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1.
N. Zh. Saifullina E. B. Galieva A. K. Tashmukhamedova 《Chemistry of Heterocyclic Compounds》2005,41(9):1183-1185
A method has been developed for the introduction of benzimidazole substituents into the dibenzo-18-crown-6 molecule by condensation
of its 4′,4″(5″)-diacetyl derivative with ortho-phenylenediamine. Increasing the length of the hydrocarbon chain of the acyl
substituent or replacing Ac by CSNH2 led to a decrease in the yield of the desired product. No product was formed when Ac was replaced by COOH or CN.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, 1388–1390, September, 2005. 相似文献
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Two constitutional isomers of dibenzo-18-crown-6 derivatives (6 and 7) were synthesised and their binding behaviours towards trivalent lanthanoid cations (La3 + , Ce3 + , Pr3 + , Nd3 + , Sm3 + , Eu3 + , Gd3 + and Tb3 + ) were investigated. Both isomers expressed better binding affinities towards Sm3 + and Tb3 + than a group of other lanthanoids, as measured by the ligand-to-metal charge-transfer (LMCT) band intensity at ca. 425 nm using UV–vis spectroscopic method. Additionally, the trans isomer 7 was shown to have a higher binding ability than the cis isomer 6 towards Tb3 + . 相似文献
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Adsorption of water vapor by granular polymer based on dibenzo-18-crown-6 and containing potassium nitrate or potassium picrate
in the polymer phase was studied by the isopiestic method at 298 K. The adsorption of water vapor is described by isotherms
corresponding (according to BDDT classification) to polymolecular absorption with a high adsorptive potential. In terms of
the Aranovich model of polymolecular absorption, the monolayer capacity and differential heat of adsorption were calculated,
and the stoichiometry of hydration of the potassium nitrate and potassium picrate complexes with immobilized crown ether was
estimated.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1940–1942, October, 1998. 相似文献
8.
D. V. Kuznetsov S. A. Andreev A. K. Tashmukhamedova 《Chemistry of Natural Compounds》2006,42(5):515-516
Diazonium salts were prepared by diazotization of 4′-amino-, 4′,4″-, and 4′,5″-diaminodibenzo-18-crown-6. Their coupling products
with kojic acid (5-hydroxy-2-hydroxymethyl-γ-pyrone) were synthesized for the first time: 4′-(6-aza-5-hydroxy-2-hydroxymethyl-γ-pyronyl)-, 4′,4″-di-(6-aza-5-hydroxy-2-hydroxymethyl-γ-pyronyl)-, and 4′,5″-di-(6-aza-5-hydroxy-2-hydroxymethyl-γ-pyronyl)-dibenzo-18-crown-6.
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Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 415–416, September–October, 2006. 相似文献
9.
K. M. Valikhanov M. G. Levkovich A. K. Tashmukhamedova 《Chemistry of Natural Compounds》2001,37(4):361-363
New derivatives of dibenzo-18-crown-6 were prepared by condensing 4,4(5)-dibenzo-18-crown-6-dicarboxylic acid dichloride with salsolidine and salsoline. The structures of these compounds were proved by PMR and IR spectral methods. 相似文献
10.
Roman Luboradzki Janusz Lipkowski Yurii A. Simonov Marina S. Fonari Edward V. Ganin Arkadii A. Yavolovskii 《Journal of inclusion phenomena and macrocyclic chemistry》1995,23(3):181-193
An X-ray—diffraction study is reported for two molecular complexes containing 3,4-diamino-1,2,5-oxadiazole as guest (G) with 18-crown-6 (18-C-6) andcis-anti-cis-dicyclohexano-18-crown-6 (DCH-6B) as host. Both complexes are of the polymeric-chain structure with the guest molecule bridging two crown neighbours. ComplexI: [18-C-6*G*H2O], 111, monoclinic,P21/n,a=8.171(1),b=15.042(2),c=16.209(6) Å, =101.15(2)°, finalR-factor 0.068. ComplexII: [DCH-6B*G], 11, monoclinicC2/c,a=21.212(4),b=9.380(2),c=13.049(3) Å, =108.61(3)°, finalR 0.047. 相似文献
11.
1INrnODUCTIoNlnthepreviouspapers,wehavereportedthesynthesisandcrystalstructureofseveralcrownetherpolyoxometalates"-",nowwestudythestructureofthetitlecomplexandcompareitwithsomeothercrownetherpolyoxometalatecomplexes.2EXPERmENTALToal5OmLaqueoussolutioncontaining32g(1OOmol)Na,WO#.2H,Opre-justedtopH=3.5withchloricacid,14g(4Ommol)(n-Bu)'NBrwasadded,thenwhitepowderwasformed.ThewhiteprecipitateobtainedwithafiltrationwaskeptasthenewmaterialAinnextstep.AmixtureoflgAandO.3g(O.8mmol)DB18… 相似文献
12.
