Effective excitation cross section and lifetime of Er<Superscript>3+</Superscript> ions in Si: Er light-emitting diodes fabricated by sublimation molecular-beam epitaxy

A series of Si: Er electroluminescent diode structures is fabricated by sublimation molecular-beam epitaxy. The diode structures efficiently emit at a wavelength of 1.5 μm under conditions of p-n junction breakdown at room temperature. The effective cross section of excitation of Er³⁺ ions with hot carriers heated by the electric field of a reverse-biased p-n junction and the lifetime of Er³⁺ ions in the first excited state ⁴I_13/2 are determined for structures that emit in a mixed breakdown mode and are characterized by the maximum intensity and excitation efficiency of the Er³⁺ electroluminescence.     

NMR-ON on196,197m,198,198m,200mAu in Fe and Ni

The zero-field hyperfine splitting frequencies of a series of Au isotopes in Fe and Ni have been determined with nuclear magnetic resonance on oriented nuclei. The results are:. For¹⁹⁸Au(2^–) in Fe the quadrupole splitting could be resolved. The results are ¦g_NB_HF/h|=259.48 (3) MHz and e²qp/h=–2.08(4) MHz. Our measurements show that most hyperfine splittings published on these isotopes have been incorrect. The quadrupole splitting of¹⁹⁸AuFe disagrees in magnitudeand sign from the value reported by single-passage NMR on oriented nuclei. The following nuclear quantities are deduced: (^197mAu,11/2^–)=5.98(9) _N; (^198mAu, 12^–)=5.85(9) _N; (^200mAu, 12^–)=5.90(9) _N; Q(¹⁹⁸Au,2^–)/Q(¹⁹⁹Au, 3/2⁺)=1.37(3). Our measurements show further that the non-contact hyperfine field for Au in Ni is smaller than assumed previously, and that the magnetic hyperfine splitting frequency of¹⁹⁷AuFe known from NMR is inconsistent with the magnetic hyperfine splitting frequencies of^{198, 199}AuFe.     

Nuclear orientation of48V in Fe and Co and NMR of48VFe

Observations of the anisotropies of the 984 and 1312 keV -rays from⁴⁸VFe and⁴⁸VCo in fields up to 4 T and temperatures down to 4 mK show extremely long nuclear spin-lattice relaxation times (3–4 h in Fe, 8 h in Co host) and indicate negative hyperfine fields in both hosts. The Fe measurements show a magnetic moment for the⁴⁸V 4⁺ ground state considerably larger than previously reported. This is confirmed by NO/NMR of⁴⁸VFe, giving (4⁺)=2.012(11) _N. The advantages of pulsed NMR techniques, especially in systems with slow relaxation, are discussed.     

Studies of Hindered Rotation and Magnetic Anisotropy by 1H, 13C and 19F NMR. The Diels-Alder Adduct of N- Pentafluorophenylmaleimide and Phencyclone: A Model for Drugs.

The potent Diels-Alder diene, phencyclone, 1, reacts with N-pentafluorophenylmaleimide, 2, to form an adduct, 3, characterized by ¹H, ¹³C, and ¹⁹F NMR at 300, 75 and 282 MHz, respectively. The one-dimensional (1D) and two-dimensional (2D) ¹H and ¹³C NMR spectra of 3 at ambient temperatures imply a slow exchange limit (SEL) regime with respect to rotation of the unsubstituted bridgehead phenyl groups about severely hindered C(sp²)-C(sp³) bonds. Major non-bonded interactions are expected between the ortho protons of the C₆H₅ groups and H-1, 8 of the phenanthrenoid moiety of 3. ¹⁹F 1D and 2D (COSY) NMR spectra show that the SEL regime also obtains for rotation about the N-C₆F₅ bond of 3, with five separate fluorine signals seen, consistent with a preferred conformation in which the C₆F₅ may lie roughly perpendicular to the plane of the pyrrolidinedione moiety, and may be in the mirror symmetry plane of 3. The results are considered relevant to hindered aryl rotations in numerous Pharmaceuticals. Selected spectral data for 2 and precursors are also presented.     

