlet–Jacobs equations. As a result, DANB has huge heat of formation (2013.5 kJ/mol) and specific enthalpy of combustion (?26.4 kJ/g). Furthermore, DANB possesses high crystal density (1.85 g/cm3) and heat of detonation (5476.0 cal/g), which lead to surprising detonation performance (D = 10.72 km/s, P = 51.9 GPa) that is greater than those of FOX‐7 (D = 8.63 km/s, P = 34.0 GPa) and CL‐20 (D = 9.62 km/s, P = 44.1 GPa). More importantly, DANB is very stable because its bond dissociation energy of the weakest bond (BDE = 357.8 kJ/mol) is larger than those of the most common explosives, such as FOX‐7 (BDE = 200.4 kJ/mol), CL‐20(BDE = 209.2 kJ/mol), HMX(BDE = 165.7 kJ/mol), and RDX (BDE = 161.4 kJ/mol). Therefore, our results show that DANB is a promising candidate for stable and powerful energetic material.  相似文献   

9.
《Journal of Electrostatics》2005,63(6-10):455-462
Paying attention to accidents related to recycling, the authors investigated factors related to the dust explosions. The minimum explosive concentrations were 30–40 g/m3 (polyurethane and plastic dusts) and 70 g/m3 (toner); the explosibility was reduced by about 40% when combustible gas (cyclopentane) existed together with the dust; ignition temperature of a dust cloud was around 500 °C; and the minimum ignition energy was about 11 mJ (polyurethane). Ignition energy was the minimum when the spark duration was about 0.2 ms or more; the explosion probability was the maximum when the spark gap was 5–10 mm; and the ignition energy was the minimum when the electrode tip angle was around 30 °C (polyurethane). From these findings, the dusts produced in the recycling process can be easily evaluated so as to know whether dust explosion is likely to occur.  相似文献   

10.
水下爆炸特性的二维数值模拟研究   总被引:1,自引:0,他引:1       下载免费PDF全文
 对带有3 mm左右厚铝壳或钢壳的柱形TNT、RS-211、T/Γ(35/65)以及ROT901装药在水下采用一端点起爆后,水中冲击波超压分布进行了二维数值模拟研究。对该四种炸药的每一种,分别考虑了药量为1 kg、3 kg、5 kg和8 kg四种TNT当量的柱形装药情况。柱形装药的长径比为L/D=1.5左右。计算使用的程序为二维欧拉多流体网格法流体力学计算程序MFIC。给出了水中冲击波超压的空间和时间分布;对铝壳和钢壳两种情况的结果进行了分析、比较;同时给出了缩比模型与1∶1模型之间相应物理量之间的缩比关系。  相似文献   

11.
This work concerns a parametric study of alkali release in a lab-scale, pulverized coal combustor (drop tube reactor) at atmospheric pressure. Measurements were made at steady reactor conditions using excimer laser fragmentation fluorescence (ELIF) and with direct optical access to the flue gas pipe. In this way, absolute gas-phase alkali species could be determined in situ, continuously, with sub-ppb sensitivity, directly in the flue gas. A hard coal was fired in the range 1000–1300 °C, for residence times in the range 3–5 s and for air numbers λ (air/fuel ratios) from 1.15 to 1.50. In addition, the amount of chlorine, water vapor and sulfur, respectively, was increased in known amounts by controlled dosing of HCl, H2O and SO2 into the combustion gas to determine effects of these components on release or capture of the alkali species. The experimental results are also compared with values calculated using ash/fuel analyses and sequential extraction to obtain a fuller picture of alkali release in pulverized fuel combustion.  相似文献   

