Propagation loss, degradation and protective coating of long drawn microfibers

Propagation losses, transmission spectra and optical degradation attributed to surface scattering, crack propagation and water absorption were characterized for long microfibers fabricated by using a drawing tower. The propagation losses and optical degradation at 1550 nm wavelength were found increasing as the diameters decreased for the microfibers. A coating setup was established where polydimethylsiloxane (PDMS) was used as coating material and a CO₂ laser as curing source to form a cylindrical film layer along the surface of microfiber. It was confirmed that no optical degradation was observed for the long drawn microfibers with protective coating over a long period of 18 h.     

Development of mean-field electrical double layer theory

In order to understand the electric interfacial behavior, mean field based electric double layer(EDL) theory has been continuously developed over the past 150 years. In this article, we briefly review the development of the EDL model, from the dimensionless Gouy–Chapman model to the symmetric Bikerman–Freise model, and finally toward size-asymmetric mean field theory models. We provide the general derivations within the framework of Helmholtz free energy of the lattice–gas model, and it can be seen that the above-mentioned models are consistent in the sense that the interconversion among them can be achieved by reducing the basic assumptions.     

Protective silicon coating for nanodiamonds using atomic layer deposition

Ultrathin silicon coating was deposited on nanodiamonds using atomic layer deposition (ALD) from gaseous monosilane (SiH₄). The coating was performed by sequential reaction of SiH₄ saturated adsorption and in situ decomposition. X-ray diffraction (XRD) and transmission electron microscopy (TEM) were utilized to investigate the structural and morphological properties of the coating. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) were used to compare the thermal stability of nanodiamonds before and after silicon coating. The results confirmed that the deposited cubic phase silicon coating was even and continuous. The protective silicon coating could effectively improve the oxidation resistance of nanodiamonds in air flow, which facilitates the applications of nanodiamonds that are commonly hampered by their poor thermal stability.     

Three generations of inorganic phosphates in solvent and water-borne paints: A synergism case

This research work is intended to compare the anti-corrosive properties of three generations of inorganic phosphate pigments in solvent-based paints and in water-borne ones, both of the epoxy type. The anti-corrosive properties of phosphate pigments were assessed by means of electrochemical techniques (corrosion potential measurements, polarisation tests, etc.), employing a steel electrode dipped into pigments suspensions. The behaviour of these pigments in anti-corrosive paints, formulated with different binders, have been studied by accelerated (salt spray cabinet and humidity chamber) and electrochemical tests (corrosion potential and ionic resistance measurements).Accelerated and electrochemical tests allowed to differentiate the anti-corrosive performance of the three phosphates studied in this research. These test are also able to detect and characterise possible synergism between the water-borne resin and the pigments.     

Conversion efficiency enhanced photovoltaic device with nanohole arrays in antireflection coating layer

In this paper, the authors introduce an enhanced photovoltaic device with nanohole arrays only in its antireflection coating. These nanoholes can improve light trapping efficiency as well as photoelectric conversion efficiency of the device. The authors analyze the light absorption of the devices with nanohole arrays by Finite-Difference Time Domain method and calculate the photoelectric conversion efficiency. The results show that the nanohole arrays can improve the light trapping more efficiently than the Si₃N₄ antireflection coating, especially, in 400-600 nm spectral range. Nanohole arrays with different characteristic parameters were fabricated in the antireflection coating layer of a Φ200 μm Si detector by using focused-ion beam system. With the optimized nanohole arrays, the enhancements factor of the experimental sample's photoelectric conversion efficiency is ~ 16% within the 400-600 nm spectral range and ~ 10% within the 400-1100 nm spectral range.     

Effect of pulse parameters on the passive layer formation on pulse plated Ni-Co alloys

From a chloride bath, Ni-Co alloys were pulse plated by varying the pulse parameters off-time and the peak current densities using a pulse generator that applies a square wave signal in order to examine the mechanism of the passive oxide layer formation on the deposited coatings in the frame of pulse parameters.Cyclic voltammetry and potential step measurements were carried out in order to characterise the electrochemical behaviour on the Ni-Co coatings at a selected electrode potential in an alkaline solution. Calculation of the oxide layer formation was evaluated from the total charge, determined by recorded current-time transients and from ICP-analysis of the samples. The most protective and compact oxide was formed on the sample that was deposited at low current densities and at high off-time.     

