Collision between an ethanol drop and a water drop

The collision between a water drop and an ethanol drop was studied. In a binary collision between unlike miscible drops with a large surface tension difference, an unbalanced-surface-force (USF) deformation on the drop of larger surface tension, i.e., the water drop, occurs during the first stage of the collision. This deformation may squeeze out small satellites from the water drop at low-impact-parameter collisions or split the water drop at high-impact-parameter collisions. The later stages of the collision behavior, namely, coalescence and separation, resemble those of the drops of the smaller surface tension, i.e., the ethanol drop.     

Particle-induced bridging in immiscible polymer blends

Pickering emulsions are emulsions whose drops are stabilized against coalescence by particles adsorbed at their interface. Recent research on oil/water/particle systems shows that particles can sometimes adsorb at two oil/water interfaces. Such “bridging particles” can glue together drops of oil in water or vice versa. We hypothesize that the same effect should apply in immiscible polymer blends with droplet-matrix morphologies, viz., added particles should glue together drops and give rise to particle-bridged drop clusters. We test this hypothesis in PIB-in-PDMS blends [PIB, poly(isobutylene); PDMS, poly(dimethylsiloxane)] with fumed silica particles. Direct visualization shows that the particles can indeed induce clustering of the drops, and the blends appear to show gel-like behavior. Such gel-like behavior is confirmed by dynamic oscillatory experiments. However, we are unable to conclusively attribute the gel-like behavior to droplet clustering: Association of the fumed silica particles in the bulk, which itself causes gel-like behavior, confounds the results and prevents clear analysis of the gluing effect of the particles. We conclude that PIB/PDMS/fumed silica is not a good model system, for studying particle-containing polymer blends. We instead propose that spherical monodisperse silica particles can offer a far more convenient model system, and provide direct visual evidence of gluing of PIB drops in a PDMS matrix.     

Techniques for generating centimetric drops in microgravity and application to cavitation studies

This paper describes the techniques and physical parameters used to produce stable centimetric water drops in microgravity, and to study single cavitation bubbles inside such drops (Parabolic Flight Campaigns, European Space Agency ESA). While the main scientific results have been presented in a previous paper, we shall herein provide the necessary technical background, with potential applications to other experiments. First, we present an original method to produce and capture large stable drops in microgravity. This technique succeeded in generating quasi-spherical water drops with volumes up to 8 ml, despite the residual g-jitter. We find that the equilibrium of the drops is essentially dictated by the ratio between the drop volume and the contact surface used to capture the drop, and formulate a simple stability criterion. In a second part, we present a setup for creating and studying single cavitation bubbles inside those drops. In addition, we analyze the influence of the bubble size and position on the drop behaviour after collapse, i.e., jets and surface perturbations.     

Direct numerical simulation of water droplet coalescence in the oil

Coalescence of two water droplets in the oil was simulated using Computational Fluid Dynamics (CFD) techniques. The finite volume numerical method was applied to solve the Navier–Stokes equations in conjunction with the Volume of Fluid (VOF) approach for interface tracking. The effects of some parameters consisting of the collision velocity, off-center collision parameter, oil viscosity and water–oil interfacial tension on the coalescence time were investigated. The simulation results were validated against the experimental data available in the literature. The results revealed that quicker coalescence could be achieved if the head-on collisions occur or the droplets approach each other with a high velocity. In addition, low oil viscosities or large water–oil interfacial tensions cause less coalescence time. Moreover, a correlation was developed to predict coalescence efficiency as a function of the mentioned parameters.     

Hydrodynamics of contact of a falling drop with a liquid free surface

A fine structure of the flows developing during primary contact of freely falling drops with a deep quiescent fluid is studied using the macrophotography and high-speed video filming methods. Water drops falling in water, alcohol, and oil, as well as drops of oil, petroleum, and aqueous solutions of salt or alcohol falling in water are investigated. The work is focused on the visualization of the finespray scattering from the primary contact area. The collisions of small droplets with the surface of the submerging drop are first recorded. The direction of the spray and streamer scattering is determined by the surface tension coefficients of the coalescing liquids. The conditions under which the spray droplets collide with the drop surface are determined.     