High-quality free-standing poly(dibenzo-18-crown-6) (PDBC) films with a conductivity of 4.1 × 10−2 S cm−1 and good thermal stability were synthesized electrochemically on stainless steel electrode by direct anodic oxidation of dibenzo-18-crown-6 (DBC) in pure boron trifluoride diethyl etherate (BFEE). In this medium, the oxidation potential onset of DBC was measured to be only 0.98 V vs. SCE, which was much lower than that in acetonitrile + 0.1 mol L−1 Bu4NBF4 (1.45 V vs. SCE). PDBC films obtained from this medium showed good redox activity and stability in BFEE. The structural characterization of PDBC was performed using UV-vis, FTIR spectroscopy. The results of quantum chemistry calculations of DBC monomer and FTIR spectroscopy of PDBC films indicated that the polymerization mainly occurred at C(4) and C(5) positions). Fluorescent spectral studies indicated that PDBC was a blue light emitter. To the best of our knowledge, this is the first report on the electrodeposition of free-standing PDBC films. 相似文献
13.
A. N. Chekhlov 《Russian Journal of Inorganic Chemistry》2006,51(8):1211-1217
A new compound, aqua(dibenzo-18-crown-6)potassium (dibenzo-18-crown-6)(perchlorato-O)potassium perchlorate ([K(DB18C6)(H2O)]+ · [K(ClO4)(DB18C6)] · ClO 4 ? ; compound I) is synthesized and studied by X-ray crystallography. The crystals are triclinic: a = 9.050 Å, b = 9.848 Å, c = 26.484 Å, α = 82.87°, β = 84.16°, γ = 77.93°, Z = 2, space group P $\bar 1$ . The structure is solved by a direct method and refined by the full-matrix least-squares method in the anisotropic approximation to R = 0.058 for 5960 independent reflections (CAD4 diffractometer, λMoK α radiation). A complex cation [K(DB18C6)(H2O)]+ and a complex molecule [K(ClO4)(DB18C6)] are of the host-guest type; they are linked into a dimer through two K+ → π(C) bonds formed by one of the two K+ cations with two C atoms of the benzene ring of the DB18C6 ligand from the adjacent complex. Both DB18C6 ligands in I have a butterfly conformation with approximate symmetry C 2v . 相似文献
14.
A. N. Chekhlov 《Russian Journal of Inorganic Chemistry》2009,54(3):467-471
A new compound, dibenzo-18-crown-6 diaqua(dibenzo-18-crown-6)potassium triiodide [K(Db18C6)(H2O)2)+ · I3− · Db18C6 (I), is synthesized and studied by X-ray crystallography. The crystals of compound I are orthorhombic: a = 22.065 ?, b = 22.140 ?, c = 9.433 ?, Z = 4, space group Pccn. Structure I is solved by a direct method and refined by the full-matrix least-squares method in the anisotropic approximation
to R = 0.098 for all 5974 unique reflections. Structure I contains the following asymmetric units: a half of the I3− centrosymmetric anion and two halves of the mixed equally average [K(Db18C6)(H2O)2]+ host—guest complex cation (a) and a free Db18C6 molecule, each stacked on the axes 2 of the perpendicularly averaged plane
of the eighteen-membered macroheterocycle. In complex I, both Db18C6 molecules (a and b) have a “butterfly” conformation with
approximate symmetry C
2v
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Original Russian Text ? A.N. Chekhlov, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 3, pp. 516–520. 相似文献
15.
NIU Mei-Ju ② DOU Jian-Min WANG Da-Qi LI Da-Cheng 《结构化学》2006,25(6):757-760
1 INTRODUCTION Since the report about unusual coordination num- bers and arrangements to metal ions of crown ether compounds by Pedersen[1], the crown ether compounds have attracted much attention. Due to their novel coordination modes, crown ethers have been widely used in catalyst, solvent extraction, iso- tope separation, bionics, material chemistry, host- guest chemistry and supramolecular chemistry[2~5]. So it is vital to study the synthesis of new crown ethers and their crystal stru… 相似文献
16.
The acylation of dibenzo-18-crown-6 by lithium, sodium, and potassium acetates in polyphosphoric acid was studied. Complexes
of dibenzo-18-crown-6 with the acetates were obtained. A new method is proposed for the production of mono- and diacetyldibenzo-18-crown-6
by the reaction of dibenzo-18-crown-6 complexes with metal acetates in polyphosphoric acid.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1146–1149, August, 2005. 相似文献
17.
