Assignments of laser lines in optically pumped CH3CN

A careful analysis of the rotovibrational spectroscopic data of CH₃CN is presented taking into account Fermi and Coriolis interactions. A large majority of the FIR lines obtained by optical pumping is assigned. New values are proposed for some molecular constants and the need of more accurate experimental investigation is pointed out.     

Diffusion and vibrational bottleneck in optically pumped submillimetre lasers

By observing the time dependence of the onset of the submm laser power in the millisecond time scale, just after the switching on of the pump laser, the vibrational bottleneck due to diffusion and vibrational relaxation has been clearly exhibited in CH₃F, D₂CO and HCOOH submm lasers. Experimental results are compared with those deduced from a simplified rate equation model. Both show a diffusion limited regime and a collisional regime.     

Similarity in growth of output power of cw far infrared lasers

By means of intracavity Stark-pulse technique, growth of output power of an optically pumped cw CH₃OH 119-m laser has been observed for various pressures of the active medium and for various input optical powers. Comparison of the results obtained in this work with those of a previous report on a HCOOH laser suggests that there is similarity relation in growth of output power. The similarity relation in a two-level laser is discussed.     

Mid infrared and far infrared studies of the propyne optically pumped laser

An extensive study of the propyne optically pumped laser is presented. 32 new far infrared and 8 new mid infrared outputs are reported, together with pump frequency offset data. Complete assignments of some far infrared transitions and partial assignments of the mid infrared outputs are given. Very strong interactions occur between the mid and far infrared laser transitions. These interactions are of vital importance in obtaining high output energies.     

FIR Stark spectroscopy on optically pumped CH3OH laser

An extensive theoretical and experimental analysis of the absorption and emission spectrum of a CH₃OH FIR-laser excited by a conventional CO₂ laser is presented. Particular interest is devoted to the Stark shifts of the pump and lasing lines and to the electric field dependence of the Fir-laser output of the various lines. The offsets with respect to the exciting radiation and the Stark shifts of the IR absorption (pump) lines are measured by means of the transferred Lamb dip technique. The theoretical behaviours of the Stark patterns are calculated for several choices of the quantum numbers and selection rules involved in the transitions. A large variety of experimental results are reported and compared to theory. Non-linear Stark shifts have been observed for the 37.5m FIR laser line and for the IR-pump transitions excited by the 9-P(38) and 10-R(38) CO₂ laser Lines. Line assignments are proposed and new FIR laser lines are reported.     

Pulsed optically pumped far infrared laser and maser action in OCS

Twenty new optically pumped far-infrared laser transitions have been observed in OCS, including four “maser” transitions of 3.6–8.2 mm wavelength. The operating conditions and assignments of these lines are reported. Rabi splitting of the FIR gain profile caused by the high intensity of the CO₂ TEA laser pump is found to be very important for some lines.     

New CW FIR laser lines obtained in ammonia pumped by a CO2 laser, using the Stark tuning method

We report fifty seven CW FIR emissions observed in NH₃, by resonant pumping with a CO₂ laser. Exact coincidences between IR absorption lines of the gas and emission lines of the CO₂ laser have been carried out by Stark tuning. IR frequency shifts, up to 30 GHz, have allowed the pumping of forty three NH₃ transitions.These FIR emissions correspond to thirty one different wavelengths in the 50–400 m range; eighteen ones of them are new emitted wavelengths by pumping with the CO₂ laser.     

Electric field effects on an optically-pumped HCOOH FIR laser and Zeeman laser theory

Electric field effects have been investigated on the output power of six far-infrared (FIR) laser lines from H¹²COOH optically-pumped by a CO₂ laser with its polarization arranged perpendicular to the Stark field. Optoacoustic signals observed on the pump lines were hardly affected by the applied electric field up to 0.6 kV/cm. By neglecting the electric field effects on the pump transitions, Zeeman laser theory has been applied to the FIR laser transitions. Numerical calculation predicts the observed FIR output power as a function of electric field. Experessions for oscillation frequency and intensity in homogeneous limit are given, which may be applicable to any FIR Stark laser so far as the pump transition is free from electric field effects.     

