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1.
The optimum rib size to enhance heat transfer had been proposed through an experimental investigation on the forced convection of a fully developed turbulent flow in an air-cooled horizontal equilateral triangular duct fabricated on its internal surfaces with uniformly spaced square ribs. Five different rib sizes (B) of 5 mm, 6 mm, 7 mm, 7.9 mm and 9 mm, respectively, were used in the present investigation, while the separation (S) between the center lines of two adjacent ribs was kept at a constant of 57 mm. The experimental triangular ducts were of the same axial length (L) of 1050 mm and the same hydraulic diameter (D) of 44 mm. Both the ducts and the ribs were fabricated with duralumin. For every experimental set-up, the entire inner wall of the duct was heated uniformly while the outer wall was thermally insulated. From the experimental results, a maximum average Nusselt number of the triangular duct was observed at the rib size of 7.9 mm (i.e. relative rib size ). Considering the pressure drop along the triangular duct, it was found to increase almost linearly with the rib size. Non-dimensional expressions had been developed for the determination of the average Nusselt number and the average friction factor of the equilateral triangular ducts with ribbed internal surfaces. The developed equations were valid for a wide range of Reynolds numbers of 4,000 < Re D < 23,000 and relative rib sizes of under steady-state condition. A Inner surface area of the triangular duct [m2] - A C Cross-sectional area of the triangular duct [m2] - B Side length of the square rib [mm] - C P Specific heat at constant pressure [kJ·kg–1·K–1] - C 1, C 2, C 3 Constant coefficients in Equations (10), (12) and (13), respectively - D Hydraulic diameter of the triangular duct [mm] - Electric power supplied to heat the triangular duct [W] - f Average friction factor - F View factor for thermal radiation from the duct ends to its surroundings - h Average convection heat transfer coefficient at the air/duct interface [W·m–2 ·K–1] - k Thermal conductivity of the air [W·m–1 ·K–1] - L Axial length of the triangular duct [mm] - Mass flow rate [kg·s–1] - n 1, n 2, n 3 Power indices in Equations (10), (12) and (13), respectively - Nu D Average Nusselt number based on hydraulic diameter - P Fluid pressure [Pa] - Pr Prandtl number of the airflow - c Steady-state forced convection from the triangular duct to the airflow [W] - l Heat loss from external surfaces of the triangular duct assembly to the surroundings [W] - r Radiation heat loss from both ends of the triangular duct to the surroundings [W] - Re D Reynolds number of the airflow based on hydraulic diameter - S Uniform separation between the centre lines of two consecutive ribs [mm] - T Fluid temperature [K] - T a Mean temperature of the airflow [K] - T ai Inlet mean temperature of the airflow [K] - T ao Outlet mean temperature of the airflow [K] - T s Mean surface temperature of the triangular duct [K] - T Ambient temperature [K] - U Mean air velocity in the triangular duct [m·s–1] - r Mean surface-emissivity with respect to thermal radiation - Dynamic viscosity of the fluid [kg·m–1·s–1] - Kinematic viscosity of the airflow [m2·s–1] - Density of the airflow [kg·m–3] - Stefan-Boltzmann constant [W·m–2·K–4]  相似文献   

2.
The electrical conductivity of silicate rocks (quartzite, granite, and dry and wet tuffs) under single shock–wave loading is measured. It is shown that even at a shock–wave pressure of 20 GPa, the conductivity of rocks changes by several orders of magnitude compared to the initial value (10–9 — 10–12 –1 · m–1 for dry rocks) and reaches 0.01 –1 · m–1 for quartzite and granite and 0.1 — 1.0 –1 · m–1 for tuff. As the shock–wave amplitude increases from 20 to 60 GPa, the electrical conductivity increases by further one or two orders of magnitude. The experiments with rocks did not reveal a drastic change in electrical conductivity similar to the that observed for silicon dioxide (fused quartz) at a pressure of about 40 GPa.  相似文献   

