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1.
In this paper we present a theoretical treatment of the energy dependence of the cross sections for direct photodissociation of linear triatomics, util 相似文献
2.
The main concepts of the nature of electronically excited states in polyatomic molecules and the intramolecular and intermolecular processes of their evolution are reported. The dependence of the probabilities of these processes on the electronic structure of the molecule is considered. Possible mechanisms of the dissociation of electronically excited molecules with bond cleavage are discussed, and the theoretical results of this consideration are given. The experimental data obtained by the authors are interpreted. In this case, attention is focused on C-H-bond photodissociation processes in a condensed phase, which are the best studied processes. The dissociation of other bonds is briefly discussed. 相似文献
3.
Ming Wu Gregory E. Hall 《Journal of photochemistry and photobiology. A, Chemistry》1994,80(1-3):45-52
The CN photofragments from the photodissociation of NCCN at 193 nm have been measured by high-resolution transient absorption spectroscopy. Doppler-broadened profiles of isolated rotational lines in the 2-0 and 3–1 vibrational bands of the CN A---X transition were observed under collisionless conditions with a tunable, single-frequency Ti:sapphire ring laser. Analysis of the Dopple profiles reveals a vector correlation between the translation and rotation of CN photoproducts, with the angular momentum of the high rotational states increasingly perpendicular to the recoil velocity. After correction for vector correlations, the laboratory-frame scalar speed distribution of state-selected photoproducts can be determined. The mean squared laboratory velocity is directly related to the average internal energy of coincident CN fragments. The wings of the Doppler profiles indicate that the available energy for a pair of ground state CN photoproducts following 193 nm dissociation of NCCN at 295 K is 5300±150 cm−1, which includes the average vibrational energy of the parent molecules selected by the photolysis laser. Phase space theory with an optimized available energy of 5300 cm−1 produces laboratory speed distributions that are in qualitatively reasonable agreement with the kinetic energy measurements, but overestimate the total internal energy of the photofragments. The measurements are good enough to warrant comparison with more sophisticated models of unimolecular decomposition. 相似文献
4.
A theory of direct collinear photodissociation is presented wherein the correct and different normal modes appropriate to the initial molecular state and the photofragments are employed. This remedies a serious deficiency in previous theories which assume that the reaction coordinates for the photodissociation is also a normal mode in the initial electronic state and that the remaining normal modes are the same for both. The theory provides an analytical expression for the vibrational energy distribution of the photofragments, and provides simple criteria for the occurrence of population inversions. Calculated vibrational distributions for HCN photodissociation are in agreement with experiment. 相似文献
5.
Rakitzis TP 《The Journal of chemical physics》2010,133(20):204301
We extend the a(q) (k)(s) polarization parameter model [T. P. Rakitzis and A. J. Alexander, J. Chem. Phys. 132, 224310 (2010)] to describe the components of the product angular momentum polarization that arise from the one-photon photodissociation of asymmetric top molecules with circularly polarized photolysis light, and provide a general equation for fitting experimental signals. We show that the only polarization parameters that depend on the helicity of the circularly polarized photolysis light are the A(0) (k) and Re[A(1) (k)] (with odd k) and the Im[A(1) (k)] (with even k); in addition, for the unique recoil destination (URD) approximation [for which the photofragment recoil v arises from a unique parent molecule geometry], we show that these parameters arise only as a result the interference between at least two dissociative electronic states. Furthermore, we show that in the breakdown of the URD approximation (for which the photofragment recoil v arises from a distribution of parent molecule geometries), these parameters can also arise for dissociation via a single dissociative electronic state. In both cases, the A(0) (k) and Re[A(1) (k)] parameters (with odd k) are proportional to cosΔφ, and the Im[A(1) (k)] parameters (with even k) are proportional to sinΔφ, where Δφ is the phase shift (or average phase shift) between the interfering paths so that Δφ can be determined directly from the A(q) (k), or from ratios of these A(q) (k) parameters. Therefore, the determination of these A(q) (k) parameters with circularly polarized photolysis light allows the unambiguous measurement of coherent effects in polyatomic-molecule photodissociation. 相似文献
6.
