Transient shear flow properties of fiber-filled polyethylene melts

The growth and relaxation of shear and normal stresses have been investigated for glass and carbon fiber-filled polyethylene melts over a wide range of shear rates and temperatures by means of a cone-and-plate rheogoniometer. Flow parameters and flow curves characterizing the stress overshoot and relaxation phenomena of the fiber-filled systems were determined experimentally. The influence of fiber loading, fiber size and temperature on the transient flow parameters are discussed.Predictions by the Meister and Bogue constitutive equations were compared with the experimental data for the transient shear and normal stresses. These equations predict satisfactorily the non-linear transient shear flow of polymer melts and its fiber-filled systems.     

Elongational properties and molecular structure of polyethylene melts

Summary The viscosity and the recoverable strain in the steady state of elongation have been measured on several polyethylenes of different molecular structures. The elongational viscosity as a function of tensile stress runs through a more or less pronounced maximum in the nonlinear range whereas in the linear range the Trouton viscosity is reached. For low density polyethylenes it could be demonstrated that the maximum of the steady-state elongational viscosity and the elasticity expressed by the steady-state compliances in shear and tension sensitively increase if the molecular weight distribution is broadened by the addition of high molecular weight components. A variation of the weight average molecular weight does only shift the elongational viscosity curve but leaves its shape unchanged. Two of the four high density polyethylenes investigated do not show a maximum of the steady-state elongational viscosity, for the others it is less pronounced than in the case of low density polyethylenes. The influence of branching on the elongational behaviour of polyethylene melts in the steady-state and the transient region is qualitatively discussed.With 11 figures and 4 tables     

Die swell of filled polymer melts

The Barus effect in polypropylene and polystyrene blended with a variety of fillers at various concentrations was investigated using a capillary extrusion rheometer. If the die swell is defined as the square of the ratio of the extrudate diameterd to the die diameterD, it is found to depend on the apparent shear stress _W . Below a certain value of _w the relation =B _B ^A applies. The die swell, _M , of a filled polymer depends on the type, size and volume fraction of the filler. In particular,A increases as the volume fraction increases and is largest for powders, smaller for flakes and smallest for fibres, whereasB shows the opposite trend but to a lesser extent.     

Some correlations involving the shear viscosity of polystyrene melts

Based upon a compilation of steady-shear and dynamic-shear viscosity data from the literature for polystyrene melts, an assessment has been made concerning the relative merits of the Cross and Carreau models in describing the shear-rate dependence of such viscosities. It is shown that the Cross model is decidedly more appropriate for PS of BMWD. Based upon master plots, it is demonstrated that the Cox-Merz relation applies to PS of both BMWD and NMWD. It is also shown that the Cox-Merz relation applies even into the second-Newtonian regime, with being independent ofM _w and MWD. In addition, the applicability of the Prest-Porter-O'Reilly relationship between shear viscosity and recoverable shear compliance is corroborated in the case of PS of NMWD.     

Ti-6Al-4V在高应变率下的动态剪切特性及失效机理

采用基于霍普金森压杆的新型加载技术对Ti-6Al-4V材料的动态剪切特性及失效机理进行了测试研究。获得了Ti-6Al-4V材料在超过10⁴ s^-1应变率下的剪应力-剪应变曲线及失效参数。研究发现,材料的流动应力存在明显的应变率强化效应;随着应变率的增加,材料的失效应力逐渐增大,而失效应变逐渐减小。采用ABAQUS/Explicit对加载过程进行了数值模拟。结果显示,剪切区材料基本处于平面剪切状态,应力应变场分布较为均匀,计算得到的剪应力-剪应变曲线与实验结果吻合较好。经断口分析可知,随着应变率的升高,Ti-6Al-4V的失效机理存在由韧窝、拉伸韧窝至台阶及河流花样的演化过程,材料的失效模式主要表现为韧性断裂。

     

