Investigation of luminescence spectra of the Y<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript> and Y<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript>:Ce single-crystal films

The luminescence spectra of single-crystal films and bulk crystals of yttrium-aluminum garnet Y₃Al₅O₁₂ and Ce³⁺-activated Y₃Al₅O₁₂ were investigated. It was shown that the room-temperature luminescence intensity of the Ce³⁺-free single-crystal Y₃Al₅O₁₂ film was considerably lower than that of the bulk crystals, while the luminescence intensity of the Ce³⁺ ions in the Y₃Al₅O₁₂:Ce films was considerably higher than that one for the corresponding bulk crystal.     

Kinetic characteristics of subterahertz phonons in optically transparent Y<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript> ceramics with twinning elements in their structure

The relationship between the kinetic characteristics of subterahertz thermal phonons and the structural features of grains and grain boundaries in optically transparent yttrium aluminum garnet (YAG) ceramics is investigated. The effect of plastic deformation on the formation of the structure of cubic oxide ceramics is analyzed. It is shown that the main mechanism of plastic deformation responsible for the formation of natural crystallographic boundaries in samples is the twinning effect.     

Laser-quality oxide Y<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript> ceramics. Comparative studies of its basic characteristics and laser ceramics of a known manufacturer

The effect of sintering aids of SiO₂, ZrO₂, B₂O₃, and MgO oxides on the optimum sintering temperature, ceramics grain growth, total volume of residual pores, and optical quality of obtained ceramics is studied. The best combinations of sintering aids are found; as a result, YAG:Nd (1 at%) samples of ceramics of high optical quality are obtained. An original method for characterizing laser properties of ceramics is developed. Comparative measurements of main laser characteristics of the obtained ceramics and ceramics of the Konoshima Chemical Corp. Ltd wellknown in the world practice, are performed.     

Luminescence and scintillation properties of Y<Subscript>3</Subscript>A<Subscript>l5</Subscript>O<Subscript>12</Subscript>:Ce single crystals and single-crystal films

Luminescence and scintillation properties of Y₃A_l5O₁₂:Ce single crystals grown from the melt by the Czochralski and horizontal directed crystallization methods in various gas media and Y₃A_l5O₁₂:Ce single-crystal films grown by liquid-phase epitaxy from a melt solution based on a PbO-B₂O₃ flux have been comparatively analyzed. The strong dependence of scintillation properties of Y₃A_l5O₁₂:Ce single crystals on their growth conditions and concentrations of Y_Al antisite defects and vacancy defects has been established. Vacancy defects are involved in Ce³⁺ ion emission excitation as the centers of intrinsic UV luminescence and trapping centers. It has been shown that Y₃A_l5O₁₂:Ce single-crystal films are characterized by faster scintillation decay kinetics than single crystals and a lower content of slow components in Ce³⁺ ion luminescence decay during high-energy excitation due to the absence of Y_Al antisite defects in them and low concentration of vacancy defects. At the same time, the light yield of Y₃A_l5O₁₂:Ce single-crystal films is comparable to that of single crystals grown by directed crystallization due to the quenching effect of the Pb²⁺ ion impurity as a flux component and is slightly lower (∼25%) than the light yield of single crystals grown by the Czochralski method.     

Luminescence properties of phosphors based on Tb<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript> (TbAG) terbium-aluminum garnet

The processes of excitation energy transfer in phosphors based on single-crystal Tb₃Al₅O₁₂:Ce (TbAG:Ce) and Tb₃Al₅O₁₂:Ce,Eu (TbAG:Ce,Eu) garnet films have been investigated. These films are considered to be promising materials for screens for X-ray images and luminescence converters of blue LED radiation. The conditions for excitation energy transfer from the matrix (Tb³⁺ cations) to Ce³⁺ and Eu³⁺ ions in TbAG:Ce and TbAG:Ce,Eu phosphors have been analyzed in detail. It is established that a cascade process of excitation energy transfer from Tb³⁺ ions to Ce³⁺ and Eu³⁺ ions and from Ce³⁺ ions to Eu³⁺ ions is implemented in TbAG:Ce,Eu via dipole-dipole interaction and through the Tb³⁺ cation sublattice.     