We present the quantum mechanical expressions for the angular momentum distribution of the photofragments produced in slow predissociation. The paper is based on our recent theoretical treatment [J. Chem. Phys. 123, 034307 (2005)] of the recoil angle dependence of the photofragment multipole moments which explicitly treat the role of molecular axis rotation on the electronic angular momentum polarization of the fragments. The electronic wave function of the molecule was used in the adiabatic body frame representation. The rigorous expressions for the fragment state multipoles which have been explicitly derived from the scattering wave function formalism have been used for the case of slow predissociation where a molecule lives in the excited quasibound state much longer than a rotation period. Possible radial nonadiabatic interactions were taken into consideration. The optical excitation of a single rotational branch and the broadband incoherent excitation of all possible rotational branches have been analyzed in detail. The angular momentum polarization of the photofragments has been treated in the high-J limit. The polarization of the photofragment angular momenta predicted by the theory depends on photodissociation mechanism and can in many cases be significant. 相似文献
7.
We present the quantum-mechanical expressions for the recoil angle dependence of the photofragment multipole moments which explicitly treat the role of molecular axis rotation on the electronic angular momentum polarization of the fragments. The paper generalizes the result of Siebbeles et al. [J. Chem. Phys. 100, 3610 (1994)] to the case of dissociation of rotating molecules. The electronic wave function of the molecule was used in the adiabatic body-frame representation. The obtained rigorous expressions for the fragment state multipoles have been explicitly derived from the scattering wave-function formalism and then simplified using the quasiclassical approximation in the high-J limit. Possible radial and Coriolis nonadiabatic interactions have been taken into consideration. It is shown that the rotation of the molecular axis is described by a number of rotation factors which depend on the rank of the incident-photon polarization matrix, on the dissociation mechanism, and on the classical angle of rotation of the molecular axis gamma. 相似文献
8.
9.
Shapiro M 《The journal of physical chemistry. A》2006,110(27):8580-8584
We explore the EPR experiment in the case of the breakup of a polyatomic molecule into two mutually entangled fragments. We give a derivation based on the properties of the dissociated wave function that no information is transferred, not even at a speed smaller than the speed of light, from one entangled partner to the other concerning its measurement or lack thereof. We also explain experiments that show that each separated fragment can retain coherences induced in its parent molecule by a broad band laser pulse, regardless of whether a measurement has been performed on its entangled partner. 相似文献
10.
11.
Clark AP Brouard M Quadrini F Vallance C 《Physical chemistry chemical physics : PCCP》2006,8(48):5591-5610
The angular momentum polarization of atomic photofragments provides a detailed insight into the dynamics of the photodissociation process. In this article, the origins of electronic angular momentum polarization are introduced and experimental and theoretical methods for the measurement or calculation of atomic orientation and alignment parameters described. Many diatomic photodissociation systems are surveyed, in order to provide an overview both of the historical development of the field and of the most state-of-the-art contemporary studies. 相似文献
12.
13.
We introduce a method for classical trajectory calculations to simulate collisions between atoms and large rigid asymmetric-top molecules. We investigate the formation of molecule-helium complexes in buffer-gas cooling experiments at a temperature of 6.5 K for molecules as large as naphthalene. Our calculations show that the mean lifetime of the naphthalene-helium quasi-bound collision complex is not long enough for the formation of stable clusters under the experimental conditions. Our results suggest that it may be possible to improve the efficiency of the production of cold molecules in buffer-gas cooling experiments by increasing the density of helium. In addition, we find that the shape of molecules is important for the collision dynamics when the vibrational motion of molecules is frozen. For some molecules, it is even more crucial than the number of accessible degrees of freedom. This indicates that by selecting molecules with suitable shape for buffer-gas cooling, it may be possible to cool molecules with a very large number of degrees of freedom. 相似文献
14.
D.C. Clary 《Chemical physics》1979,41(3):387-394
A direct method is proposed for determining polyatomic potential energy functions, expressed in terms of normal coordinates, which yield a given set of vibrational excitation energies. The method is a modification of the semiclassical technique for computing vibrational energy levels of Percival and Pomphrey. The technique is used to derive potential functions for the NO2, SO2 and ClO2 molecules. With these potentials twenty two higher vibrational excitations energies have been predicted for these molecules and these results differ from the experimental values by at most 3 cm?1. The computed potential functions are not unique despite the apparent accuracy of the vibrational energy levels. Comparison with the RKR method indicates that the present method must be extended to include rotational perturbations. 相似文献
15.
E. E. Nikitin 《Theoretical and Experimental Chemistry》1971,4(3):197-199
A model of a harmonic oscillator with friction is used to discuss the conversion of translational energy to vibrational by collision of an atom with a polyatomic molecule. It is shown that adiabatic conversion implies that E
2 may substantially exceed the value calculated, neglecting the interaction of the bond with the rest of the molecule. 相似文献
16.