12.
Due to its nature as a carbon free fuel and carrying hydrogen energy ammonia has received a lot of attention recently to be used as an alternative to fossil fuel in gas turbine and internal combustion engines. However, several barriers such as long ignition delay, slow flame speed, and low reactivity need to be overcome before its practical applications in engines. One potential approach to improve the ignition can be achieved by using oxygen enriched combustion. In this study, oxygen-enriched combustion of ammonia is tested in a constant volume combustion chamber to understand its combustion characteristics like flame velocity and heat release rates. With the help of high speed Schlieren imaging, an ammonia-oxygen flame is studied inside the combustion chamber. The influence of a wide range of oxygen concentrations from 15 to 40% are tested along with equivalence ratios ranging from 0.9 to 1.15. Ammonia when ignited at an oxygen concentration of 40% with an equivalence ratio of ϕ= 1.1 at 10 bar has a maximum flame velocity of 112.7 cm/s. Reduced oxygen concentration also negatively affects the flame velocity, introducing instabilities and causing the flame to develop asymmetrically due to buoyancy effects inside the combustion chamber. Heat release rate (HRR) curves show that increasing the oxygen concentration from 21 to 35% of the mixture can help reduce the ignition delays. Peak HRR data shows increased sensitivity to air fuel ratios with increased oxygen concentrations in the ambient gas. HRR also shows an overall positive dependence on the oxygen concentration in the ambient gas.  相似文献   

13.
Experimental data on the combustion characteristics of methane-oxidative gas (O2 + N2)-inhibitor (CHF3, C2HF5, and C4F10) mixtures and an analysis thereof show that fluorinated hydrocarbons (HFC and FC) exhibit the properties of both flame inhibitors and promoters. The flammability concentration limits, maximum explosion pressure ΔP max, maximum explosion pressure rise rate (dP/dt)max, and laminar flame speed S u are measured for near-limit methane-oxidative gas-fluorinated hydrocarbon mixtures. It is demonstrated that, when added to lean near-limit mixtures, HFC and FC behave as an additional fuel. Calculations of the thermodynamic characteristics of reactions involving fluorinated hydrocarbons capable of acting as both an inhibitor and oxidizer show that such reactions have significant heat effects, 150–700 kJ/mol, with the respective adiabatic temperatures being as high as 900–1800 K. The results of the present study suggest that the procedure of selecting fluorinated hydrocarbons for practical applications as fire and explosion suppressants should include careful tests of their promoting effect.  相似文献   

14.
The spatial and temporal locations of autoignition for direct-injection compression-ignition engines depend on fuel chemistry, temperature, pressure, and mixing trajectories in the fuel jets. Dual-fuel systems can provide insight into both fuel-chemistry and physical effects by varying fuel reactivities and engine operating conditions. In this context, the spatial and temporal progression of two-stage autoignition of a diesel-fuel surrogate, n-heptane, in a lean-premixed charge of synthetic natural-gas (NG) and air is imaged in an optically accessible heavy-duty diesel engine. The lean-premixed charge of NG is prepared by fumigation upstream of the engine intake manifold. Optical diagnostics include high-speed (15kfps) cool-flame chemiluminescence-imaging as an indicator of low-temperature heat-release (LTHR) and OH* chemiluminescence-imaging as an indicator high-temperature heat-release (HTHR). NG prolongs the ignition delay of the pilot fuel and increases the combustion duration. Zero-dimensional chemical-kinetics simulations provide further understanding by replicating a Lagrangian perspective for mixtures evolving along streamlines originating either at the fuel nozzle or in the ambient gas, for which the pilot-fuel concentration is either decreasing or increasing, respectively. The zero-dimensional simulations predict that LTHR initiates most likely on the air streamlines before transitioning to HTHR, either on fuel-streamlines or on air-streamlines in regions of near-constant ?. Due to the relatively short pilot-fuel injection-durations, the transient increase in entrainment near the end of injection (entrainment wave) is important for quickly creating auto-ignitable mixtures. To achieve desired combustion characteristics, e.g., multiple ignition-kernels and favorable combustion phasing and location (e.g., for reducing wall heat-transfer or optimizing charge stratification), adjusting injection parameters could tailor mixing trajectories to offset changes in fuel ignition chemistry.  相似文献   

