Third order response to a multifrequency photon field in semiconductors

This paper contains a detailed calculation of the photoinduced current density at third order in the coupling between a semiconductor and a multifrequency photon field, starting from its standard textbook expression which reads in terms of a triple commutator. Due to a major intrinsic problem linked to this triple commutator, such a derivation has been made possible quite recently only, thanks to the tools developed in the composite-boson many-body theory we have recently constructed. The photoinduced current density is shown to ultimately read in a compact form, in terms of the “Pauli scatterings” and “Coulomb scatterings” for exciton-exciton interactions introduced in this theory. Representation of this third order response in Shiva diagrams, which visualize interactions between excitons, is also given to better grasp the physics of the various contributions.     

Picosecond lifetime measurements in147Pm

Half-lives of excited levels in¹⁴⁷Pm have been measured using BaF₂ scintillators. New values of t_1/2 are 2420(10), 43(5), 22(9), 17(10) and 17(10) ps for the 91.1, 410.5, 489.2, 531.0 and 685.9 keV level, respectively. E2 enhancement factors of -transitions have been deduced.     

UV excitable Y2? x ? y Gd y SiO5:Ce x phosphors for cool white light emission

Cool white light was realized in Y_2−x−y Gd _x SiO₅: Ce _y phosphor under near UV excitation, due to the occupation Ce³⁺ in Y³⁺ 1st and 2nd site, synthesized using solid state carbothermal reduction route. SEM with elemental analysis show the existence of Gd in Y₂SiO₅:Ce enhances the particles size in comparison to Y₂SiO₅:Ce phosphors alone. Gd³⁺ (0.00≤x≤0.75) and Ce³⁺ (0.02≤y≤0.10) concentration was optimized to 0.50 and 0.08 in Y₂SiO₅, respectively. The CIE chromaticity color coordinates (0.24, 0.20) are close to cool white light value which could be useful for the fabrication of cool white LED.     

Long period gratings written in large-mode area photonic crystal fiber

We report for the first time, to the best of our knowledge, on the fabrication and characterization of CO₂-laser written long-period gratings in a large-mode area photonic crystal fiber with a core diameter of 25 μm. The gratings have low insertion losses (<1 dB) and high attenuation (>10 dB) at the resonant wavelengths, making them particularly interesting for high power applications.     

How does the substrate affect the Raman and excited state spectra of a carbon nanotube?

We study the optical properties of a single, semiconducting single-walled carbon nanotube (CNT) that is partially suspended across a trench and partially supported by a SiO₂-substrate. By tuning the laser excitation energy across the E ₃₃ excitonic resonance of the suspended CNT segment, the scattering intensities of the principal Raman transitions, the radial breathing mode (RBM), the D mode and the G mode show strong resonance enhancement of up to three orders of magnitude. In the supported part of the CNT, despite a loss of Raman scattering intensity of up to two orders of magnitude, we recover the E ₃₃ excitonic resonance suffering a substrate-induced red shift of 50 meV. The peak intensity ratio between G band and D band is highly sensitive to the presence of the substrate and varies by one order of magnitude, demonstrating the much higher defect density in the supported CNT segments. By comparing the E ₃₃ resonance spectra measured by Raman excitation spectroscopy and photoluminescence (PL) excitation spectroscopy in the suspended CNT segment, we observe that the peak energy in the PL excitation spectrum is red-shifted by 40 meV. This shift is associated with the energy difference between the localized exciton dominating the PL excitation spectrum and the free exciton giving rise to the Raman excitation spectrum. High-resolution Raman spectra reveal substrate-induced symmetry breaking, as evidenced by the appearance of additional peaks in the strongly broadened Raman G band. Laser-induced line shifts of RBM and G band measured on the suspended CNT segment are both linear as a function of the laser excitation power. Stokes/anti-Stokes measurements, however, reveal an increase of the G phonon population while the RBM phonon population is rather independent of the laser excitation power.     

Concentration quenching of Eu<Superscript>2+</Superscript> in a novel blue–green emitting phosphor: Ba<Subscript>2</Subscript>ZnSi<Subscript>2</Subscript>O<Subscript>7</Subscript>:Eu<Superscript>2+</Superscript>

A novel blue–green emitting phosphor Ba₂ZnSi₂O₇: Eu²⁺ was prepared by a combustion synthesis (CS) method. An efficient green emission under conditions ranging from ultraviolet to visible light was observed. The emission spectrum shows a single intensive band centered at 503 nm, which corresponds to the 4f ⁶5d ¹→4f ⁷ transition of Eu²⁺. The excitation spectrum is a broad band extending from 260 to 465 nm, which matches the emission of ultraviolet light-emitting diodes (UV-LEDs). The critical quenching concentration of Eu²⁺ in Ba₂ZnSi₂O₇:Eu²⁺ phosphor is about 0.05 mol. The corresponding concentration quenching mechanism is verified to be a dipole–dipole interaction. The value of the critical transfer distance is calculated as 19 Å, which is in good agreement with the value (20 Å) derived from the experimental data.     