Flow of oil–water emulsions through a constricted capillary

The flow of oil-in-water emulsions through quartz micro-capillary tubes was analyzed experimentally. The capillaries were used as models of connecting pore-throats between adjacent pore body pairs in high-permeability media. Pressure drop between the inlet and outlet ends of the capillary was recorded as a function of time, for several values of the volumetric flow rate. Several distinct emulsions were prepared using synthetic oils in deionized water, stabilized by a surfactant (Triton X-100). Two oils of different viscosity values were used to prepare the emulsions, while two distinct drop size distributions were obtained by varying the mixing procedure. The average oil drop size varied from smaller to larger than the neck radius. The results are presented in terms of the extra-pressure drop due to the presence of the dispersed phase, i.e. the difference between the measured pressure drop and the one necessary to drive the continuous phase alone at the same flow rate. For emulsions with drops smaller than the capillary throat diameter, the extra-pressure drop does not vary with capillary number and it is a function of the viscosity ratio, dispersed phase concentration and drop size distribution. For emulsions with drops larger than the constriction, the large oil drops may partially block the capillary, leading to a high extra pressure difference at low capillary numbers. Changes in the local fluid mobility by means of pore-throat blockage may help to explain the additional oil recovery observed in laboratory experiments and the sparse data on field trials.     

Effects of gas and droplet characteristics on drop-drop collision outcome regimes

Droplet-droplet collisions occur in many spray systems. The collision of two spherical droplets in a gas is considered in terms of the five primary phenomenological outcomes: slow coalescence (SC), bounce (B), fast coalescence (FC), reflexive separation (RS), and stretching separation (SS). The boundaries that separate these outcomes were investigated herein in terms of droplet viscosity and surface tension as well as gas pressure and density. Gas effects are not accounted for previous models, but can be important for hydrocarbon drops in pressurized sprays associated with many fuel systems. Based on a comprehensive review of available drop-drop collision data, phenomenological models were proposed herein for a wide variety of test conditions. For slow coalescence/bouncing (SC/B), increasing droplet viscosity and gas pressure were found to increase the probability of a bouncing outcome of the collision. For the B/FC boundary, increasing droplet viscosity and gas density were also found to increase bouncing probability. In both cases, the variations can be explained in terms of the stability of the gas layer that develops between the droplets. Additionally, the Brazier-Smith model for the FC/SS boundary was modified to increase robustness for a wide range of droplet viscosities. In general, the present models reasonably predicted collision outcomes for a large variety of gas pressures and densities as well as droplet viscosities and surface tensions. These are also the first models to include gas effects and the first models of the SC/B boundary. However, the droplet diameters of the data set were limited in range from 200 to 400 microns. Significantly larger droplet collisions may include effects on initial non-sphericity while significantly smaller drop collisions may include effects on non-continuum flow and gas viscosity.     

Interface stabilization in two-layer channel flow by surface heating or cooling

The linear stability of plane Poiseuille flow of two immiscible Newtonian liquids in a differentially heated channel is considered. The equations of motion and energy are fully coupled via temperature-dependent fluid-viscosity coefficients. A long-wave asymptotic formulation of the stability problem is presented together with numerical results for disturbances of arbitrary wavelength. Two combinations of immiscible liquids are analyzed: silicone/water and oil/water (water at the bottom layer in both cases). It is shown that an imposed wall temperature difference can be stabilizing or destabilizing depending on the disturbance wavenumber and layer thickness ratio. Interfacial tension has a stabilizing effect on the interface. Stabilizing influence of interfacial tension is observed at intermediate and large wavenumbers. Most importantly, for certain ranges of the controlling dimensionless parameters, stable interfaces at all disturbance wavelengths can be attained.     

Effect of impingement angle on the outcome of single water drop impact onto a plane water surface

Experiments of single water drop impact onto a plane water surface were carried out to investigate the effect of impingement angle on the total mass of secondary drops produced during the collision. When the impingement angle (the angle between the velocity vector of primary drop and the normal vector to water surface) was less than 50°, an increase in the impingement angle led to a remarkable increase in the total mass of secondary drops; this could be attributed to a significant increase in the secondary drop size. However, no secondary drop was observed within the experimental ranges tested when the impingement angle exceeded 70°.     

