Resonant absorption in LiNdP4O12 lasers

The resonant loss in LiNdP₄O₁₂ (LNP) lasers has been investigated. The effective resonant loss coefficient for the 1.047(7) μm laser emission was measured to be 0.042 cm^-1. This value can be explained by resonant absorption due to the ⁴I_{1$\text{1}\text{2}$}→⁴F_{$\text{3}\text{2}$} transition including the reabsorption effect of the fluorescence resulting from the ⁴I_{$\text{9}\text{2}$}→⁴F_{$\text{3}\text{2}$} transition.     

Thermoelectric power of (Me4N)2Ag13I15 and (Et4N)2Ag13I15

Thermoelectric power using reversible silver electrodes and electrical conductivity on the compressed pellets of (Me₄N)₂Ag₁₃I₁₅, and (Et₄N)₂Ag₁₃I₁₅ have been measured between room temperature and below 160°C. The results of θ can be expressed by the equations:?θ = 0.115 (10³/T)+0.2905VK^?1 and ?θ = 0.150 (10³/T) + 0.305mV K^?1; and those of conductivity by the equations; σ = 28.7 exp (?0.17eV/kT) ohm^?1cm^?1 and $\text{σ = 216.6 exp (?0.24e}\text{V}\text{kT}\text{)}$ ohm^?1cm^?1; respectively for Me- and Et-electrolytes. The results are discussed and compared with those of previous authors.     

Lifetimes and Franck-Condon factors for the B1Πu → X1Σg+ system of Na2

Lifetimes of 24 different levels (v′, J′) in the B¹Π_u state of Na₂ have been measured with an accuracy of about 1% using a modelocked Ar⁺ laser and a modified delayed coincidence single-photon counting technique. With these lifetimes, the variation of the transition moment R(r) with internuclear distance r has been determined. The necessary Franck-Condon factors and r centroids have been calculated from spectroscopic data obtained by previous interferometric measurements of laser-induced fluorescence. The squared transition moment |R(r)|² increases between $\text{r = 2.5}\text{A}\text{?}$ and $\text{r = 6}\text{A}\text{?}$ by about 30%. Our measurements confirm the results of M. M. Hessel, E. W. Smith, and R. E. Drullinger, who used intensity measurements of Na₂ fluorescence lines for the determination of R(r).     

Laser time-resolved selective excitation of Nd3+ ions in KNdP4O12 crystals

The emission spectra of Nd³⁺ ions in KNd_xRE_1?xP₄O₁₂ (RE = Y, La and Pr) and KNd_xCr_1?xP₄O₁₂ crystals were investigated. Under selective excitation into ²G$\text{7}\text{2}$ + ⁴G$\text{5}\text{2}$ multiples at 1.6 K the fluorescence of Nd³⁺ ions in non-equivalent crystal sites was observed. The excitation spectrum of the ${}^4\text{F}\text{3}\text{2}$ fluorescence had a complex satellite structure. Time resolved measurements showed the dependence of the fluorescence decay on the excitation wavelength. Selective excitation into the satellite lines at the wings of the main transition led to strongly non-exponential decay. The low temperature results indicated that there is no spectral energy transfer between ions in different types of sites.     

Absorption spectra of Ni2+ in (NH4)2Mg(SO4)2·6H2O and Co2+ in Na2Zn(SO4)2·4H2O

Optical absorption spectra of Ni²⁺ in (NH₄)₂Mg(SO₄)₂·6H₂O and Co²⁺ in Na₂Zn(SO₄)₂·4H₂O single crystals have been studied at room and liquid nitrogen temperatures. From the nature and position of the observed bands, a successful interpretation could be made assuming octahedral symmetry for both the ions in the crystals. The splitting observed for ${}^3\text{T}{}_{\mathrm{1g}}\text{(F)}$ band in Ni²⁺ and ${}^4\text{T}{}_{\mathrm{2g}}\text{(F)}$ band in Co²⁺ at liquid nitrogen temperature have been explained as due to spin-orbit interaction. The extra band observed at 16,325 cm^-1 in the case of Ni²⁺ at low temperature has been interpreted to be the superposition of vibrational mode of SO^2-₄ radical on ${}^3\text{T}{}_{\mathrm{1g}}\text{(F)}$ band. The observed band positions in both the crystals have been fitted with four parameters B, C, Dq and ζ.     

