A dynamic study of onion phases under shear flow: size changes

It has been shown that lyotropic lamellar phases under shear flow form structures corresponding to a close packed assembly of monodisperse multilamellar vesicles (onions). The size, which is fixed by the shear rate, can vary from a few microns to a tenth of a micron. In this study, we investigate for the first time the transient behaviour of size changes of onions under shear flow by means of small angle light scattering, direct microscopic observations, and conductivity measurements. We evidence two regimes: continuous and discontinuous. The nature of which (continuous or discontinuous) depends on the initial and final shear rate, and can be described by a dynamic phase diagram. Received: 14 November 1997 / Received in final form: 2 March 1998 / Accepted: 9 March 1998     

Photo induced collisions with laser cooled He* atoms

This paper presents an experimental investigation of cold collisions between metastable helium atoms in an optical trap at 1 mK. Penning (PI) and associative (AI) ionization reactions are distinguished using a mass spectrometer and studied under influence of near resonant laser light. Dramatic enhancement, by more than a factor 15, of the ion rate is observed when the laser is tuned close to resonance. Experimental findings are well-described, on an absolute scale, by model predictions. Received: 9 February 1998 / Revised: 4 May 1998 / Accepted: 14 May 1998     

Cooperative diffusion in weakly charged polyelectrolyte gels

A general expression for the cooperative diffusion constant of weakly charged gels is derived as a function of the thermodynamic parameters such as polyelectrolyte concentration, salt concentration, ionic strength, and the degree of crosslinking. In the low concentration range it decreases with the monomer concentration. Received: 30 January 1998 / Revised: 4 May 1998 / Accepted: 6 May 1998     

Low-energy Raman-active phonons of multiwalled carbon nanotubes

Received: 8 April 1998/Accepted: 9 April 1998     

Nonadiabatic corrections to the adiabatic Efimov potential

Abstact: The composition of forward-going projectile spectator matter in fixed-target Pb+Pb collisions at 158 A · GeV at the CERN SPS has been studied as a function of centrality. The data were measured with the NA49 veto calorimeter. We observe that forward-going spectator matter in central collisions consists of 9 neutrons, 7 protons, and half a deuteron on average. At large impact parameters most spectator nucleons are bound in fragments. The relative resolution of the average impact parameter derived from the measurement of spectator neutrons is roughly 19% in the range from zero to half maximum impact parameters. Received: 16 February 1998 / Revised version: 30 March 1998     

Expansions for the eigenvalues of three-term recurrence relations. Two applications in molecular physics

Approximate expressions for the eigenvalue of a three-term recurrence relation with a general form describing various physical problems are proposed. Their range of availability is examined by comparison with exact values for two different problems: the bound and continuum states of monoelectronic diatomic ions and the Schr?dinger equation describing molecular alignment in intense laser fields. For each case, very good predictions have been obtained, which may be useful as initial values in iterative procedures for deriving exact solutions. Received: 30 January 1998 / Received in final form: 10 April 1998 / Accepted: 25 May 1998     

High-dynamic-range pulse-front steepening of amplified femtosecond pulses by third-order dispersion

Received: 9 June 1998/Revised version: 4 November 1998     

Slow positron annihilation studies of vacancy-type defects in the near-surface region of Cu and Nb before and after wear

Received: 22 June 1998 / Accepted: 9 November 1998     

Photoinduced transformations and holographic recording in nanolayered a-Se/As2S3 and AsSe/As2S3 films

Received: 13 October 1998 / Accepted: 9 December 1998 / Published online: 24 February 1999     

Stability and vibrations of catenoid-shaped smectic films

Catenoid-shaped smectic films are spanned between two coaxial circular frames separated by a distance H. It is shown that there exists a critical height H^* such that below it two shapes of the catenoid are possible. The stability of these two shapes is analysed in terms of their vibrations. The spectrum of eigenfrequencies is calculated as a function of the catenoid height. It is shown that the frequency of the fundamental mode is real for the stable shape and imaginary for the other shape. Experimental study of vibrational eigenmodes performed on stable SCE4 films confirms this theoretical prediction. Received: 25 November 1997 / Received in final form: 30 January 1998 / Accepted: 9 March 1998     

Electron angular distributions in double photoionization: Use of effective Sommerfeld parameters

We present calculations of the fivefold differential cross-section (FDCS) for double photoionization of helium at excess energies of 6 and 20 eV above threshold. Our results are obtained using for the final double-continuum state a product of three Coulomb wave functions, with the Sommerfeld parameters modified to describe the strength of interaction of any two particles affected by the third particle. Our calculations are compared with recent absolute measurements by D?rner et al. (Phys. Rev. A 57, 1074 (1998)), both in coplanar and non-coplanar geometries. Very good agreement is obtained for the shape of the angular distributions, and differences in the absolute magnitude exist in comparison with the standard choice of Sommerfeld parameters. Received: 17 July 1998 / Received in final form and Accepted: 23 October 1998     

