On the importance of spectral responsivity of Robertson-Berger-type ultraviolet radiometers for long-term observations

A system to determine the spectral responsivity of ultraviolet (UV) radiometers has been developed and is routinely operated at the Central Ultraviolet Calibration Facility, at the National Oceanic and Atmospheric Administration. The instrument and the measurement methodologies are described. Results of measurements from thermally controlled broadband UV radiometers of the Robertson-Berger (R-B)-type are described. Systematic differences in the spectral response curves for these instruments have been detected. The effect of these differences on the field operation of UV-B radiometers has been studied by calculating the instrumental response from modeled UV spectra. The differences of the weighted spectral UV irradiances, measured by two radiometers with different spectral response functions, caused by the daily variation in the position of the sun were estimated for fixed values of total ozone, altitude and albedo, and for cloud-free conditions. These differences increase with the solar zenith angle and are as large as 8%. Larger differences in the instrumental response may be produced by ozone variations. Thus, care must be taken when analyzing data from R-B radiometers and comparing results from different instruments. Routine cycling of UV-B radiometers in operative networks without a careful determination of the spectral responsivity, or small drifts of the spectral responsivity, may strongly affect the accuracy of UV radiation measurements and produce an erroneous trend. Because of the possible differences among radiometers, it would not be practical to derive the long-term behavior of UV radiation without routine and thorough characterization of the spectral responsivities of the instruments.     

Erythemally Weighted Radiometers in Solar UV Monitoring: Results from the WMO/STUK Intercomparison

The first international intercomparison of erythemally weighted (EW) broadband radiometers was arranged in 1995 to improve the accuracy and comparability of the measurements carried out by solar UV monitoring networks. The intercomparison was arranged at the Radiation and Nuclear Safety Authority in Helsinki, Finland, in cooperation with the University of Innsbruck and with support from the World Meteorological Organization. Altogether 20 EW meters of six different types from 16 countries were (1) tested in the laboratory by measuring the spectral and angular responsivities and (2) calibrated in solar radiation against two reference spectroradiometers. Calibration factors (CFs) for the EW meters were determined by using simultaneously measured EW solar UV spectra as a calibration reference. The CFs averaged over solar elevations higher than 35° varied from 0.87 to 1.75, with the estimated uncertainty being ±10%. As a result of this intercomparison, for the first time the calibrations of more than 100 EW radiometers around the world are possible to trace to the same origin. The present experience indicates that the accuracy of temperature-controlled EW radiometers is not significantly lower than the accuracy of spectroradiometers provided that strict quality assurance/quality control procedures are followed.     

Global forecast model to predict the daily dose of the solar erythemally effective UV radiation

A worldwide forecast of the erythemally effective ultraviolet (UV) radiation is presented. The forecast was established to inform the public about the expected amount of erythemally effective UV radiation for the next day. Besides the irradiance, the daily dose is forecasted to enable people to choose the appropriate sun protection tools. Following the UV Index as the measure of global erythemally effective irradiance, the daily dose is expressed in units of UV Index hours. In this study, we have validated the model and the forecast against measurements from broadband UV radiometers of the Robertson-Berger type. The measurements were made at four continents ranging from the northern polar circle (67.4 degrees N) to the Antarctic coast (61.1 degrees S). As additional quality criteria the frequency of underestimation was taken into account because the forecast is a tool of radiation protection and made to avoid overexposure. A value closer than one minimal erythemal dose for the most sensitive skin type 1 to the observed value was counted as hit and greater deviations as underestimation or overestimation. The Austrian forecast model underestimates the daily dose in 3.7% of all cases, whereas 1.7% results from the model and 2.0% from the assumed total ozone content. The hit rate could be found in the order of 40%.     

Action spectrum conversion factors that change erythemally weighted to previtamin D3-weighted UV doses

Abstract Many solar UV measurements, either terrestrial or personal, weight the raw data by the erythemal action spectrum. However, a problem arises when one tries to estimate the benefit of vitamin D(3) production based on erythemally weighted outdoor doses, like those measured by calibrated R-B meters or polysulphone badges, because the differences between action spectra give dissimilar values. While both action spectra peak in the UVB region, the erythemal action spectrum continues throughout the UVA region while the previtamin D(3) action spectrum stops near that boundary. When one uses the previtamin D(3) action spectrum to weight the solar spectra (D(eff)), one gets a different contribution in W m(-2) than what the erythemally weighted data predicts (E(eff)). Thus, to do proper benefit assessments, one must incorporate action spectrum conversion factors (ASCF) into the calculations to change erythemally weighted to previtamin D(3)-weighted doses. To date, all benefit assessments for vitamin D(3) production in human skin from outdoor exposures are overestimates because they did not account for the different contributions of each action spectrum with changing solar zenith angle and ozone and they did not account for body geometry. Here we describe how to normalize the ratios of the effective irradiances (D(eff)/E(eff)) to get ASCF that change erythemally weighted to previtamin D(3)-weighted doses. We also give the ASCF for each season of the year in the northern hemisphere every 5 degrees from 30 degrees N to 60 degrees N, based on ozone values. These ASCF, along with geometry conversion factors and other information, can give better vitamin D(3) estimates from erythemally weighted outdoor doses.     