Use of a sliding plate rheometer to measure the first normal stress difference at high shear rates

The use of a sliding plate rheometer (SPR) to determine the first normal stress difference of molten polymers and elastomers at high shear rates is demonstrated. The simple shear flow in this instrument is not subject to the flow instabilities that limit the use of rotational rheometers to shear rates often below 1 s⁻¹. However, issues of secondary flow and wall slip must be addressed to obtain reliable data using an SPR. A highly entangled, monodisperse polybutadiene and a commercial polystyrene were the polymers studied. The inclusion of the polystyrene made it possible to compare data with those obtained by Lodge using a stressmeter, which is an instrument based on the measurement of the hole pressure. The data from the two instruments are in good agreement and are also close to the predictions of an empirical equation of Laun based on the storage and loss moduli.     

Elastic properties of a dilute surfactant solution in the shear induced state

The first normal stress differences N ₁ of a highly dilute cationic surfactant solution are investigated in a cone-and-plate rheometer. In continuation of a previous paper (Nowak 1998), where the buildup of a shear induced structure in such a solution was attained after a reduced deformation, the N ₁ turned out to be in proportion to the square of the shear rate γ˙ reduced by a critical value γ˙ _c in a first range above γ˙ _c . At higher shear rates the N ₁ tend to lower values than predicted by this relation. Relaxation experiments were performed in the same geometry to determine the characteristic time scales of the shear induced state's decay. In the lower range above &γdot; _c the stress decay is a monoexponential process, while a second time constant has to be introduced to describe the relaxation in that range, where the N ₁ deviate from the parabolic dependence of the reduced shear rate. Received: 10 May 1999 Accepted: 15 November 2000     

A comparative study of the thermotropic mesomorphic tendencies and rheological characteristics of three cellulose derivates: Ethylene and propylene oxide ethers and an acetate butyrate ester

Samples of cellulose acetate butyrate (CAB) hydroxypropyl cellulose (HPC) and ethyl cellulose (EC) are contrasted with commercial (atactic) polystyrene (PS) and isotactic polypropylene (PP) in studies of (i) differential scanning calorimetry, (ii) quiescent polarized light microscopy (iii) optical retardation variation following an imposed stress field. It is concluced that HPC and EC are thermotropic liquid crystals, while CAB behaves in a manner similar to a vitrifying isotropic melt such as PS. Studies of the shear viscosity and dynamic viscosity indicate HPC and EC exhibit yield values while CAB shows a zero shear viscosity and Vinogradov-Malkin reduced viscosity curve identical to PS. The normal stress and extrudate swell behavior of CAB are also similar to PS. The HPC and EC exhibit substantially reduced extrudate swell. Measurement of the principal normal stress difference behavior of the HPC melt is troubled by the existence of yield values.     

Phenomena of high polymer solutions while flowing through capillaries at high rates of shear

Generally solutions of high polymers show a shear-rate dependent flow behaviour and so the properties of these fluids have to be measured under conditions of shear corresponding to the practical service. Capillary viscometry is suitable for achieving high rates of shear but relaxation phenomena can effect the results, which is proved experimentally. The flow behaviour of a lubricant blended with a high polymer additive is measured and a graphical representation of the dependence of flow behaviour on temperature and rate of shear is recommended.     

