Effects of ultrasound-assisted H2O2 on the solubilization and antioxidant activity of yeast β-glucan

Yeast β-glucan (YG) possess an extensive range of biological activities, such as the inhibition of oxidation, but the poor water solubility of macromolecular YG limits its application. In this study, through the combined degradation of ultrasonic waves and H₂O₂, and the optimization of the main process parameters for solubilizing YG by response surface methodology (RSM), a new product of YG_UH was generated. The molecular weight, structural characteristics and degradation kinetics before and after solubilization were evaluated. The results showed that the optimal solubilization conditions were reaction time: 4 h, ultrasonic power: 3 W/mL, H₂O₂ concentration: 24 %. Under these conditions, ultrasound-assisted H₂O₂ increased the solubility (from 13.60 % to 70.00 %) and reduced molecular weight (from 6.73 × 10⁶ Da to 1.22 × 10⁶ Da). Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), Congo red (CR), scanning electron microscopy (SEM) revealed that ultrasound-assisted H₂O₂ increased the conformation's flexibility greatly, without changing the main structure of YG. More importantly, solubilization of YG improved free radical scavenging activity with YG_UH exhibiting the highest levels of DPPH and ABTS⁺ free radical scavenging activity. These results revealed that ultrasound-assisted H₂O₂ degradation could be a suitable way to increase the solubility of YG for producing value-added YG.     

Synergistic effects of oat β-glucan combined with ultrasound treatment on gel properties of silver carp surimi

The effect of oat β-glucan (OG) combined with ultrasound treatment on the gelation properties of silver carp surimi with different salt contents was investigated. The results demonstrated that the gelation properties of surimi gels at high salt concentration were superior than those at low salt level. The addition of OG or ultrasound treatment could significantly enhance the texture properties, gel strength and water holding capacity (WHC) of gel samples, regardless of salt contents. The ultrasound treatment improved the whiteness of surimi gels, whereas the OG addition slightly declined the whiteness. Both OG addition and ultrasound treatment markedly reduced the total sulfhydryl content (total SH) and strengthened the hydrophobic interactions, forming the more uniform and denser gel network structures, hence more water was captured in network structures and became immobilized. Moreover, the combined treatment of OG and ultrasound showed synergic action on the gelation properties of surimi, and the gel strength and WHC of low-salt surimi gel treated by the combination of OG and ultrasound were even superior than that of high-salt gel without OG by traditional heating.     

Ultrasound-assisted enzymatic hydrolysis of yeast β-glucan catalyzed by β-glucanase: Chemical and microstructural analysis

The purpose of this study was to investigate the effect of ultrasound-assisted enzymolysis on modified solubilization of yeast β-glucan and its related mechanism. The depolymerization effects of this system on the physicochemical properties and structural features of the degraded fragments were studied systematically. The structure and physicochemical properties of the samples showed that the solubility of yeast β-glucan achieved 75.35 % after modification; and ultrasonic enzymatic enhanced the degradation efficiency. The yeast β-glucan obtained after solubilization and modification owned better antioxidant activities. The yeast β-glucan particles become obviously smaller, sparsely dispersed in the aqueous solution and the stability was improved. In addition, the hydrogen bonds in yeast β-glucan native triple helix structure were partially broken. Moreover, the disruption of yeast β-glucan's original structure made it decreased thermostability and easier to dissolve in water. The atomic force microscope (AFM) imaging directly verified the branched-chain morphology of yeast β-glucan and the small-strand degradation fragments. Therefore, this research can provide a feasible and effective approach for improving solubility of water-insoluble yeast β-glucan to enlarge its food and biomedical applications.     

Effects of pressure on structural,electronic, and mechanical properties of α,β,and γ uranium

The first-principles methods have been employed to calculate the structural, electronic, and mechanical properties of the α, β, and γ phases of uranium under pressure up to 100 GPa. The electronic structure has been viewed in forms of density of states and band structure. The mechanical stability of metal U in the α, β, and γ phases have been examined.The independent elastic constants, polycrystalline elastic moduli, as well as Poisson's ratio have been obtained. Upon compression, the elastic constants, elastic moduli, elastic wave velocities, and Debye temperature of α phase are enhanced pronouncedly. The value of B/G illustrates that α and γ phases are brittle in ground state.     

