放射性核束引起的奇异核反应研究

结合开展的工作，对放射性核束流引起的核反应总截面研究、放射性束流引起的熔合反应研究、放射性束流开展的天体物理核反应研究以及其它有关的核反应研究进行了评述，并对其可能的发展作了一些探讨 .The study of total nuclear reaction cross section, nuclear fusion reaction,nuclear reaction of astrophysics and related reactions induced by radioactive nuclear beam are reviewed in this paper. The future development of this field is discussed.     

高自旋同质异能态束流及其在核谱学中的应用

介绍了在日本理化学研究所利用高自旋同质异能态束流装置上取得的核谱学研究结果。强调了可利用重离子核反应中逆运动学产生高自旋同质界能态束流,并用其进行二次核反应,描述了首次利用高自旋同质异能态束流完成的物理实验． The study of nuclear spectroscopy by using the High spin isomer Beam(HSIB)facility in RIKEN was introduced.The production of HSIB based on the inverse kinematics in heavy ion nuclear reaction,and its application for secondary nuclear reaction were stressed The first experimental result by using HSIB was also briefly discribed.     

高能质子引起器件单粒子效应的研究方法

简略介绍了高能质子在半导体芯片中引起单粒子效应的实验测量和理论分析方法,包括核反应分析方法、半经验方法,介绍了质子和重离子翻转截面间的关系,并用重离子实验数据预测器件在质子环境下的翻转率. This article introduces briefly the experimental and theoretical methods that have been used to study high energy proton induced single event effect in semiconductor devices. The theoretical methods including nuclear reaction analysis method and semi empirical method are presented. The relationship of upset cross section between proton and heavy ions is described. Finally, on orbit proton upset rates are predicted by using the heavy ion test data.     

中能核反应中反应平面的确定

介绍并分析了中高能核反应过程中与反应平面相关的可观测量 ,以及确定核反应平面的各种方法 .这些方法包括裂变碎片方位角测量、类弹碎片测量、动量流球形张量、横向动量的方向性、方位角关联和Fourier谐波分析等 . Observables that related to the nuclear reaction plane in intermediate and relativistic energy heavy ion reactions are discussed. Reaction plane determination for intermediate and relativistic energy heavy ion reactions is presented. The methods include fission fragments measurement, projectile-like fragments measurement, kinetic flow-tensor, transverse momentum directivity, azimuthal correlation, Fourier series and etc.     

核核碰撞的最新进展——第四届核核碰撞国际会议简介

本文介绍了第四次核核碰撞国际会议的主要报告内容,包括核结构、核反应机制、超相对论重离子碰撞、放射性核束及其核物理研究、核天体物理学及核技术应用.同时,也介绍了各个领域已经取得的最新进展及今后研究的热门课题. In this paper the main reports given on Nucleus—Nucleus Collisions International Con-ference Ⅳ are briefly introduced.It includes nuclear stracture,nuclear reaction mechanism,super rela-tivistic HIC,redioactive nuclear beams and its nuclear physics research,nuclear astrophysics and appli-cations of nuclear technigue.The Latest developments in every fields and the top research point in thenear future are introduced.     

重离子核反应对单粒子翻转的影响（英文）

LET作为一个传统的工程参量,并不能完全满足单粒子翻转数据表征的需要,而且也不能直接地反映核反应的一些特性(包括核反应概率与次级粒子),因此研究了重离子与器件作用过程中核反应对单粒子翻转的影响。基于蒙特卡罗模拟与深入的分析,本研究对比了在直接电离与考虑核反应两种模式下的模拟结果。在模拟中,利用不同的重离子表征了核反应在单粒子翻转发生中所起的作用。结果显示,核反应对单粒子翻转截面的贡献依赖于离子的能量,并呈现非单调的变化关系。基于模拟的结果,建议用重离子核反应引起单粒子翻转的最恶劣情况来预估空间单粒子翻转率。     

CsI(T1)+光二极管读出探测器在中能重离子核反应实验中的应用

本文报道了CsI(T1)+光二极管读出探测器在中能重离子核反应实验中的应用.研究了这种探测器与半导体探测器构成ΔE-E望远镜鉴别轻带电粒子,及利用过零时间法来鉴别轻带电粒子的实验结果.     