On the structure of non-superconducting YBa2Cu3O6+ɛ

The crystal structure of non-superconducting, tetragonal YBa₂Cu₃O₆₊ ( close to 0) (s.g.P4/mmm) was studied at room temperature by means of single crystal X-ray diffraction, electron microscopy and electron diffraction. Crystals may easily be obtained by heating YBa₂Cu₃O₇ samples under vacuum. For 0, the tetragonal single crystals are chemically and crystallographically homogeneous — without any twin domains. The only defects immediately apparent are stacking faults alongc. The structure is very closely related to that of the high-T _c superconductor YBa₂Cu₃O₇. The most important difference is, that the oxygen on theb-axis (O(1)), which together with Cu(1) forms Cu–O–Cu–O-chains alongb in YBa₂Cu₃O₇, is vacant in YBa₂Cu₃O₆. Some crystals show a superstructure with superstructure reflections which are sharp in thea ^*–a ^*-plane but form diffuse streaks alongc ^*. We propose a model which relates these superstructure reflections to a 2-dimensional ordering of residual oxygen atoms on the O(1) site (corresponding to >0 in the chemical formula YBa₂Cu₃O₆₊).     

Generation of high-current electron beams by a hollow cathode with a ferroelectric plasma source

This paper presents results and analysis of an experimental investigation of the operation of a hollow cathode (HC) with an incorporated ferroelectric plasma source (FPS). It was shown that the use of FPS based on a BaTi solid solution allows one to ignite and to sustain a 10²-10³ A HC discharge with duration of 10^-3-10^-5 s at background pressure of 5 x 10^-3 Pa while keeping the HC design with small dimensions. It was found that the development of the HC discharge is accompanied by formation at the surface of the FPS of dense plasma which serves as a powerful (hundreds of kW) pulsed source of current carrying electrons. Parameters of the HC plasma (radial distribution of the plasma density and temperature and plasma potential) for different discharge current amplitudes and two types of FPS are presented. Application of the FPS as an electron source in a diode under an accelerating pulse 300 kV and pulse duration 400 ns showed that the latter operates in a plasma pre-filled mode with a current amplitude up to 1.6 kA. Parameters of the diode and electron beam for different experimental conditions are presented and discussed.Received: 10 April 2003, Published online: 12 August 2003PACS: 52.50.Dg Plasma sources - 29.25.Bx Electron sources - 52.25.Tx Emission, absorption, and scattering of particles     

Strong probe atom dependence of the electric field gradient in Bismuth

The nuclear quadrupole interaction of the 8⁺ isomers in^{206, 208}Po was measured in the semimetallic host Bi. The comparison of the extracted electric field gradient eq for PoBi with the values for the neighboring elements Bi and Pb as probe atoms in Bi reveals a very drastic increase from Pb to Bi and to Po by an order of magnitude: eq_PbBi eq_BiBi eq_PoBi =1.64(10)4.8(3)16(2)(all values at room temperature in units of 10¹⁷ V/cm²). This behavior is discussed in terms of the changing number of outerp-electrons of the probe atoms.     

The magnetic hyperfine field and the electric field gradient at181Ta impurities in Gd metal

The magnetic hyperfine fieldH _hf and the electric field gradientV _zz at¹⁸¹Ta impurties in metallic Gd were determined by time differential perturbed angular correlation measurements with the 133 keV K-conversion electron 482 keV -cascade of¹⁸¹Ta. The sources for these measurements were prepared by implantation of radioactive¹⁸¹Hf ions into Gd. The results are: |H _hf(TaGd; 77 K)|=285(14)kG, and |V _zz(TaGd; 330 K)|=5.32(15)·10¹⁷V/cm². The value ofH _hf fits well into the systematics for 5d impurities in Gd and indicates a positive core polarisation contribution, which is expected if the conduction electrons of Gd have to a large extent d-character. The electric field gradients of the 5d impurities in Gd are not consistent with a proportionality between the ionic and the electronic contribution.     