基于虚拟源技术的双层固体结构超声成像

本文提出虚拟源与合成孔径技术相结合的成像方法来实现对双层结构的内部缺陷成像。通过相控阵探头延时聚焦的方法在界面形成虚拟声源,并对有机玻璃/钢双层结构中的聚焦声场进行了仿真,结果显示聚焦声束穿过界面后形成扩散球面波,适合采用合成孔径聚焦技术成像。实验中采用128阵元探头对含有横穿孔缺陷的有机玻璃/钢样品进行测量和波形采集,应用自适应滤波方法抑制界面回波,最后对波形使用合成孔径聚焦成像,得到的图像比B扫描成像具有较高的信噪比和横向分辨率,并且分辨率不随深度变化。     

Studies on adhesion characteristics and corrosion behaviour of vinyltriethoxysilane/epoxy coating protective system on aluminium

The corrosion stability of vinyltriethoxysilane/epoxy coating protective system on aluminium is strongly related to the strength of bonds forming at the metal/organic coating interface. This article is a study of adhesion, composition, electrochemical and transport properties of epoxy coatings electrodeposited on bare aluminium and aluminium pretreated by vinyltriethoxysilane (VTES) during exposure to 3% NaCl. The VTES film was deposited on aluminium surface from 2% vinyltriethoxysilane solution during 30 s. From the values of adhesion strength (pull-off test), time dependence of pore resistance and coating capacitance of epoxy coating (impedance measurements) and diffusion coefficient of water through epoxy coating (gravimetric liquid sorption measurements), the influence of VTES sublayer on the corrosion stability of the electrodeposited epoxy coating was shown.The work discusses the role of the VTES pretreatment in the enhanced adhesion and corrosion stability of epoxy cataphoretic coating. The electrochemical results showed that the aluminium pretreatment by VTES film improved barrier properties of epoxy coating (greater pore resistance and lower coating capacitance). The lower value of diffusion coefficient of water through epoxy coating indicates the lower porosity, while the smaller adhesion reduction points to better adhesion of epoxy coating on aluminium pretreated by VTES film. The composition of the deposited coatings investigated by XPS enabled the clarification of the bonding mechanism.     

A correlation-hole approach to the electric double layer with counter-ions only

ABSTRACT

We study a classical system of identically charged counter-ions near a planar wall carrying a uniform surface charge density. The equilibrium statistical mechanics of the system depends on a single dimensionless coupling parameter. A new self-consistent theory of the correlation-hole type is proposed which leads to a modified Poisson–Boltzmann integral equation for the density profile, convenient for analytical progress and straightforward to solve numerically. The exact density profiles are recovered in the limits of weak and strong couplings. In contrast to previous theoretical attempts of the test-charge family, the density profiles fulfil the contact-value theorem at all values of the coupling constant and exhibit the mean-field decay at asymptotically large distances from the wall, as expected. We furthermore show that the density corrections at large couplings exhibit the proper dependence on coupling parameter and distance to the charged wall. The numerical results for intermediate values of the coupling provide accurate density profiles which are in good agreement with those obtained by Monte Carlo simulations. The crossover to mean-field behaviour at large distance is studied in detail.     

具有新型双空穴注入层的有机发光二极管

采用新型双空穴注入层N, N, N', N'-tetrakis(4-Methoxy-phenyl)benzidine/Copper phthalocyanine(MeO-TPD/CuPc)及器件结构:ITO/MeO-TPD(15 nm)/CuPc(15 nm)/ N, N'-Bis(naphthalen-1-yl)-N, N'-bis(phenyl)benzidine (NPB, 15 nm)/8-hydroxyquinoline (Alq₃, 50 nm)/LiF(1 nm)/Al(120 nm), 研制出高效有机发光二极管(器件D), 与其他器件(器件A, 没有空穴注入层的器件; 器件B, MeO-TPD单空穴注入层; 器件C, CuPc单空穴注入层)相比, 其性能得到明显改善. 器件D的起亮电压降至3.2 V, 比器件A, B, C的起亮电压分别降低了2, 0.3, 0.1 V. 器件D在10 V时, 其最大亮度为23893 cd/m², 最大功率效率为1.91 lm/W, 与器件A, B, C的最大功率效率相比, 分别提高了43% (1.34 lm/W), 22% (1.57 lm/W), 7% (1.79 lm/W). 性能改善的主要原因是由于空穴注入和传输性能得到了改善, 通过单空穴型器件的J-V 曲线对这一现象进行了分析. 关键词： 有机发光二极管 空穴注入层 功率效率 势垒     