3.
A novel in-line rheometer, called Rheopac, has been designed and built in order to study the rheological behaviour of starchy products or, more generally, of products sensitive to a thermomechanical treatment. It is based on the principle of a twin channel, using a balance of feed rate between each of them, in order to make local shear rate vary in the measuring section without changing the flow conditions into the extruder. A wide range of shear rate could be reached and measurements were performed more swiftly than with a classical slit die. The viscous behaviour of maize starch was studied by taking into account the influence of the thermomechanical history, which modified the starch degradation and thus led to important variations in the viscosity. Experimental results were satisfactorily compared to previously published models.Nomenclature E activation energy (J · mol–1) - h channel depth (m) - h 1 depth under the piston valve in channel 1 (m) - h 2 depth under the piston valve in channel 2 (m) - K consistency (Pa·s n ) - K 0 reference consistency (Pa·s n ) - L total channel length (m) - L p length of the piston valve (m) - MC moisture content (wet basis) - n power law index - N screw rotation speed (rpm) - P 0 entrance pressure (Pa) - P e pressure at the entry of the piston valve (Pa) - Q 1 flow rate in channel 1 (m3 · s–1) - Q 2 flow rate in channel 2 m3·s–1) - Q T total flow rate (m3 · s–1) - R constant of perfect gas (8.314 J·mol–1·K–1) - SME specific mechanical energy (kWh · t–1) - T temperature (°C) - T a absolute temperature (K) - T b barrel temperature (°C) - T d die temperature (°C) - T p product temperature (°C) - w channel width (m) - W energetical term (J·m–3) - viscosity (Pa · s) - [gh 0] intrinsic viscosity of native starch (ml·g–1) - [] intrinsic viscosity (ml·g–1) - shear rate (s–1) - shear rate in measuring section (s–1) - maximum shear rate (s–1)  相似文献   

4.
The rheological properties of rennet-induced skim milk gels were determined by two methods, i.e., via stress relaxation and dynamic tests. The stress relaxation modulusG c (t) was calculated from the dynamic moduliG andG by using a simple approximation formula and by means of a more complex procedure, via calculation of the relaxation spectrum. Either calculation method gave the same results forG c (t). The magnitude of the relaxation modulus obtained from the stress relaxation experiments was 10% to 20% lower than that calculated from the dynamic tests.Rennet-induced skim milk gels did not show an equilibrium modulus. An increase in temperature in the range from 20° to 35 °C resulted in lower moduli at a given time scale and faster relaxation. Dynamic measurements were also performed on acid-induced skim milk gels at various temperatures andG c (t) was calculated. The moduli of the acid-induced gels were higher than those of the rennet-induced gels and a kind of permanent network seemed to exist, also at higher temperatures. G storage shear modulus,N·m–2; - G loss shear modulus,N·m–2; - G c calculated storage shear modulus,N·m–2; - G c calculated loss shear modulus,N·m–2; - G e equilibrium shear modulus,N·m–2; - G ec calculated equilibrium shear modulus,N·m–2; - G(t) relaxation shear modulus,N·m–2; - G c (t) calculated relaxation shear modulus,N·m–2; - G *(t) pseudo relaxation shear modulus,N·m–2; - H relaxation spectrum,N·m–2; - t time,s; - relaxation time,s; - angular frequency, rad·s–1. Partly presented at the Conference on Rheology of Food, Pharmaceutical and Biological Materials, Warwick, UK, September 13–15, 1989 [33].  相似文献   

5.
Summary This paper describes a torsional creep apparatus for the determination of the creep compliance in shear as a function of time. The instrument is suitable for the measurement of compliances below 5·10–8 m2/N, in the time range between 1 and 105 seconds. Within five minutes and with an accuracy of 1 C, the temperature of the specimen can be adjusted to any value between –175 and –200 C. From the torsional creep measurements can be calculated the dynamic shear modulus and the corresponding damping. The lowest damping, determined in this way, is several times 10–3.
Zusammenfassung Ein Apparat zur Messung des Torsions-Kriechverhaltens wird beschrieben. Das Instrument ist zur Bestimmung von Nachgiebigkeiten kleiner als 5·10–5 m2/N im Zeitbereich zwischen 1 und 105 Sekunden geeignet. Die Temperatur der Probe läßt sich innerhalb 5 Minuten und mit einer Genauigkeit von 1 C auf jeden Wert zwischen –175 und –200 C einstellen. Aus der gemessenen Kriechfunktion können der dynamische Schubmodul und die dynamische Dämpfung berechnet werden. Eine untere Grenze für die Dämpfung, die man auf diese Weise noch bestimmen kann, ist einige Male 10–3.


