共查询到20条相似文献,搜索用时 31 毫秒
1.
Vorontsova N. V. Rozenberg V. I. Vorontsov E. V. Antonov D. Yu. Starikova Z. A. Bubnov Yu. N. 《Russian Chemical Bulletin》2002,51(8):1483-1490
The nucleophilic addition of butyllithium, phenyllithium, methyllithium, and triallylborane to [2.2]paracyclophane-4,7-quinone (1) proceeded regio- and stereospecifically to give the corresponding cis-4,7-disubstituted 4,7-dihydroxy-4,7-dihydro[2.2]paracyclophanes 2—5 with the endo orientation of the hydroxy groups. The structures of quinone 1 and diols 2, 4, and 5 were established by X-ray diffraction analysis. 相似文献
2.
3.
4.
5.
6.
7.
Oxidation of 1,3-diphenyl-4,7-phenanthroline with potassium permanganate in alkaline medium results in transformation of the 4,7-phenanthroline ring system into 1,8-diaazafluorenone. Oxidation of 12-aryl-and 12-aryl-9,9-dimethyl-8,9,10,12-tetrahydro-7H-benzo[b][4,7]phenanthrolin-11-ones (condensation products of 6-arylmethylene-aminoquinolines with 1,3-cyclohexanedione and dimedone) with sodium nitrite in acetic acid leads to 12-aryl-9,10-dihydro-8H-benzo[b][4,7]phenanthrolin-11-ones. 13-Aryl-7,13-dihydro-12H-indeno-[2,1-b][4,7]phenanthrolin-12-ones obtained by reaction of 6-arylmethyleneaminoquinolines with 1,3-indandione are oxidized to 13-aryl-12H-indeno[2,1-b][4,7]phenanthrolin-12-ones on heating in nitrobenzene.Translated from Zhurnal Organicheskoi Khimii, Vol. 40, No. 9, 2004, pp. 1369–1375.Original Russian Text Copyright © 2004 by Gusak, Kozlov, Tereshko. 相似文献
8.
1-(2-Quinolyl)-3-aryl-4,7-phenanthrolines were synthesized by reacting arylidene-6-quinolylamines with 2-acetylqidnoline in n-butanol in the presence of hydrochloric acid. It was found that the formation of the 4,7-phenanthroline ring is preceded by the stage of formation of an intermediate aminoketone, 1-(2-quinolyl)-3-phenyl-3-(6-quinolylamino)propan-1-one. The IR, UV, PMR, and mass spectra of the synthesized compounds are discussed.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 796–800, June, 1990. 相似文献
9.
10.
11.
N. S. Kozlov K. N. Gusak V. A. Serzhanina N. A. Krot 《Chemistry of Heterocyclic Compounds》1985,21(10):1151-1154
A number of new 1,3-diaryl-4,7-phenanthrolines were synthesized by heterocyclization of arylidene-6-quinolylamines with acetophenones in the presence of an acidic catalyst. Intermediate amino ketones and side products, viz., N-(R1-benzyl)-6-quinolylamines and ,-unsaturated ketones, were isolated. The IR, UV, PMR, and mass spectra of the synthesized compounds are discussed.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1398–1401, October, 1985. 相似文献
12.
13.
14.
6-Aminoquinaldine condensation with aromatic aldehydes and cyclic -diketones (1,3-cyclohexanedione or dimedone) in butanol afforded new 12-aryl-3-methyl-8,9,10,12-tetrahydro-7H-benzo[b][4,7]phenanthrolin-11-ones and their 9,9-dimethyl derivatives.Translated from Zhurnal Organicheskoi Khimii, Vol. 40, No. 11, 2004, pp. 1709–1714.Original Russian Text Copyright © 2004 by Gusak, Tereshko, Kozlov. 相似文献
15.
L. A. Karandashova M. A. KirpichËnok D. S. Yufit Yu. T. Struchkov I. I. Grandberg 《Chemistry of Heterocyclic Compounds》1990,26(12):1338-1345
The absorption and luminescence spectra of a series of 4,7-diaminocoumarins have been investigated in ethanol and acetonitrile solution. The pka
I and pka
II values for several of the compounds have been measured. It has been found that the site of primary protonation is the nitrogen atom in the 7-position, and that the second protonation reaction occurs at the lactone oxygen atom. The effects of steric and electronic factors on the spectral-luminescence and acid-base characteristics of these compounds are discussed.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1610–1618, December, 1990. 相似文献
16.
《Tetrahedron letters》1986,27(36):4295-4298
The isobenzofuran derivatives precursors 4a-c are readily prepared from 1 ; their Diels-Alder adducts with cis-dienophiles present a stereochemistry endoexo from 4b,c and, interestingly, only exo (towards the furan moiety) from 4a. 相似文献
17.
18.
N. S. Kozlov K. N. Gusak V. A. Serzhanina L. F. Gladchenko N. A. Krot 《Chemistry of Heterocyclic Compounds》1987,23(12):1329-1332
The effect of the nature of the substituents and the solvent on the absorption and fluorescence spectra and the fluorescence quantum yields of 1,3-diaryl-4,7-phenanthrolines was studied. Electron-donor groups in the para position of the phenyl ring cause a bathochromic shift of the absorption and fluorescence spectra and an increase in the fluorescence quantum yields. A change in the polarity of the solvent leads to a significant shift of the fluorescence spectra of hydroxy and dialkylamino derivatives of 4,7-phenanthroline.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1651–1654, December, 1987. 相似文献
19.
A number of 1,4-addition reactions of 4,7-benzimidazoledione with hydrogen halides, thiols and amines are described. 相似文献
20.
Ohne Zusammenfassung
Determination of the iodine number of fats by means of 4,7-dichloroquinoline hydrobromide perbromide相似文献