共查询到20条相似文献,搜索用时 15 毫秒
1.
Anna Yu. Likhacheva Sergey V. Goryainov Aleksandr S. Krylov Taras A. Bul'bak Pinnelli S. R. Prasad 《Journal of Raman spectroscopy : JRS》2012,43(4):559-563
The high‐pressure behaviour of cordierite, a widespread ring aluminosilicate with channels incorporating fluid compounds (H2O, CO2), is characterized by the absence of phase transitions up to 2.5 GPa. However, the distortion of the ring tetrahedra observed previously at 2.3 GPa is supposed to introduce a phase transition at higher pressure, which has not been checked so far. This work presents a high‐pressure Raman spectroscopic study of natural cordierite compressed in water medium up to 4.7 GPa in a diamond anvil cell. At P > 4 GPa, a disordering of both the framework and intrachannel H2O subsystem is apparent from significant broadening of Raman peaks and the evolution of short‐range order parameters. This is followed by abrupt shifts of the framework and O–H stretching modes at about 4.5 GPa, indicating a first‐order phase transition. Its reversibility is seen from the recovery of the initial spectrum at P < 3 GPa. The shift amplitudes of different framework modes indicate the predominance of distortion over contraction of the framework polyhedra upon this transition. The disordering of the H2O subsystem in the high‐pressure phase is likely a consequence of distortion of the channel‐forming framework elements, which is supposed to be a driving force of this transition. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
2.
The effect of pressure on the Raman modes in TeO2 (paratellurite) has been investigated to 30GPa, using the diamond cell and argon as pressure medium. The pressure dependence
of the Raman modes indicates four pressure-induced phase transitions near 1 GPa, 4.5 GPa, 11 GPa and 22 GPa. Of these the
first is the well studied second-order transition fromD
4
4
symmetry toD
2
4
symmetry, driven by a soft acoustic shear mode instability. The remarkable similarity in the Raman spectra of phases I to
IV suggest that only subtle changes in the structure are involved in these phase transitions. The totally different Raman
spectral features of phase V indicate major structural changes at the 22GPa transition. It is suggested that this high pressure-phase
is similar to PbCl2-type, from high pressure crystal chemical considerations. The need for a high pressure X-ray diffraction study on TeO2 is emphasized, to unravel the structure of the various high pressure phases in the system. 相似文献
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Abstract Copper oxide has been studied at high pressure up to 50 GPa. A monoclinic structure was compatible with the measurements at all pressures, and no phase change was observed. A bulk modulus, B0, = 98 GPa, and its pressure derivative B′0 = 5.6 was obtained. 相似文献
5.
Sergei V. Goryainov Alexander S. Krylov Yuanming Pan Iliya A. Madyukov Mikhail B. Smirnov Alexander N. Vtyurin 《Journal of Raman spectroscopy : JRS》2012,43(3):439-447
Layer silicates F‐ and OH‐apophyllites, KCa4Si8O20(F, OH)·8H2O, have been investigated by Raman spectroscopy at hydrostatic and nonhydrostatic pressures up to ~8 GPa in diamond anvil cells using a 4 : 1 methanol–ethanol mix as pressure‐transmitting medium. Our experiments show that at hydrostatic compression, apophyllites retain their crystalline states (i.e. no amorphization) up to 5 GPa. The wavenumbers of most bands exhibit linear dependences on pressure, except for a few ones, e.g. at 162 and 3565 cm–1 in OH‐form (160.5 and 3558 cm–1 in F‐form) that show nonlinear dependences. Nonhydrostatic compression with additional uniaxial loading induces amorphization of apophyllites. The majority of the bands in OH‐apophyllite decreases markedly in intensity and shows considerable broadening under nonhydrostatic compression up to 3–6 GPa. In addition, the wavenumbers of several bands at nonhydrostatic compression exhibit considerable nonlinear dependences on pressure with strong hysteresis. These bands are mainly associated with vibrations of the interlayer ions and molecules and also of stretching and bending silicate sheets, hence being highly sensitive to the interlayer distance. Finally, we have calculated the lattice dynamics of F‐apophyllite and interpreted the majority of bands, and these data are used to explain the complex baric behavior of the bands. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
6.