Electric quadrupole moments of radioactive Pt isotopes

Nuclear orientation experiments were performed on¹⁸⁹Pt (I=3/2^–; T_1/2=11 h),¹⁹¹pt (I=3/2^–; T_1/2=2.8 d) and^195mpt=3/2^–; T_1/2=4.0 d) in an Os single crystal at temperatures down to 10 mK. Preliminary results for the quadrupole splitting _o=e²qQ/h are +48 (9), +39 (6), and –87 (12) MHz for¹⁸⁹ptOs,¹⁹¹ptOs, and¹⁹⁵mptOs, respectively. Preliminary results for the quadrupole moments are –0.8 (4), –0.6 (3), and +1.4 (7) b for¹⁸⁹pt,¹⁹¹pt, and¹⁹⁵mpt, respectively. In addition, the quadrupole subresonance structure of¹⁸⁹pt and¹⁹¹pt in Fe was measured with quadrupole-interaction resolved NMR-ON spectroscopy. The results for the magnetic hyperfine splitting _M=¦g_NB_HF/h¦ and _Q are:¹⁸⁹ptFe: _M=277.9 (1) MHz; _Q=+1.39 (5) MHz.¹⁹¹ptFe: _M=320.17 (3) MHZ; _Q=+1.39 (3) MHz. The ratio of the quadrupole moments of¹⁹¹pt and¹⁸⁹pt is deduced to be Q (¹⁹¹Pt/Q^l89pt)=+1.00 (4). The negative quadrupole moments of¹⁸⁹pt and¹⁹¹pt indicate a predominantly oblate shape of the ground states.     

Grand unified models including extraZ bosons

The grand unified theories (GUT) of the simple Lie groups including extraZ bosons are discussed. There are onlySU _5+m,SO _6+4n, andE ₆ under our hypothesis. First we give a general discussion forSU _5+m, then forSU ₆ andSU ₇ for illustration. We use15 +6 ^* +6 ^* fermion representations inSU ₆ but not with the fermion content, Yukawa coupling, and the hierarchy of other authors. We suggest that there is a series of clans of particles. These clans consist of the extraZ bosons and the corresponding fermions of the scale.     

1H NMR Spectral Simplification with Chiral Solvating Agents and with Achiral and Chiral Lanthanide Shift Reagents. Cis-4,5-Dihydro-4-Methyl-5-Phenyl-2-Oxazolamine, “Cis-4-Methylaminorex,” a Potent Stimulant and Anorectic

Abstract

The 60 MHz ¹H NMR spectra of racemic (+)-cis-4,5-dihydro-4-methyl-5-phenyl-2-oxazolamine, 1, have been studied at 28° in CDC1₃, solution with the achiral lanthanide shift reagent (LSR), tris(6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionato) europium(III), 2, and the chiral reagent tris[3?(heptafluoropropylhydroxymethy1ene)-d-camphor-ato]europium(III), 3. Additional NMR studies were performed at 400 MHz in CDC1, solution at 24° using the chiral solvating agents (CSA), (E)-(-)-2,2,2-trifluoro-1- (9-anthryl) ethanol, 4, and (R) - (+) -α-methoxy- α-(trifluoromethy1)phenylacetic acid, 5. Substantial enantiomeric shift differences, for the CH₃, signal of 1 using 3 or 5, and for the ortho aryl protons using4, which should make possible direct optical purity determinations of 1. Accurate 400 MHz data f o r chemical shifts and vicinal coupling constants of, of racemic cis-1 are presented, and compared with values for (optically active) (-)-trans-1; some dfferences are seen compared to previously reported data. solution. The LSR and CSA results are compared and Some additional data were obtained in C₆D₆ discussed.     