近垒重离子熔合反应中的中子转移效应(英文)

近势垒及其以下能区重离子熔合反应中的中子转移耦合道效应是一个复杂且有争议的问题。简要介绍了近年来在中国原子能科学研究院的HI-13串列加速器上,基于静电偏转板装置完成的32S+90,94,96Zr,18O+74Ge和18O+58Ni等几个典型体系的熔合反应研究情况,并结合耦合道理论对实验数据进行了分析。选取反应体系时同时关注了正Q值的中子拾取和削裂道。另外,基于完全耦合道理论计算,提出了一种能够定量提取熔合反应中中子转移效应的自洽方法。这些研究进一步证实了垒下重离子熔合反应中的中子转移效应,同时指出了其复杂性。需要进一步的实验和理论研究来澄清相关核反应机制。The effect of neutron transfers on near-and sub-Coulomb-barrier fusion of heavy-ions is still a complicated and controversial problem. This paper reviews the recent experimental results of the fusion excitation functions of several typical systems, which have been measured by using an electrostatic deflector setup at the HI-13 tandem accelerator of CIAE. Both the neutron pickup and stripping effects were studied. Moreover, a self-consistent method to reliably isolate the transfer effect quantitatively based on the coupledchannels calculation is proposed. These studies give a further support for the neutron transfer effect on sub-barrier fusion of heavy-ions and its complexity. Further experimental and theoretical studies are needed for clarifying the relevant reaction mechanisms.     

低能核反应理论的研究与应用

介绍有关低能核反应理论的研究与应用工作．The work for research and application of low energy nuclear reaction theories is introduced.     

用中能重离子反应合成新核素的一种可能机制

合成远离β稳定线核素,进而研究它的性质,发现原子核结构的新规律,是核物理研究的重要课题之一。迄今为止,重离子核反应已成为合成新核素的重要手段。人们利用低能(库仑位垒附近)重离子核反应合成新核素,主要通过熔合蒸发、若干个核子的转移和深部非弹性碰撞等反应过程。经过多年的努力,已得到许多的研究成果。中能(20-100MeV/A)重离子加速器的建成和中能区重离子核反应的研究,给核素合成工作带来新的发展和希望。     

氟分子与乙烯反应的直接动力学模拟

氟分子与乙烯可以发生三类反应，即氟原子排除反应、氟化氢分子排除反应和加合反应，但除了基机制以外，已有的其它机理都不能合理的解释低温下的反应是如何开始的．通过对氟分子与乙烯反应的直接动力学模拟，以密度泛函方法研究了长期困扰的氟分子与乙烯反应的机理．通过计算支持了基机制，轨线模拟细致地描述了三个反应通道．根据此机制对低温池中的反应给出了解释．     

Hamilton–Jacobi equation,reaction action surface and the emergence of the force concept in chemical reaction dynamics

A combination of Hamilton–Jacobi equation and fast marching algorithm can be used to study reaction dynamics by converting the potential energy surface to a reaction action surface. The reaction action surface has been found to be an important tool in theoretical chemistry, allowing us to provide a different force-based perspective of chemical reactions. Several properties such as reaction force, reaction force surface, reaction path force and reaction path force constant have been defined and calculated by using the reaction action surface. This paper investigates these newly defined properties in order to understand the role they play in chemical reaction with reference to a model 4-well potential energy surface.     

羟自由基与水杨酸反应机理的初探

探讨羟自由基与水杨酸的反应动力学过程。水杨酸与Fenton反应产生的的羟自由基反应,采用紫外-可见分光光度法（UV）和质谱法（MS）,考察反应物的浓度、反应时间、反应温度、溶剂pH值等对反应产物的浓度以及反应速率的影响。水杨酸与.OH反应生成的紫色产物在波长530nm处有最大UV吸收峰,但仅于pH=4.51的缓冲溶液和水中有吸收峰;且该产物的吸光度值,随着反应物浓度的增加而增加;随反应时间的延长而减少;随着反应温度的升高而减少。反应速率t=5s达到最大值,其后随着反应时间的延长而逐渐降低,1min时达到平衡。通过MS分析,可得到质荷比（m/Z）=153,248,249,288,289,304,328,329,344,345的离子峰。推测羟自由基与水杨酸反应的中间产物是紫色的大分子自由基,而最终产物为二羟基苯甲酸,该反应可能是加成反应和聚合反应同时进行。     

Sonocatalytic–Fenton reaction for enhanced OH radical generation and its application to lignin degradation

The present study demonstrated that the combined use of the sonocatalytic reaction (using ultrasound and titanium dioxide) and the Fenton reaction exhibited synergistically enhanced hydroxyl (OH) radical generation. Dihydroxybenzoic acid (DHBA) concentration as index of OH radical generation was 13 and 115 μM at 10 min in the sonocatalytic reaction and Fenton reaction, respectively. On the other hand, the DHBA concentration was 378 μM at 10 min in the sonocatalytic–Fenton reaction. The sonocatalytic–Fenton reaction was used for degradation of lignin. The lignin degradation ratio was 1.8%, 49.9%, and 60.0% at 180 min in the sonocatalytic reaction, Fenton reaction, and sonocatalytic–Fenton reaction, respectively. Moreover, the sonocatalytic–Fenton reaction was applied to pretreatment of lignocellulosic biomass to enhance subsequent enzymatic saccharification. The cellulose saccharification ratio was 11%, 14%, 16% and 25% at 360 min of pretreatment by control reaction, the sonocatalytic reaction, Fenton reaction, and sonocatalytic–Fenton reaction, respectively.     