Erythemal Ultraviolet Insolation in New Zealand at Solar Zenith Angles of 30° and 45°

Solar UV radiometers with spectral responsivities that are close to the erythemaVcarcinogenic action spectrum of skin have been installed at several centers of population in New Zealand, including Auckland, 37°S, Wellington, 41°s and Christchurch, 43.5°S. The data set covers the period from the time the radiometry program commenced in 1988/1989 to the end of the southern summer, March 1995. The radiometers were recalibrated annually and the data were corrected for changes in the absolute responsivity of the radiometers. Erythemally effective UV irradiances at solar zenith angles of 30° and 45° were then extracted from the data set. No monotonic trend in these data is apparent, although there are statistically significant differences in mean irradiances from one year to the next. An example of this is the decrease observed in all sites following the Mt. Pinatubo eruption in June 1991. The maximum erythemally effective insolations at solar zenith angles of 30° and 45° were consistently lower in Christchurch than in the other two New Zealand sites. This could arise from higher levels of atmospheric turbidity andlor tropospheric ozone at this location. Also, a seasonal increase in erythemally effective UV insolation from spring to autumn was observed each year in all three New Zealand sites.     

All-Weather Comparison between Spectral and Broadband (Robertson-Berger) UV Measurements

Abstract— Spectral measurements of UV irradiance at the Fraunhofer Institute at Garmisch-Partenkirchen, Germany, are intercompared with data from two different Robert-son-Berger-type meters. More than 21000 spectra gathered during 20 months of continuous operation were used for this analysis, sampling a large variety of atmospheric conditions. At low solar zenith angles the agreement (± 10%) was quite satisfactory, whereas at high solar zenith angles the broadband instruments gave systematically lower readings than the erythemally weighted spectral data. The deviation of the spectral response of the broadband instruments from the Commission Internationale de 1'Eclairage (CIE) erythema function and the cosine error provide an explanation of the observed differences that are similar for both broadband meters. Model calculations agree quite well with the observations, if an accurate measurement of the broadband spectral response is available. An analytical fit curve was established for the ratio between broadband and weighted spectral data, as a function of solar zenith angle, enabling quick and easy checks of the stability of the spectrora-diometric system. The relative standard deviation of the data from the fit function was only2–3% in the case of cloudless sky conditions and 5% for all sky conditions, including all types of systematic and instrumental errors.     

A selective Pt-CdS photodiode to monitor erythemal flux

The design and potential benefit of a solar ultraviolet (UV) radiometer reporting a maximum instantaneous flux of erythemally weighted heterogeneous energy is considered. The proposed device is electronically peak detecting; the user would ideally 'point and paint' the sun to find a localized maximum. A projected exposure time can be calculated from an instantaneous reading of erythemally weighted flux for a given minimal erythemal dose (MED) specified by the user. This calculation, though not necessarily providing a true exposure time, may be useful and informative in that it serves as a more 'recognizable' measure of erythemal flux and introduces a custom scale for each individual via their MED. Erythemal flux is calculated as the weighted integral sum [symbol: see text]j(lambda,t) epsilon(lambda) d lambda, where j (lambda, t) is the instantaneous angular integrated spectral irradiance accepted by human skin. This instrument proposal uses a single interference filter over a Pt-CdS photodiode; the interference filter is offered as a nominal design transmittance. The simulated response of the selective photodiode has a near-linear relation to the effective irradiance. Test inputs for evaluation purposes and to elucidate a transducer response are constructed from a spline interpolation of the World Radiation Center (WRC) spectrum and classic transmittance models. Our desired erythemal flux is offered in interconvertible UV Indexes (UVIs) as a function of zenith angle and atmosphere, characterized by elevation, ozone path, and turbidity.     