The magnetic hyperfine field at140Ce in nickel

The hyperfine interaction of¹⁴⁰Ce in nickel has been investigated by the time-differential perturbed-angular-correlation technique (TDPAC). The probe was produced by isotope separator implantation of the fission product¹⁴⁰Xe, the ^- decay chain of which finally populates excited states of¹⁴⁰Ce.Different spin rotation spectra were observed before and after an 8 h annealing at 415°C. The analysis of the spectra led to the conclusion that the Ce ions were in the diamagnetic 4⁺ state. The dominant contributions to the hyperfine interaction are two different magnetic hyperfine fields: |H _hf ¹|=385±7 kOe and |H _hf ²|=276±12 kOe.H _hf ¹ disappears after annealing. The fraction of nuclei which observeH _hf ² is increased by the annealing procedure from 16% to 75%. It is assumed thatH _hf ¹ is the hyperfine field of CeNi in an unperturbed substitutional site andH _hf ² is attributed to Ce ions which have trapped a single vacancy.     

The effect of the crystal-field ground-state splitting on the electrical resistivity of dilute (La,Pr)B6

We have measured the resistivity and the magnetoresistivity of some dilute (La, Pr)B₆ single crystals. At temperatures below 1 K a pronounced step in the resistivity occurs which shifts to higher temperatures with increasing Pr concentration as well as with increasing external magnetic fields. The observed resistance anomaly is caused by Pr–Pr interactions which remove the degeneracy of the ₅ crystal field ground state of Pr³⁺ in LaB₆. The resistance step reflects the temperature-dependent probability that conduction electrons are scattered from the ₅ crystal field sublevels of the Pr³⁺ ions. The shift of the resistance step in a magnetic field can be simply explained as Zeeman effect of the ₅ triplet.     

1H NMR Spectral Simplification with Achiral and Chiral Lanthanide Shift Reagents. Lofexidine

The ¹H NMR spectra of the potent anti-hypertensive drug, lofexidine, 1, have been studied in CDCl₃ at 60 and 300 MHz. Both the achiral shift reagentr tris (6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedionatol-europium(III), 2 and the chiral reagents1 tris[3-(heptafluoropropylhydroxymethylenel-d-camphoratoleuropium(III), 3 and tris[3-(trifluoromethylhydroxymethylenel-d-camphoratoleuropium(III), 4, were employed. Substantial lanthanide induced shifts were observed with 2, 3 or 4, with the largest shifts seen for the methine at the chiral centerr followed by the signal of the NH. Enantiomeric shift differences for the CH₃ signal of 1 were seen with 3 OK 4, with 4 inducing larger values of potential analytical utility. Using a non-racemic sample of 1, the (-) enantiomer was shown to have a downfield sense of magnetic nonequivalence for the methyl resonance in the presence of added 4.     

1H NMR Spectral Simplification with Achiral and Chiral Lanthanide Shift Reagents. IV. Metaxalone, 5-(3,5-Dimethylphenoxymethyl)-2-oxazolidinone; Evidence for Multidentate Chelation

The 60 MHz ¹H NMR spectra of racemic metaxalone, 1, have been studied in CDC1₃ solution at 28° with the achiral shift reagent tris(6, 6, 7, 7, 8, 8, 8-heptafluoro-2, 2-dimethyl-3, 5-octanedionato)europium(III), 2, and the chiral reagents tris[3-(trifluoromethylhydroxymethylene)-d-cam-phorato]europium(III), 3, and tris[3-(heptafluoropropylhydroxymethylene)-d-camphorato]europium(III), 4. Reagent 3 produced modest observable enantiomeric shift differences, ΔΔδ, for the CH₂0, aryl methyl, aryl H₂,6 and the NH siqnals. Although reaquent 4 produced small or no observable ΔΔδ for the CH₂0, aryl methyls or aryl protons. strikingly qreater valuesof lanthanide induced shift, Δδ, as well as ΔΔδ, were found for the NH signal using 4 relative to 3. Analytical feasibility for direct optical purity determinations of 1 with 0 using this NH siqnal sclould allow detection of 74% of the minor enantiomer or less. Results are discussed ir terms of potential bidentate or tridentate chelation of 3 by 1 makinrl a greater contribution than for 4.     