Hydrodynamics of a submerging drop: Lined structures on the crown surface

Macrophotography and high-speed videofilming are used to investigate the material transfer in a falling drop upon collision with the surface of a fluid at rest. In the experiments the drops of colored water, milk, mineral oil, and seed oil fell in pure or colored water. Emphasis was placed on recording the pattern of the drop material spreading over the surface of the receiving fluid. On the continuous surface of the primary cavity and the crown the drop material is concentrated in the form of thin fibers which form a regular streaky or netlike pattern in which triangular, quadrangular, and pentagonal cells are expressed. The cell rows are ordered in the form of layers on the lateral walls and the bottom of the cavity. The fiber dimensions and the degree of their expressiveness vary in the process of flow evolution. The upper row of structures on the crown surface is formed by vertical fibers.     

Diffusion effects on the interfacial tension of immiscible polymer blends

Most methods of measuring the interfacial tension between two immiscible polymers are based on the analysis of the shape that a drop of one polymer immersed in the other one exhibits under the action of flow or gravity. In such a situation, the small, yet nonzero mutual solubility between the two polymers acts toward mass transfer between the drop and the surrounding fluid. In this work, diffusion effects on the interfacial tension of the pair polyisobutylene/polydimethylsiloxane have been investigated by drop deformation under shear flow. When the drop was made of polyisobutylene, drop size decreased with time due to diffusion. Drop shrinkage was associated with a significant increase in interfacial tension, until an apparent plateau value was reached. The effect was attributed to a selective migration of molecular weights, which would act to enrich the drop with higher molar mass material. To support such an interpretation, drop viscosity was evaluated by drop shape analysis and it was actually found to increase with time. In some cases, the ratio between drop and continuous phase viscosity became higher than the critical value for drop breakup in shear flow. Upon inverting the phases (i.e., when the drop was made of polydimethylsiloxane), no significant transient effects were observed. In the light of these results, the problem of what are the correct values of interfacial tension and viscosity ratio for a polymer blend of a certain composition will also be discussed. Received: 25 January 1999 Accepted: 24 May 1999     

Coalescence of oil drops on the skeleton of a porous medium in filtering a water-oil mixture

Two mathematical models of filtration coalescence of oil drops when a water-oil mixture moves through a porous material are proposed. In the first model, coalescence is interpreted as the process of sorption, i.e., the accumulation of the oil phase on the pore surface up to a definite critical value above which the larger drops involved by a filtration flow stall. The second model assumes that the motion of the sorbed oil and the entire mixture obeys the generalized Darcy laws. Lavrent'ev Institute of Hydrodynamics, Siberian Division, Russian Academy of Sciences, Novosibirsk 630090. Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 39, No. 6, pp. 118–124, November–December, 1998.     

穿透现象和液滴形状的关系

拍摄了下落水滴周期性形变的照片，穿透现象（指水滴和水面碰撞后变成环状，穿入水中，直到池底）是在水滴为扁椭球形状或接近扁椭球形状时和水面碰撞发生的．表面张力是改变水滴形状的手段     

Investigation of binary drop rebound and coalescence in liquids using dual-field PIV technique

Experiments on binary drop collisions within an index-matched liquid were conducted for Weber numbers (We) in the range of 1–50. Drop pairs of water/glycerin mixture were injected horizontally into silicone oil and, due to gravitational effects, travelled on downward trajectories before colliding. A dual-field high-speed PIV measurement system was employed to quantify drop trajectories and overall collision conditions while simultaneously examining detailed velocity fields at the collision interface. Sequences of velocity and vorticity fields were computed for both larger and smaller fields of view. In the We range examined, both rebounding and coalescing behavior occurred. Coalescence was found to result from a combination of vortical flow within drops and strong drop deformation characteristic of higher We. Flow through the centers of opposing ring vortices, strengthened by drop deformation, enhanced drainage of the thin film in the impact region, leading to film rupture and coalescence. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Jet pinch-off and drop formation in immiscible liquid–liquid systems

The behavior of glycerin–water jets flowing into immiscible ambients of Dow Corning 200 fluid was investigated using laser induced fluorescence (LIF). Undistorted images were obtained by matching the index of refraction of the fluids. A sinusoidal perturbation was superposed on the flow to phase lock the drop formation. The forcing frequency dramatically affected the size, spacing, and number of drops that formed within a forcing cycle and the angle between drops and the jet interface just before pinch-off. Two fluid combinations were studied with similar density ratios, but viscosity ratios differing by a factor of 20. The viscosity ratio affected the jet stability as well as pinch-off angles and drop size. Received: 28 January 1999/Accepted: 20 January 2000     

