Particulate modification of lithium-ion battery anode materials and electrolytes

Lithium-ion batteries (LIBs) are considered a rechargeable and commercial energy storage device for electronic equipment such as smartphone and electric vehicles. Despite the prospective future of LIBs, unsatisfied electrochemical properties like reversible capacity, cycle ability and coulombic efficiency still hinder their development. High volume expansion rate, uncontrolled Li dendrite growth and unsatisfied solid electrolyte interphase also occur when LIBs are applied in long-time usage. Numerous modification methods such as exploring high-capacity anode/cathode materials, constructing artificial solid electrolyte interphase and improved conductive binders can be adopted to enhance the performances. Among them, particulate modification for LIBs anode and electrolytes is receiving tremendous attraction in the recent work. The method is composed of changing the morphology and particle size of the active materials, also introduce nano-size additives to the main structure. This review emphasizes on introducing and discussing the modification in following aspects: particulate modification on carbon group IVA element anodes, introduction of additives like transition metal oxide nanoparticles into anode and electrolyte materials, dissipate the influence of Li dendrite growth and ameliorate the performances of solid electrolyte interface. This review hopes to be denoted for the future development of LIBs with the comprehensive understanding on the particulate modification.     

Analysis of diffusion induced elastoplastic bending of bilayer lithium-ion battery electrodes

Bilayer electrode, composed of a current collector layer and an active material layer, has great potential in applications of in-situ electrochemical experiments due to the bending upon lithiation. This paper establishes an elastoplastic theory for the lithiation induced deformation of bilayer electrode with consideration of the plastic yield of current collector. It is found that the plastic yield of current collector reduces the restriction of current collector to an active layer, and therefore, enhances in-plane stretching while lowers down the rate of electrode bending. Key parameters that influence the elastoplastic deformation are identified. It is found that the smaller thickness ratio and lower elastic modulus ratio of current collector to an active layer would lead to an earlier plastic yield of the current collector, the larger in-plane strain, and the smaller bending curvature, due to balance between the current collector and the active layer. The smaller yield stress and plastic modulus of current collector have similar impacts on the electrode deformation.     

A two-scale manifold learning method for spatiotemporal modeling of lithium-ion battery thermal process

Nonlinear Dynamics - Thermal effect has a significant impact on the performance of lithium-ion batteries (LIBs). Therefore, an accurate and effective temperature distribution model is of great...     

Thermal and gas flow characterization of a fluxless Si solder bonding oven

In this paper the technology of the “Linn” type Si fluxless solder bonding oven and the thermal and gas flow characterization of the oven are discussed. This oven is used for fixing silicon chips on metal substrates with high temperature solder bonding process. The solder is applied in a foil form which is placed between the Si chip and the metal substrate. This does not contain any flux, therefore a reducing agent has to be applied to avoid the oxidation of the joints during the soldering process. In this technology the reducing agent is the forming gas which is a mixture of 10 vol.% H₂ and 90 vol.% N₂. The key factors of this soldering process was studied; the suitable temperature (350-370 °C for 13-15 min) and the adequate H₂ concentration (8-10 vol.%). A detailed 3D gas flow model of the Linn oven was prepared which is based on the finite volume model (FVM) method. The gas flow circumstances using the basic and a hypothetic oven setting were compared by simulations applied the ANSYS-FLUENT system. The gas flow model was verified by the measurements of the temperature, the H₂ concentration and the pressure inside the oven. Furthermore the heating ability of the oven under full load was characterized by the change of the heating temperature and the time coefficient of the heating.     

Thermal tests of a steam-turbine nozzle-chamber model

This paper describes the measurement of thermal strains and temperatures in a 0.25-scale aluminum-filled epoxy model of a double-flow large-steam-turbine nozzle chamber. A temperature gradient was induced by circulating chilled methyl alcohol through the interior. Strain gages and thermocouples were used to determine surface strains and temperatures at various locations for comparison with a finite-element analysis under development. A uniform cylinder was included on the inlet section of the model for calibration. The maximum measured tensile strain on the interior surface was 0.96 αΔT _n , where ΔT _n was the average temperature difference between the interior surface and the initial temperature. A maximum compressive strain of 0.50 αΔT _n was measured on the outside surface of the nozzle-bowl sidewall.     

Thermal post-bunkling analyses of functionally graded material rod

The non-linear governing differential equations of immovably simply supported functionally graded material (FGM) rod subjected to thermal loads were derived. The thermal post-buckling behaviors of FGM rod made of ZrO2 and Ti-6Al-4Vwere analyzed by shooting method. Firstly, the thermal post-buckling equilibrium paths of the FGM rod with different gradient index in the uniform temperature field were plotted, and compared with the behaviors of the homogeneous rods made of ZrO2 and Ti-6A1-4V materials, respectively. For given value of end rotation angles, the influence of gradient index on the thermal post-buckling behaviors of FGM rod was discussed. Secondly, the thermal post-buckling characteristics of the FGM rod were analyzed when the temperature difference parameter is changed while the bottom temperature parameter remains constant, and when the bottom temperature parameter is changed while the temperature difference parameter remains constant, and compared with the characteristics of the two homogeneous material rods.     