Effect of iso- and heterovalent additives on characteristics of highly transparent Nd(Yb):Y<Subscript>2</Subscript>O<Subscript>3</Subscript> ceramics

The possibility of synthesis and characteristics of highly transparent Y₂O₃ ceramics doped with Nd³⁺ and Yb³⁺ were studied. The ceramics crystal structure was disordered for the first time by simultaneously substituting Y³⁺ cations by Lu³⁺ or Sc³⁺ isovalent ions and Zr⁴⁺ heterovalent ions. The developed technique allowed synthesis of highly transparent Nd³⁺:Y₂O₃, Nd³⁺: Y₂O₃ + 6 mol % ZrO₂, Nd³⁺: (Lu_0.25Y_0.75)₂O₃ + 6 mol % ZrO₂, Nd³⁺:(Sc_0.25Y_0.75)₂O₃ + 6 mol % ZrO₂, and Yb³⁺:(Sc_0.25Y_0.75)₂O₃ + 6 mol % ZrO₂ ceramics with transmittance to 82.2%. It was shown that introduction of iso- and heterovalent additives Sc₂O₃, Lu₂O₃, and ZrO₂ into Nd³⁺:Y₂O₃ decreases average crystallite sizes to ∼1 μm and reduces the pore content, thus making it possible to produce pore-free ceramics. These additives broaden the spectral band of the ⁴ F _3/2 → ⁴ I _11/2 transition of the neodymium ion to 40 nm.     

Spectral properties of Nd<Superscript>3+</Superscript> ions in samples of transparent Y<Subscript>2</Subscript>O<Subscript>3</Subscript> ceramics

The spectral and luminescent characteristics of samples of Y₂O₃:Nd³⁺ ceramics obtained from different precursors under different preparation conditions (the concentration of an HfO₂ compacting additive, the temperature and time of synthesis) are studied at 300 and 77 K. It is shown that the spectral positions of absorption and luminescence lines of ceramics correspond to those of a Y₂O₃:Nd³⁺ single crystal. At the same time, the absorption and luminescence spectra show an inhomogeneous broadening, characteristic of disordered crystals and glass. The energies of the ⁴ I _9/2 and ⁴ F _3/2 Stark states of the Nd³⁺ ion are calculated. The calculation results nearly coincide with the data from the literature for the Y₂O₃:Nd³⁺ single crystal and transparent ceramics. Samples containing the compacting additive show additional lines, whose intensities correlate with its concentration and the method of preparation of Y₂O₃:Nd³⁺ ultradispersed powders. It is assumed that these lines are related to the fact that either Nd³⁺ ions enter the composition of the HfO₂ compacting additive or Hf⁴⁺ ions are present in the nearest environment of Nd³⁺ ions at the boundaries of granules enriched with HfO₂.     

Femtosecond laser written stress-induced Nd:Y<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript> (Nd:YAG) channel waveguide laser

Single tracks and pairs of tracks were written into undoped and Nd-doped YAG crystals using a commercial femtosecond laser system delivering pulses with pulse duration of 140 fs and pulse energies up to 10 μJ. The pulses were focused by a 50× microscope objective below the surface of the crystals. Due to the elasto-optical effect, stress-induced birefringence was observed in domains surrounding the single tracks and between the pairs of tracks. Waveguiding was demonstrated in certain channels in these domains. To investigate the underlying guiding mechanism highly selective chemical etching of the modified material was performed with etching rates up to 5 μm/h. Pumped at 808 nm, laser operation at a wavelength of 1064 nm was achieved. The maximum output power was 25.5 mW at 261 mW of launched pump power with a slope efficiency of 23%.     

Laser performance of holmium-doped Lu<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript> and (Lu,Y)<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript> crystals pumped by Tm:fiber laser

Optical properties of Ho³⁺-doped Lu₃Al₅O₁₂ and (Lu,Y)₃Al₅O₁₂ crystals were investigated and compared. Substitution of Y for Lu in the host garnet Lu₃Al₅O₁₂ results in broad absorption and emission spectra, and improvements in the laser behavior of Ho³⁺. Pumped by Tm:fiber laser, a maximum output power of 5.02 and 5.73 W of Ho-doped Lu₃Al₅O₁₂ and (Lu,Y)₃Al₅O₁₂ have been obtained, respectively. The center lasing wavelength are 2124.5 and 2123.0 nm for Lu₃Al₅O₁₂ and (Lu,Y)₃Al₅O₁₂, respectively.     