15.
Underwater explosions have been studied intensively in the United States since 1941 [e.g., R. H. Cole, Underwater Explosions (Princeton University Press, Princeton, NJ, 1945), pp. 3-13]. Research to date has primarily focused on the initial shock and subsequent pressure waves caused by the oscillations of the "gas-globe" resulting from charge detonation. These phenomena have relatively short timescales (typically less than 2 s). However, after the gas-globe rises through the water column and breaks the surface, there remains behind a cloud of bubbles and perhaps debris from the explosion container which has been markedly less studied. A recent experiment measured the spatial and temporal acoustic response of the bubble cloud resulting from a 13.6 kg PBXN-111 charge detonated at 15.2 m (50 ft) depth. A directional projector was used to propagate linear frequency-modulated (5-65 kHz) and 40 kHz tonal pulses through the bubble cloud. Two hydrophone arrays were positioned so as to measure the energy lost in propagating through the bubble cloud. Three methods have been utilized to invert measurements and estimate the bubble population. The bubble population estimates have been used to develop a model for the bubble population resulting from an underwater explosion.  相似文献   

16.
Combustion experiments on fuel droplet–vapor–air mixtures have been performed with a rapid expansion apparatus which generates monodispersed droplet clouds with narrow diameter distribution using the condensation method. The effects of fine fuel droplets on flame propagation were investigated for ethanol droplet–vapor–air mixtures at various pressures from 0.2 to 1.0 MPa. A stagnant fuel droplet–vapor–air mixture, generated in a rapid expansion chamber, was ignited at the center of the chamber using an ignition wire. Spherical flame propagation under constant-pressure conditions was observed with a high-speed video camera and flame speed was measured. Total equivalence ratio, and the ratio of liquid fuel mass to total fuel mass, was varied from 0.6 to 1.4 and from zero to 56%, respectively. The mean droplet diameter of fuel droplet–vapor–air mixtures was set at 8.5 and 11 μm. It was found that the flame speed of droplet–vapor–air mixtures less than 0.9 in the total equivalence ratio exceeds that of premixed gases of the same total equivalence ratio at all pressures. The flame speed of fuel droplet–vapor–air mixtures decreases as the pressure increases in all total equivalence ratios. At large ratios of liquid fuel mass to total fuel mass, the normalized flame speed (the flame speed of droplet–vapor–air mixtures divided by the flame speed of the premixed gas with the same total equivalence ratio), increases with the increase in pressure for fuel-lean mixtures, and it decreases for fuel-rich mixtures. The outcome is reversed at small ratios of liquid fuel mass to total fuel mass; the normalized flame speed decreases with the increase in pressure for fuel-lean mixtures, and increases for fuel-rich mixtures. The results suggest that the increase in pressure promotes droplet evaporation in the preheat zone.  相似文献   

17.
It is commonly assumed that the burning of ammonium nitrate–aluminum mixtures is much less prone to undergo a transition to explosion and detonation than similar mixtures based on ammonium perchlorate. However, this conclusion has been made for mixtures based on commercial-grade ammonium nitrate with large particles. In this study, the combustion of fine loose-packed mixtures of ammonium nitrate and aluminum in a closed-volume bomb has been examined. It has been shown that fine mixtures (ammonium nitrate with a particle size of less than 40 µm and an ASD-4 aluminum powder with spherical particles with a size of about 4 µm) undergo high-intensity combustion; in experiments with a stoichiometric mixture, explosions are observed. The explosions occur in the initial phase of convective combustion and lead to abrupt pressure pulsations with an amplitude of a few kilobars and to the destruction of the cup in which the sample is placed. The dynamics of development of the explosion has been analyzed in detail using numerical simulation. According to the results of experiments with varied parameters—the degree of dispersion of the ammonium nitrate powders, the aluminum content in the mixture, the length and diameter of the charge, and the level of pressure generated by the combustion of the igniter,—threshold conditions have been determined to separate the following modes: the absence of ignition, layer-by-layer combustion, or convective combustion with a transition into an explosion in experiments with a stoichiometric mixture.  相似文献   

