Effect of mechanical activation on thermal and electrical conductivity of sintered Cu,Cr, and Cu/Cr composite powders

The results of measurement of electric resistivity and thermal conductivity of materials obtained by spark plasma sintering from powders of Cu, Cr, and their mixtures in the range of 300–600 K are presented. It is shown that the grinding of powders in planetary mills results in a reasonably substantial change in the electric and thermal properties of materials: to increasing electric resistivity and decreasing thermal conductivity and temperature coefficients of electric resistivity. The possible causes of these effects are considered.     

Temperature fields control in the process of spark plasma sintering of thermoelectrics

The process of creating thermoelectrics by spark plasma sintering of nanostructured powders in order to obtain materials with improved thermoelectric properties has been modeled. The factors that influence the distribution of thermal field in the sintering process have been analyzed. The influence of geometric parameters of tooling on the formation of temperature gradient field required for effective sintering of functionally gradient materials and segmented branches of thermo-elements has been considered. The results can be used to determine the conditions and modes of sintering of functionally gradient materials in installations of spark plasma sintering and hot pressing.     

On the electron energy distribution in the gas discharge positive column: Langmuir paradox

The results of calculations of electron drift characteristics in a dc spatially inhomogeneous periodic electric field are presented. It is shown that the effect of field inhomogeneities on the drift velocity and the average electron energy is insignificant under typical conditions of experiments with gas-discharge plasma at low gas pressures. However, the intensity of the processes of excitation, ionization, and plasma spatial distribution are strongly affected by the inhomogeneity (variance) and field variation behavior. It is shown that the electric field inhomogeneity in the gas discharge positive column leads to maxwellization of the electron energy distribution function.     

Ionization formation of plasma inhomogeneity by the near-zone field of a magnetic-type source in a magnetized plasma

An investigations is made of the steady-state structure of a plasma inhomogeneity arising as a result of high-frequency heating and additional ionization of a background magnetized plasma by the near-zone field of a magnetic-type source (ring electric current). It is assumed that the source axis is parallel to an external magnetic field; the source frequency belongs in the low hybrid band. The main attention is focused on the particular case (important for possible applications) when the characteristic longitudinal and transverse scales of density distribution considerably exceed the corresponding scales of distribution of the electron temperature and of the source field. Simplified equations for the near-zone field of the source, the electron temperature, and the plasma density are written for this particular case. Based on the numerical solution of these equations, steady-state distributions of plasma parameters in the formed plasma inhomogeneity are found. It is demonstrated that a plasma inhomogeneity proves to be markedly extended along the external magnetic field. It is found that, for the values of the source current that are attainable under the conditions of active ionospheric and model laboratory experiments, the maximum plasma density in a nonuniform plasma may appreciably exceed the background value.     

Cherenkov radiation waves in inhomogeneous dusty plasma

A kinetic theory is employed to study Cherenkov wave in an inhomogeneous dusty plasma. Two different frequency regimes are considered incorporating the plasma species temperatures. The dispersion relation for one-dimensional Cherenkov wave is derived and analyzed. The plasma species temperatures, their cyclotron frequencies, and the plasma density inhomogeneity effect the growth/damping of Cherenkov waves. It is shown that the plasma inhomogeneity contributes to damping of Cherenkov waves.     

热压制备(AgSbTe2)100-x-(GeTe)x合金的热电性能

以Pb粉、Te粉、Ag粉、Ge粉为原材料,在真空气氛下合成(AgSbTe₂)_100-x-(GeTe)_x (x=80---90) (TAGS)合金热电材料, X射线衍射(XRD)分析表明,热压烧结后合金具有低温菱形结构. 通过热压烧结法将TAGS粉末制备成块体材料,运用XRD和扫描电子显微镜对材料的物相成分、 晶体结构和形貌进行了表征.采用直流四探针法测定样品的电导率,当样品两端的温差为1---4℃ 的情况下测量Seebeck系数.通过材料热电性能测试,研究了30---500℃温度范围内不同组分 样品性能参数的变化.结果表明,所制备的TAGS热电材料具有纳米结构, 其性能随着组分的变化而变化, TAGS-80具有较好的热电性能,在530℃时具有最高热电优值(ZT=1.80).     