The work was partly sponsored by the Office of Naval Research, Washington, D. C., under contract number N 62558-3884.  相似文献   

6.
Zusammenfassung Die rheologischen Eigenschaften gesunder menschlicher Gelenksflüssigkeiten im Geschwindigkeitsgefällebereich vonD = 10–3-103 s–1 wurden untersucht. Es wurden die Scherviskosität und die erste Normalspannungsdifferenz gemessen. Gesunde Synovialflüssigkeiten besitzen hohe Anfangsviskosität (~40 Pa · s) und zeigen eine starke Abhängigkeit vom Geschwindigkeitsgefälle. Der SchermodulG ist im Gegensatz zu pathologischen Proben niedrig und über weite Bereiche konstant. Die längsten Relaxationszeiten betragen 5–10 s. Die kritische Konzentration, bei der Netzwerkbildung einsetzt, beträgt 0,75 10–3 g/ml. Die Proben lassen sich zu einer Masterkurve vereinigen, die als verallgemeinertes Fließgesetz für gesunde Synovia aufgefaßt werden kann. Eine Untersuchung über die zeitliche Abhängigkeit der post-mortem-Synovia zeigt, daß innerhalb von 12 Stunden keine nennenswerten Veränderungen eintreten.
The rheology of healthy human synovial fluids has been investigated at a shear-rate between 10–3-103 s–1. Shear viscosity and first normal-stress difference were measured. Healthy synovial fluids show high zero-shear viscosity (about 40 Pa · s) and a strong shear rate dependence. The modulusG is constant over a large range, in contrast to pathological samples. The longest relaxation times are 5–10 s. The critical concentrationc cr , at which entanglement occurs is about 0.75 10–3 g/ml. The samples can be represented by a master-curve, which may be regarded as the constitutive equation of healthy synovial fluids. An investigation of the time dependency of synovial fluids indicated no changes within 12 hours post mortem.
Herrn Prof. Dr. DDr. h. c. O. Kratky zum 80. Geburtstag mit den besten Wünschen gewidmet.  相似文献   

7.
An experimental investigation was made into the thermal effect of a single gas jet on a plate at Mach numbers of the nozzles in the range 2–6.1, specific heat ratio = 1.4, total pressure difference up to 6·107, gas temperature 450–520 °K in the forechamber, and pressure in the forechamber (10–20)· 105 Pa. The proposed dimensionless numbers made it possible to obtain generalized dependences of the distribution of the heat flux to the plate on the conditions of the problem. A method of approximate calculation of the heat fluxes is proposed.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 4, pp. 119–126, July–August, 1981.  相似文献   

8.
Mixed convection induced in the entrance region of a horizontal plane channel by a bottom heat source of finite dimensions is considered. The calculations were performed for the Prandtl number Pr = 1, Grashof numbers ranging from 4 · 103 to 3.2 · 104, and Reynolds numbers varying from 0 to 10. The dimensions of the heat source and its location were also varied. The results were obtained from a numerical solution of the 2D unsteady Navier-Stokes equations in the Boussinesq approximation, written in vorticity – stream function – temperature variables. The solution was found by the Galerkin finite element method.  相似文献   