The electric double layer effect on the microchannel flow stability and heat transfer

The effect of the electric double layer (EDL) on the linear stability of Poiseuille planar channel flow is reported. It is shown that the EDL destabilises the linear modes, and that the critical Reynolds number decreases significantly when the thickness of the double layer becomes comparable with the height of the channel. First results coming from direct numerical simulations on the non-linear effects show also that the by-pass transition is much more rapid in the presence of EDL. There is an acceptable qualitative correspondence between the estimated transitional Reynolds numbers and some experiments, showing that early transition is plausible in microchannels under some conditions. Several questions remain however unanswered such as the surface conduction effect on EDL.     

Performance of double layer electrolyte cells Part I: Model behavior

The present work reports on the estimated performance of double layer electrolyte based cells, including one yttria stabilized zirconia (YSZ) electron blocking layer. In order to evaluate the impact of the relative magnitude of the materials properties on the cell performance, a range of electrical properties has been considered, taking YSZ as reference. At constant temperature, the open circuit voltage, the oxygen permeability and the oxygen partial pressure profiles in such two layer electrolyte cells are related to the materials ionic and electronic transport properties, layers thickness and overall cell oxygen partial pressure boundary conditions. The effectiveness of the electron blocking characteristics of YSZ layers is demonstrated for a variety of materials, but consideration of the exact electrical properties (the n-type but also the p-type and ionic conductivities) of the second electrolyte layer is shown to be a fundamental requirement for proper design of such cells.     

高功率微波对双层屏蔽腔体的孔缝耦合特性

 用多模传输线模型对高功率微波与双层屏蔽腔体的孔缝耦合特性进行了研究,此方法可以考虑高功率微波孔缝耦合进入腔内时的较宽的频率范围。用这种模拟方法获得了双层屏蔽腔体微波耦合的一些规律性结果：双层屏蔽可以使得腔体内的耦合电场比单层屏蔽时有显著的减弱,这与FDTD方法的结论是一致的;双层屏蔽外腔体中的一些谐振会影响到内腔体的耦合系数,外腔体中的场模式经由内孔缝会影响内腔体中的场模式;不论是单层屏蔽还是双层屏蔽,保持每层孔缝总面积不变时,随着孔阵中孔缝数量的增加,进入腔体内的耦合电场也逐步地减弱,这与单层屏蔽时的结论一致;通风总面积不变的情况下,孔缝数量越多,屏蔽效能越好。     

Influence of air-oxidation on electric double layer capacitances of multi-walled carbon nanotube electrodes

In this work, air-oxidized multi-walled carbon nanotube (MWCNT) electrodes have been prepared from catalytically grown MWCNTs of high purity and narrow diameter distribution. The experimental results show that air-oxidation modifies the intrinsic structure of individual MWCNTs and a little improves the dispersity of the MWCNTs. The specific capacitances of the electrodes in electric double layer capacitors (EDLCs) based on oxidized MWCNTs are obviously improved through air-oxidation. The specific capacitance of 50 F/g is obtained in the air-oxidized MWCNTs at 600 °C on a single cell device with 35 wt% H₂SO₄ as an electrolyte. This is probably increased BET specific surface area and mesopore volume of the oxidized MWCNT electrode materials of EDLCs. These properties are, therefore highly desirable for the development of electrochemical capacitors with high power and long cycle life.     

Fake double layers in double plasma devices

The double layer like potential jumps have been observed in a double plasma device. They do not correspond to a switching of plasma potential from one metastable state to another but are caused by the ionisation of a very minute amount of the gas that inevitably leaks into the system during the probe movement.     

Contact value relations and density functional theory for the electrical double layer

The recently developed contact-corrected density functional theory is applied to an electric double layer containing a valence and size symmetric electrolyte. The restricted primitive model is used to describe the electrolyte, and a non-polarisable, smooth, planar, uniformly charged hard surface is used to model the electrode. Comparison with Monte Carlo simulation results for this system shows that the theory satisfies the first contact value relation in line with the premise of the approach. Additionally, the theory is found to satisfy the semi-empirical second contact value relation quite closely. This is a welcome result, since no reference is made to this second relation nor is the relation used in the theoretical development. The second contact relation is closely related to the anomalous positive temperature derivative of the double layer capacitance at low temperature, low ion concentration, and low electrode charge, and indeed, the contact-corrected density functional theory predicts this effect.     