Magnetic field dependent optical dephasing in LaF3:Er3+

Optical dephasing of the 5388 Å transition between the lowest Kramers doublets of the ⁴S_{$\text{3}\text{2}$} and ⁴I_{$\text{15}\text{2}$} multiplets of Er³⁺:LaF₃ has been studied by photon echo, optical phase switching and optical free induction decay. Er³⁺?¹⁹F hyperfine interactions produce dephasing which is two orders of magnitude faster than in previously studied non-Kramers systems, but at high field changes in the spin dynamics result in microsecond dephasing. For the lower Zeeman component of ⁴S_{$\text{3}\text{2}$}, T₂ (=6μs) is independent of H₀ whereas for the upper component the dephasing is rapid and strongly field dependent. This is quantitatively accounted for by spin lattice relaxation of the upper component of ⁴S_{$\text{3}\text{2}$}. Below 20 kG concentration and temperature dependent dephasing due to electron spin diffusion is observed.     

Simultaneous cw laser oscillation on transitions of Cd+ and I+ in a hollow-cathode He-CdI2 discharge

Continuous-wave laser oscillation has been obtained on four transitions of Cd⁺ and eleven transitions of I⁺ using a hollow-cathode He-CdI₂ discharge as active medium. Laser output characteristics are similar for both Cd⁺ and I⁺ transitions, and simultaneous cw oscillation has been achieved at wavelengths ranging from blue (4416 Å Cd⁺) through green $\text{(}\text{5337}\text{5378}$ Å Cd⁺, 5407 Å I⁺), yellow $\text{(}\text{5678}\text{5761}$ Å I⁺) and orange (6127 Å I⁺) to red (6585 Å I⁺).     

Lifetime measurements of the metastable 1s2s2p 4P52 state in the lithium-like N,O and Ne

Lifetimes of the metastable three electron 1s2s2p ⁴P_{$\text{5}\text{2}$} state have been studied with a time-of-flight beam-foil technique. The lifetimes were measured to be 53.5 ± 13, 20.0 ± 3 and 10.4 ± 1.5 nsec for nitrogen, oxygen and neon respectively. Lifetimes and energies of this state are in excellent agreement with theoretical values.     

Environmental effects on the 2E → 4A2 luminescence of a series of Cr(III)-oxalate complexes

The phosphorescence of the Cr(ox)^3-₃ ion has been studied in 13 crystal lattices. Excited state splittings, lifetimes and phosphorence quantum yields are reported for the various lattices and as a function of Cr(III) concentration. The differences in photophysical properties are shown to arise almost exclusively from radiationless deactivation of the ${}^2\text{E}$ state.     

High-resolution laser spectroscopy of the Swan system (d3Πg-a3Πu) of C2 in an organic halide-alkali metal flame

The 0–1 band of the Swan system (d³Π_g-a³Π_u) of C₂ has been recorded by laser-induced fluorescence of C₂ formed by reaction between Na and C₂Cl₄. Most of the spectrum was recorded at Doppler-limited resolution, but overlapped lines were resolved using sub-Doppler techniques. The Q branches of the $\text{ΔΩ = 0}$ subbands and rotational lines for which $\text{ΔΩ = ±1}$ are observed for the first time. Molecular parameters defined in the effective Hamiltonian of Brown and Merer are obtained for both ³Π states.     

High spin states in 57Co

High spin states of ⁵⁷Co have been studied via prompt γ-ray spectroscopy in the reactions ⁴⁸Ti(¹²C, p2n) and ⁵⁴Fe(α, p) at 26–48 MeV and 12–24 MeV, respectively. The energies and decay modes of these levels were determined from the analysis of γ-ray singles and γ-γ coincidence spectra, excitation functions, angular distributions and correlations. The relevant lifetimes were measured by the Doppler-shift attenuation method. The new levels established in this work are at 4037, 4814 and 5918 keV with the most probable J^π assignment of $\text{15}\text{2}{}^{\mathrm{?}}$, if $\text{17}\text{2}{}^{\mathrm{?}}$ and $\text{19}\text{2}{}^{\mathrm{?}}$, respectively. The previously known level at 2524 keV was assigned to have $\text{J}{}^{\mathrm{\pi }}\text{=}\text{13}\text{2}{}^{\mathrm{?}}$. These together with the known $\text{9}\text{2}{}^{\mathrm{?}}$(1224 keV) and $\text{11}\text{2}{}^{\mathrm{?}}$(1690 keV) levels constitute the yrast states of ⁵⁷Co. The measured lifetimes of the above six levels are (in order of increasing energies) 0.085±0.030, 0.32±0.10, 0.16±0.06, 0.10_?0.07^+0.06, 1.5_?0.5⁴ and 0.17_?0.07^+0.08 ps, respectively. Comparisons with some theoretical calculations are presented.     