9.
One-dimensional problems of the flow in a boundary layer of finite thickness on the end face of a model and in a thin viscous shock layer on a sphere are solved numerically for three regimes of subsonic flow past a model with a flat blunt face exposed to subsonic jets of pure dissociated nitrogen in an induction plasmatron [1] (for stagnation pressures of (104–3·104) N/m2 and an enthalpy of 2.1·107 m2/sec2) and three regimes of hypersonic flow past spheres with parameters related by the local heat transfer simulation conditions [2, 3]. It is established that given equality of the stagnation pressures, enthalpies and velocity gradients on the outer edges of the boundary layers at the stagnation points on the sphere and the model, for a model of radius Rm=1.5·10–2 m in a subsonic jet the accuracy of reproduction of the heat transfer to the highly catalytic surface of a sphere in a uniform hypersonic flow is about 3%. For surfaces with a low level of catalytic activity the accuracy of simulation of the nonequilibrium heat transfer is determined by the deviations of the temperatures at the outer edges of the boundary layers on the body and the model. For this case the simulation conditions have the form: dUe/dx=idem, p0=idem, Te=idem. At stagnation pressuresP 02·104 N/m2 irrespective of the catalycity of the surface the heat flux at the stagnation point and the structure of the boundary layer near the axis of symmetry of models with a flat blunt face of radius Rm1.5·10–2 m exposed to subsonic nitrogen jets in a plasmatron with a discharge channel radius Rc=3·10–2 m correspond closely to the case of spheres in hypersonic flows with parameters determined by the simulation conditions [2, 3].Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 135–143, March–April, 1990.  相似文献   

10.
It is known from experiments [1–3] that the velocity of streamers, induced in the center of the interelectrode gap and propagating to the electrodes under conditions when the streamer length is comparable with the distance between the electrodes, increases linearly as the streamer length increases. This relationship is in qualitative agreement with theory [4], Nevertheless, the velocity of streamers starting from the electrodes and propagating in a long interelectrode gap remains practically constant during the whole propagation process [5, 6], In the case of short gaps (2–5 cm), constancy of the velocity is observed during the stage of the process when the length of the streamer is much less (20%) than the length of the gap [7], Since the electric field at its end controls the streamer propagation, the constancy of the streamer velocity indicates that the controlling field is constant under these conditions. A number of theoretical models were proposed in [8–13] which describe uniformly moving anode- and cathode-directed streamers (henceforth called anode and cathode streamers). Comparison of experimental data with the corresponding theoretical model enables one to determine the streamer parameters: the electric field, the charged-particle density, the current density, the channel radius, etc. In the case of an anode streamer in Xe an attempt at such a comparison was made, in particular, in [6]. However, the lack of reliable data on the value of the drift velocity and the diffusion coefficient of electrons in Xe for E/p (102 – 103) V/cm · mm Hg allowed only rough estimates to be made. In this paper a numerical calculation is made of the drift velocity, the diffusion coefficient of electrons in Xe, and the rate of excitation of Xe atoms in the resonance level in the range of values of E/p (101–103) V cm · mm Hg, and the volt-ampere characteristic of the breakdown is measured under conditions described in [6] (p0=300 mm Hg and E 104–105 V/cm). Using these results, the formulas for the velocity of anode [12] and cathode [13] streamers, and experimental data [6], the parameters of the streamers studied in [6] are determined.Translated from Zhurnal Prikladnoi Meknaniki i Tekhmcheskoi Fiziki, No. 3, pp. 6–11, May–June, 1976.The authors thank A. T. Rakhimov and A. N. Starostin for useful discussions, and A. V. Markov for help with the experiments.  相似文献   

11.
The results of balance aerodynamic tests on model straight wings with smooth and ribbed surfaces at an angle of attack =–4°–12°, Mach number M=0.15–0.63, and Reynolds number Re=2.4·106–3.5·106 are discussed. The nondimensional riblet spacings +, which determines the effect of the riblets on the turbulent friction drag, and the effect of riblets on the upper and/or lower surface of a straight wing on its drag, lift, and moment characteristics are estimated.Moscow. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 2, pp. 33–38, March–April, 1995.  相似文献   

12.
The possibility of reducing turbulent friction with the help of large-eddy-breakup devices (LEBUs) and riblets is studied experimentally. The tests were conducted in a low-turbulence wind tunnel on a flat plate for 2·106 Re 7·106. The local friction coefficient was measured using internal strain-gauge balances, and the total drag was estimated by the momentum-transfer method. It is shown that a combination of LEBUs and riblets makes it possible to reduce the total turbulent friction drag of a flat plate 1800 mm long by 16%. The effects of the length of a ribbed surface on the efficiency of friction reduction and of LEBUs and riblets on the structure of a turbulent boundary layer are analyzed.Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 3, pp. 39–46, May–June, 1995.  相似文献   