Modeling spurt and stress oscillations in flows of molten polymers

The paper presents an approach for modeling polymer flows with non-slip, slip and changing non-slip — slip boundary conditions at the wall. The model consists of a viscoelastic constitutive equation for polymer flows in the bulk, prediction of the transition from non-slip to sliding boundary conditions, a wall slip model, and a model for the compressibility effects in capillary polymer flows. The bulk viscoelastic constitutive equation contains a hardening parameter which is solely determined by the polymer molecular characteristics. It delimits the conditions for the onset of solid, rubber-like behavior. The non-monotone wall slip model introduced for polymer melts, modifies a slip model derived from a simple stochastic model of interface molecular dynamics for cross-linked elastomers. The predictions for the onset of spurt, as well as the numerical simulations of hysteresis, spurt, and stress oscillations are demonstrated. They are also compared with available data for a high molecular weight, narrow distributed polyisoprene. By using this model beyond the critical conditions, many of the qualitative features of the spurt and oscillations observed in capillary and Couette flows of molten polymers, are described.Notations upper convected derivative of elastic strain tensor - f, f_m, f_min dimensionless (sliding) shear friction characteristics, and its maximum and minimum - G Hookean elastic modulus - G_p plateau modulus - G, G storage and loss moduli - I₁, I₂ first and second invariant of strain tensor - I₁, I₀ capillary and barrel lengths - M non-dimensional mass flow rate - M_C critical molecular weight - M^*, M_e molecular weights of a statistical segment, and of polymer chain between entanglements - M_n, M_W number average and weight average molecular weights - m, k two fitting parameters of slip model - _s , _s ^o nominal and characteristic sliding velocities - u non-dimensional sliding velocity - u _sc initial (infinitesimal) slip velocity - u ₁ upper limit of u on the lower branch - u ₂ lower limit of u on the upper branch - u _max value of u corresponding to f_min - u _min value of u corresponding to f_max - U piston speed - Q nominal volumetric flow rate - q non-dimensional volumetric flow rate - R, R_o capillary and barrel radii - M non-dimensional mass flow rate     

不同剪切率来流作用下柔性圆柱涡激振动数值模拟

采用浸入边界法对细长柔性圆柱在线性剪切流条件下的涡激振动进行三维数值模拟。细长柔性圆柱振动采用三维索模型模拟,其两端铰接,质量比为6,长细比为50,无量纲顶张力为496。来流为线性剪切流,剪切率从0到0.024变化,最大雷诺数为250。研究发现:剪切流作用下柔性立管横流向振动表现为驻波模式,而顺流向振动表现为行波-驻波混合模式。随着剪切率增大,振动频谱呈现多频响应,振动能量逐渐向低频转移。阻力系数平均值随着展向变化,脉动阻力系数和升力系数的均方根值均表现为“双峰”模式。流固能量传递系数沿立管轴向的分布表明,振动激励区集中于高流速区,而振动阻尼区多位于低流速区。剪切率较小时,圆柱的泻涡为平行交叉模式;剪切率较大时,圆柱的泻涡为倾斜泻涡模式,且由于泻涡频率沿立管轴向变化,尾流发生涡裂现象,形成泻涡频率不同的胞格结构。      

确定材料在高温高应变率下动态性能的Hopkinson杆系统

描述了一种利用Hopkinson杆装置确定在高温（温度可高达1 173 K）、高应变率下材料动态性能的试验方法。在试样加温过程中,试样不与入射杆及透射杆接触。当试样加热到预定温度时,气压驱动同步组装系统,推动透射杆及试样,使得应力波到达入射杆与试样接触面时,入射杆、试样及透射杆紧密接触。利用以上系统,完成了连铸单晶铜及上引法连铸多晶铜从室温到1 085 K范围内的应力应变曲线。测试结果表明,不论是上引法连铸多晶铜还是连铸单晶铜,流动应力随温度的升高而下降,在温度低于585 K时,材料的应变硬化率明显大于在温度高于585 K时的应变硬化率。     

高温高应变率下异种不锈钢激光焊接件的力学性能

利用改进的SHTB实验设备,对316L和304不锈钢焊接结构的动态力学性能进行了实验.提出了一种适用于焊接结构件的新型的SHTB夹持装置,并在应变率约103 s-1、温度为25～500℃的环境下获得了焊接结构件动态应力-应变曲线.研究表明:随应变率的升高,结构件的屈服强度和抗拉强度随应变率的增大而增大,随温度的升高而降...     