Luminescence of excitons and antisite defects in Lu<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript>:Ce single crystals and single-crystal films

The luminescence of excitons and antisite defects (ADs) was investigated, as well as the specific features of the excitation energy transfer from excitons and ADs to the activator (Ce³⁺ ion) in phosphors based on Lu₃Al₅O₁₂:Ce (LuAG:Ce) single crystals and single-crystalline films, which are characterized by significantly different concentrations of ADs of the Lu _Al ³⁺ type and vacancy-type defects. The luminescence band with λ_max = 249 nm in LuAG:Ce single-crystal films is due to the luminescence of self-trapped excitons (STEs) at regular sites of the garnet lattice. The excited state of STEs is characterized by the presence of two radiative levels with significantly different transition probabilities, which is responsible for the presence of two excitation bands with λ_max = 160 and 167 nm and two components (fast and slow) in the decay kinetics of the STE luminescence. In LuAG:Ce single crystals, in contrast to single-crystal films, the radiative relaxation of STEs in the band with λ_max = 253.5 nm occurs predominantly near Lu _Al ³⁺ ADs. The intrinsic luminescence of LuAG:Ce single crystals at 300 K in the band with λ_max = 325 nm (τ = 540 ns), which is excited in the band with λ_max = 175 nm, is due to the radiative recombination of electrons with holes localized near Lu _Al ³⁺ ADs. In LuAG:Ce single crystals, the excitation of the luminescence of Ce³⁺ ions occurs to a large extent with the participation of ADs. As a result, slow components are present in the luminescence decay of Ce³⁺ ions in LuAG:Ce single crystals due to both the reabsorption of the UV AD luminescence in the 4f-5d absorption band of Ce³⁺ ions with λ_max = 340 nm and the intermediate localization of charge carriers at ADs and vacancy-type defects. In contrast to single crystals, in phosphors based on LuAG:Ce single-crystal films, the contribution of slow components to the luminescence of Ce³⁺ ions is significantly smaller due to a low concentration of these types of defects.     

Diode-pumped Yb:Y<Subscript>2</Subscript>SiO<Subscript>5</Subscript>-LiB<Subscript>3</Subscript>O<Subscript>5</Subscript> cyan laser at 501.7 nm

We describe the output performances of the 928 nm ⁴ F _3/2 → ⁴ I _9/2 transition in Nd:CLNGG under diode-laser pumping. An end-pumped Nd:CLNGG crystal yielded 1.3 W of continuous-wave output power for 17.8 W of absorbed pump power. The slope efficiency with respect to the absorbed pump power was 11.2%. Furthermore, with 17.8 W of diode pump power and the frequency-doubling crystal LiB₃O₅ (LBO), a maximum output power of 260 mW in the blue spectral range at 464 nm has been achieved. The blue output power stability over 4 h is better than 3.2%.     

Temperature effect on the elastic properties of yttrium garnet ferrite Y<Subscript>3</Subscript>Fe<Subscript>5</Subscript>O<Subscript>12</Subscript>

The Young’s moduli along the [100] and [110] crystallographic directions and the shear modulus along the [100] direction in a high-purity yttrium garnet ferrite single crystal are measured in the temperature range from 20 to 600°C. All the independent elastic constants are calculated for this temperature range. The behavior of the elastic moduli and elastic anisotropy factor is analyzed in the vicinity of the critical temperature of the magnetic phase transition.     

The influence of the specific surface of grains on the luminescence properties of Nd<Superscript>3+</Superscript>-doped Y<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript> nanopowders

Nd³⁺:Y₃Al₅O₁₂ (Nd:YAG) powders were prepared by the Pechini method in the temperature range of 800 to 1400 °C. The pure garnet phase of the obtained materials was confirmed by XRD studies. The size of the grains was controlled by the annealing temperature of the samples. Their morphologies were investigated by TEM and porosity measurements (BET). The effect of annealing temperature on the morphology and luminescence properties of Nd:YAG nanocrystallites was studied, and the results were compared to the properties of a Nd:YAG single crystal. A significant enhancement of the ⁴F_3/2→⁴I_9/2/⁴F_3/2→⁴I_11/2 intensity ratio with decreasing grain size was observed. It was found that the decay times of the Nd³⁺ luminescence depends on the specific surface and is significantly longer for well crystallized nanocrystalline grains than for single crystals having the same concentration of Nd³⁺ ions. The role of crystallinity and specific surface on the radiative processes is analyzed. PACS 78.55.-m; 78.20.Ci; 78.67.Bf; 78.68.+m     

Synthesis and characterization of mono-dispersed Y<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript>:Er<Superscript>3+</Superscript>-coated SiO<Subscript>2</Subscript> nanoparticles by co-precipitation process

In this paper, a facile co-precipitation process for preparing mono-dispersed core–shell structure nanoparticles is reported. The 110 nm SiO₂ cores coated with an yttrium aluminum garnet (Y₃Al₅O₁₂) layer doped with Er³⁺ were synthesized and the influence of the concentration ratio of [urea]/[metal ions] on the final product was investigated. The structure and morphology of samples were characterized by the X-ray powder diffraction, Fourier transform IR spectroscopy and transmission electron microscopy, respectively. The results indicate that a layer of well-crystallized garnet Y₃Al₅O₁₂:Er³⁺ were successfully coated on the silica particles with the thickness of 20 nm. The near infrared and upconversion luminescent spectra of the SiO₂@Y₃Al₅O₁₂:Er³⁺ powders further confirm that a Y₃Al₅O₁₂:Er³⁺ coating layer has formed on the surface of silica spherical particles.     