13.
The development of a turbulent boundary layer at the initial portion of a pipe with rough walls is considered in the framework of the boundary-layer theory. It is shown that the consideration of roughness can be carried out by introducing into the standard law of friction a function which takes into account this factor. An experimental investigation is carried out on a test portion of a pipe with natural roughness whose relative value equals 10–3. The range of Reynolds numbers is 5.1 · 104-3.4 · 105. The method of calculation proposed here leads to results which satisfactorily agree with the data of the experimental investigation.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 5, pp. 109–116, September–October, 1971.  相似文献   

14.
This paper gives the results of experimental determinations of the critical heat fluxes in the boiling of Liquid nitrogen in forced-flow conditions in the mass velocity range 2 · 103-40 · 103 kg/m2 · sec, pressure range 29 · 104–245 · 104 N/m2, and at underheatings corresponding to the onset of normal boiling crises.Notation q0 critical heat flux - r heat of vaporization - i enthalpy of flow corresponding to saturation point - i enthalpy of flow corresponding to liquid temperature - surface tension - density of liquid - density of saturated vapor - C f friction factor - Wg mass velocity - Fr* Froude number - g acceleration due to gravity  相似文献   

15.
Zusammenfassung Die Arbeit behandelt das Blasensieden an einer ebenen, horizontalen, 64·10–4m2 gro\en KupferoberflÄche von Stickstoff, Methan, Aethan und Gemischen aus Stickstoff/Methan und Methan/Aethan bei verschiedenen Drücken. Die Messwerte und empirischen Ausgleichskurven sind angegeben. Die Daten für die binÄren Gemische bestÄtigen die Gleichung von Happel und Stephan.
Heat transfer in nucleate boiling of liquified gases and their binary mixtures
The paper deals with pool boiling of nitrogen, methane, ethane and mixtures of nitrogen/methane and methane/ethane at different pressures. The boiling surface was a horizontal, plan copper disk of 64·10–4m2· The measured data points and their fit by an empirical correlation are given. For mixtures the correlation of Happel and Stephan provides a good agreement with the results.

Formelzeichen a1, a2, a3 Konstanten - b1,b2 Konstanten - K Konstante - n,n1,n2 Konstanten - p Druck Pa, M Pa - pred reduzierter Druck (p/pkritisch) - q* WÄrmestromdichte W/m2 - Rp Rauhtiefe m - x Molanteil der leichter flüchtigen Komponente in der Flüssigkeit - y Molanteil der leichter flüchtigen Komponente im Dampf - WÄrmeübergangskoeffi-W m–2 K–1zient - i idealer WÄrmeüber-W m–2K–1 - i gangskoeffizient - realer WÄrmeübergangs-W m–2K–1 - r koeffizient - T Temperaturdifferenz K  相似文献   

16.
The volume flow of poly (vinyl chloride) ( = 45,000,T g = 350 K) has been measured in an Instron Capillary Rheometer.The elastic modulus in longitudinal compression, the longitudinal volume viscosity and initial longitudinal volume viscosity, and retardation times were determined at temperatures both below (324 – 343 K) and above (403 – 453 K) the glass transition temperatureT g , and at compression rates between approximately 10–5 and 200 · 10–5 s–1.An increase in the longitudinal volume viscosity was observed for decreases in the volume deformation, increases in the compression rate and increases in temperature.T g decreased at 0.16 K/MPa. The volume flow activation energy was found to be equal to that for shear flow with a constant value of 91.37 kJ/mol.  相似文献   