Clarification of the dispersion mechanism of three typical chemical dispersants in lithium-ion battery (LIB) slurry

This paper mainly clarified the dispersion mechanism of three typical chemical dispersants which are polyethylene glycol octylphenyl ether (Triton X-100, T-100), polyethylene pyrrolidone (PVP) and carboxymethyl cellulose (CMC) within lithium-ion battery (LIB) slurry. Initially, the optimum amounts of T-100, PVP and CMC are selected from 0%, 0.5%, 1.5% and 2.5% by evaluating the impedance of LIB slurry in the case of adding each typical chemical dispersant with EIS method. Moreover, the impedance spectrum of three different slurry samples which are PVDF-NMP solution, LiCoO₂ slurry and Carbon Black (CB) slurry with the optimum amount of each dispersant are also investigated. After using SEM and C element distribution images of LIB slurry to verify the correctness of the dispersion mechanism of each dispersant, it is concluded that the dispersion CMC with its optimum amount 1.5% is the best one to promote the formation of conductive paths and CB-coated LiCoO₂ network structure within LIB slurry, which has the considerably potential to improve the performance of LIB.     

Fracture-toughness tests and displacement and crack-stability analyses of tungsten round bend specimens

Plane-strain fracture-toughness tests were performed using the recently proposed round-bar bend test procedure with a liquid-phase sintered tungsten alloy. The tests included a direct comparison of fracture toughness from rectangular and round-bend specimens and measurements of load-line compliance using the unloading technique ofJ-integral fracture tests. Complementary displacement and crack-growth stability analyses of the round bar were performed as an extension of recent work in these two areas.Paper was presented at the 1990 SEM Spring Conference on Experimental Mechanics held in Albuquerque, NM.     

Continuous measurement of material damping during fatigue tests

An experimental procedure for continuously measuring strain level, temperature, and energy-dissipation rate during resonant fatigue tests is described. The technique is based on a previous method for measuring loss factor (Ref. 3) using base-excited cantilever-beam specimens vibrating at resonance. The amplitude and frequency dependence of loss factor is therefore included directly in the measurement. For beams vibrating in vacuum, energy-dissipation rate and temperature measurements provide a basis for irreversible thermodynamic analysis of fatigue. This procedure provides a continuous measurement of energy-dissipation rate during fatigue-crack nucleation, and is the basis for experimental study of the hypothesis that the entropy gained during fatigue failure is a material constant.     

Thermal analysis of an infinite tube during quenching

 This paper deals with a numerical solution of the two-dimensional convection–diffusion equation in an infinite domain, arising out of quenching of an infinite tube. On the wetted side, upstream of the quench front, a constant heat transfer coefficient is assumed. The downstream of the quench front as well as the inside surface of the tube are assumed to be adiabatic. The solution gives the quench front temperature as a function of various model parameters such as Peclet number, Biot number and the radius ratio. The solution has been found to be in good agreement with the available analytical solutions and thus validates the numerical procedure suggested. Received on 10 July 2000     

Thermal degradation of two liquid fuels and detonation tests for pulse detonation engine studies

The use of liquid fuels such as kerosene is of interest for the pulse detonation engine (PDE). Within this context, the aim of this work, which is a preliminary study, was to show the feasibility to initiate a detonation in air with liquid-fuel pyrolysis products, using energies and dimensions of test facility similars to those of PDEs. Therefore, two liquids fuels have been compared, JP10, which is a synthesis fuel generally used in the field of missile applications, and decane, which is one of the major components of standard kerosenes (F-34, Jet A1, ...). The thermal degradation of these fuels was studied with two pyrolysis processes, a batch reactor and a flow reactor. The temperatures varied from 600°C to 1,000°C and residence times for the batch reactor and the flow reactor were, respectively, between 10–30 s and 0.1–2 s. Subsequently, the detonability of synthetic gaseous mixtures, which was a schematisation of the decomposition state after the pyrolysis process, has been studied. The detonability study, regarding nitrogen dilution and equivalence ratio, was investigated in a 50 mm-diameter, 2.5 m-long detonation tube. These dimensions are compatible with applications in the aircraft industry and, more particularly, in PDEs. Therefore, JP10 and decane were compared to choose the best candidate for liquid-fuel PDE studies. This paper was based on work that was presented at the 20th International Colloquium on the Dynamics of Explosions and Reactive Systems, Montreal, Canada, July 31 – August 5, 2005.     

Field tests and theoretical analyses concerning the rolling resistance of a track-laying vehicle due to plastic deformation

Submerged vehicles, especially those with floating tanks, are subjected to rolling resistance due to soil under various vehicle operating conditions, soils, and external forces. It is desirable to obtain simple, general solutions for the peak contact pressure and rolling resistance due to plastic deformation. In this paper, these theoretical analyses for a track-laying vehicle are presented and related to tests on submerged sands.     

