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1.
The millimeter wave spectrum of the isotopically substituted CO dimer, (13C16O)2, has been studied for the first time, confirming and extending a recent infrared study. Eighty-seven transitions in the 77-180 GHz region have been assigned and analyzed in terms of a model-independent term value scheme involving 57 rotational levels with J=0-8. The levels can be classified into 7 “stacks” which have symmetry classifications of either A/B+ or A+/B and K-values of either 0 or 1. For the normal isotope, symmetry and nuclear spin statistics cause alternate rotational levels to be missing, but for (13C16O)2 all levels are present with an intensity alternation of 1:3 between A and B symmetries. The four A/B+ stacks have not previously been observed, and the lowest of them establishes the tunneling splitting of (13C16O)2 to be 3.769 cm−1, slightly larger than the (12C16O)2 value of 3.731 cm−1. A large amount of precise experimental data is now available for the CO dimer, which should lead to greater theoretical insight into its structure and tunneling dynamics.  相似文献   

2.
Far-infrared and millimeter wave spectra of copper ion conducting crystal RbCu4Cl3+xI2−x, which has the same structure as the room temperature silver ion conductor RbAg4I5, were investigated. Broad absorption peaks observed around 40, 80, and 110–200 cm−1 at room temperature show doublet structures at low temperature; this may be attributed to the difference of local structure by chlorine and iodine ion. The 110–200 cm−1 bands seem to be symmetric breathing modes of CuX4 (X = Cl or I) tetrahedron and the frequency shift coincides with the square root of the mass ratio of conduction ions. The 80 cm−1 band seems to be Rb-X vibration in RbX6 octahedron. The 40 cm−1 band seems to be the attempt mode which is an outward motion of the mobile ion in halogen cage. The increase of the absorption intensity at the low energy side with temperature corresponds to an increase of the DC conductivity. Plasmon fitting in energy loss function spectra was attempted.  相似文献   

3.
By use of a quasi-optical, broad-banded spectrometer in the frequency range of 40–90 GHz (λ = 7.5 ? 3.3 mm), the temperature dependence of absorption of the ionic conductor CuTeBr has been investigated for the first time. An abrupt and reversible jump in absorption independent of the incident frequency is observed at (69 ± 2)°C. This is attributed to a first order phase transition from an orthorhombic superstructure to a tetragonal structure. The results are discussed in connection with the high ionic conductivity of this material.  相似文献   

4.
The characteristics and applicability of the absorption spectroscopy system using the coherent transition radiation light source have been investigated. The configurations of the system are relatively simple. The operational conditions of an electron linear accelerator have been evaluated. The stability of the light intensity has been within ±2–3% in a wavenumber range of 4–13 cm−1. The light intensity has been found to be more than six orders of magnitude higher than that for the lowest limit for detection.  相似文献   

5.
New results of the study of ozone concentration variations in the upper stratosphere over Moscow in the layer at a height of 40 km, which is most sensitive to anthropogenic impacts, are presented. Changes in the ozone concentration and its relation to other atmospheric parameters in cold periods of 2008–2009 and 2009–2010 are analyzed. It was shown that there exist regions with decreased ozone content in the polar vortex and outside of it in air with higher temperature in the upper stratosphere. These phenomena cause deformations of vertical ozone distribution profiles and an appreciable shift of the maximum of the relative content of ozone to lower stratosphere layers.  相似文献   

6.
Resonance splitting effect in multibarrier tunneling   总被引:1,自引:0,他引:1  
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7.
A large exchange splitting of the conduction band in ultrathin films of the ferromagnetic semiconductor EuO was determined quantitatively, by using EuO as a tunnel barrier and fitting the current-voltage characteristics and temperature dependence to tunneling theory. This exchange splitting leads to different tunnel barrier heights for spin-up and spin-down electrons and is large enough to produce a near-fully spin-polarized current. Moreover, the magnetic properties of these ultrathin films (<6 nm) show a reduction in Curie temperature with decreasing thickness, in agreement with theoretical calculation [R. Schiller, Phys. Rev. Lett. 86, 3847 (2001)10.1103/Phys. Rev. Lett.86.3847].  相似文献   