The nonlinear interaction of vortex rings with a free surface

Nonlinear interactions of vortex rings with a free surface are considered in an incompressible, ideal fluid using the vortex contour dynamics technique and the boundary integral equation method. The flow is axisymmetric and the vorticity is linearly distributed in the vortex. Effects of the gravity and the surface tension as well as the initial geometric parameter of the vortex on the interaction process are investigated in considerable detail. The interaction process may be divided into three major stages: the vortex free-traveling stage, the collision stage, and the vortex stretching and rebounding stage. Time evolutions of both the vortex and free surface under various conditions are provided and analyzed. Two kinds of waves exist on the free surface during interaction. In a special case where the gravity and surface tension are very weak or the vortex is very strong, an electric-bulb-like ‘cavity’ is formed on the free surface and the vortex is trapped in the ‘cavity’ for quite a long time, resulting in a large amount of fluid above the mean fluid surface. The project supported by the National Education Commission of China and NASA under cooperative grant agreement # NCC5-34     

Numerical Investigation of the Coalescence of Viscous-Liquid Drops

The coalescence of two identical viscous-liquid drops in weightlessness under the action of surface tension is considered. Inside the drops, the flow is described by the Navier-Stokes and Poisson (for the pressure) equations. On the liquid free surface in contact with the medium at rest, the dynamic and kinematic conditions are used. The problem is solved by a finite-difference method. The coalescence of the drops and the subsequent oscillations of the resultant drop are investigated. The results are compared with the known data.     

The fate of soluble and insoluble surfactant monolayers subjected to drop impacts

Surfactant monolayers were formed on a water surface and subjected to water drops falling from a nozzle. Surface tension was measured during these experiments to determine the effect of the drop impacts on the surfactant monolayer. The purpose of this work was to determine whether monolayers can be altered by drop impacts without the formation of a splash. Accordingly, a small fall height was used to avoid drop splashes and concomitant surfactant loss by droplet ejection. The relevance of this work pertains to the fate of surfactant monolayers during rain events. Results are presented for a soluble and insoluble surfactant. The results show that the insoluble monolayer is virtually unaffected by the drops, indicating that the monolayer immediately reforms after the drop impact. The soluble monolayer shows significant changes in measured surface tension during droplet impact when the surfactant concentration is high.     

Studying heat exchange of dispersion-drop gas-liquid flow in granular layer

Conclusions Experimental procedure has been developed for physical modeling of monopropellant decomposition in a catalytic packet upon limiting stage of the process, i.e., during evaporation of a liquid in drop conditions. Heat exchange of liquid drops in a catalyst layer heated to high temperatures has been analyzed. Experimental dependence of a volume heat transfer coefficient on grain diameter, liquid flow rate and catalyst material has been obtained. It has been shown that within parameter variations this coefficient is practically independent of the gas velocity and drop diameter. Evaporation mechanism of drops in a heated granular layer has been discussed and carried out. For a more comprehensive examination of the interaction mechanism between the drops and the catalyst layer, a further experimental investigation is necessary in a wider range of change of the basic parameters of the process and use of mathematical modeling in analyzing experimental data. Novosibirsk. Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, No. 4, pp. 118–123, July–August, 1994.     

水击谐波流场中乳化油液滴粒径的PIV测量

为了掌握乳化油液滴在水击谐波流场中的碰撞、破裂、聚集和变形等微观形态的变化规律,采用粒子图像测速(PIV)技术对水平方管中乳化油液滴的水击谐波流场进行了测量,分析了在水击谐波流场中,不同激振力作用下乳化油液滴的粒径变化。测量结果表明,在水击谐波流场作用下,乳化油液滴平均粒径的增长率随着激振力的减小而减小,随着作用时间的增大呈增加趋势,直至粒径处于一种动态平衡;乳化液滴随着激振力增大到达波节聚集位置的时间减少,可见增大水击谐波激振力有利于乳化液滴的聚集并合并为大尺度的液滴,从而有效地提高了水击谐波流场作用下的油水分离效果。