Optical study of CaF2 : Er3+

For ⁴S_{$\text{3}\text{2}$} ? ⁴I_{$\text{15}\text{2}$} transition, lines have been assigned according to cubic and tetragonal symmetries in high resolution thermoluminescence and fluorescence spectra of CaF₂ : Er³⁺ (0.1%). Associated vibronic lines are also classified. A qualitative interpretation of the existence of both types of symmetries is discussed.     

Signature-dependent ml and e2 transition probabilities in 155ho and 157ho

¹⁵⁵Ho and ¹⁵⁷Ho have been populated in the reactions ¹⁴¹Pr(¹⁸O,4n) and ¹⁴⁶Nd(¹⁵N, 4n) at 85 and 74 MeV, respectively. In both nuclei bands built on the $\text{7}\text{2}$?[523] configuration were established to spin values considerably above the first backbend. A signature dependence in the excitation energies as well as in the ratio of M1 to E2 transition rates is observed below, but not above, the backbend in both nuclei. In ¹⁵⁷Ho lifetimes were measured with the recoil-distance method. The ΔI = 2; E2 transition probabilities obtained show very little variation with either signature or spin and no irregularity at the backbend. The signature dependence and strong rise in the ratio B(M1)/B(E2) observed at the backbend in ¹⁵⁷Ho therefore must be caused by the B(M1) values. A signature dependence in the B(E2, I → I ?1)/B(E2, I → I ?2) ratios also found in ¹⁵⁷Ho below the backbend is mainly the result of signature dependence in the ΔI = 1 ; E2 transition rates. Qualitatively, most of the features observed can be explained by nonaxial deformations, which change from large negative to slightly positive values of γ at the backbend.     

Collisional quenching of HgBr(B2∑+12)

Rate coefficients for the quenching of HgBr(B²∑⁺_{$\text{1}\text{2}$}) by HgBr₂, H₂, CO₂, CO, O₂, N₂, Xe, and Br₂ are reported. HgBr(B²∑⁺_{$\text{1}\text{2}$}) is formed by the photolysis of HgBr₂ with the output from an ArF laser. The rate coefficients are determined by monitoring the time resolved B²∑⁺_{$\text{1}\text{2}$} → X²∑⁺_{$\text{1}\text{2}$} emission as quenching species are added. Radiative lifetimes at particular emission frequencies are also reported, and quenching mechanisms are discussed.     

Spectral and temperature characteristics of Cs2Na(Er,Yb, Y)Cl6 upconverters

Spectral luminescence characteristics of the Cs₂Na(Er, Yb, Y)Cl₆ type upconverter have been measured in the range 300–650 K. A nearly sixfold decrease of the emission intensity of an upconverter was observed in the green area. This emission corresponds to two luminescence transition of Er³⁺ ions: ${}^2\text{H}{}_{\mathrm{<mtext>11</mtext><mtext>2</mtext>}}\text{→}{}^4\text{I}{}_{\mathrm{<mtext>15</mtext><mtext>2</mtext>}}$ and ${}^4\text{S}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{→}{}^4\text{I}{}_{\mathrm{<mtext>15</mtext><mtext>2</mtext>}}$. A mechanism of the luminescence intensity decrease has been proposed, in which deexcitation of the ${}^4\text{S}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ level to the ${}^4\text{I}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}$ level is caused by a neighbouring Er³⁺ ion being excited to the ${}^4\text{I}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}$ level.     