17.
An analysis is carried out to study the effects of localized heating (cooling), suction (injection), buoyancy forces and magnetic field for the mixed convection flow on a heated vertical plate. The localized heating or cooling introduces a finite discontinuity in the mathematical formulation of the problem and increases its complexity. In order to overcome this difficulty, a non-uniform distribution of wall temperature is taken at finite sections of the plate. The nonlinear coupled parabolic partial differential equations governing the flow have been solved by using an implicit finite-difference scheme. The effect of the localized heating or cooling is found to be very significant on the heat transfer, but its effect on the skin friction is comparatively small. The buoyancy, magnetic and suction parameters increase the skin friction and heat transfer. The positive buoyancy force (beyond a certain value) causes an overshoot in the velocity profiles.A mass transfer constant - B magnetic field - Cfx skin friction coefficient in the x-direction - Cp specific heat at constant pressure, kJ.kg–1.K - Cv specific heat at constant volume, kJ.kg–1.K–1 - E electric field - g acceleration due to gravity, 9.81 m.s–2 - Gr Grashof number - h heat transfer coefficient, W.m2.K–1 - Ha Hartmann number - k thermal conductivity, W.m–1.K - L characteristic length, m - M magnetic parameter - Nux local Nusselt number - p pressure, Pa, N.m–2 - Pr Prandtl number - q heat flux, W.m–2 - Re Reynolds number - Rem magnetic Reynolds number - T temperature, K - To constant plate temperature, K - u,v velocity components, m.s–1 - V characteristic velocity, m.s–1 - x,y Cartesian coordinates - thermal diffusivity, m2.s–1 - coefficient of thermal expansion, K–1 - , transformed similarity variables - dynamic viscosity, kg.m–1.s–1 - 0 magnetic permeability - kinematic viscosity, m2.s–1 - density, kg.m–3 - buoyancy parameter - electrical conductivity - stream function, m2.s–1 - dimensionless constant - dimensionless temperature, K - w, conditions at the wall and at infinity  相似文献   

18.
Nuclear Magnetic Resonance Imaging (MRI) can noninvasively map the spatial distribution of Nuclear Magnetic Resonance (NMR)-sensitive nuclei. This can be utilized to investigate the transport of fluids (and solute molecules) in three-dimensional model systems. In this study, MRI was applied to the buoyancy-driven transport of aqueous solutions, across an unstable interface in a three-dimensional box model in the limit of a small Péclet number (Pe<0.4). It is demonstrated that MRI is capable of distinguishing between convective transport (fingering) and molecular diffusion and is able to quantify these processes. The results indicate that for homogeneous porous media, the total fluid volume displaced through the interface and the amplitude of the fastest growing finger are linearly correlated with time. These linear relations yielded mean and maximal displacement velocities which are related by a constant dimensionless value (2.4±0.1). The mean displacement velocity (U) allows us to calculate the media permeability which was consistent between experiments (1.4±0.1×10–7cm2).U is linearly correlated with the initial density gradient, as predicted by theory. An extrapolation of the density gradient to zero velocity enables an approximate determination of the critical density gradient for the onset of instability in our system (0.9±0.3×10–3 g/cm3), a value consistent with the value predicted by a calculation based upon the modified Rayleigh number. These results suggest that MRI can be used to study complex fluid patterns in three-dimensional box models, offering a greater flexibility for the simulation of natural conditions than conventional experimental modelling methods.  相似文献   

19.
The underlying theory is described for a method of diagnosing a hydrogen plasma by means of beams of helium atoms of different energy. The range of measured density is 1014 to 1016 cm–3 with a length of plasma section probed 10 cm. The highest accuracy ( ± 20%) is attained in the middle of the range. The accuracy in measuring electron temperature from 10 to 50 eV is no worse than 10–30%. Higher temperatures can be determined with an accuracy of the same order. Methods have been developed in recent years for active diagnosis of a high-temperature plasma using beams of fast neutral particles [1–5]. These methods, in spite of involving somewhat unwieldy apparatus, promise to permit the study of a plasma in the range of parameters difficult to investigate by traditional methods (probes, microwave equipment, and so on). In addition, they have relatively high timewise and spatial resolutions and are noncontact methods in practice.Translated from Zhurnal Prikladnoi Mekhaniki i Teknicheskoi Fiziki, Vol. 11, no. 2, pp. 7–11, March–April, 1970.  相似文献   