Effects of relativistic and ponderomotive nonlinearities on the interaction of high-power laser beam with an inhomogeneous warm plasma

The influence of relativistic-ponderomotive nonlinearities and the plasma inhomogeneity on the nonlinear interaction between a high-power laser beam and a warm underdense plasma are studied. It is clear that the relativistic ponderomotive force and the electron temperature modify the electron density distribution and consequently change the dielectric permittivity of the plasma. Therefore, by presenting the modified electron density and the nonlinear dielectric permittivity of the warm plasma, the electromagnetic wave equation for the propagation of intense laser beam through the plasma is derived. This nonlinear equation is numerically solved and the distributions of electromagnetic fields in the plasma, the variations of electron density, and plasma refractive index are investigated for two different background electron density profiles. The results show that the amplitude of the electric field and electron density oscillations gradually increase and decrease, during propagation in the inhomogeneous warm plasma with linear and exponential density profiles, respectively, and the distribution of electron density becomes extremely sharp in the presence of intense laser beam. It is also indicated that the electron temperature and initial electron density have an impact on the propagation of the laser beam in the plasma and change the plasma refractive index and the oscillations' amplitude and frequency. The obtained results indicate the importance of a proper choice of laser and plasma parameters on the electromagnetic field distributions, density steepening, and plasma refractive index variations in the interaction of an intense laser beam with an inhomogeneous warm plasma.     

Instability Caused by an Inhomogeneous Energy Density Distribution as a Possible Source of Electrostatic Broadband Noise

Plasma instability caused by an inhomogeneous energy density distribution is considered. It is shown that this instability can lead to the excitation of electrostatic ion-cyclotron and oblique ion-acoustic waves, generated in the presence of an inhomogeneous transverse electric field and a shear in the parallel drift velocity of the plasma particles. The considered physical mechanisms of the instability generation in plasma can serve as possible sources of broadband electrostatic turbulence in the auroral ionosphere.     

非化学计量比AgSbTe2+x化合物制备及热电性能

采用高纯元素直接熔融、淬火并结合放电等离子烧结方法制备了非化学计量比AgSbTe_2+x(x=0—0.05)系列样品,研究了不同Te含量在300—600 K范围内对样品热电性能的影响规律.结果表明:随着Te含量的增加,Ag⁺离子空位浓度增加,空穴浓度和电导率大幅度提高,Seebeck系数减小.热导率随Te过量程度的增加略有增加,但所有Te过量样品的晶格热导率均介于0.32—0.49 W/mK之间,低于化学计量比样品的值,接近理论最低晶格热导率.AgS 关键词： 2')" href="#">AgSbTe₂ 非化学计量比 热电性能 热导率     

Electric control of emergent magnonic spin current and dynamic multiferroicity in magnetic insulators at finite temperatures

Conversion of thermal energy into magnonic spin currents and/or effective electric polarization promises new device functionalities. A versatile approach is presented here for generating and controlling open circuit magnonic spin currents and an effective multiferroicity at a uniform temperature with the aid of spatially inhomogeneous, external, static electric fields. This field applied to a ferromagnetic insulator with a Dzyaloshinskii–Moriya type coupling changes locally the magnon dispersion and modifies the density of thermally excited magnons in a region of the scale of the field inhomogeneity. The resulting gradient in the magnon density can be viewed as a gradient in the effective magnon temperature. This effective thermal gradient together with local magnon dispersion result in an open-circuit, electric field controlled magnonic spin current. In fact, for a moderate variation in the external electric field the predicted magnonic spin current is on the scale of the spin (Seebeck) current generated by a comparable external temperature gradient. Analytical methods supported by full-fledge numerics confirm that both, a finite temperature and an inhomogeneous electric field are necessary for this emergent non-equilibrium phenomena. The proposal can be integrated in magnonic and multiferroic circuits, for instance to convert heat into electrically controlled pure spin current using for example nanopatterning, without the need to generate large thermal gradients on the nanoscale.     

