Calculation of second Kerr effect virial coefficients of H2S

Second Kerr effect virial coefficients B _K of H₂S have been calculated using our recent molecular tensor theory of B _K for molecules of nonlinear symmetry. After optimization of the intermolecular potential interaction parameters and molecular quadrupole moment for H₂S, the calculated B _K values are seen to agree with the experimental values found in the literature to within 10% over the temperature range of the measured data. The components of the quadrupole moment tensor obtained by optimization are not in good agreement with the one set of calculated values reported in the literature.     

Effect of pressure on pressed pellets in XRS

In this study, the absorption experiments which are an application area in XRS are discussed. The effect on the absorption parameters of the pressure applied to make pellet powder samples was investigated. The mass attenuation coefficients ( μ _m ), mean free paths and half-value layers of samples prepared at different pressures were experimentally determined. C₆H₁₀O₅, VF₄, CaO and Y₂O₃ samples were pressed at 1.91, 3.82, 5.72 and 7.63 tons/cm². A variable energy x-ray source from Amersham (AMC.2084) was used in order to irradiate the samples at energies 13.39, 19.63, 24.90, 32.06, 36.39, 44.48, 51.70 and 59.54 keV. The photon intensities were measured by using an HPGe detector with a resolution of 182 eV at 5.9 keV. The theoretical radiation absorption parameters were calculated by WinXCOM program. The calculated values were compared with the experimental values. Good agreement has been observed within experimental uncertainties for low pellet pressure. The obtained results show that the radiation absorption parameters change with the amount of pressure applied to the sample.     

Temperature dependence of pressure broadening of NH3 perturbed by H2 and N2

The temperature dependence of pressure broadening of 134 rovibrational transitions of several branches in the ν₄ and 2ν₂ bands of ammonia perturbed by H₂ and N₂ has been measured using a high-resolution Fourier transform spectrometer. The temperature range covered during the experiments was between 235 and 296 K. The pressure-broadening linewidths were obtained using the method of multipressure fitting to the measured shapes of the lines. These broadenings were also calculated using a semiclassical model leading to a reasonable agreement with the observations and reproduces well the strong systematic experimental J and K quantum number dependencies. The retrieved values of the linewidths, along with those previously determined from the spectra at room temperature, were used to derive the temperature dependence of both H₂ and N₂ broadening of NH₃ lines. The broadening coefficients were shown to fit closely the well-known exponential law. For both experimental and theoretical results, the temperature exponent n has been obtained. Careful inspection of the experimental values shows that, contrary to the linewidths, the coefficient n is nearly K independent within each J multiplet. Also for a given J it does not seem to exhibit any noticeable variation with the type of rotational transition. On the other hand, the calculated n values exhibit a strong J and K systematic dependencies. n increases with K for a given J, decreases with J for a given K and are independent of the type of rotational transition.     

Photoelectric cross-sections of light elements and compounds at low photon energies

Total photon mass attenuation coefficients in C, Al, S, Ti, B₂O₃, LiF, ZnO, Y₂O₃ and H₈O₂C₅ (perspex) are measured on a good geometry set-up using proportional counter, Si(Li) and Ge(Li) detecting systems in the energy region from 6.47 to 52.014 keV employing x-rays and gamma rays from radioactive sources. The deduced photoelectric cross-sections are found to agree with the theoretical values of Storm and Israel, Scofield and semiexperimental values of Veigele wherever available within a few percent. The photo-electric cross-sections in elements, S, Ti and Y at their respectiveK-edges obtained by extrapolation technique agree with the theoretical values of Storm and Israel and Scofield at the respectiveK-edges except in S. In the case of S both the theoretical values atK-edges are found to be underestimations, more in the case of Scofield evaluations.     

Measurements of K-shell ionization cross sections of35Br,37Rb,39Y using low energy protons

K-shell ionization cross section measurements are reported for₃₅Br,₃₇Rb and₃₉Y targets caused by protons over 300–400 keV energy range in 20 keV increment. The K-shell ionization cross sections (σ _k ^l ) at different energies were deduced from the K_α and K_β X-ray production cross sections which were obtained from X-ray yields of the K_α and K_β transitions. The experimental values are compared with the calculated values of ECPSSR theory and empirical reference cross sections. The resultant K-shell ionization cross sections are found to be in reasonable agreement with the ECPSSR theory. The K_α/K_β intensity ratios are also presented and compared with other experimental values and also with the theoretical one-hole values given by Scofield.     