Spatial coherence measurements from two L-shape arrays in Shallow Water

In the Shallow Water’ 06 experiment, two L-shape arrays (ARRAY52 and ARRAY32) were deployed. The vertical line array (VLA) components of both ARRAY52 and ARRAY32 were exactly perpendicular to the direction of sound propagation. The horizontal line array (HLA) component of ARRAY52 was exactly perpendicular to the direction of sound propagation. The HLA component of ARRAY32 was exactly parallel to the direction of sound propagation. This configuration offered an opportunity to simultaneously analyze the three dimensional (3-D) spatial coherences: vertical, transverse horizontal and longitudinal horizontal. When the source and the receivers were below the thermocline, both the vertical and longitudinal horizontal coherence lengths in units of wavelength increased with increasing range and frequency. When the source was within the thermocline, the transverse horizontal coherence length in units of wavelength decreased with frequency and exhibited weak range dependence. The text was submitted by the authors in English.     

High-spin states of odd-odd156Ho

High spin states in the nucleus¹⁵⁶Ho have been studied via the fusion-evaporation reaction¹⁴⁰Ce(¹⁹F,3n)¹⁵⁶Ho at the beam energy of 82 MeV.- coincidences, E, I and excitation functions have been measured. With two rotationally-aligned bands identified as [h_11/2] [i_13/2], we found two new bands with a signature splitting, whose structure is believed to arise from either [h_9/2] or [f_7/2] coupled to [h_11/2]. Our placement of rays belonging to these new bands suggests that the previously known level scheme should be corrected. We also found many new low-energy rays in the low excitation energy. As compared to¹⁵⁴Ho, the present nucleus with two more neutrons becomes more collective, and shows well-observed rotationally-aligned bands with a clear signature splitting.Communicated by B. Herskind     

Methods for controlling of the laser-induced absorption in a BTO crystal by using of cw-laser radiation

The iron-atom concentration distribution as well as the gas-phase temperature was measured via laser-induced fluorescence (LIF) during iron-oxide nanoparticle synthesis in a low-pressure hydrogen/oxygen/argon flame reactor using ironpentacarbonyl (Fe(CO)₅) as precursor. Temperature measurements based on multi-line NO-LIF imaging are used to correct for temperature-dependent ground-state populations. The concentration measurement is calibrated based on line-of-sight absorption measurements. The influence of the precursor on the flame is observed at precursor concentrations larger than 70 ppm as the flame front moves closer to the burner surface with increasing Fe(CO)₅ concentration.     

Temperature dependence of photoconductivity and persistent photoconductivity of single ZnO nanowires

Photoelectrical properties of single ZnO nanowires have been investigated using photocurrent–voltage characteristics measurements varying with excitation photon energy and temperature. It is found that persistent photoconductivity (PPC) exists, and the PPC decreases with decreasing temperature. The temperature dependence of the PPC effect indicates that thermally activated return of electrons from shallow traps is responsible for the PPC phenomenon. The photosensitivity is found to be linear with the applied voltage, and it increases with decreasing temperature. A temperature dependence of photoconductivity gain was introduced to explain the experimental results.     

Hyperspherical approach to description of electron correlation in negative ion of exciton

The binding energy of excitonium negative ion for the ground^1,3S-states in bulk semiconductors GaAs and ZnO in the hyperspherical coordinate method was found. Angular and radial correlations between electrons in gerade and ungerade states were taken into account by channel functions, that are the eigenfunctions of Hamiltonian on the surface of the sphere in the three-dimensional configuration space. Energy values were calculated using the adiabatic and Born-Oppenheimer approximations. The obtained energy values are in agreement with those obtained using variational method.     

Anisotropic carrier transport properties of highly aligned oligophenylenevinylenes in organic field-effect transistors

We have studied the electronic excitations of fluorinated copper phthalocyanine, CuPcF₁₆, thin films using electron energy-loss spectroscopy in transmission. This allowed for the derivation of the dielectric function in a wide energy range. Furthermore, we have analyzed the lowest excitation feature using a Lorentz model, which enabled the determination of the dielectric background in the energy range of the gap excitation, and an analysis of the momentum dependence of the spectral intensities at low energies.     

Exciton-phonon coupling strength in single wall carbon nanotubes

The coupling strength of the exciton and different phonons, including the radial breathing mode (RBM), longitudinal (LO) and transverse (TO) optical phonons, are calculated for different diameter single wall carbon nanotubes (SWNTs) in the framework of tight-binding model. It is found that the exciton-phonon coupling strength with the LO mode or RBM shows a clear (2n+m)-family behavior due to the trigonal warping effect, but it with the TO mode remains to be zero. In the same SWNT, the E₂₂ exciton-phonon coupling strength is found to be slightly smaller than that of E₁₁ exciton. Finally, the exciton-RBM-phonon coupling strengths for several SWNTs are found to be in good agreement with the recent experimental data [Phys. Rev. Lett. 98, 037405 (2007)].     

