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1.
The wetting behavior of a ternary mixture of oil, water, and amphiphile in the presence of a surface is studied. An interface model carefully derived from an underlying Ginzburg-Landau theory is introduced, which contains position dependent rigidity and stiffness coefficients. Using this model we predict a rich surface phase diagram containing thin-thick, first-order, and continuous wetting transitions. Application of the model to other interface behavior in these mixtures is also addressed.  相似文献   

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3.
A rigorous inequality is derived relating density gradient, interface thickness, transverse correlation length, and distance of the interface from the wall in the presence of an explicit gravitational (resp. wall potential). The results are relevant to various possible scenarios, e.g. (critical) wetting, drying, roughening, free interfaces (i.e., far away from a wall). Attention is concentrated on the structure of the liquid-gas interface in a gravitational field. Results seem to indicate that the usual intuition concerning the fine structure of the liquid-gas interface (e.g., the capillary wave picture) cannot be entirely correct. The predictions are particularly puzzling in space dimension two. The results are physically interpreted, giving a more refined picture of the interface layer.  相似文献   

4.
Using the Wilhelmy plate technique, the role of chemical defects in hysteretic wetting behavior was investigated. The wetting and dewetting work differ significantly, depending on the defect energy (i.e., high or low energy with respect to the matrix). For one, or an array of high-energy defects, advancing measurements departed from equilibrium theory, while the receding data were in close agreement. Conversely for low-energy defects, only the receding measurements showed significant departure from theory. We propose that distinct wetting mechanisms for high- and low-energy defects explain the phenomenon of asymmetric hysteresis, where the advancing or receding contact angle deviates more strongly from the equilibrium angle.  相似文献   

5.
具有基本流动的两层流体界面和表面孤波   总被引:1,自引:0,他引:1       下载免费PDF全文
颜家壬  钟建新 《物理学报》1990,39(9):1393-1399
本文研究了具有基本流动的两层流体浅水孤波,利用多重尺度摄动方法求得了两流体界面和表面波所满足的KdV方程和相应单孤波解;对所得结果进行了讨论,并将其应用到海洋温跃层和有剪切流动的均匀密度流体两种常见情形。 关键词:  相似文献   

6.
We have measured the contact angle of the interface of phase-separated 3He-4He mixtures against a sapphire window. We have found that this angle is finite and does not tend to zero when the temperature approaches T(t), the temperature of the tricritical point. On the contrary, it increases with temperature. This behavior is a remarkable exception to what is generally observed near critical points, i.e., "critical point wetting." We propose that it is a consequence of the "critical Casimir effect" which leads to an effective attraction of the 3He-4He interface by the sapphire near T(t).  相似文献   

7.
We study the dynamics of an interface between two phases in interaction with a wall in the case when the evolution is dominated by surface diffusion. For this, we use an SOS model governed by a conservative Langevin equation and suitable boundary conditions. In the partial wetting case, we study various scaling regimes and show oscillatory behavior in the relaxation of the interface toward its equilibrium shape. We also consider complete wetting and the structure of the precursor film.  相似文献   

8.
We present confocal microscopy experiments on the wetting of phase-separated colloid-polymer mixtures. We observe that an unusually thick wetting layer of the colloid-rich phase forms at the walls of the glass container that holds the mixture. Because of the ultralow interfacial tension between the colloid-rich and the polymer-rich phases, the thermally activated roughness of the interfaces becomes very big and measurable. We observe that close to the critical point the roughness of the interface between the wetting layer and the polymer-rich phase decreases with decreasing layer thickness: large excursions of the interface are confined in the wetting layer. The measured relationship between the roughness and the thickness of the wetting layer is in qualitative agreement with the predictions of renormalization group theory for short-range forces and complete wetting.  相似文献   

9.
Sanjay Puri 《Physica A》2007,384(1):100-107
We review our understanding of surface-directed spinodal decomposition (SDSD), i.e., the interplay of wetting and phase separation in an unstable AB mixture placed in contact with a wetting surface. In this context, we present results for two problems, viz., SDSD in a semi-infinite geometry with a completely wet surface; and SDSD in a thin-film geometry with partially wet surfaces.  相似文献   