Compression modes and the nuclear matter incompressibility coefficient

We review the current status of the nuclear matter (N=Z and no Coulomb interaction) incompressibility coefficient, K _nm , and describe the theoretical and the experimental methods used to determine K _nm from properties of compression modes in nuclei. In particular we consider the long standing problem of the conflicting results obtained for K _nm , deduced from experimental data on excitation cross sections for the isoscalar giant monopole resonance (ISGMR) and data for the isoscalar giant dipole resonance (ISGDR).     

Intrinsic <Emphasis Type="Italic">g</Emphasis><Subscript><Emphasis Type="Italic">K</Emphasis></Subscript> factors of odd-mass <Superscript>167–179</Superscript>Lu isotopes

In this paper, g _K -factors of the intrinsic magnetic moments and effective spin gyromagnetic factors (g _s^eff) of the ^167–179Lu isotopes have been studied within the Tamm-Dancoff approximation (TDA) (Kuliev et al, Sov. J. Nucl. Phys. 9, 185 (1969)) by using a realistic potential such as Woods-Saxon potential for the first time. The effects of the spin-spin and spin-isospin interactions on magnetic moments were investigated. The results of the theoretical calculations are compared with the experimental data for related nuclei. The experimental values of g _K and g _s^eff were computed from the observed magnetic moments (Georg et al, Eur. Phys. J. A3, 225 (1998)) using the spin matrix elements. The theoretical predictions for the g _K factors exhibit good agreement with the experimental g _K factors with increasing mass number A of the lutetium isotopes. The strongest influence of the neutron-proton spin interaction occurs at q = −1. Sufficient agreement between the calculated and the experimental values of g _K is obtained for κ = (45/A) MeV and q = −1.     

Electric dipole moment and charge transfer in alkali-C molecules

Electron excitation rate coefficients for 2p (2p₁, 2p₂, 2p₃, 2p₄, 2p₅, 2p₆) and 3p(3p₅, 3p₆, 3p₇, 3p₈, 3p₁₀) (in Paschen notation) levels of xenon atom have been measured by using electron drift tube technique. The absolute excitation coefficients were obtained from the optical signal at the anode in Townsend xenon discharges, after correction for detector quantum efficiency. The ionization coefficients were determined from the spatial emission profile. The measurement were made for the electric field to xenon atom number density ratios (E/N) from Vm² to Vm². The data were obtained between moderate E/N values where electrons are in equilibrium and very high E/N values where electrons may not be in equilibrium with the local field. It was found that at the highest values of E/N heavy particles do not contribute to the excitation under the present conditions. The absolute excitation coefficients for the studied levels of xenon are to our knowledge the only experimental data available in the literature. Received 17 March 1999 and Received in final form 9 August 1999     

Comparison of the Seltzer Coefficient C 1 to Experimental Data

Experimental Coulomb isotope shifts δE _Coul from K _α transitions, and radius differences δ〈r ²〉 _eμ measured by electron scattering and muonic atom X-rays were used to derive ‘experimental’ coefficients C _1,exp for 54 isotope pairs of 18 elements from Mo to U. A χ²-analysis shows that these experimental coefficients are – on average – 3.5% lower than the theoretical C ₁ values calculated by Seltzer, or more precisely: C _1,exp=0.965(± 0.014)×C ₁. The need for more accurate theoretical calculations is stressed, and consequences of this deviation are discussed. This revised version was published online in July 2006 with corrections to the Cover Date.     

Mixed state in a superlattice

Presented in this paper is a theoretical calculation of the vortex solution in a chosen superlattice (Nb/NbZr) using the Gibbs free energy of an inhomogeneous superconductor. The eigenvalue obtained in this geometry from de Gennes-Werthamer proximity coupling theory is first examined according to a set of experimental data, while the correspondent eigenfunctions are then used to construct vortex solutions with either square lattice or triangle lattice symmetry. The Gibbs free energy is calculated in terms of the vortex solutions of both symmetries. The effective Ginzburg-Landau parameter,K _NS , for this superlattice is determined asK _NS =0.218 by requiring a consistency between the microscopic and macroscopic theoretical calculations. Of particular importance is a new mechanism revealed by this calculation that a highly localized state of superconducting condensate in its hosting layer, despite the spatially rapid varying characteristic of its correspondent nucleating order parameter, provides a lower eigenvalue state, which results in a dimensional crossover. A further examination of this mechanism is carried out in the mixed state calculation. Finally, a generalization of the present theoretical results to a large class of superlatices is discussed.     