Features of Calculation of the Equation of State,Composition, and Conductivity for a Plasma of Dense,Supercritical Metal Vapors—a Plasma Fluid

Journal of Experimental and Theoretical Physics - The caloric and thermal equations of state, composition, and conductivity have been calculated for a supercritical aluminum plasma fluid. A...     

Nanoscale PhysiCs ＆ Devlces Laboratory , nstitute of Physics, Chinese Academy of Sciences

概况 中国科学院物理研究所纳米物理与器件实验室的前身是中国科学院北京真空物理开放实验室,成立于1985年。二十多年来,实验室在科研工作中取得了一系列具有国际先进水平和国际领先水平的成果。目前实验室有四个研究组构成,实验室的运作特色是加强各研究组之间的交叉合作,发挥集体智慧,     

Nanoscale Physics ＆ Devices Laboratory,Institute of Physics,Chinese Academy of Sciences

Brief History Formerly known as Beijing Vacuum Physics Laboratory of Chinese Academy of Sciences since 1985, Nanoscale Physics ＆ Devices Laboratory （NPDL） was established in 2001. The mission of NPDL is to construct and study nanomaterials that address the challenges presented bythe national research strategy. For more than 20 years, NPDL has been dedicated to the study of fundamental physics related to nanomaterials and their applications in information and energy devices.     

Department of Physics, Hong Kong University of Science and Technology, Clear Water Bay, Hong Kong

在近代量子力学的图像中，环绕着原子与分子的电子云具有各种不同的形态结构，一般在某一测定时间内，其形状为球状或哑铃状．这类形状通常称为电子轨道，它们可在飞秒量级的时间内明显地观测到．这些电子轨道也可在简并态(具有相同能量的量子态)间相互跃迁；如在相同轴上由垂直哑铃转变为水平哑铃等．     

First-principles calculation of the structural,electronic, elastic,and optical properties of sulfur-doping ε-GaSe crystal

The structural,electronic,mechanical properties,and frequency-dependent refractive indexes of GaSe_(1-x)S_x(x=0,0.25,and 1) are studied by using the first-principles pseudopotential method within density functional theory.The calculated results demonstrate the relationships between intralayer structure and elastic modulus in GaSe_(1-x)S_x(x=0,0.25,and 1).Doping of ε-GaSe with S strengthens the Ga-X bonds and increases its elastic moduli of C_(11) and C_(66).Born effective charge analysis provides an explanation for the modification of cleavage properties about the doping of e-GaSe with S.The calculated results of band gaps suggest that the distance between intralayer atom and substitution of S_(Se),rather than interlayer force,is a key factor influencing the electronic exciton energy of the layer semiconductor.The calculated refractive indexes indicate that the doping of ε-GaSe with S reduces its refractive index and increases its birefringence.     

Assignment of Photoelectron Spectra of MC2 （M= V, Cr, Fe, and Co）

Hybrid density functional theory （DFT） calculations are performed to study MC2 （M= V, Cr, Fe and Co） clusters in the neutral and anionic charge states. We find that the equilibrium geometries of MC2 and their anions are all cyclic structures with C2v symmetry, which agrees well with the previous theoretical studies. The Mulliken charge and spin populations of MC2 clusters and their anions are also calculated, and it is found that the electron charge transformations from anions to neutral molecules mainly take place on the M atoms. Time-dependent DFT is used to calculate the excited states, and a theoretical assignment for the features in the experimental photoelectron spectrum is given, which are in good agreement with the available experimental data.     

