超铀区缺中子新同位素~（235）Am的合成与鉴别

用３５ＭｅＶ质子轰击同位素靶２３８Ｐｕ，通过２３８Ｐｕ（Ｐ，４ｎ）２３５Ａｍ反应，合成了新的缺中子同位素２３５Ａｍ．利用Ｈｅ－ｊｅｔ及毛细管传输技术收集反应产物，然后用放射化学法除去产物中的裂变碎片并分离出Ａｍ活性．根据观测到的２３５Ｐｕ的衰变Ｙ及ＮＰ的特征Ｘ射线的生长－衰变行为和Ｘ－Ｙ符合测量，肯定了２３５Ａｍ的首次合成，测得２３５Ａｍ的半衰期为１５±５ｍｉｎ．     

Prompt neutron multiplicity distribution for ~（235）U（n,f） at incident energies up to 20 MeV

For the n+²³⁵U fission reaction, the total excitation energy partition of the fission fragments, the average neutron kinetic energy <ε>(A) and the total average energies E_γ(A) removed by γ rays as a function of fission fragment mass are given at incident energies up to 20 MeV. The prompt neutron multiplicity as a function of the fragment mass, ν(A), for neutron-induced fission of ²³⁵U at different incident neutron energies is calculated. The calculated results are checked with the total average prompt neutron multiplicities ν and compared with the experimental and evaluated data. Some prompt neutron and γ emission mechanisms are discussed.     

重丰中子新同位素——238Th

利用兰州重离子加速器（ＨＩＲＦＬ）提供的６０ＭｅＶ／ｕ的１８Ｏ离子束照射天然铀靶,通过多核子转移反应生成２３８Ｔｈ．用快速放射化学分离技术从铀及其反应产物的混合物中分离出Ｔｈ同位素．使用两台高纯锗（ＨＰＧｅ）探测器测量了样品的γ射线活性,观测到了２３８Ｔｈ的β－衰变子体２３８Ｐａ的γ射线的生长、衰变行为,测定２３８Ｔｈ的半衰期为9.4±2.0min A new nuclide 238Th has been produced via multinucleon transfer reaction by 60 MeV/u 18 O ion irradiation of natural uranium. The produced thorium was radiochemically separated from the mixture of uranium and its reaction products. The activity of thorium was measured by using a HPGe detector and a planar HPGe detector. 238 Th has been identified for the first time by measuring the growth and decay of the γ rays from its daughter nucleus 238 Pa.     

A～130过渡区核的高自旋态研究

评述了Ａ～１３０过渡区Ｉ、Ｘｅ、Ｃｓ和Ｂａ核的高自旋核结构研究．在这些核中观测到的极为丰富的核结构现象,如质子中子转排竞争、形状共存、带终结、带交叉延迟、Ｓｉｇｎａｔｕｒｅ反转和八极关联等与这些核的价质子、价中子都位于ｈ１１／２支壳及这些核易产生γ形变有关. The studies of high spins states of A ～130 transitional I,Xe,Cs and Ba nuclei are reviewed. The variety of nuclear structure, such as proton neutron alignment competition, shape coexistance, band termination, crossing delay, signature inversion, octupole correlation, etc. observed in these nuclei is closely related to that both the valence proton and neutron of these nuclei are located in the h 11/2 subsell and the nuclei are soft against the γ deformation.     

Effects of pressure on structural,electronic, and mechanical properties of α,β,and γ uranium

The first-principles methods have been employed to calculate the structural, electronic, and mechanical properties of the α, β, and γ phases of uranium under pressure up to 100 GPa. The electronic structure has been viewed in forms of density of states and band structure. The mechanical stability of metal U in the α, β, and γ phases have been examined.The independent elastic constants, polycrystalline elastic moduli, as well as Poisson's ratio have been obtained. Upon compression, the elastic constants, elastic moduli, elastic wave velocities, and Debye temperature of α phase are enhanced pronouncedly. The value of B/G illustrates that α and γ phases are brittle in ground state.     

Nonlinear optical properties of [（CH3）4N]Au（dmit）2 using Z-scan technique

The third-order optical nonlinearities of [（CH3）4N]Au（dmit）2 （dmit = 4,5-dithiolate-1,3-dithiole-2-thione） at 532 nm and 1064 nm are investigated using the Z-scan technique with pulses of picoseconds duration. The Z-scan spectra reveal a strong nonlinear absorption （reverse saturable absorption） and a negative nonlinear refraction at 532 nm. No nonlinear absorption is observed at 1064 nm. The molecular second-order hyperpolarizability γ for the [（CH3）4N]Au（dmit）2 molecule at 532nm is estimated to be as high as （2.1 ±0.1） × 10^-31 esu, which is nearly three times larger than that at 1064 nm. The mechanism responsible for the difference between the results is analysed. Nonlinear transmission measurements suggest that this material has potential applications in optical limiting.     