18.
There is an obvious contradiction between the statistics of the devastating explosions that take place with the participation of ammonium nitrate and explosive properties of this material determined in standard tests. Pure ammonium nitrate does not burn under normal conditions and has a very low sensitivity to conventional mechanical and thermal stimuli. So far, ammonium nitrate has been detonated only by using high explosives. Causes of accidental explosions involving large masses of ammonium nitrate are likely to be found in a nonconventional behavior of ammonium nitrate. These changes may arise due to different chemical or physical factors, such as those associated with the presence of active additives, crushing of particles, etc., and lead to acceleration of the process at the initial stage of explosion. This work is devoted studying the convective burning and the initial stage of deflagration-to-detonation transition in dry and wet mixtures of ammonium nitrate with various, largely combustible additives. Experiments were conducted on loose-packed charges in a constant-volume bomb and by using the method of the critical bed height with recording pressure-time diagrams by a piezoelectric sensor. Ammonium nitrate of two different types was used: granular and powdered. The fuel additives were charcoal and aluminum powder, whereas the additives inhibiting the combustion of ammonium nitrate were water and monosodium salt of phosphoric acid. In addition, finely dispersed mixture of four components (ammonium nitrate, aluminum, powdered sugar, and TNT in a proportion of 76: 8: 12: 4) was used. The experiments in the constant-volume bomb were supplemented by numerical simulations, which made it possible to obtain a better understanding of the convective burning of the test mixtures and to evaluate the possibility of using a constant-volume bomb to collect quantitative information on the intensity of the combustion of the mixture at the initial stage of the explosion.  相似文献   

19.

Abstract  

A spark plug fuel injector (SPFI), which is a combination of a fuel injector and a spark plug was developed with the aim to convert any gasoline port injection spark ignition engine to gaseous fuel direct injection (Mohamad in Development of a spark plug fuel injector for direct injection of methane in spark ignition engine. PhD thesis, Cranfield University, 2006). A direct fuel injector is combined with a spark plug using specially fabricated bracket connected to a fuel pipe and a fuel path running along the periphery of a spark plug body to deliver the injected fuel to the combustion chamber. The injection nozzle of SPFI is significantly bigger than normal direct fuel injector nozzles. Therefore, it is important to understand the effect of such a configuration on the injection process and subsequently the air–fuel mixing behaviour inside the combustion chamber. The flow was visualized using the planar laser-induced fluorescent technique. For safety reasons, nitrogen was used as fuel substitute. Nitrogen at 50, 60 and 80 bar pressure was seeded with acetone as a flow tracer and injected into a bomb containing pressurised nitrogen. Bomb pressure was varied to simulate the pressure inside combustion cylinder during the compression stroke where actual injections in engine experiments will take place. The shape and depth of tip penetration of the gas jet were measured. Results show that the gas jet follows the behaviour suggested by vortex ball model (Turner in Mechanics 13:356–369, 1962). The cone angle and the maximum jet width of the fully developed gas jets from the SPFI injection are 23° and 25 mm, respectively regardless of the injection pressures. The penetration lengths of the fully developed jets are between 90 and 100 mm at 8–14 ms after the start of injection, depending on the bomb and injection pressure. Jet penetration is directly proportional to the injection pressure but inversely proportional to the cylinder or bomb pressure. The penetration lengths indicate that sufficient distance should be travelled by the gas jet for satisfactory air–fuel mixing in the engine.  相似文献   

20.
 在用水中爆炸法测量以TATB为基的TBL炸药能量的研究中,设计了2种具有高爆压和大质量的扩爆药柱。通过2类扩爆药柱的能量测试实验得到的扩爆药柱能量与理论结果相同,TBL炸药的能量为TNT炸药能量的70%左右;炸药的爆压越高,冲击波能量随爆炸距离的衰减越快。  相似文献   

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