The Ã1B2-X̃1A1 two-photon fluorescence excitation spectrum of 1,3-difluorobenzene

The $\text{A}\text{?}{}^1\text{B}{}_2\text{-}\text{X}\text{?}{}^1\text{A}{}_1$ system of 1,3-difluorobenzene has been observed using the technique of two-photon fluorescence excitation obtained with a pulsed dye laser. Calibration was achieved by a combination of the neon optogalvanic spectrum and etalon fringes. In circular, compared to linear, polarization the bands divide into two groups, those which are B₂-A₁ and which retain their intensity with circular polarization, and those which are A₁-A₁ and lose about 60% of their intensity under the same conditions. These two kinds of bands also show characteristic rotational contours. All of the A₁-A₁ bands whose assignments are established obtain their intensity through vibronic interaction in which the vibration ν′₂₅ (ν′₁₄ in the Wilson numbering) mixes the $\text{A}\text{?}$ with, presumably, the $\text{X}\text{?}$ state. There is an important Fermi resonance between the 9¹ and 10¹11¹ levels. Parts of the one-photon absorption spectrum have been photographed to identify sequences associated with the 0₀⁰ band for comparison with those observed in the two-photon spectrum, and to search for bands involving odd quanta of b₂ vibrations, including ν′₂₅ (ν′₁₄); none was found.     

The nuclear quadrupole interaction in Pr3+:LaF3 — An optical-RF double resonance measurement of the ground electronic state

The nuclear quadrupole hyperfine splittings of Pr³⁺ in LaF₃ have been measured for the ground electronic state using a RF optical resonance technique. A hamiltonian $\text{H}\text{= P[(I}{}^2{}_{\mathrm{z}}\text{?}\text{1}\text{3}\text{I(I+1) + (η/6)(I}{}^2{}_{\mathrm{+}}\text{?I}$²_-)] was fitted to the data with zP=4.185 ± 0.003 MHzandη = 0.105 ± 0.010. Linewidths of 180 kHz were observed.     

Reexamination of the I2 spectrum near the B(3Π0u+) state dissociation limit

The disagreement of Danyluk and King's (Chem. Phys.25, 343 (1977)) rotational constants for levels lying near the dissociation limit of B-state I₂ with the mechanical behavior predicted by near-dissociation theory is investigated. The discrepancies are shown to be much too large to be explained by either the neglect of centrifugal distortion effects in the original analysis or by rotational or spin-rotation coupling to a nearby repulsive 1_u state. These differences are therefore attributed to experimental error, a conclusion which is confirmed by more recent experimental results. A reanalysis of the best available data for levels near the dissociation limit of B-state I₂ then yields improved values for the B-state dissociation limit $\text{D}$ = 20 043.16 (±0.02) cm^?1 of the vibrational index at dissociation v_$\text{D}$ = 87.32 (±0.04) and of the long-range potential constant $\text{C}{}_5\text{= 2.88 (±0.03) × 10}{}^5\text{cm}{}^{\mathrm{?1}}\text{A}\text{?}{}^5$. This in turn implies a slightly improved ground-state dissociation energy of $\text{D}$₀ = 12 440.18 (±0.02) cm^?1.     

Proton particle states in the region around 13250Sn82

The decay of ¹³³Sn leading to levels in ¹³³₅₁Sb₈₂, which has one proton outside the closed shell, has been observed at the OSIRIS isotope separator on-line facility. The half-life is 1.47±0.04 sec and the $\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$. level is found at an excitation of 963 keV. The decay of $\text{18±1}\text{sec}{}^{135}\text{Te}$ to one-particle and three-particle levels in ^135₅₃I₈₂ has also been studied.     

Er3+/Yb3+共掺碲硼硅酸盐玻璃的光谱性质和热稳定性研究

制备了系列Er³⁺/Yb³⁺共掺碲硼硅酸盐玻璃样品(85-x)TeO₂-15B₂O₃-xSiO₂ (TBS x=0,5,10,15,20 mol%).测试和分析了样品的吸收光谱、荧光光谱、能级寿命、红外透射光谱及差热特性.并通过对Er³⁺离子⁴I_13/2→⁴I_15/2跃迁发射谱线的高斯拟合，设计了一个简单的四能级结构估算了Er³⁺离子⁴I_13/2和⁴I_15/2能级在碲硼硅酸盐中的Stark分裂情况.研究表明SiO₂的引入能有效地改善玻璃的热稳定性和光谱性能，玻璃析晶温度T_x与玻璃转变温度T_g之差(ΔT=T_x-T_g)可达178℃，说明碲硼硅酸盐是一种适合于光纤拉制的玻璃基质材料.比较了不同基质玻璃中Er³⁺离子的荧光半高宽和受激发射截面，结果表明TBS玻璃系统具有较好的带宽性能，是一种优良的宽带光纤放大器候选基质材料. 关键词： 碲硼硅酸盐 热稳定性 高斯拟合 -基')" href="#">OH^-基