Maximum mass-particle velocities in Kantor's information mechanics

Kantor's information mechanics links phenomena previously regarded as not treatable by a single theory. It is used here to calculate the maximum velocities _m of single particles. For the electron, _m/c1–1.253814×10^–77. The maximum _m corresponds to _m/c1–1.097864×10^–122 for a single mass particle with a rest mass of 3.078496×10^–5g. This is the fastest that matter can move. Either information mechanics or classical mechanics can be used to show that _m is less for heavier particles. That _m is less for lighter particles can be deduced from an information mechanics argument alone.     

Magnetic moments of Gd nuclei

Low temperature nuclear orientation experiments down to 2 mK on¹⁴⁷GdFe,¹⁴⁹GdFe,¹⁴⁹GdGd and¹⁵³GdGd have yielded the magnetic hyperfine interaction strength. Bhf as 31.0(1.6) _NT, 28.3(2.0) _NT, 33.8(4.7) _NT and 13.3(2.1) _NT respectively. From these values the respective ground state magnetic moments ¦¦ of¹⁴⁷Gd,¹⁴⁹Gd and¹⁵⁹Gd were deduced as 1.12(20) _N, 1.01(16) _N and 0.40(8) _N.     

Upconversion blue emission dependence on the pump mechanism for Tm<Superscript>3+</Superscript>-heavy-doped NaY(WO<Subscript>4</Subscript>)<Subscript>2</Subscript> crystal

Upconversion blue emissions of Tm³⁺-ion-heavy-doped NaY(WO₄)₂ crystals are investigated with three different near-infrared pump mechanisms. The dependence of upconversion efficiency on the pump mechanism is analyzed from the scope of the concentration quenching effect. Three cross-relaxation processes, , , and , which influence the upconversion dominantly in the Tm³⁺-heavy-doped system, are demonstrated theoretically and experimentally. The results indicate that Yb³⁺ ions can weaken the concentration quenching effect of Tm³⁺ ions significantly so that the blue emission efficiency can be enhanced by one order of magnitude. At the same time, the wavelength of the pump source also has considerable influence on both the population of some crucial energy levels and the upconversion mechanism. Experiments show that the upconversion blue emission in Tm³⁺/Yb³⁺ co-doped NaY(WO₄)₂ crystal under 980-nm laser diode excitation is the most intensive of these three different near-infrared pump mechanisms. The conclusions are confirmed by spectra measurements and calculations of Judd–Ofelt theory and Miyakawa–Dexter theory. PACS 42.70.Hj; 78.55.-m     

1H NMR Spectral Simplification with Achiral and Chiral Lanthanide Shift Reagents. Meparfynol, 3-Methyl-L-Pentyn-3-Ol. Apparent Anomalous Results with a Binuclear Shift Reagent

The 60 MHz ¹H NMR spectra of racemic meparfynol, 1, have been studied in CDCl₃ solution at 28° with the achiral shift reagentt tris(6,6,7,7,8,8,8-hepta-fluoro-2,2-dimethyl-3,5-octanedionato) europium (III), 2, and the chiral reagent, tris[3-(heptafluoropropyl-hydroxymethylene)-d-camphorat01 europium(III), 3. With 3, observable enantiomeric shift differences for the 3-methyl should make possible direct optical purity determinations. Additions of increments of (6,6,7,7,8,8,8-heptafluoro-2,2-dimenthyl-3,5-octane-dionato)silver(I) 4, to a CDCl₃ solution of 1 and 3 resulted in changes in Δδ magnitudes and in some line intensities that are discussed in terms of interactions with the ethynyl and hydroxyl groups.