Synthesis,Characterization of 9, 9＇-Bianthracene and Fabrication of 9, 9＇-Bianthracene Field-Effect Transistors

We synthesize and purify 9, 9＇-bianthracene with the purity up to 96.4%. The electronic and crystallographic structures of 9, 9＇-bianthracene are studied. The results of a joint experimental investigation based on a combination of x-ray diffraction （XRD） spectra, hydrogen nuclear magnetic （HNMR） spectra, infrared absorption （FT-IR） spectra, and mass spectra （MS） of 9, 9＇-bianthracene are obtained. The uniform compact film is observed by an atomic-force microscope （AFM）. Organic field effect transistors （OFETs） with an active layer based on the synthesized 9, 9＇-bianthracene are fabricated for the first time. Its field-effect mobility is as large as 0.067 cm^2 /（V·s） and the on/off ratio is above 5 ×10^4. The result demonstrates that the oligomerization of a small semiconductor molecule is an effective method to develop high-mobility organic semiconductors.     

Study of Hard-sealed,Tunable,Photoelastic Birefringent Dual-frequency Lasers

ＳｔｕｄｙｏｆＨａｒｄｓｅａｌｅｄ，Ｔｕｎａｂｌｅ，ＰｈｏｔｏｅｌａｓｔｉｃＢｉｒｅｆｒｉｎｇｅｎｔＤｕａｌｆｒｅｑｕｅｎｃｙＬａｓｅｒｓＨＡＮＹａｎｍｅｉＺＨＡＮＧＳｈｕｌｉａｎＬＩＹａｎＬＩＫｅｌａｎ（ＴｈｅＳｔａｔｅＫｅｙＬａｂ．ｆｏｒＰ...     

Reconstruction of all-electron orbitals from one-electron pseudowave functions and calculations of the intensities of Si X-ray emission spectra of Si, β-SiC,stishovite, and β-cristobalite crystals

The intensities of Si X-ray emission spectra of Si, β-SiC, stishovite, and β-cristobalite crystals are calculated. The wave functions of the initial and final states are obtained in the framework of the density-functional theory with the use of the norm-conserving and ultrasoft pseudopotentials. The all-electron crystal orbitals are reconstructed from the one-electron pseudowave functions. The probabilities of X-ray emission transitions are calculated by reconstructing the all-electron orbitals in two different gauges, namely, the length and velocity gauges. The calculated intensities are compared with the experimental spectra and the partial densities of states.     

Application of the multireference equation of motion coupled cluster method,including spin–orbit coupling,to the atomic spectra of Cr,Mn, Fe and Co

The recently introduced multireference equation of motion (MR-EOM) approach is combined with a simple treatment of spin–orbit coupling, as implemented in the ORCA program. The resulting multireference equation of motion spin–orbit coupling (MR-EOM-SOC) approach is applied to the first-row transition metal atoms Cr, Mn, Fe and Co, for which experimental data are readily available. Using the MR-EOM-SOC approach, the splittings in each L-S multiplet can be accurately assessed (root mean square (RMS) errors of about 70 cm^?1). The RMS errors for J-specific excitation energies range from 414 to 783 cm^?1 and are comparable to previously reported J-averaged MR-EOM results using the ACESII program. The MR-EOM approach is highly efficient. A typical MR-EOM calculation of a full spin–orbit spectrum takes about 2 CPU hours on a single processor of a 12-core node, consisting of Intel XEON 2.93 GHz CPUs with 12.3 MB of shared cache memory.     

Analysis of the common characteristics of the Hartmann,Ronchi, and Shack–Hartmann tests

An overview of the settings of the planes for the filters and observed patterns in the Hartmann and Ronchi tests is presented. Also a new set of filters for both test were developed. In a similar way, it is easy to extend this analysis to the Shack–Hartmann test, and to propose a new Null Shack–Hartmann filter.     

Quantitative estimates of the content of the metastable Si-XII,Si-III,and α-Si phases of silicon in the areas of indenter impressions

A quantitative estimate is presented of the specific and total volumes of the metastable Si-XII, Si-III, and α-Si phases of silicon in a locally strained (Berkovich pyramid) area. Calculations are performed using experimental data obtained via Raman spectroscopy and in situ registration of the Si-I → Si-II phase transitions of silicon under the indenter.