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1.
We study topological properties of quasi-particle states in the non-Abelian quantum Hall states. We apply a skein-theoretic method to the Read-Rezayi state whose effective theory is the SU(2)K Chern-Simons theory. As a generalization of the Pfaffian (K = 2) and the Fibonacci (K = 3) anyon states, we compute the braiding matrices of quasi-particle states with arbitrary spins. Furthermore we propose a method to compute the entanglement entropy skein-theoretically. We find that the entanglement entropy has a nontrivial contribution called the topological entanglement entropy which depends on the quantum dimension of non-Abelian quasi-particle intertwining two subsystems.  相似文献   

2.
Steady-state spectroscopic studies of two ortho (-OCH3 and -OH) derivatives of methyl p-dimethylaminobenzoate have been performed. The absorption spectra of molecules under study are analyzed taking into consideration results of quantum chemical semiempirical calculations. The fluorescence spectra of these molecules possess in polar solvents two bands, i.e., the locally excited and intramolecular charge transfer (ICT) fluorescence band. Their intensity ratio as well as the fluorescence/phosphorescence intensity ratio determined at 77 K depends on the solvent polarity. Theoretical studies of the TICT phenomenon have been made in order to explain the dual emission of molecules under study. Calculated electric dipole moments of these molecules in the ground, S0, and excited, S1(LE) and S1(ICT) states, have been compared with experimentally determined data. Theoretically determined transition energies, ΔEi, oscillator strengths, fi, and electric dipole moments μS0, μS1(LE) and μS1(ICT) of the planar donor-acceptor (D/A) conformer agree with experimental data. According to Marcus theory inner- and outer-solvatation sphere reorganization energies (λout, λin) are calculated using the determined spectroscopic properties of molecules under study.  相似文献   

3.
The title subjects (in the vapor phase) were assessed to be in the weak-coupling limit as Frenkel-type excitons of a La-type excited state, by examining reported data on these systems: (1) Lb/La interconversion by dimerization (in the solution) just like what happens in the monomer by the change of solvent polarity, e.g., from 3-methylpentane to ethanol. (2) Good correspondence between the monophotonic excitation spectrum of the tautomer fluorescence (after excited-state double proton-transfer reaction of the dimer) and mass-selected (2 + 2) photoionization spectrum of the dimer, as is predicted theoretically. (3) Potential minima for locally excited configurations, as were predicted by ab initio calculations. Comments on the current controversy about the mechanism of its excited-state tautomerization, i.e., whether it is of one step or two steps, are made as well.  相似文献   

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