An improved outdoor calibration procedure for broadband ultraviolet radiometers

This article aims at improving the broadband ultraviolet radiometer's calibration methodology. For this goal, three broadband radiometers are calibrated against a spectrophotometer of reference. Three different one-step calibration models are tested: ratio, first order and second order. The latter is proposed in order to adequately reproduce the high dependence on the solar zenith angle shown by the other two models and, therefore, to improve the calibration performance at high solar elevations. The proposed new second-order model requires no additional information and, thus, keeps the operational character of the one-step methodology. The models are compared in terms of their root mean square error and the most qualified is subsequently validated by comparing its predictions with the spectrophotometer measurements within an independent validation data subset. Results show that the best calibration is achieved by the second-order model, with a mean bias error and mean absolute bias error lower than 2.2 and 6.7%, respectively.     

Routine measurement of erythemally effective UV irradiance on inclined surfaces

Measurements of erythemally weighted UV radiation are usually related to a horizontal surface. The radiation is weighted with the sensitivity of the human skin, but the surface of the human body has only few horizontal surfaces. Therefore the UV radiation on inclined surfaces has to be quantified to investigate UV effects on humans. To fulfill this task three fully automatic measuring systems were built to measure the erythemally weighted UV radiation in 27 directions within 2 min. This system measures routinely during the whole day and has now been in operation for nearly three years (in total 2000 measurement days) under any kind of meteorological conditions. The measurements provide the informations needed for further investigations concerning the UV effects on humans. The calibration of the erythemally weighting radiometers was performed in a way to provide reliable UV index measurements for all directions. The results of four exemplary measurement days in summer and winter for clear sky and overcast conditions are presented.     

Facial solar UV exposure of Austrian farmers during occupation

Optoelectronic personal UV-meters were used to monitor the occupational facial solar erythemally effective exposure of 12 Austrian full-time farmers with high temporal resolution. To ensure high quality measurements several quality assurance procedures were applied, like calibration with respect to solar elevation and total ozone column. From April to October the test persons carried the UV-meters on the forehead during working hours. A digital diary (activity, location, weather, photoprotective measures) was completed on an hourly basis. Our field test produced 1427 complete daily records (measurement and diary). The total exposures showed high variability (77 –757 standard erythema dose [SED]) which correlates with the number of working days and even stronger with the little numbers of days with high exposure (>10 SED). Risk factors for high exposures were: mixed-culture farms with aggravated working conditions, low degree of automation of working processes, inadequate operating logistics (summarized as manual work outdoor), driving machines without cabins, and female gender. UV exposure of female farmers was approximately twice as high as that of men: Women received 15% of ambient radiation while men got 8%. Avoiding daily exposure >10 SED could reduce exposure down to 40% and the risk in developing skin cancer by a factor of 40.     

The Austrian UVA‐Network

The ultraviolet‐A (UVA) part of the solar spectrum at the Earth's surface is an essential environmental factor but continuous long‐time monitoring of UVA radiation is rarely done. In Austria, three existing stations of the UV monitoring network have been upgraded with UVA broadband instruments. At each station, one instrument measures global UVA irradiance and—in parallel—a second instrument measures diffuse irradiance. Recent and past measurements are available via a web page. This paper describes the used instruments, calibration and quality assurance and control procedures. Global and diffuse UVA measurements during a period of up to 5 years are presented. Data indicate clear annual courses and an increase of UVA with altitude by 8–9% per 1000 m. In the first half of the year, UVA radiation is higher than in the second half, due to less cloudiness. In Vienna (153 m asl), the mean daily global UVA radiant exposure in summer is almost as high as at Mt. Gerlitzen (1540 m asl), equalizing the altitude effect, due to less cloudiness. However, in winter, the UVA radiant exposure at Mt. Gerlitzen is double as high, as in Vienna.     

Measurement of solar UVB variations by polysulphone film

Sheets of polysulphone film have been extensively used as detectors to monitor solar UVB radiation. The advantages of polysulphone detectors are that they are small in size, they have good thermal stability and they are sensitive to UVB radiation. The principal disadvantage of polysulphone detectors is that their spectral sensitivity includes part of the short-wavelength UVA. In this study, we investigate the spectral sensitivity of the polysulphone detector with a series of monochromatic (+/- 2 nm) excitations. We then compare the polysulphone-effective solar radiation with the erythemally effective solar radiation by comparing solar UVB data obtained with polysulphone films with those obtained with a spectroradiometer. From polysulphone data on the seasonal variation of solar UVB radiation, we estimate the corresponding fluctuations of the absorption of the ozone layer. We show that the spectral sensitivity of the polysulphone film is closer to the erythema action spectrum than that indicated by earlier data and that polysulphone detectors can be used to predict the erythema risk of solar UVB. Measurements on solar UVB with polysulphone films and with a spectroradiometer were found to be strongly correlated (R2 > 0.95). Finally, polysulphone-based measurements provide a good measure of the fluctuations of the stratospheric ozone layer.     

