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1.
Micellar preconcentration has been proposed to improve the procedure of spectrophotometric determination of sodium dodecyl sulfate (SDS). It involves quantitative extraction by reversed micelles of Triton N-42 in n-decane and the subsequent formation of an ion associate with methylene blue and azure A upon destruction of the micellar solution by diluting it with a mixture of chloroform and n-decane in the presence of small concentrations of a dye solution. The absence of losses of 10?7?10?5 M SDS upon from 5-to 50-fold preconcentration is confirmed by the standard addition method (RSD = 4–5%); the determination limit of SDS equals 5 × 10?8 M. 相似文献
2.
Kinetics of dissolution of silver nanoparticles inside triton N-42 reversed micelles 总被引:1,自引:0,他引:1
V. V. Tatarchuk A. I. Bulavchenko I. A. Druzhinina 《Russian Journal of Inorganic Chemistry》2009,54(10):1678-1683
Our spectrophotometric study of the kinetics of dissolution of silver nanoparticles by nitric acid inside inverted micelles
of Triton N-42 (a nonionic surfactant) verified the universal character of the mechanism for this type of process, which includes
the interaction of surface metal atoms with an oxidizer in two routes: either with (autocatalysis) or without newly formed
ionic species of the oxidized metal. Effective rate constants for both routes are independent of the value of solubilization
capacity (V
s
/V
o
is the ratio of the volume of the dispersed aqueous phase to the volume of the micellar solution); the solubilization capacity
is useful to control the micelle and particle sizes: k
1 = 0.018±0.003, 0.010±0.003, and 0.012±0.003 s−1 and k
2 = 2.5±0.8, 1.5±1.1, and 1.4±0.4 L/(mol s) for 100 V
s
/V
o
= 1, 2, and 3%, respectively. 相似文献
3.
4.
The effect of surfactants on the fluorescence of the niobium—morin system is described. Cationic surfactants strongly enhanced the intensity (e.g., cetyltrimethylammonium bromide (CTAB) gives an 80-fold increase), while anionic and non-ionic surfactants are without effect. The formation of 1:1 and 1:3 (Nb:morin) complexes is demonstrated spectrophotometrically. The conditional stability constants for these complexes in CTAB micelles are β1 = (1.14 ± 0.01) × 104 l mol?1 amd β3 = (5.66 ± 0.02 × 1010 l3 mol?3. The micellar-enhanced fluorimetric method has a 1 μg l?1 detection limit, and is highly selective. The r.s.d. for the determination of 50 μg l?1 Nb is 3.5%. 相似文献
5.
6.
Tomás Pérez-Ruiz Carmen Martínez-Lozano Virginia Tomás Conceptión Paredes 《Mikrochimica acta》1995,118(3-4):203-211
The color-forming reactions of molybdenum(VI) and vanadium(IV) with carminic acid (CA) in the presence of cetyltrimethylammonium bromide (CTAB) were used in the flow-injection determination of these metals. The micellar medium enhances the spectrophotometric features of the Mo(VI)-CA and V(IV)-CA binary complexes, and the higher solubility of these complexes when the CTAB concentration is above critical micelle concentration permits the easy application of flow-injection systems. Under the optimum conditions, linear calibration graphs were obtained from 0.76 to 28.8 g/ml for molybdenum and from 0.30 to 9.1 g/ml for vanadium. The detection limits were 0.33 and 0.16 g/ml for molybdenum and vanadium, respectively. The selectivity of the method was investigated and the procedure was successfully applied to the determination of molybdenum in steels and pharmaceuticals and of vanadium in petroleum products. 相似文献
7.
A radiometric method based on substoichiometric isotope dilution analysis has been developed for the determination of mercury
using cetyltrimethylammonium bromide (CTAB) as the substoichiometric reagent. The method is based on the extraction of mercury
as an ionassociation complex of tetraiodomercurate(II) ion with a substoichiometric amount of CTAB in benzene. The calibration
graph was found to be linear in the range 0–10 μg Hg (II) in the aqueous phase of 10 ml volume. A detection limit of 0.06
μg·ml−1 could be achieved by the proposed method. The relative standard deviation of the method was found to be 3.0% and the method
has been successfully applied to study the determination of mercury in various synthetic mixtures. 相似文献
8.