10.
在宏观介电连续近似下,采用转移距阵方法,研究了三元合金缺陷层对有限超晶格中局域界面光学声子模的影响.在这种有限超晶格结构中,可以清楚地看到所有界面模的演化轨迹.结果表明:存在两类局域模,它们的宏观静电势波函数分别局域在缺陷层和表面层附近,且这些模随着超晶格组分层和缺陷层的相对厚度和介电常数的改变,其局域位置和特性发生显著变化.此外,发现虽然能隙中局域模的数目不守恒,但所有界面模的总数守恒.  相似文献   

11.
The problem of the doubling of states is investigated in the framework of the theory of discrete quantum gravity under the assumption that the theory has a continuum (macroscopic) limit. It is demonstrated that irregular (in some sense) modes of fields (i.e., modes that change abruptly on scales of a lattice step and have a finite energy when the lattice step tends to zero) are separated from the normal modes. Some cosmological consequences of this finding are discussed.  相似文献   

12.
In this paper we consider a quantum optics model where two-mode quantum light cavity with Kerr-like medium is coupled to an atom via two-photon process. The dynamical evolution of the system is studied in terms of entanglement measured by quantum relative entropy. The entanglements for the different bipartite partitions of the system, i.e., atom-two modes, mode-mode, mode-(atom+mode), are calculated explicitly and interesting trade-off relations between the different kinds of entanglement can be observed in different cases. The results show the entanglement between mode-mode is generally out of phase with that between atom and two modes, even though the two modes do not interact directly, and the Kerr-like medium prevents the atom and two modes from entangling.  相似文献   

13.
The wetting properties of solid substrates with customary (i.e., macroscopic) random roughness are considered as a function of the microscopic contact angle of the wetting liquid and its partial pressure in the surrounding gas phase. Analytic expressions are derived which allow for any given lateral correlation function and height distribution of the roughness to calculate the wetting phase diagram, the adsorption isotherms, and to locate the percolation transition in the adsorbed liquid film. Most features turn out to depend only on a few key parameters of the roughness, which can be clearly identified. It is shown that a first-order transition in the adsorbed film thickness, which we term "Wenzel prewetting", occurs generically on typical roughness topographies, but is absent on purely Gaussian roughness. It is thereby shown that even subtle deviations from Gaussian roughness characteristics may be essential for correctly predicting even qualitative aspects of wetting.  相似文献   

14.
We theoretically study binary mixtures of thin and thick hard rods with diameter ratio more extreme than 1:4. The bulk phase diagram of these systems exhibits a triple point, where an isotropic (I) phase coexists with two nematic phases ( N1 and N2) of different composition. Using density functional theory, we predict that the I-N2 interface is completely wet by N1 upon approach of the the I-N1-N2 triple point. This entropic triple point wetting should be experimentally observable in colloidal suspensions of rodlike particles.  相似文献   

15.
The morphological stability of the interface between two fluids has been analyzed for the case where one of them displaces the other in a radial Hele-Shaw cell. The numerical calculation has shown for the first time that the critical size of instability decreases with an increase in the perturbation amplitudes of the interface and reaches a value previously determined from independent analytical calculations of the thermodynamic entropy production and the maximum entropy production principle. This reason is important evidence for the hypothesis that the entropy production makes it possible to predict nonequilibrium phase transitions in hydrodynamic systems (i.e., it is an analog of the thermodynamic potential). In other words, the entropy production determines a kinetic binodal, i.e., the interface of a metastable region in the case of perturbations with arbitrary amplitude.  相似文献   

16.
This paper is a study of the vibration and stability of symmetrical sandwich cantilevers with elastic bonding. The horizontal displacements of the face layer and the core are discontinuous due to the elasticity of the interface bond. The shear traction at the interface is assumed to be proportional to the relative horizontal displacement of the layers. The core layer is subjected to a horizontal (conservative) or tangential (non-conservative) axial force at its free end. It is shown that a symmetrical sandwich beam with elastic bonding has two kinds of vibration modes: i.e., bending modes and longitudinal modes. Numerical results are given for a beam composed of FRP face layers and a syntactic-foam core layer. It is shown that the divergence and the flutter type instability loads, as well as the natural frequency, are affected considerably by the stiffness of the interface bond.  相似文献   