New far infrared laser lines in optically pumped CD3F

Summary Using a high pressure CO₂-laser we have studied laser action in¹²CD₃F stimulated by R-branch pumping. We used an arrangement with low-feedback mirrors as suitable for Raman laser action. However, no Raman laser action has been observed in¹²CD₃F though similar experimental conditions were met as for¹²CH₃F and¹³CH₃F. The reason for the different behavior of the gases is not yet clear.Instead of Raman laser action we found 15 FIR resonant laser lines with 13 of them unknown up to now in the frequency range from 50 cm^–1 to 68 cm^–1. We reached FIR pulse energies up to 900 J, corresponding to a photon conversion efficiency of 12%. For our arrangement the optimum operation pressure varied from 40 torr at low J values (J=36) to 70 torr at high J values (J=49).     

Assignment of laser lines in an optically pumped submillimeter and near millimeter laser: (H2CO)3

A large number of emissions is obtained in the submillimeter and near millimeter range with the (H₂CO)₃ laser optically pumped by a CO₂ laser. A study of the microwave absorption spectrum of the molecule carried out simultaneously with the submm analysis allows us to assign six of the laser lines in thev ₅ excited state of the molecule and to determine the rotational constants and vibrational energy ofv ₅.     

铯Rydberg原子Stark态的避免交叉

在磁光阱中利用双光子激发制备49S铯Rydberg原子,研究了超冷49S态原子在外加电场中的Stark效应和nS态原子与(n-4)多重态之间的避免交叉现象.利用态选择脉冲场电离方法测量并获得了避免交叉点附近的离子谱,测量了避免交叉点附近离子谱的变化情况,并观察到避免交叉点附近由相互作用导致的态转移现象.     

Investigation of privatization by level crossing approach

Privatization — a political as well as an economic policy — is generally defined as the transfer of a property or the responsibility for it from the public to the private sector. But privatization is not merely the transfer of the ownership and efficiency of the market should be considered. A successful privatization program induces better profitability and efficiency, higher output, more investment, etc. The main method of privatization is through introducing new stocks to the market to motivate competition. However, for a successful privatization the capability of a market for absorbing the new stock should also be considered. Without paying attention to this aspect, privatization through the introduction of new stocks may lead to reduced market efficiency. We study, based on the complexity theory and in particular the concept of Level Crossing, the effect of the stages of the development, activity, risk, and the waiting times for special events on the privatization.     

Frequency measurements of far infrared cw lasing lines in optically pumped CHCl2F

The wavelengths, frequencies, and relative polarizations of 15 FIR cw lasing lines obtained by optically pumping CHCl₂F with a cw CO₂ laser have been measured. The lines are in the wavelength range from 340.3 to 905.4 m and were pumped by P- and R-branch laser lines in the 9 m band of CO₂.Supported in part by a joint grant with the U. S. National Science Foundation grant # INT80-19014 and the Brazilian Consellio Nacional de Pesquisas (CNPq)Contribution of the U. S. Government, not subject to copyright.     

A review of optically pumped far-infrared laser lines from methanol isotopes

The technique of optical pumping in polar molecules is the most efficient for Far-Infrared (FIR) laser generation, providing also a versatile and powerful tool for molecular spectroscopy in this spectral region. Methanol (CH₃OH) and its isotopic varieties are the best media for optically pumped FIR laser, with over thousand lines observed, and the most widely used for investigations and applications. In this sense, it is important organize and make available catalogues of FIR laser lines as complete as possible. Since the last critical reviews of 1984 [1] on methanol and its isotopic varieties [2,3,4], over hundred papers have been published dealing with hundreds of new FIR laser lines. In 1992 a review of FIR laser lines from CH₃OH was presented [5]. In this communication we extend this work to the other methanol isotopes, namely CH₃OD, CD₃OH, CD₃OD,¹³CH₃OH,¹³CD₃OH,¹³CD₃OD, CH₃ ¹⁸OH, CH₂DOH, CHD₂OH and CH₂DOD.Work supported by FAPESP, CNPq, FAEP-Brasil, and CNR-Italia     

Study of the saturation effect and output power of optically pumped FIR laser

In this paper, the density matrix equation of a six-level system has been solved, in case of the FIR wave signals in the system were not small enough to be neglected. The output power density of the laser system has been calculated by means of the iteration method. The saturation effect of the system has been revenled by the numerical calculation. Several sets of curves of laser output power vs, the length of laser with defferent pumping detuning and the optimum operating pressure under certain condition have been obtained. These calculated values were in good agresment with the data provided in the literatures.     