Effect of hot-consolidation method on the superconducting properties of B- and C-doped FeSe0.5Te0.5

The effect of hot consolidation method on the microstructures and superconducting properties of FeSe_0.5Te_0.5 (+B, C) was examined. FeSe_0.5Te_0.5 (+B, C) compounds were prepared by four different hot-consolidation methods: in-situ sintering, infra-red radiation sintering, hot-pressing and spark plasma sintering. The results showed that, among the employed consolidation methods, the spark plasma sintering is the most effective processing route for enhancing the critical current density due to enhanced densification. The doping of B or C also increased the critical density of FeSe_0.5Te_0.5, in particular, for spark plasma sintered specimens, but its beneficial effect was less pronounced for the specimens prepared by the other methods.     

Transport and mechanical properties of Yb-filled skutterudites

A series of Yb-filled skutterudites were produced and powder samples consolidated using spark plasma sintering (SPS). The effect of different heating cycles on the resulting transport properties of the consolidated samples was explored. Specifically, the effect of sample uniformity on the electrical and thermal transport properties was explored. In addition to the optimal Yb-filling fraction, other factors, such as heating profiles and sintering conditions, were found to play a pivotal role in the performance of these materials. Large quantities of Yb-filled skutterudite material can be generated with high purity and uniformity. Resonant ultrasound spectroscopy was used to determine the elastic modulus and Poisson's ratio. Fracture strength was measured for 12 specimens and, taken with information obtained from resonant ultrasound spectroscopy and from thermal expansion and thermal transport characteristics, the thermal shock resistance parameter was evaluated. These parameters will be important for the engineering of thermoelectric modules based on skutterudite materials.     

Determination of elastic moduli of rock samples using resonant ultrasound spectroscopy

Resonant ultrasound spectroscopy (RUS) is a method whereby the elastic tensor of a sample is extracted from a set of measured resonance frequencies. RUS has been used successfully to determine the elastic properties of single crystals and homogeneous samples. In this paper, we study the application of RUS to macroscopic samples of mesoscopically inhomogeneous materials, specifically rock. Particular attention is paid to five issues: the scale of mesoscopic inhomogeneity, imprecision in the figure of the sample, the effects of low Q, optimizing the data sets to extract the elastic tensor reliably, and sensitivity to anisotropy. Using modeling and empirical testing, we find that many of the difficulties associated with using RUS on mesoscopically inhomogeneous materials can be mitigated through the judicious choice of sample size and sample aspect ratio.     

Some exact solutions for the classical Hall effect in an inhomogeneous magnetic field

The classical Hall effect in inhomogeneous systems is considered for the case of one-dimensional inhomogeneity. For a certain geometry of the problem and for the magnetic field linearly depending on the coordinate, the distribution of current density corresponds to the skin-effect.     

Enhanced thermoelectric performance of TiO_2-based hybrid materials by incorporating conducting polymer

In order to study the thermoelectric properties of TiO2-based hybrid materials, TiO2/polyparaphenylene(PPP)nanocomposites are fabricated by spark plasma sintering(SPS). The results show that the electrical conductivity follow percolation theory is enhanced due to the electron transfer highway provided by the conducting PPP phase. Furthermore,the thermal conductivity is reduced due to the drastic difference of vibrational spectra between organic and inorganic components. As a result, the greatest ZT= 0.24 is obtained for Ti O2/0.75 wt% PPP sample, which is 15-fold higher than pure Ti O2(ZT= 0.016).     