Effect of dioctyl sulfide on the kinetics of oxidative dissolution of gold nanoparticles in triton N-42 reverse micelles 总被引:1,自引:0,他引:1
V. V. Tatarchuk A. I. Bulavchenko I. A. Druzhinina A. P. Sergievskaya 《Russian Journal of Inorganic Chemistry》2011,56(5):808-815
The effect of additions of hydrophobic dioctyl sulfide (L) on the kinetics of dissolution of gold nanoparticles in the interaction
with a dispersed aqueous hydrochloric solution of H2O2 in Triton N-42 reverse micelles (decane was the dispersion medium) was studied spectrophotometrically. The process consists
of a two-stage oxidation Au0 → AuCl2− → AuCl4− at the surface of gold particles; the first stage occurs in two ways: a spontaneous reaction and an autocatalytic reaction
involving AuCl4− ions. With small additions of L (c
L < c
Au), only spontaneous oxidation of Au(0) to Au(I) takes place because Au(I) is completely bound in an inert complex AuLCl. When
unbound L is exhausted, the newly formed AuLCl is accumulated in micellar shells, changes the properties of the medium inside
the micelles, and affects the rate constant of the autocatalytic reaction, which increases with increasing c
L. At high concentrations of L, the coagulation of particles occurs instead of their dissolution, because of the deterioration
of the protective properties of micellar shells as a result of the ingression and accumulation of dioctyl sulfide molecules
on account of selective adsorption on gold particles. The rate constants of all stages of dissolution and coagulation are
determined. 相似文献
9.
10.
Cortez Ely V. Felipe Maria das Graças de Almeida Roberto Niês C. Pessoa Adalberto Vitolo Michele 《Applied biochemistry and biotechnology》2001,91(1-9):753-759
Applied Biochemistry and Biotechnology - Xylose reductase enzyme (EC 1.1.1.21) produced by Candidaguilliermondii in sugarcane bagasse was extracted by reversed micelles of N-benzyl-N-dodecyl-N-bis... 相似文献
11.
A. I. Bulavchenko A. T. Arymbaeva O. A. Bulavchenko V. V. Tatarchuk N. I. Petrova 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2006,80(12):1980-1985
The distribution of Au(III) between an acid (3 mol/l HCl) aqueous phase and a micellar Triton N-42 solution in n-decane was studied as a function of the concentration of Na2SO4 (0–3.55 mol/l). The high distribution coefficients (200–500) allow 50-fold absolute concentration to be performed at a 90% extraction. Au0 nanoparticles were obtained by the injection solubilization of a reducing agent (hydrazine) into micellar extracts. At low solubilization capacities (≤1 vol %) and high reducing agent concentrations (≥0.2 mol/l) in Triton N-42 micelles, stable systems of Au0 nanoparticles suitable for the spectrophotometric determination of gold were obtained. At high solubilization capacities and low hydrazine concentrations, reduction was accompanied by coagulation and sedimentation processes. These processes were studied by spectrophotometry and the static and dynamic light scattering methods. 相似文献
12.
Cudina O Janković I Comor M Vladimirov S 《Journal of colloid and interface science》2006,301(2):692-696
In this study, the interaction of the anion of quinapril (QUIN), angiotensin converting enzyme (ACE) inhibitor, with cationic surfactant cetyltrimethylammonium bromide (CTAB) was investigated. The effect of cationic micelles on the spectroscopic and acid-base properties of QUIN was studied at pH 8. The binding of QUIN anion to CTAB micelles implied a shift in drug acidity constant (pK(a)(water)-pK(a)(micelle)=1.39) proving the great affinity of negatively charged QUIN ion for the positively charged CTAB micelle surface. The strong dependence of the partition coefficient K(x) on QUIN concentration, obtained by using pseudo-phase model, is consistent with an adsorption-like phenomenon. From the dependence of differential absorbance at lambda=272 nm on CTAB concentration, by using mathematical model that treats the solubilization of QUIN anion as its binding to specific sites in the micelles (Langmuir adsorption isotherm), the binding constant K(b)=(2.3+/-0.4)x10(3) mol(-1)dm(3) was obtained. QUIN-CTAB binding constant was also calculated from micellar liquid chromatography (MLC) and this method was found to be not accurate enough for its determination. 相似文献
13.
This paper proposes a methodology based on electrochemical reduction for the simultaneous determination of three sunscreen agents, namely 4-methylbenzylidene camphor (MBC), benzophenone-3 (BENZO) and 2-ethylhexyl-4-methoxycinnamate (EHMC) by differential-pulse polarography (DPP). The highest peak currents and optimal separation of reduction peaks were obtained by using a supporting electrolyte consisted of Britton-Robinson buffer-methanol (8:2) solution at pH 4.0 and cationic surfactant 3.0 x 10(-4)mol L(-1) cetyltrimethylammonium bromide (CTAB). The methodology was validated using four commercial sunscreen preparation as a sample and the results showed high recovery rates. The efficiency of the proposed methodology was demonstrated by comparing the results obtained by DPP with those obtained by the high-performance liquid chromatography (HPLC) method. 相似文献
14.