Vibrational properties of Cs4W11O35 and Rb4W11O35 systems: high pressure and polarized Raman spectra
K. Pereira da Silva W. Paraguassu M. Maczka A. G. Souza Filho P. T. C. Freire J. Mendes Filho J. Hanuza 《Journal of Raman spectroscopy : JRS》2011,42(3):474-481
Cs4 W11O35 (CW) and Rb4 W11O35 (RW) belong to the class of hexagonal bronzes whose structure originates from the KxWO3 superconductor hexatungstate. Charge‐imbalanced tungsten bronzes are dielectric materials with rich polymorphism, ferroelectric properties and second‐harmonic generation. In this work, we report the polarized Raman spectra results for both CW and RW, as well as results of high‐pressure Raman scattering experiments (0.0–11.0 GPa) for the Cs4 W11O35 system, in which we have observed two structural phase transitions at ∼4 and 7.5 GPa. We discuss these transformations and polarized Raman spectra on the basis of lattice dynamics calculation in the related system KNbW2O9. Polarized Raman spectra provide strong indication that the highest wavenumber modes observed in these systems originate from tungsten or oxygen vacancies. The observation of a soft‐like mode indicates that the observed phase transitions exhibit a displacive‐type behavior, thus further indicating that these transformations are likely related to reorientations of the octahedral units. The soft mode nature is discussed as well. PACS: 77.80.Bh; 78.30.Hv; 78.30.‐j. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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Abstract Well—resolved Raman spectra of crystalline sulfur have been recorded in a diamond anvil cell (DAC) in the pressure range from atmospheric pressure to 50 GPa at room temperature, using an 0.6 m triple spectrograph and a CCD multichannel detector. The spectra indicate two phase transitions in the pressure region between 10 and 15 GPa. 相似文献
9.
The high-pressure behavior of solid hydrogen has been investigated by in situ Raman spectroscopy upon compression to 300 GPa at ambient temperature. The hydrogen vibron frequency begins to decrease after it initially increases with pressure up to 38 GPa. This softening behavior suggests the weakening of the intramolecular bond and the increased intermolecular interactions. Above 237 GPa, the vibron frequency softens very rapidly with pressure at a much higher rate than that of phase III, corresponding to transformation from phase III into phase IV. The phase transition sequence has been confirmed from phase I to phase III and then to phase IV at 208 and 237 GPa, respectively. Previous theoretical calculations lead to the proposal of an energetically favorable monoclinic C2/c structure for phase III and orthorhombic Pbcn structure for phase IV. Up to 304 GPa, solid hydrogen is not yet an alkali metal since the sample is still transparent. 相似文献
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Abstract An experimental technique is described which enables one to measure the pressure-volume (P-V) relationship of solids and powder compacts and the linear compressibility of anisotropic single crystals by means of the resistive strain gauges at hydrostatic pressure up to 9 GPa. The potential of this technique is demostrated for solids possessing pressure induced phase transitions (PbTe, SmSe) and anisotropic crystals (Sb). For the first time P-V relationship is measured for highly compressible powder compact at increase and decrease of pressure. 相似文献
12.
Abstract The melting curve of NaCl0.5Br0.5 has been measured under pressure up to 4.5 GPa. The melting temperatures of Ag and NaCl have been used to determine the pressure in the sample at its melting temperature. 相似文献
13.
Abstract Phase transitions of orthorhombic sulfur were investigated above 10 GPa by Raman spectroscopy using red light excitation. Transitions into several phases that have been reported in previous studies using green light excitation, are confirmed. The phase behaviour is observed to depend strongly on the preparation method. In the presence of a pressure transmitting medium (methanol/ethanol, 4:1), a sequence of phases α-S8 → [intermediate phase (“ip”) + S6] → [S6 + high pressure-low temperature phase (“hplt”)] is described and characterized. Without the use of a pressure transmitting medium, the phase sequence α-S8 → [“ip” + “hplt”] + “hplt” is observed. In addition, contributions of amorphous sulfur are detected around 10 GPa, i.e. at pressures below the transformation of α-S8 into the above-mentioned phases. Characteristic Raman spectra of the different phases are extracted and documented over a wide pressure range. 相似文献
14.