Self-broadening coefficients in the ν2 and ν5 bands of CH3F at 183 and 298 K

The self-broadening coefficients of 33 rovibrational lines in the ν₂ and ν₅ bands of ¹²CH₃F were measured at a sample temperature of 183 K using a diode-laser spectrometer. We have also realized the measurement of these coefficients at room temperature for 10 of these lines in order to determine their temperature dependence. These results were obtained by fitting to the experimental profile the Voigt lineshape and the Rautian and Galatry models taking into account the collisional narrowing. Calculations of the self-broadening coefficients were also performed for the same temperatures from a semiclassical model involving only electrostatic interactions in the intermolecular potential. The calculated values are significantly larger than the experimental data for both temperatures but the J-dependences of the self-broadenings are well reproduced. Moreover, the theoretical temperature dependence of these coefficients is in good agreement with that derived from the measurements.     

Perturbation allowed transitions in the infrared spectrum of 14ND3: determination of the K-dependent parameters in the ground state

ABSTRACT

Accurate values of the K-dependent constants ^{( i )} C, ^{( i )} D_K and ^{( i )} H_K in the ground state of ¹⁴ND₃, with i = s, a, have been determined for the first time thanks to the detections of ‘perturbation allowed’ transitions in the ν₁, ν₂, ν₃, ν₄ and 2ν₄ infrared bands. The rotation–inversion and inversion transitions from the literature, together with 7289 ground state combination differences from the infrared vibration–rotation–inversion transitions have been simultaneously analysed. The adopted rotation–inversion Hamiltonian includes distortion constants up to the eighth power and the Δk = ±3 and Δk = ±6 interaction terms. Precise values of the diagonal constants and of the Δk = ±3 interaction coefficients have been obtained. Accurate values of the ground state term values have been calculated for both s and a levels up to J = 21.     

Gain and absorption of an X-ray pre-ionized XeCl discharge laser at high gas pressures

An experimental study was undertaken to investigate the characteristics of XeCl discharge lasers at high gas pressures ( 15 atm). From a comparison of the fluorescence measurements with the net small signal gain coefficients, it was concluded that absorption is the main cause of the catastrophic drop in laser output power in higher pressures. Accounting for such molecular absorbers as Xe⁺ ₂, Xe^* ₂, and Xe₂Cl^*, the absorption coefficient,K, was calculated using a simple steady-state analysis and the net gain coefficients deduced from the calculated absorptions came to within an order of magnitude of the measured values.     

Measurements and calculations of ethylene line-broadening by argon in the ν7 band at room temperature

Argon broadening coefficients are measured for 32 vibrotational lines in the ν₇ band of ethylene at room temperature using a tunable diode-laser spectrometer. These lines with 3 ≤ J ≤ 19, 0 ≤ K_a ≤ 4, 2 ≤ K_c ≤ 19 in the P, Q and R branches are located in the spectral range 919–1023 cm^?1. The fitting of experimental line shapes with Rautian profile provides collisional widths slightly larger than those derived from the Voigt profile. The independent theoretical estimation of these line widths is performed by the semiclassical approach of Robert-and-Bonamy type with exact isotropic trajectories generalized to asymmetric tops. Even with a rough atom–atom intermolecular potential model the calculated values show good agreement with experimental results.     