Gain of a CW optically pumped far-infrared laser with sandwich resonator

The FIR laser gain of CW optically pumped HCOOH was measured and compared to theoretical calculations. Since the laser has a transversely pumped parallel-plate (or sandwich) waveguide, the pump field is the same for oscillating and amplifying operation. Therefore, true FIR-gains were measured. The theory takes into account several phenomena, that are frequently simplified when considering FIR lasers, such as the pump and the FIR beam's spatial distribution, power broadening of the pump absorption, as well as heat and molecular diffusion. As a result, good quantitative agreement between theory and measurement was achieved.     

Theoretical study of multi-mode optically pumped NH3 FIR laser

The two or multi-mode optically pumped NH₃ FIR laser had been studied theoretically. The NH₃ molecular gas was assumed to be a three-level system and obeyed the time-dependent behavior of the density matrix equations. Considering the situation of playing the two or multi-mode optical pumping and the FIR laser field were same polarized. The gain coefficient and the output FIR power of the system could be calculated by using the iteration method.It had been predicted that the two or multiple longitudinal mode optically pumped NH₃ FIR laser could have a greater output power or higher lasing efficiency than single mode pumped FIR laser under suitable selected operating parameters of laser.Supported by The Education Foundation of PRC.     

Infrared spectrum involving forbidden transitions & coriolis interaction and identification of optically pumped far infrared laser lines in asymmetrically mono-deuterated methanol (Methanol-D1)

In this paper new type of ΔK = 2 and 0 transitions have been identified in the Fourier Transform spectrum of Methanol-D₁ (CH₂DOH). These transitions are normally forbidden but a “Coriolis” type interaction with nearby states is believed to be contributing sufficient transition strength through intensity borrowing effect. This is the first time such forbidden transitions are reported to be identified in the excited states, in this molecule. The present conjecture is supported by observation of a many strong allowed transitions to upper terminating levels which are seen to be highly perturbed. This conclusion has been reached by comparing calculated energy levels using known molecular parameters (Pearson et al., 2012; Coudert et al., 2014; El Hilali et al., 2011; Quade et al., 1998; Richard Quade, 1998, 1999; Mukhopadhyay, 1997) and the actually observed FIR lines. The upper levels are seen to be upshifted from expected position. A closer look at the calculated energy values seems to indicate a possible interaction between the above states and other proximate torsional–rotational states could occur. The possible candidates for the interacting level manifolds are narrowed down through the presence of the forbidden transition. We also take the opportunity to propose alternate rotational quantum numbers for some of the assignments recently reported in the literature (El Hilali et al., 2011). Some ambiguities are pointed out on the data and the reported analysis. There remain too many such irregularities and we propose to gather a large body assigned transitions in a future catalog. Assignments and relevant comments on optically pumped FIR laser radiation are also made.     

Applications of high resolution spectroscopy to the identification of far-infrared laser emission from optically pumped13CH3OH

High-resolution infrared (IR) and far infrared (FIR) Fourier transform absorption spectra have been employed to investigate assignments of FIR laser lines reported from optically-pumped¹³CH₃OH. The spectroscopic measurements are used in conjunction with the reported IR pump and FIR laser frequencies to form closed combination loops for several systems, serving to confirm the assignments and in some cases to improve the accuracy of the FIR laser frequencies. Frequency predictions from combination differences are also presented for a number of potential new FIR laser lines.     

Theoretical study of miniature optically pumped cavity NH3 Far-infrared laser

Miniature optically pumped cavity NH3 Far-infrared laser was studied theoretically, with the length of the FIRL cavity as short as 1.5cm, the dependences of FIRL output power and laser lineshape on operating gas pressure and output coupling condition, and on the effect of laser line saturation broadening were calculated.Supported by the National Natural Science Foundation of China.