Sensitivity of erythemally effective UV irradiance and daily exposure to temporal variability in total ozone

The provision of information to the public about current levels of the erythemally effective UV radiation is an important issue in health care. The quality of promoted values is therefore of special importance. The atmospheric parameter which affects the erythemally effective UV radiation under clear sky most is the total ozone content of the atmosphere. In this paper we examined the sensitivity of the erythemally effective irradiance and daily radiant exposure to the temporal variability of total ozone on time scales from 1 to 15 days. The results show that the sensitivity is highest for the first 24 h. Larger time scales do not exhibit a similar influence. Total ozone measurements of the previous day may already cause uncertainties higher than 0.5 UV index (UVI) independent of the geolocation. For comparison, a temporal persistence of 15 days may cause uncertainties of 1.2 UVI at 50°N, 1 UVI at 30°S and less than 1 UVI at the equator. The results of this study allow finding the necessary temporal resolution of total ozone values when a certain accuracy for the UVI or for the purpose of sun protection is required. The results are compared with those of two preceding studies where we quantified the influence of measurement uncertainties and spatial total ozone variability to the erythemally effective irradiance at noon and to the daily dose. We conclude that temporal variability of total ozone is the most critical issue, but also measurement uncertainties do have a noticeable influence on the erythemally effective radiation.     

Modified calibration procedures for a Yankee Environmental System UVB-1 biometer based on spectral measurements with a brewer spectrophotometer

The calibration of the erythemal irradiance measured by a Yankee Environmental System (YES) UVB-1 biometer is presented using two methods of calibration with a wide range of experimental solar zenith angles (SZAs) and ozone values. The calibration is performed through simultaneous spectral measurements by a calibrated double-monochromator Brewer MK-III spectrophotometer at "El Arenosillo" station, located in southwestern Spain. Because the range of spectral measurements of the Brewer spectrophotometer is 290-363 nm, a previously validated radiative transfer model was used to account for the erythemal contribution between 363 and 400 nm. Both methods are recommended by the World Meteorological Organization and we present and discuss here a wide range of results and features given by modified procedures applied to these two general methods. As is well established, the calibration factor for this type of radiometric system is dependent on atmospheric conditions, the most important of which are the ozone content and the SZA. Although the first method is insensitive to these two factors, we analyze this behavior in terms of the range used for the SZA and the use of two different mathematical approaches for its determination. The second method shows the dependence on SZA and ozone content and, thus, a polynomial as a function of SZA or a matrix including SZA and ozone content were determined as general calibration factors for the UV radiometric system. We must note that the angular responses of the YES radiometer and Brewer spectroradiometer have not been considered, because of the difficulty in correcting them. The results show in detail the advantages and drawbacks (and the corresponding associated error) given by the different approaches used for the determination of these calibration coefficients.     

SEASONAL TRENDS IN ERYTHEMAL and CARCINOGENIC ULTRAVIOLET RADIATION AT MID-SOUTHERN LATITUDES1989–1991

A network of solar carcinogenic/erythemal ultraviolet radiometers has been established in New Zealand. Daily integrated irradiances of this biologically harmful ultraviolet radiation for 1989, 1990 and 1991 are reported from radiometers located at Wellington (41°S) and Christchurch (43.5°S) and for 1990 and 1991 from the Auckland (37°S) radiometer. Although the monitoring program has not been running sufficiently long to discern any long-term changes in levels of solar ultraviolet radiation, shorter term trends are apparent, which are attributed to a seasonal cycle in levels of ozone at midlatitudes and changes in atmospheric aerosols.     

THE EFFECT OF CHANGES OR DIFFERENCES IN ROBERTSON-BERGER RADIOMETER RESPONSIVITY ON SOLAR ULTRAVIOLET-B MEASUREMENT

Two long-term solar UV measurement campaigns, in the USA and in Austria, using Robertson-Berger radiometers found opposite trends for measured levels of ultraviolet-B radiation reaching the earth's surface. This could be a consequence of the method used to calibrate the radiometers. Changes or differences in responsivity were compensated for by adjusting the sensitivity of the field radiometers to match the output of a reference radiometer.
This radiometer intercomparison procedure has been evaluated in terms of the normalization wavelength to which the Robertson-Berger effective irradiance refers. There are small differences in spectral responsivities apparent in the radiometers used in the USA campaign, which require the field radiometers to be normalized at different wavelengths to match the response of the reference radiometer. This normalization wavelength is shown to depend on the time-averaged spectrum experienced by the instruments during the intercomparison. As a result there are substantial interradiometer variations in their calculated response to solar radiation when the measured spectral distribution is different from the spectrum used for the radiometer intercomparison procedure.     