Optical properties of gold metal clusters: A time-dependent local-density-approximation investigation

The optical response of free and matrix-embedded gold metal clusters Au_N is investigated in the framework of the time-dependent local-density-approximation (TDLDA). The characteristics of the surface plasmon resonance are carefully analyzed as a function of the model parameters and the particle radius. The strong influence of the frequency-dependence of the 5d core-electron dielectric function in the vicinity of the interband threshold is emphasized. The size evolution of the Mie-frequency in free gold clusters exhibits a noticeable blue-shift trend as the particle size decreases, much stronger than in silver clusters. The width and shape of the resonance, essentially ruled by the decay via the interband transitions, are found closely correlated to the imaginary component of the core-electron dielectric function. In presence of a surrounding matrix the blue-shift trend is largely rubbed out. Agreement with recent experimental results on size-selected gold clusters embedded in an alumina matrix may be achieved by taking into account the porosity effects at the metal/matrix interface. The comparison with the predictions of classical models is also provided. Received: 9 March 1998 / Revised: 5 June 1998 / Accepted: 3 July 1998     

Structural properties of junctions between two carbon nanotubes

Received: 9 November 1998 / Accepted: 25 November 1998     

A new stable organic metal: -(BETS)C(CN). The first -type radical cation salt with a planar-triangular discrete organic anion

The -(BETS)₂C(CN)₃ radical cation salt was prepared by electrocrystallization, and its crystal structure was determined by single crystal X-ray diffraction. The electronic structure of -(BETS)₂C(CN)₃ was studied by means of the extended Hückel tight binding method. The electrical conductivity of this salt as a function of temperature shows a metallic behaviour down to 1.3 K. Shubnikov-de Haas oscillations reveal both the classical and magnetic breakdown orbits on the Fermi surface typical of the -type organic conductors. In addition, a low frequency oscillation (250 T) which is not predicted by the band structure calculations has been found in the oscillation spectrum. Received: 11 March 1998 / Revised: 9 June 1998 / Accepted: 11 June 1998     

Phase properties of a Jaynes-Cummings model with Stark shift and Kerr medium

Phase properties of the field interacting with a two-level atom in a lossless cavity Jaynes-Cummings model, taking into account the level shifts produced by Stark effect with an additional Kerr medium for one-mode are studied using the phase formalism of Pegg and Barnett. It is shown in particular that phase properties of the field reflect the collapse and revival phenomena. The results for the time evolution of the phase probability distribution and the phase fluctuations are obtained. The effect of Stark shift on the phase properties in both the absence and presence of a Kerr medium is analyzed. Phase localization is found for certain choice of the parameters. Received: 27 March 1998 / Revised: 8 June 1998 / Accepted: 9 June 1998     

Microdeposition of metal and oxide structures using ultrashort laser pulses

2 O₃ on glass and silicon substrates is performed. The superior quality of the results allows the direct, one-step fabrication of binary-amplitude and multilevel optical diffractive structures. Received: 4 February 1998/Accepted: 9 February 1998     

On the impeded growth of oxide films on Si in N2O ambient

Growth kinetics of thin oxide films on silicon in nitrous oxide were investigated in the very early stage of the process. It was found that the resistance to oxidation reaches an almost stationary value for about 10 s at 1100 °C. The observation is explained by the incorporation of nitrogen atoms at the interface in the film, which impede the further growth. Received: 24 September 1998 / Accepted: 9 December 1998 / Published online: 24 March 1999     

Saturation spectroscopy of the A-X transition of the ICl molecule

We describe the first saturation spectroscopy experiment concerning the A-X transition of ICl with considerably better resolution than previous works. Form our data, improved constants for the hyperfine structure of the excited state are determined. The A-X transition of ICl could be used to develop a set of secondary frequency standards and its metrologic qualities are discussed. Received: 27 July 1998 / Received in final form: 30 November 1998     

”Direct” causal cascade in the stock market

We use wavelets to decompose the volatility (standard deviation) of intraday (S&P500) return data across scales. We show that when investigating two-point correlation functions of the volatility logarithms across different time scales, one reveals the existence of a causal information cascade from large scales (i.e. small frequencies) to fine scales. We quantify and visualize the information flux across scales. We provide a possible interpretation of our findings in terms of market dynamics. Received: 9 January 1998 / Received in final form and accepted: 13 January 1998