Sulfur dioxide measurements using an ultraviolet light-emitting diode in combination with gas correlation techniques

The important air pollutant sulfur dioxide has a strong structured absorption band in the ultraviolet (UV) region around 300 nm. Recently, light-emitting diodes (LEDs) with structureless emission in a band about 15-nm wide in the UV region have become available. We demonstrate that they can be ideal sources for gas absorption measurements combined with the gas correlation technique, where an absorption cell with an optically thick column of the gas under investigation is used for analysing the target gas contents in a path between the LED and the measurement device. A sensitivity of 0.4 ppm sulfur dioxide was obtained with a 19-cm optical path length and 60-s integration time. Particularly compact and cost-effective monitors especially for industrial emissions can be envisaged.     

The spin-orbit field in superdeformed nuclei: a relativistic investigation

Relativistic Mean Field (RMF) theory is used to investigate the behavior of the spin orbit potential,V _ls, in nuclear states of very large deformation and high angular velocity. As a by-product we present a set of parameters for an approximation of the relativistic scalar- and vector-potentialsS andV in the Dirac equation in terms of Saxon-Woods shapes. These reproduce more or less the same single particle specta as a full selfconsistent relativistic mean field calculation.Dedicated to Prof. Dr. H.J. Mang on the occasion of his 60th birthday     

Diffusion anisotropy and void development under cascade irradiation

Cascade irradiation of metals gives rise to swelling as a result of the creation of voids and the evolution of the void ensemble. Under suitable circumstances, the originally disordered void distribution transforms into to a void lattice. As demonstrated previously, the understanding of the evolution and the unique features of the void ensemble requires a difference in the anisotropy of the diffusion (DAD) of vacancies and self-interstitial atoms (SIAs), which is achieved by one-dimensional diffusion of the SIAs. On the other hand, void swelling has been successfully modeled in terms of three-dimensional diffusion of both vacancies and SIAs. In the present paper it is shown that these seemingly contradicting interpretations and all related observations can be quantitatively reconciled by a small DAD created by only ～1% of SIAs diffusing one-dimensionally. It is also demonstrated that at the initial stage of void-lattice formation, ordering occurs mainly on close-packed crystal planes, which is in contrast to the naïve expectation that one-dimensional diffusion of SIAs should result in a void ordering along close-packed directions. Finally it is found that, in the case of a small DAD, voids annihilate via stochastic shrinkage much faster than by coalescence. This falsifies the argument in the literature that one-dimensional diffusion of SIAs would necessarily lead to the coalescence of voids and destabilization of the void lattice.     

Laser-induced point-defect reaction in proton-irradiated SiC

The defects produced in 4H-SiC epitaxial layers by irradiation with 200-keV H⁺ were characterized by low-temperature photoluminescence. These defects induce sharp luminescent lines, the so-called alphabet lines. Their intensity shows an evolution under UV-laser irradiation not previously observed. By monitoring the change in the resulting photoluminescence spectra versus time, we distinguish two original ‘families’ of peaks called PB₁ and PB₂. They display a different, and opposite, behaviour with laser irradiation but they are strongly correlated. In particular, the recovering rate of the PB₁ family and the growth rate of the PB₂ family are the same, indicating a structural rearrangement of defects.     

Transient field measurements of first-excited stateg-factors in188,190,192Os

Transient-field precessions were measured simultaneously for the 2₁ ⁺ states of^188,190,192Os as ions of these nuclei traversed a thin polarized iron foil. In contrast with most earlier measurements, the relative gyromagnetic ratios deduced here are independent of the level lifetimes. Emphasis is placed upon determination of theg-factor of the first excited state in¹⁹⁰Os, as disparities in measurements of the lifetimes of this level have led to uncertainties in itsg-factor.The cooperation and continued support of the staff of the Australian National Unversity Pelletron Laboratory is appreciated greatly. We would like to thank A.H.F. Muggleton for assistance with prepartion of the target, P.M. Davidson for aid during the experiment, and T.H. Heseltine for contributions to aspects of the analysis.     

Nonlinear interferometry and phase measurements for surface second-harmonic generation in a dispersive geometry

Direct measurement of the phase of the surface nonlinear susceptibility is based on the interference of nonlinear optical signals. Up to now, this has not been possible for Second-Harmonic Generation (SHG) in geometries such as Total Internal Reflection (TIR) due to the refractive dispersion of harmonic and fundamental light created in TIR. We demonstrate two schemes which enable us to overcome this dispersion, leading to interference between two second-harmonic signals generated consecutively by the same laser. The advantages and limitations of the two approaches are discussed. We use this technique to check the theoretical predictions for the nonlinear Fresnel factors for SHG in the TIR geometry.Paper presented at the 129th HE-Heraeus-Seminar on Surface Studies by Nonlinear Laser Spectroscopies, Kassel, Germany, May 30 to June 1, 1994