Sensitivity of UV erythemally effective irradiance and daily dose to spatial variability in total ozone

Abstract The total ozone column (TOC) is the most significant quantity for estimating the erythemally effective UV radiation under clear sky conditions. Uncertainties in TOC measurements and a limited spatial and temporal resolution therefore influence the quality of calculated erythemally effective radiation. The UV Index, the internationally accepted measure of the erythemally effective radiation, is used in public and the media to inform about current levels of UV radiation and builds the base for sun protection. Thus, the accuracy of the promoted values is essential. While in a preceding study we estimated the influence of measurement uncertainties, in this study we analyze the influence of spatial gaps and variability of TOC to the erythemally effective irradiance at noon and to the daily dose. The results allow defining the necessary spatial resolution of TOC values when a certain accuracy for the UV Index or for the purpose of sun protection is required. In case of the erythemally effective irradiance this study reveals that spatial gaps in TOC or the assumption of spatial invariability causes similar uncertainties independent of the geographic location. At higher latitudes the higher spatial variability of TOC counteracts the lower level of irradiance. For the daily dose gaps in TOC have an even higher impact at higher latitudes.     

The European Light Dosimeter Network: four years of measurements

The European Light Dosimeter Network (ELDONET) has now been functional for more than four years. The network is based on dosimeters which measure radiation in three biologically relevant wavelength bands (UV-B, 280-315 nm; UV-A, 315-400 nm; and Photosynthetic Active Radiation, PAR, 400-700 nm). The ELDONET network is currently based on 33 stations with 40 instruments. The distribution of the instruments all over Europe allows measurement of the latitudinal and longitudinal light climate distribution. In addition, several instruments are active in South America, New Zealand, India, Africa and Japan. With some exceptions, the measured yearly doses depend on the latitude. While the maximal daily doses are almost comparable from station to station, seasonal changes and the different maximal solar zenith angles account for the differences in total yearly doses. Ratioing between UV-B and PAR allows the detection of subtle changes in the local light climate, due, for example, to mini-ozone holes encountered in northern Europe during spring. Comparison of satellite ozone data with terrestrial ELDONET measurements revealed an overall weak correlation between these data sets. However, local weather conditions, solar zenith angle and latitude as well as reflectivity (i.e. clouds and aerosol; satellite data) show a much stronger correlation to the doses received. The close relationship between the spectral sensitivity of the UV-B sensor used in the ELDONET dosimeter and the CIE erythemal action spectrum allows determination of the erythemal dose on the basis of the dosimeter readings.     

Risk of erroneously deciding conformity of measuring instruments

Due to the unavoidable measurement uncertainty associated with every measurement and calibration result, conformity testing always implies the risk of taking erroneous decisions. Whereas end-users of measuring instruments are concerned mainly with instruments that have successfully passed a conformity test but actually indicate outside their specifications, instrument manufacturers are interested primarily in a low fail-error probability. In this paper, a straightforward Bayesian approach to evaluating pass- and fail-error probabilities in deciding conformity of measuring instruments is presented. It is based mainly on the expression of both knowledge of the respective calibration result of a measurement and the distribution of error values of the instrument population by means of appropriate probability distributions. The risk-calculating approach is explained using the example of conformity testing of a precision scale.     

Applicability of the polysulphone horizontal calibration to differently inclined dosimeters

Polysulphone (PS) dosimetry has been a widely used technique for more than 30 years to quantify the erythemally effective UV dose received by anatomic sites (personal exposure). The calibration of PS dosimeters is an important issue as their spectral response is different from the erythemal action spectrum. It is performed exposing a set of PS dosimeters on a horizontal plane and measuring the UV doses received by dosimeters using calibrated spectroradiometers or radiometers. In this study, data collected during PS field campaigns (from 2004 to 2006), using horizontal and differently inclined dosimeters, were analyzed to provide some considerations on the transfer of the horizontal calibration to differently inclined dosimeters, as anatomic sites usually are. The role of sky conditions, of the angle of incidence between the sun and the normal to the slope, and of the type of surrounding surface on the calibration were investigated. It was concluded that PS horizontal calibrations apply to differently inclined dosimeters for incidence angles up to approximately 70° and for surfaces excluding ones with high albedo. Caution should be used in the application of horizontal calibrations for cases of high-incidence angle and/or high albedo surfaces.