8.
The pressure broadening of the different K components of the J=3–4 rotational line of CH3CN have been measured. A novel experimental apparatus employing a very small cell with an acoustic detector is described and a comparison with theoretically estimated linewidths is discussed.  相似文献   

9.
通过脑电长程相关性的分析,定量研究了35 GHz毫米波辐照大鼠时产生的应激反应.通过退趋势分析法,得到反映高频成分的标度指数.显示在辐照前该成分具有布朗噪声的特性,辐照时具有长程相关性;而反映低频成分的标度指数显示在辐照前该成分具有长程相关性,辐照时成为布朗噪声.引进应激指标参量低频成份标度指标数/高频成份标度指标数,...  相似文献   

10.
通过脑电长程相关性的分析,定量研究了35 GHz毫米波辐照大鼠时产生的应激反应。通过退趋势分析法,得到反映高频成分的标度指数,显示在辐照前该成分具有布朗噪声的特性,辐照时具有长程相关性;而反映低频成分的标度指数显示在辐照前该成分具有长程相关性,辐照时成为布朗噪声。引进应激指标参量低频成份标度指标数/高频成份标度指标数,用其值的平均变化率来衡量大鼠在35 GHz毫米波作用下应激反应的剧烈程度。通过计算得到辐照时应激指标参量增加了49.9%±13.6%,说明35 GHz毫米波辐照使得大鼠脑电的高频部分变得更加有序,而低频成分变得更加无序,表明大鼠受35 GHz毫米波辐照而产生了剧烈应激反应。  相似文献   

11.
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13.
We calculate the surface density of state of iron based LaFeAsO1-xFx superconductor. The gap function is obtained microscopically by solving the Eliashberg equation in a 5-band Hubbard model with the random phase approximation (RPA). Although the gap function has a sign change between Fermi surfaces, we cannot find zero bias conductance peak for [1 0 0] and [1 1 0]-oriented interface.  相似文献   

14.
In this paper simple closed form expressions of surface wave fields for microstrip dipoles on grounded substrates are presented. The surface power, radiated power and radiation efficiency are calculated. It is shown that the radiation efficiency decreases with the increase of substrate electrical thickness. Hence new type antennas are needed to radiate millimeter wave because of the effect of the surface waves in substrate.  相似文献   

15.
Inelastic Electron Tunneling Spectroscopy of CO adsorbed on alumina supported Rh allows the observation of the low frequency metal-carbon vibrational modes (~1000 cm?1) that cannot be seen by Infrared Spectroscopy. We present a preliminary attempt to assign the modes observed, using istopic shifts C16OC18O.  相似文献   

16.
17.
The interaction between electron beam and RF fields of H811 -mode in an eighth harmonic cusptron at f0=35GHz is studied numerically. The finite thickness and eccentricity of a rotating annular electron beam and the cusp magnetic field in the imbalance case (Bc–B0) are considered in the mumerical calculation. The results show that these pratical factors have a great influence upon the electron efficieency.  相似文献   

18.
This paper describes an algorithm which can determine the global optima of the power combiner of solid-state millimeter wave resonator. The global optimization mehtod can determine a neighborhood of the global optima of an objective function and an estimation of the global optima. In this paper the objective function as follow: In the quasi-optical resonator, the objective function are the fundamental mode power, the fractional power of fundamental mode and the combining dfficiecy were done the objective functiona respectively, to calculate the global optima respectively. In the power combiner of solid-state millimeter wave source in rectangular waveguide cavity. the performance parameter are presentes by combining efficiency, tuning range, frequency drift, and FM noise were done the objective functions respectively. And to calculate the global optima respectively.  相似文献   

19.
Resonance tunneling through localized eigenstates is proven to allow for the localization spectroscopy. Evaluated characteristics of the resonance oscillations are in agreement with experiments.  相似文献   

20.
In this paper, the CAD of millimeter wave VCO is investigated based on a frequency-domain harmonic balance technique, where the external-circuit mutual impedances looking outside from two active devices are calculated in terms of a rigorous definition and a mixed technique of modes expansion, Galerkin method and collocation method. The CAD results are in agreement with the experimental results, which shows the raliability of the presented model and optimisation.  相似文献   

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