17.
An experimental investigation is presented of chemically driven dynamic instability of an oil-water interface in a cylindrical and annular glass container. The immiscible liquids are water containing a surfactant (TSAC) and nitrobenzene containing iodine. The reaction at the interface leads to complex deformation patterns including rotating solitary waves, multiple wave trains, periodic and nonperiodic oscillations, source-to-sink propagation, and intermittent behavior. A phase diagram is established for the two solute concentrations ranging from 10-4 to 10-1 M. It shows five distinct regions of different dynamic regimes, determined by interaction of at least three mechanisms: dynamic wetting of the container wall, capillary effect, and Marangoni instability of the liquid-liquid interface. The influences of aspect ratio, concentration product, and temperature are investigated and local time traces are derived from electropotential differences. Their spectral analysis reveals details of periodic or irregular motion. Transitions between the dynamic modes of the system during its temporal evolution are recorded. Quantitatively determined profiles of regular waves are analyzed by exponential functions and a simple model for this is proposed.  相似文献   

18.
We review the construction of a low-energy effective field theory and its state space for “abelian” quantum Hall fluids. The scaling limit of the incompressible fluid is described by a Chern–Simons theory in 2+1 dimensions on a manifold with boundary. In such a field theory, gauge invariance implies the presence of anomalous chiral modes localized on the edge of the sample. We assume a simple boundary structure, i.e., the absence of a reconstructed edge. For the bulk, we consider a multiply connected planar geometry. We study tunneling processes between two boundary components of the fluid and calculate the tunneling current to lowest order in perturbation theory as a function of dc bias voltage. Particular attention is paid to the special cases when the edge modes propagate at the same speed, and when they exhibit two significantly distinct propagation speeds. We distinguish between two “geometries” of interference contours corresponding to the (electronic) Fabry–Perot and Mach–Zehnder interferometers, respectively. We find that the interference term in the current is absent when exactly one hole in the fluid corresponding to one of the two edge components involved in the tunneling processes lies inside the interference contour (i.e., in the case of a Mach–Zehnder interferometer). We analyze the dependence of the tunneling current on the state of the quantum Hall fluid and on the external magnetic flux through the sample.  相似文献   

19.
In this work, we propose a new model of evolution networks, which is based on the evolution of the traffic flow. In our method, the network growth does not take into account preferential attachment, and the attachment of new node is independent of the degree of nodes. Our aim is that employing the theory of evolution network, we give a further understanding about the dynamical evolution of the traffic flow. We investigate the probability distributions and scaling properties of the proposed model. The simulation results indicate that in the proposed model, the distribution of the output connections can be well described by scale-free distribution. Moreover, the distribution of the connections is largely related to the traffic flow states, such as the exponential distribution (i.e., the scale-free distribution) and random distribution etc.  相似文献   

20.
本文简要介绍对称性及其破缺的概念和基本的数学上所说的幺正对称性等的微观粒子实现,从而为利用抽象的数学描述物理问题奠定基础。本文还简要介绍早期宇宙强相互作用物质演化过程的对称性及其破缺,尤其是可见物质质量的产生(比如DCSB)以及强相互作用等基本相互作用的规范对称性和破缺,为有意向探讨早期宇宙强相互作用物质演化的青年学者和研究生提供必要的知识储备,并打开一扇窗口。同时,还简要讨论原子核的对称性及其破缺,尤其是作为强相互作用多体系统的束缚态研究中的基本理论方法、(多粒子)壳模型及相互作用玻色子近似模型(IBM)、集体运动的描述及集体运动模式演化(形状相变)的研究方法及进展简况,提供一些在基本理论方法与前沿研究课题之间建立桥梁的实例。  相似文献   

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