Measuring the stiffness of concrete shear walls during dynamic tests

Results from a series of experiments designed to measure the stiffness of low-aspect-ratio, reinforced-concrete shear walls subjected to simulated seismic inputs on a shake table are reported. The geometry of the test structures allows them to be modeled as single-degree-of-freedom systems. Forces were estimated from accelerometer measurements on masses attached to the structures. Dynamic relative-displacement measurements were obtained from groups of strain gages wired in series to act as one continuous gage. Because this method measures relative displacements, potential sources of error associated with unspecified base motion are avoided. tiffness values determined from the relative displacement measurements were compared with stiffness values determined indirectly from frequency-response functions. Measured, accelerometer data were used to calculate the frequency-response functions. The stiffness values determined from the relative-displacement measurements gave results similar to those given by mechanics-of-materials beam theory that accounts for shear deformation. The stiffness values determined from the frequency-response functions were considerably less than those from the theory.     

Thermal explosion during the flow of a viscous liquid

Frank-Kamenetskii has discussed a steady-state formulation of thermal explosions [1]. Bostandzhiyan et al. [2] and Bostandzhiyan and Chernyaeva [3] have shown, for the flow in a cylindrical tube of Newtonian and non-Newtonian liquids having a strong (nonlinear) temperature dependence of the viscosity, that a phenomenon analogous to thermal explosion may occur during the flow of a chemically inert liquid. Bostandzhiyan et al. [4] have also studied Couette flow and the flow between two rotating circular cylinders of a Newtonian liquid having the same temperature dependence for its viscosity. It was shown that, although the heat balance equation reduces to the equations of the steady-state theory of thermal explosion for the corresponding region, hydrodynamic thermal “explosion” was not observed in these cases. This phenomenon was found to be characteristic of only pressurized flows. Below, we study thermal explosions during the Poiseuille flow of a viscous, chemically reactive liquid in an infinite circular cylindrical tube, and during the motion of the liquid between infinite rotating cylinders. The combined effect of chemical and mechanical heat cources are considered. Zhurnal Prikladnoi Mekhaniki i Teknicheskoi Fiziki, Vol. 9, No. 5, pp. 38–43, 1968     

Analysis of strain localization during tensile tests by digital image correlation

This paper presents an imaging technique developed to study the strain localization phenomena that occur during the tension of thin, flat steel samples. The data are processed using digital speckle image correlation to derive the two in-plane components of the displacement vectors. The authors observe that the calculation of the intercorrelation function reveals a systematic error and propose a numerical method to limit its influence. Plastic incompressibility and thin-sheet assumptions are used to derive the third displacement component and, hence, the various strain and strain rate components. Numerous checks are presented at each step in processing the data to determine the final accuracy of the strain measurements. It is estimated that this accuracy is quite sufficient to track the inception and the development of localization. Examples of possible application are presented for mild steels whose strain localization mechanisms appear to be precocious and gradual.     

Thermal shock analyses for a strip containing an infinite row of periodically distributed cracks normal to its edge

The transient thermal stress problem of a semi-infinite plate containing an infinite row of periodically distributed cracks normal to its edge is investigated in this paper. The elastic medium is assumed to be cooled suddenly on the crack-containing edge. By the superposition principle, the formulation leads to a mixed boundary value problem, with the negating tractions arisen from the thermal stresses for a crack-free semi-infinite plate. The resulting singular integral equation is solved numerically. The effects on the stress intensity factors due to the presence of periodically distributed cracks in a semi-infinite plate are illustrated. For both the edge crack and the embedded crack arrays, the stress intensity factors increase, due to the reduction of the shielding effect, as the stacking cracks are more separated. For the case of embedded crack array, one has the further conclusion that the stress intensity factors decline as the crack array shifts from the plate edge.     

微重力池沸腾过程中的气泡热动力学特征研究

微重力池沸腾过程中的气泡热动力学特征研究项目是实践十号返回式卫星科学实验任务之一,主要关注微重力池沸腾过程中孤立生长气泡周围局部流动与传热机理.目前,实验装置SOBER-SJ10正样产品已完成研制和地面测试,并开展了一系列地面对比实验.地面实验结果表明设备工作正常,性能指标达到设计要求.地面实验结果表明过冷度对起始沸腾过热度影响甚微.空间飞行实验将于近期进行,其结果将加深对沸腾传热机理的认识.     

Thermal analysis of thin multi-layer metal films during femtosecond laser heating

Multi-layer metals films are widely used in modern engineering applications such as gold-coated metal mirrors used in high power laser systems. A transient heat flux model is derived to analyze multi-layer metal films under laser heating. The two separate system composed of electrons and the lattice is considered to take into account the electron–lattice interaction. The present model predicted the effects of underlying chromium’s thermal properties on temperature rise of the top gold layer. The effects of two adjacent and different metals with different electron–lattice coupling factors are analyzed for the heating mechanism of different lattices. The derived transient model combined with the two different conservation equations for the lattice and electrons are applied for the ultra short-pulse laser heating of a multi-layer film composed of gold and chromium.