Complete structural characterization of dibenzo-18-crown-6·2 CH3NO2 and dibenzo-18-crown-6·2 CH3CN have been carried out, including location and refinement of the methyl hydrogen atoms. Dibenzo-18-crown-6·2 CH3NO2 is monoclinic,P21/c, with (at –150°C)a=9.573(2),b=14.636(2),c=33.471(7) Å, =93.77(2)°, andD
calc=1.37 g cm–3 forZ=8. Interactions between the solvent methyl groups and the crown ethers and other solvent nitro groups associate the 1 : 2 complexes into polymeric chains alongb. The acetonitrile adduct exists as discreet 1 : 2 complexes in the solid state with C–H...O interactions exlusively to the ether. This complex is triclinic,P 1, with (at –150°C)a=9.458(6),b=9.570(5),c=14.404(5) Å, =73.18(4), =79.85(5), =66.82(6)°, andD
calc=1.28 g cm–3 forZ=2.
Supplementary Data relating to this article are deposited with the British Library as Supplementary Publication No. SUP 82070 (22 pages).For part 4, see reference [1]. 相似文献
18.
A. N. Chekhlov 《Russian Journal of General Chemistry》2009,79(2):278-282
New mixed complex compound aqua(dibenzo-18-crown-6)potassium (dibenzo-18-crown-6)(tetrachlorocuprato(II)-Cl)potassium, [K(CuCl4)(Db18C6)]? · [K(Db18C6)(H2O)]+, is synthesized and its crystal structure is studied by the method of x-ray structural analysis. The structure includes two independent complex ions, both of guest-host type: two cations K+ are located in the respective cavities of the Db18C6 crown-ligand (one in each) and each is coordinated by all its six O atoms and one Cl atom of the anion-ligand [CuCl4]2? or O atom of the ligand water molecule. Coordination of these two K+ cations is completed to hexagonal pyramidal one by formation by each of unusually weak coordination bond K+ → π(\(C\dddot - C\)) with two C atoms of respective benzene ring in the neighboring Db18C6 ligand. In this crystal structure the complex anions and cations form dual infinite chains via these coordination bonds and interionic O-H?Cl hydrogen bonds. 相似文献
19.
A. N. Chekhlov 《Russian Journal of Inorganic Chemistry》2007,52(6):859-864
An ionized crystalline adduct of dibenzo-18-crown-6, perchloric acid, and water (H3O)[DB 18K6](ClO4) is synthesized and structurally studied by X-ray diffraction. The crystals are triclinic: a = 8.582 Å, b = 10.486 Å, c = 26.293 Å, α = 79.45°, β = 82.00°, γ = 79.36°, Z = 4, space group P \(\bar 1\). The structure is solved by a direct method and refined by the full-matrix least-squares method in the anisotropic approximation to R = 0.098 for 5936 independent reflections (CAD4 automated diffractometer, λMoK α radiation). The structure contains two independent DB18C6 molecules, two independent H3O+ ions, and two independent ClO 4 ? ions. The H3O+ ions each lie in the cavity of each of the two DB18C6 molecules and are retained there by three strong hydrogen bonds. Two DB18C6 molecules have close geometric parameters and a butterfly conformation with approximate symmetry C 2v . One of the two independent ClO 4 ? anions is disordered over two orientations. 相似文献
20.
Sille Ehala Petr Toman Emanuel Makrlík Václav Kašička 《Journal of chromatography. A》2009,1216(45):7927-7931
Affinity capillary electrophoresis (ACE) and quantum mechanical density functional theory (DFT) calculations have been employed for investigation of non-covalent interactions between macrocyclic ligand, benzo-18-crown-6-ether (B18C6) and ammonium cation, NH4+. Firstly, by means of ACE, the strength of the B18C6-NH4+ complex in mixed binary hydro-organic solvent system, methanol–water (50/50, v/v), was determined from the dependence of effective electrophoretic mobility of B18C6 (corrected to reference temperature 25 °C and constant ionic strength, 10 mM) on the concentration of ammonium ion in the background electrolyte (BGE) using non-linear regression analysis. The logarithmic form of the apparent binding (stability) constant (log Kb) of B18C6-NH4+ complex in the above binary solvent system was found to be equal to log Kb = 1.63 ± 0.10. Secondly, the structural characteristics of B18C6-NH4+ complex were described by quantum mechanical density functional theory (DFT) calculations. According to these calculations, in the energetically most favoured form of the B18C6-NH4+ complex, three strong hydrogen bonds are formed between central ammonium ion and B18C6 ligand, one of them is directed to aryl-O-alkyl (Ar–O–CH2) ethereal oxygen and the other two hydrogen bonds are oriented to alkyl-O-alkyl (CH2–O–CH2) ethereal oxygen atoms of the macrocyclic crown ligand. 相似文献