Shear softening and thixotropic properties of wheat flour doughs in dynamic testing at high shear strain

Shear softening and thixotropic properties of wheat flour doughs are demonstrated in dynamic testing with a constant stress rheometer. This behaviour appears beyond the strictly linear domain (strain amplitude ₀ 0.2%),G,G and |^*| decreasing with ₀, the strain response to a sine stress wave yet retaining a sinusoidal shape. It is also shown thatG recovers progressively in function of rest time. In this domain, as well as in the strictly linear domain, the Cox-Merz rule did not apply but() and | ^*())| may be superimposed by using a shift factor, its value decreasing in the former domain when ₀ increases. Beyond a strain amplitude of about 10–20%, the strain response is progressively distorted and the shear softening effects become irreversible following rest.     

Asymptotics of stresses and strain rates near the tip of a transverse shear crack in a material whose behavior is described by a fractional-linear law

An approximate solution of the problem of determining the fields of stresses and strain rates due to creep near the tip of a transverse shear crack in a material whose behavior is described by a fractional-linear law of the theory of steady-state creep is given. It is shown that the strain rates have a singularity of the type ∼ r^−α near the crack tip; the order of singularity α changes discretely, depending on the polar angle, and takes the values 1, 2/3, and 1/2. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 50, No. 1, pp. 165–176, January–February, 2009.     

单向恒定侧压下混凝土动态抗压特性试验研究

利用大连理工大学自行研制、改造的大型液压伺服混凝土静动三轴试验系统对立方体试件进行一向恒定侧压的动态压缩试验。完成了四个侧向恒定压力等级的试验,应变速率变化范围为10-5~10-2 s-1。探讨了不同应变速率以及不同恒定侧压条件下混凝土强度与变形的变化规律。以试验数据为基础,在八面体应力空间中建立了适用于单向恒定侧压条件下混凝土双轴动态破坏的强度公式,为大坝、海上采油平台等大型混凝土结构的抗震安全分析提供了参考。     

碳纤维增韧的陶瓷基复合材料在高温高应变率下的压缩力学行为

利用高温电子万能试验机和具有高温同步自组装功能的Hopkinson压杆对二维C/SiC复合材料进行了应变率为10-4~103s-1,温度为293~1273K下的单轴压缩力学性能测试。实验结果表明:二维C/SiC复合材料破坏时并未表现出典型的脆性破坏,而是在应力达到压缩强度时出现了显著的应变软化,在经历了较大的变形后才最终破坏,同时材料还表现出良好的高温承载能力及一定的温度和应变率依赖性。随着温度的升高,复合材料的压缩强度呈降低的趋势。与准静态下室温压缩时相比,材料在1273K 时的压缩强度的降低程度不超过30%,但压缩强度对应变率的敏感性随着温度的升高而增大。由于高温下试样氧化,C/SiC复合材料压缩强度对应变率的敏感性在温度为1073K时显著增大。     

The rheological behavior of flexible-chain polymers in the region of high shear rates and stresses,the critical process of spurting,and supercritical conditions of their movement at T > Tg

Methods of capillary viscometry were used in studying the rheological properties and behavior of a broad range of rubbers, including polymers with narrow and wide molecular-weight-distribution as well as commercial rubber grades, at widely varying shear rates and stresses. As is shown, in full conformity with the previously conducted experiments, during transition from a fluid to highelastic (quasi-cross-linked) state, they are chracterized by spurting followed by sliding over the channel walls. This relaxation transition is characterized by a critical shear stress value invariant with respect to the molecular weight, molecularweight distribution and temperature. The parameters defining spurting of polymer flow as a function of molecular-weight characteristics, temperature, and channel geometry have been investigated in detail. It is shown for the first time that under supercritical conditions the rate of polymer flow through channels does not depend, in the first approximation, on the molecular weight of the polymer, its molecularweight distribution, temperature, and filling, but is determined only by the shear stress.