20.
Zusammenfassung Stoffaustauschuntersuchungen an einem flüssig-in-flüssig-Strahl der Zweiphasensysteme (a)/(b) mit (a)-Benzol, iso-Amylol, Tetrachlorkohlenstoff, (b)-Wasser und Wasser-Glycerin zeigen, daß mit (a) und (b) als Strahlphase beim Stoffübergang von n-Propanol in beiden Richtungen eine Beschleunigung des Transportvorganges um einen FaktorF 1,5 ... 4 im Vergleich mit der Penetrationstheorie auftritt. (F- Quotient aus experimentellem und theoretischem Stoff Übergangskoeffizienten). Die Änderungen vonF mit der Konzentrationstriebkraft c sind für beide Austauschrichtungen, zumindest für Zweiphasensysteme mit hoher Grenzflächenspannung, charakteristisch und weitgehend systemunabhängig. Als Folge der Theorie der hydrodynamischen Instabilität [11] wächstF mit c für die Stoff übergangsrichtung mit der Bedingung Instabilität unter starkem Einfluß des Durchsatzes der StrahlphaseQ an. Für die Bedingung hydrodynamischer Stabilität durchläuftF mit c Maxima bei geringem Einfluß vonQ. Eine 1 bis 10%ige Vergrößerung der Phasenkontaktfläche durch Wellenbildung schließt eine bis zu 30%ige Erhöhung der Stoffübergangsgeschwindigkeit ein. Zusätze von Cetylalkohol im Phasengleichgewicht (a)/(b) reduzieren die Austauscligeschwindigkeit.
Mass transfer investigations for a liquid-in-liquid jet
Mass transfer was investigated in a liquid-in-liquid jet for the two phase systems (a)/(b) with (a) benzene, iso-amylol, carbon tetrachloride, (b) water or water-glycerol. It is shown that with (a) and (b) as jet phase for the mass transfer of npropanol (asanindicator)intobothdirections an acceleration of the transfer occurs by a factorF 1, 5 ... 4 in comparison to the penetration theory. (F=quotient of the experimental and the theoretical mass transfer coefficient). The changes ofF with the concentration driving force c are characteristical and rather system independent for both exchange directions, at least for two phases systems with high interfacial tension. According to the theory of the hydrodynamical instabilityF increases with c for the direction of mass transfer with the condition instability, showing a high influence of the flow rateQ of the jet-phase. Under the conditions of hydrodynamical stabilityF traverses maxima in dependence of c and with a low influence ofQ. An increase of the contact area of the phases of 1 to 10% by wave formation leads to an increase of the mass transfer rate up to 30%. Addition of Cetylalcohol for (a)/(b) being at phase equilibrium reduces the rate of exchange.

Bezeichnungen A geometrische mittlere Ausdehnung der Phasenkontaktfläche cm2 - B definiert nach (5) - a, b Phasenbezeichnungen - c Konzentration mmol·cm3 - c definiert nach (25) - D Diffusionskoeffizient cm2·s–1 - d Strahldurchmesser cm - F definiert nach (16) - f, g Geschwindigkeitsfunktionen der axialen Richtung nach Ort und Zeit cm·s–1 - G definiert nach (7) - h Gesamtstrahlhöhe cm - i 1j Fluß durch die Phasenkontaktfläche mmol ·s–1 - K Stoffübergangskoeffizient cm·s–1 - k, l, n, p Konstanten - m Verteilungskoeffizient - Q Flüssigkeitsdurchsatz cm3· s–1 - q, r, s Integrationsvariable - t Strahlkontaktzeit s - u, v Geschwindigkeiten in axialer und radialer Strahlrichtung cm· s–1 - V Phasenvolumina cm3 - W definiert nach (6) - x, y Axial- und Radialkoordinate - , , Konstanten - definiert nach (18) - integrale Versuchszeit s - kinematische Viskosität cm2· s–1 - Strahlabschnitt in axialer Richtung cm - Dichte g · cm–3 - Grenzflächenspannung dyn · cm–1 - g Dichtedifferenz g · cm–3 Indices 0, beziehen sich auf=0 (Start-) und=(Phasengleichge wichtsbedingung) - * an der pasengrenzfläche - 0 an der Strahlkapillare (x=0) - n normiert Kurzbezeichnung der verwendeten Zweiphasensysteme I (a) iso-Amylol/(b) Wasser - II (a) Benzol/(b) Wasser - III (a) Benzol/(b) Wasser-Glycerin - IV (a) Tetrachlorkohlenstoff/(b) Wasser  相似文献   

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