T. Yu. Podlipskaya A. I. Bulavchenko L. A. Sheludyakova 《Journal of Structural Chemistry》2011,52(5):970-979
FT-IR and photon correlation spectroscopy methods are used to study the distribution of free (bulk) and bound (hydration)
water in Triton N-42 reverse micelles under the conditions of injection solubilization of hydrochloric acid solutions. The
amount of each type of water is calculated depending on the solubilization capacity (V
s/V
o) and HCl concentration in the aqueous pseudophase. According to the IR spectroscopy data, the distribution of water is largely
determined by the solubilization capacity of the micellar solution, while the fraction of bulk water exceeds significantly
the value calculated by the geometric approach based on the photon correlation spectroscopy data. The difference shows that
there is bulk water in the surface layer formed by oxyethyl groups of Triton N-42 molecules in spherocylindrical micelles. 相似文献
15.
A. B. Mirgorodskaya L. Ya. Zakharova F. G. Valeeva A. V. Zakharov L. Z. Rizvanova L. A. Kudryavtseva H. E. Harlampidi A. I. Konovalov 《Russian Chemical Bulletin》2007,56(10):2000-2007
The variation of the microscopic properties (surface potential, micropolarity, etc.) of the interface of cetyltrimethylammonium bromide micelles upon the addition of a background electrolyte or the nonionic
surfactant Triton X-100 decreases the rates of ion-molecular reactions, namely, alkaline hydrolysis of carboxylic acid esters
and tetracoordinate phosphorus acid esters, and results in the shift of acid-base equilibria.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1933–1940, October, 2007. 相似文献
16.
A ternary complex between germanium, Catechol Violet (CV) and cetyltrimethylanunoniuni bromide is proposed for the determination of germanium. The stoichiometric ratio Ge:CV is 1:2. Beer's law is obeyed from 0.1 to 1.0 ppm of Ge. The method is highly selective. Interference from Sn(IV), Fe(III), Bi(III), Cr(VI), Mo(VI), V(V) and Sb(III) in mg amounts is eliminated by extracting the germanium into carbon tetrachloride from 9M HC1 and then stripping into water before the photometric determination. 相似文献
17.
The thorium-Xylenol Orange reaction sensitized by cetyltrimethylammonium bromide ( = 5.51 x 10(4) l.mole(-1).cm(-1)) is accompanied by a bathochromic shift from 570 to 600 nm. The system is more selective than the binary system, because the reaction pH is lowered from 4.0 to 2.5; Beer's law is obeyed for 0.04-4.00 ppm of thorium. 相似文献
18.
P. K. Tarafder P. Murugan L. Kunkal D. P. S. Rathore 《Journal of Radioanalytical and Nuclear Chemistry》2002,253(1):135-142
A novel procedure for the extraction of uranium has been described. UO2
2+ forms a 1:3 anionic complex with 2,3-dihydroxynaphthalene in the pH range, 4–12. This anionic complex is best extracted into ethyl acetate at pH 11–12 under the influence of a counter cation, cetyltrimethylammonium bromide. This extraction technique has been extended to the separation of uranium from silicate rock matrices for its determination by fluorimetry. Except Co, Cr, and Fe, most elements present in silicate rocks do not interfere. While the interferences of Co and Cr are suppressed by the addition of EDTA, iron is removed by prior extraction at pH 4–5 as its neutral complex with 2,3-dihydroxynaphthalene. The results compare favourably with those obtained from the conventional technique, i.e., extraction of uranium in ethyl acetate from NHO3 medium under the influence of Al(NO3)3
.9H2O as salting out agent. The extraction system under study is capable of separating even ultra-trace amounts of uranium quantitatively from complex matrices of rock samples. Besides, the method is simple, rapid, cost effective and precludes the use of reagents like nitric acid and aluminum nitrate (salting out agent) required in bulk quantities in the conventional system. 相似文献
19.
T. Yu. Podlipskaya A. I. Bulavchenko L. A. Sheludyakova 《Journal of Structural Chemistry》2011,52(5):980-984
FT-IR spectroscopy is used to study the distribution of bulk (free) and hydration (bound) water during the extraction of Pt(IV)
and Au(III) from acid sulfate-chloride media by Triton N-42 reverse micelles. The bulk water fraction in Triton N-42 micelles
reduces from 44% to 23% with an increase in the sodium sulfate concentration up to 3.5 mol/l in the feed. A decrease in the
total concentration of micellar water and bulk water fraction complies well with an increase in the Pt(IV) and Au(III) distribution
coefficients and concentration during the extraction by Triton N-42 reverse micelles. 相似文献
20.
The reaction of scandium(III) with o-chlorophenylfluorone (o-CIPF) in the presence of cetyltrimethylammonium bromide (CTMAB) has been studied. In an acetate buffer at pH 4.4, a red-purple complex is obtained, with maximum absorption at 569 nm and a molar absorptivity of 1.31 x 10(5)1.mole(-1).cm(-1). The composition of the complex is found to be 1:2:2 Sc-o-CIPF-CTMAB. Beer's law is obeyed over the range 0-12 mug/25 ml scandium. The proposed method has been used for determination of trace scandium in tungsten ores after its prior separation by solvent extraction. 相似文献