利用碳化硅压腔在室温(25℃)下,研究了异辛烷(2,2,4-三甲基戊烷)在常压至1.2GPa条件下的拉曼光谱特征。研究结果表明,异辛烷CH2和CH3的碳氢伸缩振动的拉曼位移随着压力的增大均呈线性向高频方向移动,其拉曼位移与压力的函数关系为:ν2 873=0.002 8P+2 873.3;ν2 905=0.004 8P+2 905.4;ν2 935=0.002 7P+2 935.0;ν2 960=0.012P+2 960.9。在1.0GPa附近,异辛烷的拉曼位移出现突变,与显微镜下观察发生的异辛烷液-固相变一致。结合异辛烷在常压下的熔点数据,获得了异辛烷的液-固两相相图,并根据克拉贝龙方程获得了液-固相转变过程中的摩尔体积变化量ΔVm=4.46×10-6 m3.mol-1和熵变ΔS=-30.32J.K-1.mol-1。 相似文献
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PbTe has been investigated using synchrotron X-ray diffraction (XRD) in a diamond anvil cell under quasi-hydrostatic pressures up to 50 GPa. Upon compression to 6.6 GPa, the initial NaCl phase transforms to an intermediate phase, which is confirmed to be an orthorhombic structure with a space group Pnma. At 18.4 GPa, the intermediate Pnma phase undergoes a phase transition to the CsCl structure. The systemic analysis of the crystal structures between the NaCl and intermediate phases indicates that the structure of the Pnma phase could be derived from the distortion of the NaCl structure. The bulk modulus of the CsCl phase is B0=52(2) GPa with V0=60.8(4) Å3 and B′0=4.0 (fixed), slightly larger than the NaCl phase (B0=44(1) GPa) and the intermediate phase (B0=49(3) GPa). 相似文献
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Vibrational properties and structural changes under pressure of a highly luminescent molecular organic crystal have been investigated by ultraviolet resonant Raman spectroscopy with a 244‐nm excitation. Resonant Raman modes of α‐perylene crystal up to 1GPa were followed under hydrostatic pressure in an anvil cell with a sapphire window transparent to ultraviolet light. Nonlinear evolution of intra‐molecular modes is induced by pressure. Abrupt shifts of Raman wavenumbers suggest structural and planar modifications of the molecules in the crystal. We interpret these shifts as a first‐order phase transition to a lower volume of unit cell. The luminescence of perylene crystal is gradually modified as a consequence of these structural changes. The present experimental setup allows investigating with Raman spectroscopy very luminescent molecules involved in chemical reactions and molecular organic crystals under relatively high pressure (up to 1GPa). Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
19.
Ph. Pruzan J. C. Chervin M. M. Thiéry J. P. Itié J. M. Besson J. P. Forgerit 《高压研究》2013,33(1-6):215-217
Abstract After a pressure cycle to 30 GPa, benzene transforms to a white solid which can be recovered at ambient. Results obtained from infrared spectroscopy and other physico-chemical methods show that the recovered solid is a highly cross-linked polymer. The molecular structure of benzene is very likely completely altered by the transformation. 相似文献
20.
Abstract Neutron scattering experiments on the two-dimensional Heisenberg ferromagnets Cs2 CuF4 and K2CuF4 have been performed around 2 ~ 3 GPa over 1·4–15 K. At ambient pressure both the intralayer and the interlayer exchange interactions in these two compounds are ferromagnetic. At about 2 GPa, the interlayer exchange coupling in Cs2 CuF4 is found to change from ferromagnetic to antiferromagnetic, while the ferromagnetic intralayer exchange interaction is maintained. Contrary to Cs2CuF4, the ferromagnetism in K2Cuf4 is not destroyed by pressure up to 9 GPa, that was confirmed in the early study of the magnetic susceptibility measurements. 相似文献