缓冲层对LBO晶体上1 064 nm，532 nm增透膜附着力的影响

 采用电子束蒸发方法在LBO晶体上制备了无缓冲层和具有不同缓冲层的1 064 nm,532 nm二倍频增透膜。利用分光光度计、纳米力学综合测试系统以及调Q脉冲激光装置对样品的光学性能、附着力以及抗激光损伤性能进行了测试分析。结果表明：所有样品在1 064 nm和532 nm波长的剩余反射率都分别小于0.1％和0.2％;与无缓冲层样品相比,预镀Al₂O₃缓冲层样品的附着力提高了43.1％,具有SiO₂缓冲层样品的附着力显著提高,而MgF₂缓冲层的插入却导致薄膜附着力降低。应用全塑性压痕理论和剪切理论对薄膜的附着力增强机制进行了分析。薄膜的抗激光损伤性能分析表明,SiO₂缓冲层也有助于改进薄膜的激光损伤阈值。     

高功率微波对双层屏蔽腔体的孔缝耦合特性

用多模传输线模型对高功率微波与双层屏蔽腔体的孔缝耦合特性进行了研究,此方法可以考虑高功率微波孔缝耦合进入腔内时的较宽的频率范围。用这种模拟方法获得了双层屏蔽腔体微波耦合的一些规律性结果：双层屏蔽可以使得腔体内的耦合电场比单层屏蔽时有显著的减弱,这与FDTD方法的结论是一致的;双层屏蔽外腔体中的一些谐振会影响到内腔体的耦合系数,外腔体中的场模式经由内孔缝会影响内腔体中的场模式;不论是单层屏蔽还是双层屏蔽,保持每层孔缝总面积不变时,随着孔阵中孔缝数量的增加,进入腔体内的耦合电场也逐步地减弱,这与单层屏蔽时的结论一致;通风总面积不变的情况下,孔缝数量越多,屏蔽效能越好。     

Measurement of the double layer capacitance of aluminium samples by holographic interferometry

In the present investigation, holographic interferometry was utilized for the first time to measure the double layer capacitance of aluminium samples during the initial stage of anodization processes in an aqueous solution without any physical contact. The anodization process (oxidation) of the aluminium samples was carried out chemically in different sulphuric acid concentrations (0.5–3.125% H₂S0₄) at room temperature. In the meantime, a method of holographic interferometry was used to measure the thickness of anodization (oxide film) of the aluminium samples in aqueous solutions. Along with the holographic measurement, a mathematical model was derived in order to correlate the double layer capacitance of the aluminium samples in solutions to the thickness of the oxide film of the aluminium samples which forms due to the chemical oxidation. The thickness of the oxide film of the aluminium samples was measured by real-time holographic interferometry. Consequently, holographic interferometry is found to be very useful for surface finish industries, especially for monitoring the early stage of anodization processes of metals, in which the thickness of the anodized film as well as the double layer capacitance of the aluminium samples can be determined in situ. In addition, a comparison was made between the obtained data of the double layer capacitance from the holographic measurements and the double layer capacitance data obtained from measurements of electrochemical impedance spectroscopy. The comparison indicates that there is good agreement between the data from both techniques.     

Structure of a planar electric double layer containing size-asymmetric ions: density functional approach

We have studied the structure of the electrolytes with asymmetries in charge and size near a charged planar electric double layer by a density functional theory. In the present theory, the hard-sphere contribution has been approximated as the direct pair correlation function with the coupling parameter, whereas the electronic contribution has been approximated as the mean-spherical approximation in the bulk phase. This theoretical approach for the size-symmetric and size-asymmetric electrolytes displays a good agreement with the simulation results over a wide range of surface charge densities and electrolyte concentrations. However, the accuracy between the present theory and the simulation results slightly deteriorates for the highly size-asymmetric electrolytes and the multivalent electrolytes. In these cases, the performance of the present theory is comparable to those of the simplified extension of the Poisson–Boltzmann theory and the modified Poisson–Boltzmann theory. The calculated result indicates that the surface charge distribution function, which was introduced as an indicator for studying the charge reversal, layering effect, and surface charge amplification in a planar electric double layer, describes the electronic properties of a planar electric double layer well.