Indirect dissociative recombination of low-energy electrons and molecular ions often occurs through capture into vibrationally excited Rydberg states. Properties of vibrational autoionization, the inverse of this capture mechanism, are used to develop some general ideas about the indirect recombination process, and these ideas are illustrated by examples from the literature. In particular, the Δv = -1 propensity rule for vibrational autoionization, i.e., that vibrational autoionization occurs by the minimum energetically allowed change in vibrational quantum numbers, leads to the prediction of thresholds in the dissociative recombination cross sections and rates at the corresponding vibrational thresholds. Capture into rotationally excited Rydberg states is also discussed in terms of recent low-temperature studies of the dissociative recombination of H(3)(+). 相似文献
17.
V. G. Plotnikov 《International journal of quantum chemistry》1979,16(3):527-541
The processes of radiationless conversion in aromatic and heteroaromatic molecules are investigated theoretically. The values of constant rates of internal conversion are calculated. The theoretical estimation of constant rates of S–T conversion aromatic hydrocarbon molecules and in their carbonyl-, thiocarbonyl-, and nitroderivatives and in azaheterocyclic molecules are given. The S-T conversion probability between the states of different orbital nature (nπ* and ππ*) is equal to ca. 1010–1011 sec?1 that is two to four orders higher than the conversion probability between the states of the same orbital nature. It is shown that the process of T-S conversion may be described in the second and in the highest orders of perturbation theory. The luminescent characteristics of molecules are connected with the relative position of electron states of different orbital nature and multiplicity and conversion characteristics. 相似文献
18.
CH-stretching modes were first excited by picosecond infrared pulses and the generated excess population was monitored by anti-Stokes scattering of subsequent ultrashort probe pulses. Experimental data are reported on five molecules: CHCl3, CH2Cl2, CH3CCl3, CH3CH2OH, and CH3I in the neat liquid and/or in solutions of CCl4. The observed time constants vary between 1 and 100 ps depending upon the individual molecule and surrounding. Theoretical calculations show that rotational coupling, Fermi resonance, Coriolis coupling, and resonance energy transfer can strongly effect the vibrational population lifetime. The relevance of these processes is quite different for the various molecules investigated. 相似文献
19.
G. K. Ivanov G. V. Golubkov 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1986,1(2):199-206
The photodissociation (PD) of the moleculeXY near the ionisation threshold is considered within the framework of the multichannel quantum defect theory. The general analytical dependence, determining the relation between the PD amplitude, the adiabatic amplitudes of dipole transitions and elements of the collisions matrix describing the associative ionisation (X+Y→e ?+XY +) and resonance scattering of atoms (X+Y→X′+Y′), has been obtained. The collisions matrix is determined by the system of algebraic equations and is expressed via the parameters which can be reconstructed from the molecule terms adiabatic picture. The obtained expressions can be used in case of a random number of Rydberg and dissociative channels. The role of the resonance mechanism of the molecules intermediate predissociative and autoionisational states population has been investigated. The peculiarities of the PD spectra structure for different physical situations have been studied. It has been shown that the Rydberg continuum states population increases the process general efficiency (the PD cross-section averaged over resonances increases). The NO molecule near-threshold PD, proceeding through thenpπ Rydberg states is calculated. 相似文献
20.
《Chemical physics》1986,104(1):41-48
Supersonic free jets and beams have been characterized in terms of the terminal Mach number, velocity spread, translational temperature and the average value of specific heat ratio (γ) pertinent to supersonic expansion. It has been found that for a polyatomic molecule, the average value of γ, used to describe the flow, depends upon the stagnation conditions. Vibrational relaxation of SF6 as a representative of polyatomic molecules has been investigated using the “sudden freeze” model of Knuth and the relaxation rate equation model of Quah. Though the “sudden freeze” model predicts the experimental terminal vibrational temperature of Luijks et al., it overestimates cooling close to the nozzle exit. Quah's model shows that the vibrational relaxation cross section (σv) increases with decrease in temperature, contrary to the prediction of the Landau—Teller relaxation mechanism. This has been attributed to enhanced efficiency of vibrational relaxation at lower temperature due to facile exchange of internal energy with translational energy through the formation of quasi-resonant and van der Waals complexes. 相似文献