Identification of luminescence bands of Nd<Superscript>3+</Superscript> ions in yttrium aluminates Y<Subscript>3</Subscript>Al<Subscript>5</Subscript>O<Subscript>12</Subscript> and YAlO<Subscript>3</Subscript>

The pulsed cathodoluminescence spectra of yttrium aluminum garnet and perovskite activated by neodymium are investigated at room temperature in the wavelength range 250–750 nm. The luminescence bands are identified, and all of them are assigned to Nd³⁺ transitions, including those from the doublet levels.     

Fabrication and laser performance of highly transparent Nd:YAG ceramics from well-dispersed Nd:Y<Subscript>2</Subscript>O<Subscript>3</Subscript> nanopowders by freeze-drying

Well-dispersed Nd:Y₂O₃ powders with uniform particle size of about 60 nm were synthesized from freeze-dried precursors. Highly transparent 2 at.% Nd:YAG ceramics were fabricated from the as-synthesized Nd:Y₂O₃ powders and commercial Al₂O₃ powders by vacuum sintering at 1,750 °C for 5 h. Phase evolution, microstructures, and spectroscopic properties of the Nd:YAG transparent ceramics were investigated. Freeze-drying played an important role in the synthesis of high-quality Nd:Y₂O₃ nanosized powders, which were essential for the fabrication of highly transparent Nd:YAG ceramics. Optical transmittance of a 3-mm thick sample reached 82% in the wavelength range of 200–900 nm. 5.23 W output power was obtained with 14.3 W diode laser pumping, giving a slope efficiency of 36.5%.     

Various types of photoactive behavior of the Y<Subscript>3</Subscript>Fe<Subscript>5</Subscript>O<Subscript>12</Subscript> ferrimagnetic insulator

The photomagnetic behavior of single-crystal yttrium iron garnet Y₃Fe₅O₁₂ doped with iridium, substituting the cation of iron in the octahedron, is investigated upon illumination at room temperature. It is shown that the photomagnetic properties of Y₃Fe_4.97Ir_0.03O₁₂ samples are to a large degree related to the impurity distortion of the sublattice of iron atoms in octahedral coordination, rather than solely to the possible presence of Fe⁴⁺ cations, which are inactive at room temperature and may even be lacking in single crystals doped with iridium. It is concluded that the photoinduced change in the magnetic parameters of this material is determined by the location of impurity cations and increased surface imperfection of the material. The reasons for the different photoactive behavior of this promising material for spintronics, that is, a singlecrystal yttrium iron garnet, are summarized.     

Luminescence in collisions of low-energy ions with graphite and Al<Subscript>2</Subscript>O<Subscript>3</Subscript>

Excitation of H⁺, H₂ ⁺, H₃ ⁺, He⁺, and Ar⁺ ions by impact on graphite and Al₂O₃ was investigated by means of emission spectroscopy in the 50–1000 eV energy range of the projectiles. Emission of Balmer series from excited neutral hydrogen is observed for both targets. In addition, for the Al₂O₃ target a continuum emission is observed. The continuum probably originates from excited M_nO_m molecules produced in the collision cascade, when surface atoms bound by ionic bonds are released after the bond breaking caused by neutralization. The spectra obtained under Ar⁺ -bombardment show Ar II lines emitted by backscattered ions.     

Formation and mechanical properties of alumina ceramics based on Al<Subscript>2</Subscript>O<Subscript>3</Subscript> micro- and nanoparticles

Alumina micro- and nanopowders with the particle size from 200 μm to 40 nm synthesized by the sol-gel method are studied. The particle size dependence of γ-Al₂O₃→α-Al₂O₃ phase transformation is studied by differential thermal analysis, X-ray diffraction method, and transmission electron microscopy. X-ray diffraction data show that for alumina nanoparticles γ-Al₂O₃→θ-Al₂O₃ phase transformation occurs at 900°C, and for micro-particles it occurs in the temperature range 1150–1200°C. The alumina ceramics produced of alumina nanoparticles is shown to have higher flexural strength under three-point bending than the ceramics produced of micro-particles. The obtained results demonstrate that alumina particle size reduction stabilizes the formation of α-Al₂O₃ at lower temperatures, due to which the grain growth rate decreases and the flexural strength of monolithic oxide ceramics increases.