康普顿背散射技术对贮存环电子束诊断及其应用-II贮存环电子束的极化度测量

简单介绍以激光 电子康普顿背散射原理为基础建立的康普顿背散射极化仪, 采用它能实时、 非破坏性地监测电子束的极化. 该项工作可作为上海激光电子γ源（SLEGS）低能γ束应用研究的内容之一. The Compton backscattering polarimeter is described briefly on the basis of the principle of Compton backscattering in this paper. The polarization of the electron beam can be measured and monitored on time and nondestructively. The project will be one of applications of low energy γ ray beam of SLEGS.     

Discrimination of neutrons and γ-rays in liquid scintillator based on Elman neural network

In this work,a new neutron and γ(n/γ) discrimination method based on an Elman Neural Network(ENN) is proposed to improve the discrimination performance of liquid scintillator(LS) detectors.Neutron andγ data were acquired from an EJ-335 LS detector,which was exposed in a ~(241)Am-~9Be radiation field.Neutron and γ events were discriminated using two methods of artificial neural network including the ENN and a typical Back Propagation Neural Network(BPNN) as a control.The results show that the two methods have different n/γdiscrimination performances.Compared to the BPNN,the ENN provides an improved of Figure of Merit(FOM)in n/γ discrimination.The FOM increases from 0.907 ± 0.034 to 0.953 ± 0.037 by using the new method of the ENN.The proposed n/γ discrimination method based on ENN provides a new choice of pulse shape discrimination in neutron detection.     

核泵浦气体激光研究

本文介绍了利用核能激励Ｎｅ、Ｈｅ、Ｘｅ、Ａｒ等气体产生激射这一领域内所取得的成果．利用￣（２３８）Ｐｕ源激励Ｎｅ、Ｈｅ－Ａｒ、Ｎｅ－Ｈｅ、Ｎｅ－Ｈ＿２体系,测到了Ｈｅ、Ｎｅ、Ａｒ、Ｈ＿２对Ｎｅ（２ｐ＿１）态的倒空速率常数．利用３００￣＃稳态堆激励Ｈｅ－Ｈｅ体系,测得其增益为２×１０￣（－２）／ｃｍ．在ＣＦＢＲ－Ⅱ脉冲堆上进行了Ｈｅ－Ａｒ－Ｘｅ体系的激射实验,测到了激光信号,其波长为１．７３μｍ,激光功率约为１０ｍＷ． The results of nuclear pumping Ne, He, Ar, Xe are introduced in this paper.￣(238)Pu was used to exite Ne, Ne-Ar, Ne-He, Ne-H_2 systems. The elimination rate constantsof Ne (2p_1 ) by Ne,He,H_2,Ar were measured. 300￣# stable reactor was used to encourage HeNe system, the gain measured was 2 ×10￣(-2)/cm. Lasing experiment of He-Ar-Xe system wasdone on CFBR-Ⅱ pulse reactor, lasing sign was measured, λ=1.73μp, lasing power wasabout 10 mW.     

Prompt neutron multiplicity distribution for 235U(n,f) at incident energies up to 20 MeV

For the n+<'235>U fission reaction, the total excitation energy partition of the fission fragments, the average neutron kinetic energy <ε>(A) and the total average energies E<,γ>(A) removed by γ rays as a function of fission fragment mass are given at incident energies up to 20 MeV. The prompt neutron multiplicity as a function of the fragment mass, ν(A), for neutron-induced fission of <'235>U at different incident neutron energies is calculated. The calculated results are checked with the total average prompt neutron multiplicities ν and compared with the experimental and evaluated data. Some prompt neutron and γ emission mechanisms are discussed.     

A new neutron-deficient isotope, 235Am

The new transuranium neutron-deficient isotope ²³⁵Am was produced by bombarding of ²³⁸Pu with 35-MeV protons beam via the (p,4n) reaction. The reaction products were transported by a helium-jet system. A rapid radiochemical method was employed for separating the americium isotopes from the complex products. From the observed Kx-rays of Np, γ-ray of ²³⁵Pu and x-γ coincidence measurements, the new neutron-deficient isotope ²³⁵Am with a half-life 15±5min was definitely identified for the first time.     

Infrared Spectra of the Square Planar Rhodium(I) Complexes cis-[Rh(CO)2(pyridine) (X)] (X = Cl,Br): Isotopic Labelling Studies and Normal Coordinate Analysis

Abstract

The infrared spectra (4000 - 50 cm^?1) of the square planar rhodium(I) complexes cis-[Rh(CO)₂ (pyridine) (X)] (X = Cl, Br) and their isotopomers with pyridine-d ₅ and ¹³CO have been determined. Assignments are based on earlier studies on pyridine and its complexes and on the shifts in infrared bands which are caused by the isotopic substitutions employed. Normal coordinate analysis following the procedure of Becher and Mattes has been used to confirm the empirical assignments. The two v(RhC) bands are observed near 490 and 450 cm^?1. v(RhN) is found near 210 cm^?1 and v(RhX) occurs at 310 (X = Cl) and 235 (X = Br) cm^?1. At frequencies below 200 cm^?1, the bands are assigned to bending modes in the following sequence: δ (RhN) > δ (CRhC) > δ (RhCl) > γ (RhCl) > γ (RhN).     