Synthesis and thermoelectric properties of Mn-doped AgSbTe₂ compounds

Polycrystalline p-type Ag 0.9 Sb 1.1 x Mn x Te 2.05(x = 0.05,0.10,and 0.20) compounds have been prepared by a combined process of melt-quenching and spark plasma sintering.The sample composition of Ag 0.9 Sb 1.1 x Mn x Te 2.05 has been specially designed in order to achieve the doping effect by replacing part of Sb with Mn and to present the uniformly dispersed Ag 2 Te phase in the matrix by adding insufficient Te,which is beneficial for optimizing the electrical transport properties and enhancing the phonon scattering effect.All the samples have the NaCl-type structure according to our X-ray powder diffraction analysis.After the treatment of spark plasma sintering,only the sample with x = 0.20 has a small amount of MnTe 2 impurities.The thermal analysis indicates that a tiny amount of Ag 2 Te phase exists in all these samples.The presence of the MnTe 2 impurity with high resistance and high thermal conductivity leads to the deteriorative thermoelectric performance of the sample with x = 0.20 due to the decreased electrical transport properties and the increased thermal conductivity.In contrast,the sample with x = 0.10 exhibits enhanced thermoeletric properties due to the Mn-doping effect.A dimensionless thermoelectric figure of merit of 1.2 is attained for the sample with x = 0.10 at 573 K,showing promising thermoelectric properties in the medium temperature range.     

气体火花开关初始放电等离子体演化过程北大核心CSCD

气体火花开关的初始放电过程对研究其工作状态有着非常重要的影响,通过基于网格粒子法-直接蒙特卡罗法(PIC-DSMC)耦合算法模拟了气体火花开关从放电开始到等离子体通道初步形成的完整过程,得到了电子和离子的数密度时空分布变化,分析了间隙中电场分布随时间变化规律,完整清晰地揭示了气体火花开关从放电初始到等离子体通道初步形成的物理过程,并初步开展了气体火花开关击穿过程的光学诊断实验,为进一步深入研究气体火花开关的物理机理打下了基础。     

<Emphasis Type="Italic">I–V</Emphasis> characteristics and current instability in a high-temperature superconductor with a nonuniform temperature distribution over the cross section

The effect of a nonuniform temperature distribution in the cross section of a high-temperature superconductor on the formation of its I–V characteristic and the conditions for conservation of a stable distribution of the input current are analyzed. The equations permitting us to determine the boundary values of the electric field and current above which current instability can be developed with allowance for the dimensional effect are derived. It is shown that the input current quench determining the maximal permissible value of the input current decreases if thermal inhomogeneity of electrodynamic states is taken into account in theoretical analysis of its stability conditions. It is found that the limiting admissible values of the electric field and current are nonlinear functions of the thermal resistance of the superconductor, its critical parameters, and external heat-exchange conditions. Therefore, intense cooling of the superconductor does not result in an increase in the current corresponding to the emergence of instability in proportion to the increase in its cross-sectional area or critical current density.     

制备工艺对p型碲化铋基合金热电性能的影响

利用区熔法、机械合金化、放电等离子烧结(SPS)技术、热压法等多种工艺制备了p型碲化铋基热电材料.在300—500K的温度范围内测量了各热电性能参数，包括电导率(σ)、塞贝克系数(α)和热导率(κ)，研究了制备工艺对热电性能的影响.结果表明，所制备的块体材料与同组成区熔晶体相比，性能优值ZT均有不同程度的提高.其中，利用区熔法结合SPS技术可获得热电性能最佳的块体材料，其ZT值达1.15. 关键词： 碲化铋 放电等离子烧结 区熔法 热电性能     

晶粒细化对MgB_2超导临界电流密度的作用

在多晶系统的MgB2超导体中存在晶粒间较小的整体电流和晶粒内大的局域电流.用改变升温速率的方法制备了不同晶粒大小和晶粒连接性的MgB2样品,并对它们的晶粒大小进行了统计.采用一种测量超导临界电流密度的Campbell法,分别测量和计算得到了它们的整体电流和局域电流密度.研究表明:长时间的烧结造成晶粒变大,材料有较大的整体临界电流密度,而短时间烧结的样品则相反;同时发现晶粒细化只提高了样品的局域临界电流密度,而且样品内部缺陷、杂质及晶界等因素是影响MgB2超导体整体电流传输的主要因素.