替代反应法测量锕系核(n,f)和(n,xn)截面

对于某些中子反应截面,在直接测量上存在困难。为了获得那些对核能发展极其重要的核数据,人们提出替代反应法,即利用带电粒子代替中子进行反应,从而实现中子反应截面间接测量的方法。现有替代反应一般采用非弹激发、转移等周边反应,涉及的角动量远比中子反应的大,需要理论修正,这造成了一定的困难。有鉴于此,提出利用轻带电离子的俘获反应作为替代反应,其复合核自旋与中子反应的相当,有效避免了自旋修正的困难。根据这个思路,采用236U的（α,f）和（α,2n）反应作为替代反应,成功提取了239Pu的（n,f）和（n,2n）反应截面,与ENDFB7评价库数据在误差范围内符合较好,表明了替代反应法的优越性,可以在核数据测量中推广应用。There are always difficulties in the direct measurement of reactions induced by neutron, in order to obtain the neutron induced nuclear reaction data which are extremely important for nuclear power development, the surrogate reaction method, which uses charged particles instead of neutron, was proposed. The existing surrogate reaction method generally chooses peripheral reaction as the surrogate reaction, such as inelastic scattering excitation or transfer reaction. As a result, the angular momentum involved is always far larger than the neutron induced reaction, which causes difficulties in the theoretical calculation. Because of this, we proposed to use light-ion capture reaction as the surrogate reaction, the compound nuclei spin is similar with that of the neutron induced reaction, so that the difficulties in spin correction can be effectively avoided. Based on this idea, the 239Pu(n, f) and (n, 2n) reaction cross sections were successfully extracted using 236U(α,f) and (α,2n) reactions as the surrogate reaction. The results coincide well with the data of ENDFB7 within the error range, which shows that the surrogate reaction method has its own superiority, and it can be applied in the measurement of nuclear data.     

固-液-气三相环境下非均相苯加氢反应的原位核磁共振研究

本文使用原位核磁共振（NMR）方法成功实现了对固-液-气三相环境下加氢反应的在线监测.在反应过程中,无需分离产物.以Pd纳米颗粒粉末及不同晶面形貌的Pd催化剂作为研究对象,我们研究了反应压强、反应时间,以及催化剂表面性质对加氢反应的影响.结果表明,压强和反应时间都可以影响加氢反应产物的产率,使用暴露不同晶面的Pd共催化剂时,苯加氢产物不同.该原位NMR方法为研究固-液-气三相催化环境下的加氢反应机理提供了可能.     

炭黑非催化还原NO的实验研究

在石英管式炉固定床反应器上研究了程序升温条件下炭黑与NO反应的规律。实验表明:天然气炭黑比其它炭黑具有更高的脱除率、最低的起始反应温度;炭黑的起始反应温度随着NO反应气浓度增大而升高;升温速率越大,NO 的脱除率越大,起始反应温度越低;炭黑质量浓度越大,NO的脱除率越大,起始反应温度越低;反应气中氧存在可以降低炭黑-NO起始反应温度。     

速度分群情况下氘氚热核反应率的模拟与分析

研究两种原子核粒子参与反应的热核聚变,假定一种原子核粒子处于热动平衡状态,对另一种原子核粒子速度分布进行分群,推导分群热核反应率以及平均热核反应率,编制相应计算程序;以氘氚热核聚变反应为例计算分群热核反应率和相应的平均热核反应率,并与直接积分结果进行对比;同时,细致研究平均热核反应率与速度分群数目的关系.     

Insights into the Maillard reaction. The mechanism of Schiff's base formation from the reaction force perspective

Schiff's base formation of the Maillard reaction is described from a theoretical viewpoint. The double proton transfer reaction was investigated within the frame of reaction force analysis in which global and local electronic properties were monitored within reaction regions defined along the reaction coordinate. Calculations based on density functional theory show that Schiff's base formation in the Maillard reaction occurs through an asynchronous double proton transfer, the second proton transfer being the determinant step of the reaction.     

PBT与固化剂的反应机理研究

本文采用密度泛函理论(DFT)研究了粘合剂端羟基3,3-双叠氮甲基氧杂环丁烷-四氢呋喃(BAMO-THF)共聚醚(PBT)和固化剂甲苯二异氰酸酯(TDI)模型化合物的结构性质.对粘合剂PBT和固化剂TDI进行了结构优化,通过计算与分析静电势能图,探究了固化反应可能的反应位点.PBT与TDI反应位点较多,易于形成网络结构.基于模型化合物,预测了四种可能的固化反应产物,计算了固化反应可能产物的结构和能量.确定了固化反应过程中热力学稳定结构,并对最可几的产物反应路径中的过渡态进行了计算,得到了最可能的固化反应的反应路径和活化自由能.该研究可为进一步分析PBT推进剂中涉及的老化反应提供依据.