Does the coherent bremsstrahlung of fission fragments exist?

The spectrum of γ rays from the neutron-induced fission of ²³⁵U nuclei has been studied in a range of 10–90 MeV. The experiment has been carried out in the horizontal experimental channel of a nuclear reactor. The energy spectrum was measured using a single-crystal NaI(T1) spectrometer. The data on the energy dependence of the yield of γ rays have been obtained in a range of 12–38 MeV. The upper limit on the probability of the emission of γ rays has been determined for a range of 38–90 MeV. It has been shown that the experimental data are inconsistent with available models attributing the yield of γ rays in this energy range to the coherent bremsstrahlung of fission fragments in the Coulomb field.     

EC and α decays of 235Am

EC and decays of ²³⁵Am have been studied using a gas-jet coupled on-line isotope separator. Excited states in ²³⁵Pu have been established for the first time by means of -ray spectroscopy following the EC decay of ²³⁵Am. The deduced log ft value suggests that the ground state of ²³⁵Am should have the 5/2^-[523] configuration. The - coincidence result has revealed that the 5/2^-[523] state in ²³¹Np populated by the favored transition of ²³⁵Am is located at < 15 keV, which allows us to precisely determine the Q value of ²³⁵Am.     

Study of the high-energy part of the spectrum of γ rays from the neutron-induced fission reaction of 235U nuclei

The spectrum of γ rays from the neutron-induced fission reaction of ²³⁵U nuclei has been investigated in the energy range 10–90 MeV. The experiment was performed in the horizontal channel of a nuclear reactor. The energy spectra was measured using a single-crystal NaI(Tl) spectrometer. The data on the energy dependence of the yield of γ rays have been obtained in the energy range 10–36 MeV. The upper limit of the probability of γ-ray emission has been determined for the range 36–90 MeV.     

Calculation of prompt fission neutron spectra for 235U(n,f)

The prompt fission neutron spectra for the neutron-induced fission of ²³⁵U at E_n < 5 MeV are calculated using nuclear evaporation theory with a semi-empirical model, in which the nonconstant and constant temperatures related to the Fermi gas model are taken into account. The calculated prompt fission neutron spectra reproduce the experimental data well. For the n(thermal)+²³⁵U reaction, the average nuclear temperature of the fission fragment, and the probability distribution of the nuclear temperature, are discussed and compared with the Los Alamos model. The energy carried away by γ rays emitted from each fragment is also obtained and the results are in good agreement with the existing experimental data.     

替位式掺杂的富勒烯分子C77X(X=B,N原子)的非线性光学性质

采用推广的Su-Schrieffer-Heeger模型和sum-over-state方法计算了掺杂的富勒烯分子C₇₇X(X=B或N原子)的三阶非线性极化率γ.计算结果表明：1)与C₇₈相比,各C₇₇X分子的三阶非线性极化率γ的静态值均有不同程度的提高(3—40倍);2) C₇₇X的非线性动态光学响应不仅与掺杂原子有关,还与异构体种类和掺杂位置有关. 关键词：     

Chemical states of57Fe-atoms after ec-decay of57Co-labelled Co(BrO3)2·6H2O studied by coincidence Mössbauer spectroscopy

Two kinds of time differential Mössbauer spectra of⁵⁷Co-labelled Co(BrO₃)₂·6H₂O were measured at room temperature by delayed coincidence technique, i.e., one was the delayed coincidence between 122 keV γ ray and 14.4 keV γ ray (γ, γ-ray coincidence), and another was the coincidence between 6.3 keV KX ray and 14.4 keV γ ray (X, γ-ray coincidence). The time dependence of chemical states of⁵⁷Fe-species were observed on γ, γ-ray and X, γ-ray coincidence Mössbauer spectra. The relative area intensities of⁵⁷Fe(II) observed on the X, γ-ray coincidence spectra were larger than those on the γ, γ-ray coincidence spectra on every time windows.     

Calculation of prompt fission neutron spectra for 235U(n,f)

The prompt fission neutron spectra for the neutron-induced fission of ²³⁵U at E_n < 5 MeV are calculated using nuclear evaporation theory with a semi-empirical model, in which the nonconstant and constant temperatures related to the Fermi gas model are taken into account. The calculated prompt fission neutron spectra reproduce the experimental data well. For the n(thermal)+²³⁵U reaction, the average nuclear temperature of the fission fragment, and the probability distribution of the nuclear temperature, are discussed and compared with the Los Alamos model. The energy carried away by γ rays emitted from each fragment is also obtained and the results are in good agreement with the existing experimental data.