Collisional broadening and line intensities in the ν2 and ν4 bands of PH3

Using a tunable diode-laser spectrometer self-broadening coefficients and absolute intensities have been measured for 26 lines of PH₃ at 298 K in the QR branch of the ν₂ band and the PP and RP branches of the ν₄ band. The recorded lines with J values ranging from 2 to 14 and K from 0 to 11 are located in the spectral range 995-1093 cm⁻¹. Self-broadening coefficients have also been measured at 173.4 K for nine of these lines. The collisional widths and line strengths are obtained by fitting each spectral line with different theoretical profiles. The results obtained for the line intensities are in good agreement with recent measurements [J. Mol. Spectrosc. 215 (2002) 178]. The self-broadening coefficients are also calculated on the basis of a simple semiclassical model involving only the electrostatic interactions. A satisfactory agreement is obtained except for high J values or K values equal to J, for which the calculated results are notably underestimated. By comparing broadening coefficients at room and low temperatures, the temperature dependence of these broadenings has been determined both experimentally and theoretically.     

White and some colored marbles as alternative radiation shielding materials for applications

ABSTRACT

In this paper, the radiation shielding parameters such as linear attenuation coefficients (LAC, µ), mass attenuation coefficients (MAC, µ/ρ), effective atomic numbers (Z_eff), effective electron densities (N_eff), half value of layers (HVL), mean free paths (MFP) and buildup factors (exposure (EBF) and energy absorption (EABF)) were investigated for cream (M1), pink (M2), white (M3), maroon (M4) and green (M5) marbles. Attenuation coefficients were measured in the energy region 31.18–661.66 keV photon energies. The values of Z_eff and N_eff were then calculated using these coefficients with logarithmic interpolation method, and HVLs and MFPs were calculated using the values of LAC of marble samples at the same photon energies. The experimental results were compared with the theoretical values obtained from WinXCom program, and good agreements were observed between the experimental and theoretical results. HVLs and MFPs of all marble samples were compared with those of some concretes, glasses and commercial radiation shielding glasses (SCHOTT Co.). The studied marbles were better radiation shielding materials than standard shielding concretes due to lower HVL and MFP values lower than the ordinary concrete. Finally, EBFs and EABFs of the marbles were calculated in the energy region 0.015–1?MeV up to penetration depths of 40 mfps by Geometric Progression method (G-P), and the results were discussed in terms of photon energies and chemical compositions of the marbles.     

Hydrogen-broadening coefficients in the ν7 band of ethylene at low temperature

H₂-broadening coefficients have been measured for 35 lines of C₂H₄ at 173.2 K in the P, Q, and R branches of the ν₇ fundamental band near 10 μm, using a tunable diode-laser spectrometer. These lines were individually fitted with a Voigt and a Rautian profile to determine their collisional widths. The resulting broadening coefficients, as well as those previously measured at room temperature are compared with values calculated on the basis of a semiclassical model of interacting linear molecules, using an atom-atom Lennard-Jones potential in addition to the weak electrostatic contributions. A satisfactory agreement is obtained for the results at room temperature, but the theoretical results at low temperature are generally smaller than the experimental data. Finally, the temperature dependence of the broadening coefficients has been determined both experimentally and theoretically.     

Broadening and shifting of vibrational-rotational lines corresponding to the highly excited rotational states of the water molecule

Self-pressure-induced, as well as argon- and nitrogen-induced, broadening γ and shifting δ coefficients of vibrational-rotational lines of the water molecule have been calculated. The asymptotic behavior of the coefficients γ and δ at J → 42 and K _a → J has been studied. For the calculation of the parameters γ and δ, we used the wave functions obtained from the analysis of highly excited rotational states of the H₂O molecule with the maximal ever observed values of rotational quantum numbers J _max = 42, K _amax = 32. Rotational states were analyzed in the method of effective Hamiltonians using generating functions for the first eight vibrational states of the molecule.     

Anomalous conversion in the decay of197mHg

The total andK-shell conversion coefficients of the 165 keV transition in the decay of^197mHg are determined from intensity balance considerations and a coincidence technique using a Ge(Li)—NaI (Tl) system respectively. The resultant values area _T =274.8±19.2 anda _K =47±12, whil the corresponding theoretical values are 344 and 77 respectively, indicating anomalous conversion. The gamma ray transition probability however, shows a hindrance of only about 6 and cannot be correlated with the present anomalous conversion data. TheK/L ratio of the 130 keV transition, determined using a summing method with a Ge(Li) detector, yielded 0.090±0.012, while the corresponding theoretical value is 0.048, indicating anomalous conversion. The corresponding gamma transition probability shows a hindrance of about 3000, in correlation with anomalous conversion.